REVISION WORKSHEET FOR TERM-1

CLASS XII

SESSION 2024-25

Worksheet-1

1. The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic acid (B),
acetic acid (C) and formic acid (D) is
(a ) B > A > D > C (b) B > D > C > A
(c ) A > B > C > D (c ) A > C > B >D
2. Out of the following, the strongest base in aqueous solution is:

( a) dimethylamine ( b ) aniline

(c) methylamine (d) trimethylamine

3. Which of the following compound will not undergo azo coupling reaction with benzene

diazonium chloride?

(a) Phenol (b) Aniline

(c) Nitrobenzene (d) Anisole

4. The unit of ebullioscopic constant is:

(a) K kg mol-1 (b) K-1 kg mol
(c) K kg-1 mol-1 (d) K kg-1 mol
5. Fused NaCl on electrolysis gives .............. on cathode.

(a) Chlroine (b) Sodium

(c) Sodium amalgam (d) Hydrogen

6. Increasing the temperature of an aqueous solution will cause:

(a) decrease in molality (b) decrease in molarity

(c) decrease in mole fraction (d) decrease in % (w/w)

7. The value of KH for Ar(g), CO2 (g),HCHO(g) and CH4 (g) are 40.39, 1.67, 1.83 x 10 -5

and 0.413 respectively. Arrange these gases in increasing order of solubility.

Page 1 of 16
 ( a) Ar < CO2 < CH4 < HCHO ( b ) Ar < CH4 < CO2 < HCHO

(c) HCHO < CH4 < CO2 < Ar (d) HCHO < CO2 < CH4 < Ar

8. Which of the following cannot reduce Fehling’s solution?

(a) Formic acid (b) Acetic acid
(c) Formaldehyde (d) Acetaldehyde

9. The boiling points of alcohols are higher than those of hydrocarbons of comparable masses
due to:

(a) ion-dipole interaction (b) dipole -dipole interaction

(c) hydrogen bonding (d) vander Waals forces

10. Which has highest freezing point:

(a) 1 M Glucose (b) 1 M NaCl

(c) 1 M CaCl 2 (d) 1 M AlF 3

11. The compound obtained by the reaction of nitrous acid on aliphatic primary amine is:

( a) alkyl nitrite ( b ) alcohol

(c) nitroalkane (d) secondary amine

12. In a dry cell, which of the following is the electrolyte?

(a) Potassium hydroxide (b) Sulphuric acid

(c) Ammonium chloride (d) Manganese dioxide

Directions (Q. Nos. 13-16) : Each of the following questions consists of two statements, one is Assertion
and the other is Reason. Give answer :

(a) Both Assertion and Reason are true but Reason is not a correct explanation of Assertion.

(b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.

(c) Assertion is fake but Reason is true.

(d) Assertion is true but Reason is fake.

13. Assertion : Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling

points either greater than both the components or less than both the components.
Page 2 of 16
 Reason : The composition of the vapor phase is same as that of the liquid phase of an
azeotropic mixture.

14. Assertion : DNA has a double strand helix structure.

Reason : The two strands in a DNA molecule are exactly similar.

15. Assertion : Tertiary butylamine can be prepared by the action of NH3 on tert-butylbromide.

Reason : Tertiary butyl bromide being 3° alkyl halide prefers to undergo elimination on

the treatment with a base.

16. Assertion : Phenol is more reactive than benzene towards electrophilic substitution reaction.
Reason: In the case of phenol, the intermediate carbocation is more resonance stabilized.

Worksheet-2

1. Assertion (A): Cu is less reactive than hydrogen.

Reason (R): E°Cu2+/Cu is negative.

Solution: (c) Cu is less reactive than hydrogen because E°u2+ Cu is positive.

2. Assertion (A): Ecell should have a positive value for the cell to function. Reason (R). E cathode —E
anode

3. Assertion (A): Conductivity of all electrolytes decreases on dilution.

Reason (R): On dilution number of ions per unit volume decreases.

Solution:

4. Assertion (A):Molar conductivity for weak electrolytes shows a sharp increase when the electrolytic
solution on dilution of solution.

Reason (R): For weak electrolytes dissociate partially in concentrated solution. On dilution, their degree of
dissociation increases hence their Am increases sharply

Q2. The cell reaction of the galvanic cell.

Q3. How much charge in Faraday is required for the reduction of 1 mol of Ag+ to Ag?

Page 3 of 16
Q4. Conductivity of 2.5 X 10-4M methanoic acid is 5.25 X 10-5 S cm-1 Calculate its molar conductivity
and degree of dissociation.

Given: A°(H+) = 349.5 S cm2 mol-1 and A°(HCOO– ) = 50.5 S cm2

Q5. . Calculate the emf of the following cell at 25 °C:

Zn | Zn2+ (0.001 M) | | H+(0.01 M) | H2(g) (1 bar) | Pt(s)

Q6. . (a) Predict the products of electrolysis in each of the following:

(i) An aqueous solution of AgNO3 with platinum electrode.

(ii) An aqueous solution of H2S04 using platinum electrode.

(b) Estimate the minimum potential differences needed to reduce Al2O3 at 500°C. The Gibbs free energy
change for the decomposition reaction.

Q6. What type of a battery is lead storage battery? Write the anode and cathode reactions and the overall
cell reaction occurring in the operation of a lead storage battery.

Q7. (a) Define molar conductivity of a substance and describe how for weak and strong electrolytes, molar
conductivity changes with concentration of solute. How is such change explained?

(b) A voltaic cell is set up at 25 °C with the following half-cells:

Ag+ (0.001 M) | Ag and Cu+2 (0.10 M) | Cu What would be the voltage of this cell?

(E0cell= O.4V)

17. The vapour pressure of water is 12.3 kPa at 300K; calculate the vapour pressure of 1 molar

solution of a solute in it.

18. Which one of the following pairs of substances undergoes S N 2 substitution reaction faster

and why?

(i) CH 3 CH(Br)CH 3 or CH 3 CH 2 CH 2 Br

(ii)

19. A cell is constructed between copper and silver

Cu(s) ‫ ׀‬Cu2+ (aq) ‫ ׀ ׀‬2 I + (aq) ‫ ׀‬I2 (s)

If the two half-cells are working under standard condition, then calculate the emf of the

cell. E。Cu2+/Cu = + 0.34 V , E。Ag+ /Ag = + 0.80 V

Page 4 of 16
20. Identify compounds (Y) and (Z) in the following reactions and write the related
balanced chemical equation :

Complete and name the following reaction:

(i) RNH 2 + CHCl 3 + 3KOH

(ii) RNH 2 + NaOBr

21. (i) What do you mean by reducing sugars? Giv e on e ex amp le.

(ii) What type of linkage holds together the monomers in DNA?

22. The standard electrode potential for Daniell cell is 1.1V. Calculate the standard Gibbs energy for the
reaction: Zn(s) + Cu2+ (aq) → Zn2+ (aq) + Cu(s)
23. Calculate Ecell for the reaction given below, if E0cell = 3.17V
Mg (s) + 2Ag+(0.0001M) →Mg2+ (0.130M) + 2Ag (s)
24 Write the product(s) in the following reactions:

( iii) C 6 H 5 OH + B r 2 ? + ?

25. 3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K.

Calculate the Van’t Hoff factor and predict the nature of solute (associated or dissociated).
(Given : Molar mass of benzoic acid = 122 g mol-1, Kf for benzene = 4.9 K kg mol-1)

(i) Measurement of osmotic pressure method is preferred for the determination of molar mass
of macromolecules such as proteins and polymers.

(ii) Elevation of boiling point of 1M KCl solution is nearly double than that of 1 M

sugar solution why ?

(iii) On mixing liquid X and liquid Y, the volume of the resulting solution increases. What type of
deviation from Raoult’s law is shown by the resulting solution? What change in temperature
would you observe after mixing liquids X and Y?

26. A solution containing 18 g of non -volatile solute in 200g of water freezes at 272.07
Page 5 of 16
 K. calculate the mo lecular mass of solu te (given Kf = 1.86 K/m)

2 7 . (a) What happens when :

(i) Benzene diazonium chloride is treated with fluoroboric acid.

(ii) Benzylchloride is treated with ammonia followed by the reaction with

Chloromethane.

(b) Arrange the following compounds in a decreasing order of pKb values :

C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NH2

28. How will you convert ethanal to the following compounds?

(i) Butane-1,3 diol

(ii) But-2-enal

(iii) But-2enoicacid

29. A student determined value of i at various concentration of NaCl, KCl, MgSO 4 and K2SO4 . The
values are given in the following table. Table: Values of van’t Hoff factor, i, at Various Concentrations
for NaCl, KCl, MgSO4 and K2SO4

represent i values for incomplete dissociation. Answer the following questions based on above table.

(a) How is van’t Hoff factor related to molality and why?

(b) What is value of i in case of (i) electrolyte (ii) non-electrolyte?

(c) Determine the amount of CaCl2 (i =2.47) dissolved in 2.5 L of water such that its osmotic pressure
is 0.75 atm at 27°C. [ R= 0.082 L atm K-1 mol-1 , Ca=40 u , Cl=35.5 u]

(d) Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K 2SO4 in 2 L solution
at 25°C Assuming it is completely ionised. [ R= 0.082 L atm K-1 mol-1 , K=39 u , S=32u, O=16]

30. An amino acid is a compound that contains both carboxyl group and an amino group. Although,
many types of amino acids are known, the α -amino acids are the most significant in the
biological world because they are the monomers from which proteins are constructed

Page 6 of 16
The internal salt of an amino acid is given the special name Zwitter ion. Note that
a Zwitter ion has no net charge, it contains one positive charge and one negative charge.
Because they exist as Zwitter ions, amino acids have many of the properties associated with
salts. They are crystalline solids with high melting points and are fairly soluble in water
but insoluble in non-polar organic solvents such as ether and hydrocarbon solvents.
According to the above passage, Answer the following questions :

( i ) Amino acids are usually colourless, crystalline solids. They behave like salts rather
than simple amines or carboxylic acids. Why amino acids show such a behaviour?
(ii) Amino acids are essential and non-essential depending upon their need. One of the essential
amino acid is lysine. Can you say why lysine is considered an essential amino acid?

(iii) Here are given some amino acids—lysine, Tyrosine, Glycine, Alamine. One of these

amino acids is not optically active. Which one is that amino acid? Also, provide the reason.

(iv) What is the difference between acidic amino acid and basic amino acid?

OR

( iv ) Wr it e d if f er en t ty p es o f s eco n d ar y s tr u ctu r es o f p r o te in s .

31. (i) The cell in which the following reaction occurs:

2Fe3+ (aq) + 2I − (aq) 一> 2Fe2+ (aq) + I 2 (s)

It has E。Cell = 0.236 Volt at 298K. Calculate the standard Gibbs energy of the cell

reaction. (Given : 1F = 96,500 C mol–1)

(ii) Explain the following with reason :

(a) Chlorine can displace iodine from KI solution but iodine can not displace bromine
from KBr solution.

(b) Following reaction is possible or not.

Hg + H 2 SO 4 一> HgSO 4 + H 2

(c) Mercury cell provides constant current throughout its life. how?

(i) The electrical resistance of a column of 0.05 M NaOH solution of diameter 1 cm and length 50
cm is 5.55 × 103 ohm. Calculate its resistivity, conductivity and molar conductivity.

Page 7 of 16
 (ii) Write the name of the cell which is generally used in inverters. Write the reactions taking place

at the anode and the cathode of this cell.

32. (a)A solution is prepared by dissolving 5 g of non-volatile solute in 95 g of water. It has a vapour
pressure

of 23.375 mm Hg at 25°C. Calculate the molecule mass of the solute, (vapour pressure of pure water
at 25 °C is 23.75 mm Hg).

(b) What type of deviation is shown by a mixture of ethanol and acetone? What type of azeotrope is
formed

by mixing ethanol and acetone?

(c ) Out of two 0.1 molal solutions of glucose and of potassium chloride, which one will have a higher
boiling point and why?

33. (a) Predict the products of the following reactions :

(b) Give simple chemical test to distinguish between the following pairs of compounds :

(i) Butanal and Butan-2-one. (ii) Benzoic acid and Phenol.

OR

An organic compound (A) with molecular formula C 3 H 7 NO on heating with Br 2

and KOH forms a compound (B), compound (B), on heating with CHCl 3 and

alcoholic KOH

produces a foul smelling compound (C) and on reacting with C 6 H 5 SO 2 Cl forms a

compound

(D) which is soluble in alkali. Write the structures of (A), (B), (C) and (D).

1. Calculate the mass percentage of aspirin (C9H8O4) in acetonitrile (CH3CN) when 6.5 g of
C9H8O4 is dissolved in 450 g of CH3CN . Ans. Mass of solution = 1.424%

2. A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in

500g of water. This solution has a boiling point of 100.42C while pure water boils at 100 ͦ C. What
mass of glycerol was dissolved to make the solution? (Kb of water = 0.512 K kg/mol)
Page 8 of 16
3. After removing the outer shell of the two eggs in dil. HCl, one is placed in distilled water
and the other in a saturated solution of NaCl. What will you observe and why?

4. Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid
components are 105.2 kPa and 46.8 kPa, respectively. What will be the vapour pressure of a
mixture of 26.0g of heptane and 35.0 g of octane?

5. A statement of assertion is followed by a statement of reason. Mark the correct

choice from the options given below:

(a) Both assertion and reason are true and reason is the correct explanation of assertion.

(b) Both assertion and reason are true but reason is not the correct explanation of assertion.

(c) Assertion is true but reason is false.

(d) Both assertion and reason are false.

6. Assertion: In an ideal solution, ∆mix H is zero.

Reason : In an ideal solution, A - B interactions are lower than A-A and B-B interactions.

7. Assertion : Osmosis does not take place in two isotonic solutions separated by semi -
permeable membrane.

Reason : Isotonic solutions have same osmotic pressure.

8. Assertion : Lowering of vapour pressure is not dependent on the number of species present
in the solution.

9. Reason : Lowering of vapour pressure and relative lowering of vapour pressure are
colligative properties.

10. 4. Assertion : 1 M solution of KCl has greater osmotic pressure than 1 M solution of
glucose at same temperature.

11. Reason : In solution KCl dissociates to produce more number of particles.

Worksheet-3

1. The value of Henry’s constant KH is:

a) greater for gases with higher solubility

b) greater for gases with lower solubility.

c) constant for all gases.

Page 9 of 16
d) not related to the solubility of gases.

2. Increasing the temperature of an aqueous solution will cause:

a) decrease in molality

b) decrease in molarity

c) decrease in mole fraction

d) decrease in % (w/w)

3. Which has highest freezing point:

(a) 1 M Glucose (b)1 M NaCl

(c) 1 M CaCl2 (d)1 M AlF3

4. A dilute aqueous solution of Na2SO4 is electrolyzed using Pt electrodes. The products at the
anode and cathode are

(a) O2, H2

(b) S2O82-, Na

(c) O2, Na

(d) SO4,H2

5. Saturated solution of KNO3 is used to make salt bridge because

(a) Velocity of K+ ion is greater than that of NO3-

(b) Velocity of K+ ion is lesser than that of NO3-

(c) Velocity of K+ and NO3- ions are equal

(d) KNO3 is highly soluble in water

6. In which of the following molecules carbon atom marked with asterisk (*) is asymmetric?

(i) (a), (b), (c), (d)

(ii) (a), (b), (c)

(iii) (b), (c), (d)

Page 10 of 16
(iv) (a), (c), (d)

7. What is Q in the following reaction?

Alkyl fluorides are synthesized by heating an alkyl chloride/bromide in presence of_

(a) Ca F2 (b) PF3

(c) Hg2F2 (d) NaF

8. Which of the following compounds do not react with NaHSO3 ?

a) HCHO

b) C6H5COCH3

c) CH3COCH3

d) CH3CHO

9. Which of the reactions below can result in ketones?

a) Oxidation of primary alcohols

b) Oxidation of secondary alcohols

c) Dehydrogenation of tertiary alcohols

d) Dehydrogenation of primary alcohols

10. Which of the following compounds is formed when benzyl alcohol is oxidised with

KMnO4?

a. CO2 and H2O

b. Benzoic acid

c. Benzaldehyde

d. Benzophenone

11. Amine that cannot be prepared by Gabriel phthalimide synthesis is -

a) Aniline

b) benzyl amine

c) tertiary-butylamine

d) isobutylamine

Page 11 of 16
12. Which of the following is not a polysaccharide?

a) Cellulose

b) Stachyose

c) Starch

d) Glycogen

ASSERTION REASONING QUESTIONS

In the following questions, a statement of assertion followed by a statement of reason is given.

Choose the correct answer out of the following choice.

(a) Assertion and reason both are correct statements, but the reason is the correct explanation for
assertion.

(b) Assertion and reason both are correct statements but the reason is not a correct explanation for
assertion.

(c) Assertion is a correct statement but the reason is a wrong statement.

(d) Assertion is a wrong statement but the reason is correct

(e) Assertion and reason both are wrong.

13. Assertion (A) :SN2 reaction of an optically active alkyl halide with an aqueous solution of
KOH always gives alcohol with opposite sign of rotation.

Reason(R): SN2 reactions always proceed with inversion of configuration.

14. Assertion(A) : The α-hydrogen atom in carbonyl compounds is more acidic then phenol.

Reason (R): The anion formed after the loss of α-hydrogen atom is resonance stabilised

15. Assertion(A) : Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction.

Reason(R) : Aromatic aldehydes are almost as reactive as formaldehyde.

16. Assertion (A) – The reduction potential of the electrode can be increased by increasing

the concentration of metal cations.

Reason (R ) – E is directly proportional to [Mn+]

OR

Page 12 of 16
 Assertion (A) – E° is an intensive property.

Reason (R ) – E° is constant for a particular electrode at a given temperature

17. On mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of
deviation from Raoult’s law is shown by the resulting solution? What change in temperature would
you observe after mixing liquids X and Y?

18. Equimolal solutions of NaCl and BaCl2 are prepared in water. Freezing point of NaCl is
found to be – 20C, What freezing point do you expect for BaCl2 solution?

OR

(i) What happens when we place the blood cell in water (hypotonic solution)?

(ii) What happens when we place the blood cell in water (hypertonic solution)?

19. Aldehydes are more reactive than Ketones towards nucleophilic additions. give reason?

20. Arrange the following compounds in increasing order of their property as indicated:

(i) F – CH2COOH, O2N – CH2COOH, CH3COOH, HCOOH — acid character

(ii) Acetone, Acetaldehyde, Benzaldehyde, Acetophenone — reactivity towards

addition of HCN

21. How will you distinguish between the following pairs of compounds:

i) Aniline and ethanamine.

ii) Aniline and N-methylaniline

22. Consider the following diagram in which an electrochemical cell is coupled to an electrolytic
cell. (i) What will be the polarity of electrodes ‘A’ and ‘B’ in the electrolytic cell?

(ii) Write the cell notation.

23. Calculate E°eI1 and ArG° for the following reaction at 25 °C:

A2+(aq) + B+(aq) ——–> A5+(aq) + B(s)

[Given E°eI1 =0.592 V, 1F=96500 C mol-1]

SECTION C

24. Predict the products of the following reactions:

Page 13 of 16
25. a) Write the chemical reaction of methylamine with benzyl chloride and write the

IUPAC name of the product obtained.

b) Arrange the following in the increasing order of their pkb values:

C6H5NH2 , NH3 , C2H5NH2 ,(C2H5)2 NH

26. How will you convert the following?

(i) Propan-2-ol to propanone

(ii) Phenol to 2, 4, 6-tribromophenol

27. Calculate E°cell for the following reaction at 25 °C:

A + B2+ (0.001 M) ——–> A2+ (0.0001 M) + B

Given : Ecell = 2.6805 V, 1 F = 96500 C mol-1

28. Complete the following reactions :

(i) CH3CH=C(CH3)2 + HBr -------

(ii) CH3CH2CH2OH + SOCl2 -----------

(iii) CH3CH2Br + Mg ---------

SECTION-D

Case Study Questions

29. Read the passage given below and answer the following questions:

The standard electrode potentials are very important and we can extract a lot of useful information
from them. If the standard electrode potential of an electrode is greater than Zero then it’s reduced
form is more stable compared to hydrogen gas. Similarly, if the standard electrode potential is
negative than hydrogen gas is more stable than the reduced form of the species. It can be seen that
the standard electrode potential for Fluorine is the highest indicating that F2 gas has the maximum
tendency to get reduced to Fluoride ion F- and therefore Fluorine gas is the strongest oxidizing
agent and Fluoride ion is the weakest reducing agent.
Page 14 of 16
(i) Which element can act as the strongest reducing agent?

(ii) How cell potential can be measured?

(iii) Which electrode can work as anode in galvanic cell?

(iv) Find out E°Cell for Zn/Zn2+(0.1M//Cu2+(0.10M)/Cu

[given E°Zn2+/Zn and E°Cu2+/Cu are -0.76 V and +0.34 V respectively]

OR

Write cell reaction for the above galvanic cell and mention cathode and anode.

30. Read the passage given below and answer the following questions:

gases at room temperature. Higher members are liquids or solids. As we have already learnt,
molecules of organic halogen compounds are generally polar. Due to greater polarity as well as
higher molecular mass as compared to the parent hydrocarbon, the inte rmolecular forces of
attraction (dipole-dipole and van der

Waals) are stronger in the halogen derivatives. That is why the boiling points of chlorides,
bromides and iodides are considerably higher than those of the hydrocarbons of comparable
molecular mass. The attractions get stronger as the molecules get bigger in size and have more
electrons.

i)Draw all the possible isomers structure of bromobutane and arrange them in increasing order of
boiling points. (2 marks)

ii)Even though haloalkanes are polar compounds these compounds are least soluble in water.
Why?(1 mark)

iii) How will you distinguish between chloroethane and bromoethane?(1 mark)

31. (a) What is the basic structural difference between starch and cellulose?

(b) Which form of glucose is obtained by crystallization from hot and saturated aqueous

solution at 371K?

(c) What is chemical formula of glyceraldehyde?

(d) What are oligosaccharides?

(e) The molecular formula of a compound is C2(H2O)2? Is it a carbohydrate, explain your answer?

Page 15 of 16
32. (a) Determine the osmotic pressure of a solution prepared by dissolving 2.5 X 10-2 g of
K2SO4 in 2 L of water at 25 °C, assuming that it is completely dissociated. (R = 0.0821 L atm K -1
mol-1, Molar mass of K2SO4= 174 g mol-1).

(b) Henry’s law constant (KH) for the solution of methane in benzene at 298 K is 4.27 X 105
mmHg. Calculate the solubility of methane in benzene at 298 K under 760 mm Hg.

33. Give reasons for the following:

(i) Phenol is more acidic than methanol.

(ii) The C—O—H bond angle in alcohols is slightly less than the tetrahedral angle (109°28 ).

(iii) (CH3)3C—O—CH3 on reaction with HI gives (CH3)3C—I and CH3—OH as the main
products and not (CH3)3C—OH and CH3—I.

OR

Name the reagents used in the following reactions:

(i) Nitration of phenol to 2, 4, 6-trinitrophenol

(ii) Butanal to Butanol .

(iii) Friedel – Crafts acetylation of anisole

(iv) Oxidation of primary alcohol to aldehyde

(V) Nitration of Phenol.

Page 16 of 16