Target DPP Test Contact Number: 9667591930 / 8527521718

1. The ratio of the wavelengths of the last lines 6. From the given equation, certain conclusions
of the Balmer and Lyman series is: are drawn.
2
1. 4:1 E = −2.178 × 10−18 (J) nz 2
2. 27:5
3. 3:1 Choose the incorrect statement:
4. 9:4 The negative sign in the equation implies
that the energy of an electron bound to the
2. The energy of the emitted photon when an 1. nucleus is lower than it would be if the
electron in Be 3+ ion returns from n=2 level to electron were at an infinite distance from
the ground state is the nucleus.
1. 2.616 x 10-17J The larger the value of n, the greater the
2.
orbit radius.
2. 26.16 x 10-17J
The equation can be utilized to calculate the
3. 261.6 x 10-18J
3. change in energy when the electron
4. 2616 x 10-17J transitions between orbits.
For n=1, the electron has a more negative
3. If the size of the first orbit of the hydrogen
energy than it does for n=6. This means that
atom is 5.29 nm, the size of the second orbit of 4.
the electron is more loosely bound in the
He+ is smallest allowed orbit.
1. 2.65 nm
2. 21.16 nm
3. 10.58 nm
7. The wavelength of the spectral line obtained
4. 5.29 nm +2
in the spectrum of Li
4. The ratio of the difference in energy between when the transition takes place between levels
the first and second Bohr orbit of H to that whose sum −6 is 4 and the difference is 2, will be:
between the second and the third Bohr orbit is 1. 11.4 x 10 cm
1. 1/2 2. 1.14 x 10−6 cm
−6
2. 1/3 3. 0.114 x 10 cm
−8
3. 4/9 4. 1.14 x 10 cm
4. 27/5
8. Of the following transitions in hydrogen
5. Which of the following is not correctly atom, the one which gives an absorption line of
matched? lowest frequency is:
1. Energy associated with Bohr's orbit E = 1. n = 1 to n = 2
−2.18×10−18 ×Z 2 2. n = 3 to n = 8
n2 3. n = 2 to n = 1
2. Energy gap between two orbits 4. n = 8 to n = 3
ΔE = −hc Z 2 RH [ n 2 − ]
1 1
1 n2 2
3. Kinectic energy of the ejected electron hv =
hv0 + 1/2mv2
4. Energy of one mole of photons E = N0hv/C

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 Target DPP Test Contact Number: 9667591930 / 8527521718

9. Helium can be singly ionized by losing one 12. Given below are two statements:
electron to become a cation. Which of the The splitting of spectral lines in
following statements is true concerning this Assertion (A): an electric field is called the
helium cation? stark effect.
The line spectrum of this helium cation will Reason (R): It is explained by Bohr's theory.
1. resemble the line spectrum of a hydrogen
atom. In the light of the above statements, choose the
The line spectrum of this helium cation will most appropriate answer from the options
2. resemble the line spectrum of a lithium given below:
cation. Both (A) and (R) are true and (R) is the
1.
The line spectrum of this helium cation will correct explanation of (A).
3.
remain the same as for unionized helium. Both (A) and (R) are true but (R) is not the
2.
The line spectrum of this helium cation will correct explanation of (A).
4. resemble the line spectrum of a hydrogen 3. (A) is true but (R) is false.
ion. 4. (A) is false but (R) is true.

10. Which of the following statements about 13. Assertion: The spectrum of He+ is expected
spectral series is incorrect?
to be similar to that of hydrogen
The lines in the Balmer series correspond to
Reason: He+ is also a one-electron system.
1. electron transitions from energy levels
1. If both assertion and reason are true and the
higher than n-2 energy level
reason is the correct explanation of assertion.
Paschen series appears in the infrared 2. If both assertion and reason are true but the
2.
region reason is not the correct explanation of
The lines of Lyman series appear in the assertion.
3.
visible region 3. If the assertion is true but the reason is false
Transitions from higher energy levels to 5 th 4. If both assertion and reason are false
4. energy level produce the Pfund series which
falls in the infrared region 14. Determine the maximum number of
emission lines produced when an electron in a
hydrogen atom transitions from the n = 6
11. The change in orbit angular momentum energy level to the ground state :
corresponding to an electron transition from 1. 30
4th excited state to the ground state of a 2. 21
hydrogen atom can be given by: 3. 15
h 3h 4. 28
1. 2.
π 2π 15. The wavelength of light emitted when the
h 2h electron in a H atom undergoes the transition
3. 4.
2π π from an energy level with n = 4 to an energy
level with n = 2, is :
1. 586 mm
2. 486 nm
3. 523 nm
4. 416 pm

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 Target DPP Test Contact Number: 9667591930 / 8527521718

16. The wave number for the longest 21. With a ground state energy of –13.6 eV for a
wavelength transition in the Balmer series of hydrogen atom, what would be the energy in
atomic hydrogen would be : the second excited state?
1. 1. 52 × 106 m−1 1. –6.8 eV
6 −1 2. –3.4 eV
2. 3. 14 × 10 (cm)
3. –1.51 eV
3. 15. 2 × 106 m−1 4. –4.53 eV
6 −1
4. 1. 52 × 10 (cm)
22. The wave number for the shortest
17. The energy of an electron in an H - atom is wavelength transition in Balmer series of He+
−18
given by En = (−2.18 × 10 )/n2 J. The ion is:
shortest wavelength of light that can be used to RH
remove an electron completely from n = 2 1. 4RH 2.
2
orbit will be:
3. RH 4. 2RH
1. 3647 Å 2. 5132 Å
3. 3017 Å 4. None of these
23. The ratio of radii of 2nd orbit for He+ ion to
the 2nd orbit of Be3+ ion is
18. Ionization energy of second orbit of Li+2 1. 1: 2
will be: 2. 4: 1
1. 122.4 eV 3. 2: 1
2. 40.8 eV 4. 1: 4
3. 30.6 eV
4. 13.6 eV 24. The ionization energy of the H-atom is 13.6
eV. The ionization energy of Li2+ ions is:
19. The transition in the hydrogen spectrum 1. 54.4 eV
that would have the same wavelength as 2. 122.4 eV
Balmer transition from n = 4 to n = 2 of He+ 3. 13.6 eV
spectrum is : 4. 3.4 eV
1. n1 = 3 to n2 = 4
2. n2 = 3 to n1 = 2 25. The radius of 2nd orbit of He⊕ is r0 . The
3. n2 = 3 to n1 = 1 radius of 4th orbit of Be+3 is xr0 . The value of
4. n2 = 2 to n1 = 1 x is:
1. 4
20. The radius of the second Bohr orbit for 2. 2
hydrogen atom is: 3. 6
–34 4. 8
(Planck's Const. h = 6.6262 × 10 Js; mass of
electron = 9.1091 × 10–31 kg; charge of electron 26.
The ratio of radii of 2nd & 3rd Bohr’s orbit of
e = 1.60210 ×10–19 C; permittivity of vaccum H-atom is:
∈0 = 8.854185 ×10–12 kg–1m–3A2) 1. 2 : 3
1. 0.529 Å 2. 3 : 2
2. 2.12 Å 3. 4 : 9
3. 1.65 Å 4. 9 : 4
4. 7.76 Å

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 Target DPP Test Contact Number: 9667591930 / 8527521718

27. How do the energy gaps between successive

electron energy levels in an atom vary from Fill OMR Sheet*
low to high n values?
1. All energy gaps are the same. *If above link doesn't work, please go to test link
2. The energy gap decreases as n increases. from where you got the pdf and fill OMR from
3. The energy gap increases as n increases. there
4. The energy gap changes unpredictably as n
increases.

28. The frequency of microwaves with

wavelength 4 x 107 nm is 7.5 x 109 s-1. The
wavenumber of the microwave is: CLICK HERE to get
1. 30 m-1
2. 25 m-1 FREE ACCESS for 2
3. 40 m-1
4. 35 m-1
days of ANY
29. If the shortest wavelength in the Lyman
NEETprep course
series of a hydrogen atom is A, then what is the
longest wavelength in the Paschen series of
He+?
5A
1. 9
9A
2. 5
36 A
3. 5
36 A
4. 7

30. The energy of an electron is given by – 2.178

Z2
×10−18 J( ) . The wavelength of light
n2
required to excite an electron in a hydrogen
atom from level n = 1 to n = 2 will be (given, h =
6.62 × 10–34 Js and c = 3.0 × 108 ms–1):
1. 1.214 × 10–7 m
2. 2.816 × 10–10 m
3. 6.500 × 10–17 m
4. 8.500 × 10–13 m

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