Atomic Structure DTS-0
Atomic Structure DTS-0
2. Calculate the number of angular nodes and radial nodes present in 3p orbital.
3. An atom having atomic mass number 13 has 7 neutrons. What is the atomic number of the atom?
8. According to de Broglie, matter should exhibit dual behaviour, which is both particle and wave nature.
However, a cricket ball of mass 100 g does not move like a wave when it is thrown by a bowler at a speed
of 100 km/h. Calculate the wavelength of the ball and explain why it does not show wave nature.
9. Chlorophyll present in green leaves of plants absorbs light at 4.620 × 1014Hz. Calculate the wave length
of radiation in nanometer. Which part of the electromagnetic spectrum does it belong to?
10. Table-tennis ball has a mass 10 g and a speed of 90 m/s. If speed can be measured within an accuracy
of 4% what will be the uncertainty in speed and position?
11. Hydrogen atom has only one electron, so mutual repulsion between electrons is absent. However, in
multi-electron species mutual repulsion between the electrons is significant. How does this affect the
energy of an electron in the orbitals of the same principal quantum number in multi-electron species?
12. The distance between 4th and 3rd Bohr orbits of He is :
13. A hydrogen atom in the ground state is excited by monochromatic radiation of wavelength Å. The
resulting spectrum consists of maximum 15 different lines. What is the value of wavelength ?
( R H 109737 cm 1 )
18. Electrons jump from fourth energy level to finally first energy level in one mole hydrogen atom. How many
maximum possible numbers of photons can be emitted?
19. Arrange the electrons represented by the following sets of quantum numbers in decreasing order of
energy.
(A) n = 4, 0, m = 0, s = +1/2 (B) n = 3, 1, m = 1, s = –1/2
(C) n = 3, 2, m = 0, s = +1/2 (D) n = 3, 0, m = 0, s = –1/2
21. (A) Calculate the total number of electrons present in one mole of methane.
(B) Find (a) the total number and (b) the total mass of neutrons in 7 mg of 14C
(Assume that the mass of neutron = 1.675 × 10–27 kg)
(C) Find (a) the total number and (b) the total mass of protons in 34 mg of NH3 at S.T.P. (Assume the
mass of proton = 1.6726 × 10–27 kg)
22. A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal being 2.13 eV.
Calculate
(A) the energy of the photon (eV) (B) the kinetic energy of the emission and
(C) the velocity of the photoelectron
(1 eV = 1.602 × 10–19 J).
23. A 25 watt bulb emits monochromatic yellow light of wavelength of 0.57 m . Calculate the rate of
emission of quanta per second.
24. How much energy is required to ionise a hydrogen atom if the electron occupies n = 5 orbit? Compare
your answer with the ionisation energy of hydrogen atom (energy required to remove the electron from
n = 1 orbit).
25. Following results were observed when sodium metal is irradiated with different radiations.
Calculate (a) threshold wavelength and (b) Planck’s constant.
λ(nm ) 500 450 400