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KTG

The document discusses various principles and problems related to the Ideal Gas Laws, including temperature, pressure, and volume relationships of gases, as well as calculations involving mixtures of gases and their properties. It includes multiple-choice questions and scenarios to illustrate these concepts, such as the root mean square speed of gas molecules and the effects of temperature changes. The content is structured in a question-answer format, aimed at testing understanding of gas behavior under different conditions.

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tarun raaz
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25 views13 pages

KTG

The document discusses various principles and problems related to the Ideal Gas Laws, including temperature, pressure, and volume relationships of gases, as well as calculations involving mixtures of gases and their properties. It includes multiple-choice questions and scenarios to illustrate these concepts, such as the root mean square speed of gas molecules and the effects of temperature changes. The content is structured in a question-answer format, aimed at testing understanding of gas behavior under different conditions.

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tarun raaz
Copyright
© © All Rights Reserved
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Ideal Gas Laws a 1, The temperature of a gas having 2.0 198 erat 1.38 atm (Given, k Iolecules per eubie a . 38 * 102 IK) is; 129 Jan, 2024 (Shift-1 (@) SK (6) 200K (6) 00K Gh too 2, TwovesselsAand Bare ofthe same size andae at same teniperature ‘contains Ig of hydrogen and B contains 1g of oxygen, PA and PB are ihe pressures ofthe gases in A and B respectively, then jg a [29 Jan, 2024 (8 @ 6 Hs 4 @ 2 3, PT diagram of an ideal gas having thre different densities p, py f, (in three different cases) is shown in the figure. Which of the following is correc: DL {04 April, 2024 (Sbit-D) PL Pa P lr Ps T (0) p,P, © e, [, Each part of the eylinder contains n moles of an ideal gas at ‘equal temperature 7: Ifthe piston is stationary, its mass, m, will be given by:(R is universal gas constant and g is the acceleration due to gravity) [12 Jan, 2019 (Shift-I)} ar} ar [24h ° al Ts | oe Fl th ] nerf a ner hh © Shri] o ei] 16. In a process, temperature and volume of one mole of an ideal ‘monoatomic gas are varied according tothe relation VT™= K, where is aconstamt. In this process the temperature ofthe gas is increased by AT: The amount of heat absorbed by gas is (Ris gas constant) [11 Jan, 2019 (Shift-1) 1 1 3 2K @ 1 oy) 4, ) Spar en (@ pRar () >KRaT () Sear) “Sar RMS, Average and Most Probable 17. At which temperature the r.m.s. velocity of a hydrogen molecule equal to that of an oxygen molecule at 47°C? 130 Jan, 2024 (Shift) @ WK H-BK |4K 20K ‘A sample contains mixture of helium and oxygen gas. The ratio of root mean square speed of helium andl oxygen in the sample, is 106 April, 2024 (Shite 19. 20. a. 2. 23. 4, 28, 26, aye wo ot w + @) 55 1 4 w temperate 300 KthermsspeedoFonyeen meen tines that of ts average SEE The hg 2 re : 29 Ja willbe (use n=) 90 ara @ 32 (6) 28 wn root mean square velocity of hydrogen molecule a eae aad pec is 2 Kise root mena fof oxygen atthe same condition in Kms is 1 Feb, 2024 4, (@ 20 (05 o 1s @w Iftherms. speed of chlorine molecule is 490 m'12°C he, speed of argon molecules at the same temperature wil te 112 Apr, 2023 iy (a) 751.1 mis (6) 451.7 mvs (C) 651.7 mS (a) S517 The root mean square velocity of molecules of gasis [25 Jan, 203 tiny (a) Proportional 1 square of temperature (7) 24 Ba aE (®) Inversely proportional to square root of temperature (©) Proportional to square root of temperature JF (@ Proportional to temperature (7) ‘The rms speed of oxygen molecule in a vessel at patie | vy, where v is the average sped of temperature is ‘molecule. The value of x will be: (Take 1 7 113 Apr, 2023 (hit (@ 28 (27 os ws ‘The temperature of an ideal gas is increased from 200 K tosl0k Iftms. speed of gas at 200 K is v,. Then, rm. speed ofthe gst 800 K will be: [6 Apr, 2023 (Sti @ », © 4, © % wr 4 ‘The root mean square speed of molecules of nitrogen gs 82°C is approximately: Given mass of a nitrogen molecule ~4.6 « 10 kg and Boltzmann constant k= 14 « 102° JK") [11 Apr, 2028 stil (a) S23 m/s (b) 1260. m/s (c) 91 mis (d) 274 ms Given below are vo statements ee statements I: The temperature of a gas is ~73+C. When the is ented 6527, the fot mean aque speed of 2 is doubted. Statement It: The product of pressure and volume of ani! willbe equal translational kinetic energy ofthe molesUe> Inthe light of the above statements, choose the correct answet the options given below : [24 Jan, 13 (sit () Both statement and Statement tare rue (6) Statement lis true ‘but Statement UI is false (c) Both Statement t and ‘Statement I are false (@) Statement is false ‘but Statement IL is true ra Fa x uM 2, 3B sels ofequal volume contain Sout THe Fist esl contains sen omnes eons chlorine (atom) and had coos ee seaonn ce e i i n Wey sauare speed (V.) and choose the correct answer fom tne ons given blOW 1 Apr, 2023 (Site, ey 700)= M4 (t)= 1 (ply A) Helonono)> V(dia)> ¥~ (poly) fo) Palla) < Vu 019) < ¥tm0n0) tip Flonon0) =, (di) < (ply) ‘ue tltion between root mean square speed (¥,) and most Juble speed (¥,) forthe molar mass fof oxygen gas molecule pe temperature of 300K willbe: [2 June 2022 (Shit) E 5, © v= 45% ) v= fy v= 5% m= 45%, 0) Vou =", Ma fb ‘What willbe the effect on the root mean square velocity of oxygen rolecules if the temperature is doubled and oxygen molecule dissociates into atomic oxygen? [28 June, 2022 (Shift- IN {o) The velocity of atomic oxygen remains same (@) The velocity of atomic oxygen doubles {@) The velocity of atomic oxygen becomes half (a) The velocity of atomic oxygen becomes four mes Same gas is filed in two vessels ofthe same volume atthe same temperature. If the ratio of the number of molecules is 1:4 then [27 July, 2022 Shitt-)] (A) Therm. velocity of gas molecules in two vessels will be the (8) The ratio of pressure in these vessels willbe I:4 {€) The ratio of pressure will be 1:1 (0) The rms. velocity of gas molecules in two vessels will be in the ratio of Lt (@) Aand Conly (6) Band D only (©) Aand B only (@ Cand Donly ‘Theroot mean square speed of smoke particles of mass 5» 10" kg in their Brownian motion in air at NTP is approximately. (Given k = 138 10 Jey {29 July, 2022 (Shift-1D] (2) 60mm st (4) 12mmst (e) 1ISmms* (@) 36mms* (0056kg of Nitrogen is enclose ina vessel ata temperature of 27°C, ‘Theamount of heat required to double the speed ofits molecules is —_keeal (Take R= 2 cal mole ' K:") @ v= {24 June, 2022 (Shift) The rms speed of the molecules of Hydrogen, Oxygen and Carbondioxide at the same temperature are Fy» Vo and Ve ‘espectivey then [26 Aug. 2 (6) My? Vo? Vo (O Myu=¥o Ke Consider a mixture of gas molecule of types 4, B and C having asses. << The rato oftheir oot mean square speeds at ‘ormalemperature and pressures: [20July, 2021 (ShiN-] ey ieee H(Shift-)} wy (Dvn %F8 35. Given below are two statements: 36. a. 38. 39. 40. 41 n 4. iven ‘Statement Ina diatomic molecule, the rotational energy at 5 temperature obeys Maxwell's distribution. ; Statement tf: In distomic molecule, the rotational enerEy 3t tiven temperature equals the translational Kinetic enerey for e2< molecule. em Inthe light ofthe above statements, choose the correct answer theopiom gente [os Fe. 202 (SBD (a) Statement is false but Statement Il is true. (8) Both Statement {and Statement Il are tru. {c) Statement is true but Statement Il is false (4), Both Statement {and Statement I are false IF the ems speed of oxygen molecules at 0°C is 160 mis, find the ims speed of hydrogen molecules at 0°C = [27 Aug, 2021 (Shift-1D)] (a) 332m/s (6) 640m/s. (@) 40ms_— (a) SOs Consider a sample of oxygen behaving like an ideal gas. At 300K, the ratio of root mean square ms) velocity tothe average velocity (of gas molecule would be: (Molecular weight of oxygen is 32 g/mol; R = 8.3 JK" mol") [18 March, 2021 (S! fax is a E @y f=) ce) | @ JF OF OF OG 5 “The root mean square specd of molecules ofa given mass of a gasat 27°C and | atmosphere pressure is 200 ms". The root mean square speed of molecules of the gas at 127°C and 2 atmosphere pressure D1 is ms". The value ofx will be__. 3 [24 Feb, 2021 (Shift-I)] Asystem consists of two types of gas molecules and B having same number density 2 10%. The diameter of and B are 1OA and SA respectively. They suffer collision at room temperature. The ratio of average distance covered by the molecule to that of| B between two successive collision is 10°. {25 July, 2021 (Shift-11)) Ina dilute gas at pressure P and ternperaire 7, the mean time between successive collisions of a molecule varies with Tas {6 Sep, 2020 (Shift @ i wT 1 ws Nitrogen gas is at 300°C temperature. The temperature (in K) ‘at which the rms speed of aH, molecule would be equal to the rms speed of a nitrogen molecule, (Molar mass of N, gas 28 g). 105 Sep, 2020 (Shift-I)) Amixtute of 2 moles of helium gas (atomic mass =4 u),and | mole ‘of argon gas (atomic mass = 40 u) is kept at 300 K in a container. The ratio oftheir ms speeds (% ecie| is close to Fg argon) (9 Jan, 2019 (Shit-1y} 224 area of 7 such squares taking (9 April, 2019 (Shift-tny} (©) 37.03em* Gh 37.030 em? (@ 346 (032) O45 ‘The area of a square i $.29 em’. The into account the significant figures is (a) 37cm (6) 37.0em' 44, Fora given ga at | atm pressure, ms sped of the molecules is 200 ms at 127°C. At atm pressure and at 227°C, the rms speed of the molecules will be: [9 April, 2019 (Shi (2) 80mvs—(H) BOVE mvs) 100m (2) 100v5 ms 45, Themumber density of molecules ofa gas depends on heir dstancer from the originas, n(t)=n,e™". Then the total number of molecules is proporional to: 112 April, 2019 (Shite) nor @ frat? 46. The temperature, at which the rot mean square velocity of hydrogen molecules equals their eseape velocity from the earth is closest to: {[Boltzmans Constant 23 ky = 1.38 » 10 1/ K Avogadtro number N,~ 6.02 * 10, kg Radius of Earth: 6.4 « 10m Gravitation acceleration on Earth = 10 ms] [8 April, 2019 (Shift-tD}] (2) 800k — (1K — (3x1 (dy 650K 47. A115 gmass of nitrogen gas is enclosed ina vessel at temperature 27°C. Amount of heat transfered tothe gas, so that ms velocity oF ‘molecules is doubled, is about: [Take R= 8.3 1K mole] [9 Jan, 2019 (Shift 1D] @ Ks (@) ng (© neo" (©) WK (@) 09KJ— (b) 6KI Energy and Pressure of Gas 48. Given below are two statements: Statement (I): The mean fice path of gas molecules is inversely proportional to square of molecular diameter. Statement (II): Average kinetic energy of gas molecules is directly proportional to absolute temperature of gas. In the light ofthe above statements, choose the correct answer from the option given below: [08 April, 2024 (Shift-LD] (@) Statement Lis false but Statement Il is true (6) Statement Lis true but Statement I! is false. (6) Both Statement I and Statement If are false (d) Both Statement I and Statement If are true. 49. A flask contains hydrogen and oxygen in the ratio of 2: 1 by mass at temperature 27°C. The ratio of average kinetic energy per molecule of hydrogen and oxygen respectively is: [30 Jan, 2023 (Shift @2:1 ®t Ola Mast 50, A flask contains Hydrogen and Argon in the ratio 2: 1 by mass ‘The temperature ofthe mixture is30°C. The ratio of average kinetic, energy per molecule of the two gases (K. argon K hydrogen) is: (Given: Atomic Weight of Ar=39.9) [15 Apr, 2023 (Shif-D)] @1 2 © 32 was 51, ‘The temperature at which the kineti becomes double than its value at 27 D) snergy of oxygen molecules 8 Apr, 2023 (Shift-I1) @ IRPC ()92TC (A REC (AC 2, The average kinetic energy of molecule of the gas is re [1 Feb, 2023 (Shitt-1)] (a) Proportional to absolute temperature {@) Proportional to volume {0 Proportional to pressure (dependent onthe ae FB 85 2 oepero Kinetic theory f 036, 27 Sune, 2022, 58 esthe movin ofthe gs molecules fees at 0°C (Shy ath of gas molecules decreases (B) The mean free path ite © crmolecules is increased. = uy, ‘The mean fe path of gas molecules nereases iy (©) eres kesping ese ons Hey sae kinetic energy per molecule per depreeo “Average kinetic emery Pet ln 3 gar (lormonoatomic 8) Cchoce the most appropiate answer from the option get (27 Sane, 202 (ing (6) Band Conly (©) Aand B only (f) Cand Dey 54, Following statements are given: (2S July, 202 (ng (a) The average kinetic energy ofa gas molecule decessay the temperature is reduced. (B) The average kinetic energy of a gas molecule incre xg jnoreae in pressure a constant temperature. (©) The average kinetic energy of a gas molecule decreas increase in volume. (D) Pressure ofa gas inereases with increase in temper constant pressure. (6) The volume of gas decreases with increas in tempennae ‘Choose the correct answer from the options given below: (a) (A)and (D) only (B) (A). (B) and (D) only (©) (B)and (D) only (d) (A). (B) and E)only 58, Given below are two statements: ‘Statement I: The average momentum of a molecule ina spe an ideal gas depends on temperature. Statement Hl; The rms speed of oxygen molecules ina pss Ifthe temperature is doubles and the oxygen molecules dst into oxygen atoms, the rms speeds will become v. Inthe ight the above statements, choose the correct answer fom te = given below: {28 July, 2022 sist (a) Both Statement I and Statement I are true (6) Both Statement I and Statement Il are false (6) ‘Statements His true but Statement I is se (Statement Lis false but Statement I is tue 56. On the basis of kinetic theory of gases, the gas exerts pro because is molecules {24 Feb, 2021 Si (@) Continuously lose ther energy til it reaches wall. (b) Suffer change in momentum when impinge on the walt container. (©) Are attracted by the walls of container. (@), Continuously stick to the walls of container. 57. The number of molecules in one litre of an ideal 8° 300 K and? atmospheric pressure with mean kinetic ent)2* Sper molecule is: 127 July, 202 (SH (@) 0.75% 10") 3 10" Ge) 6x10" 1Se" ‘58. A mono-atomic gas of mass 4.0 w is kept in an insulated oot Container is moving with velocity 30 ms. If container 8% stopped then change in temperature of the gas (R = g38 °°" a [25 Feb, 2021 sai o (@ AandConly Z. Value of xis 7 ofxis | aoter of molecules a vole of feat of apefict me ' meer fens sake of arora FES ax fetmeccenes | TL ADS ee ® pucocumnmnn [mteapm oflescfoms 6 esinnd eek con Bose to? (Given. mean Kinetic energy of a mciecute of gases # conse: vane TIPE _ . SO cms censny cf sey Calne 108 Aped. 2024 (SBiA-DI tees = 10% (2) 40+ 10" £0 +108 syeksed ee! CCoUES O.| mole of a meestomae weal gas 22 00 fhe ume mx OK aioe Se sx tecaperanure (i K) ofthe ens inthe vessel ai be close uaa (04 Sep, 2020 (Stit-Dy 58 *10* ( Equipartion Theory, Degrees of Freedom, Specific Heat Capacity @. The wel Eece (a) 69553 (6) 592203 124 (Sb) [10 Ape, 2023 (SB [31 Jan. 2024 (Stif-D) @) ome — 6 A pas cinnre consists of § moles of pen and 6 males of eryRS mtemperance T. Neglecting all bratenal modes Se wa [SL Jan. 2024 (SRif-UD] to) 78T aie sx moles [1 Feb, 2024 (S8iN-D] ©. Tromoles amoncurcens pass BS The molar spastic Beat RO & The ranslanonal degrees of freedom (f) and rouatonal degrees of | freien DeofCH, molecdeare: — (OEApAL NDS (SAAD) | (2) fs2andf=2 1) f= Sans, © fetes (fad . Eserey of 10 noe rigid distomic molecules at erapeTA Yee april 2024 (SND) KT BAT WS ‘Choose the correct answer from the options given below: [10 Apr, 2023 (Shift-D)] (a) A-IV;B— IN; C1; D1 () ASIV;BS1;C4 Di () ASEBo IC IV.Dom @ As1;B1V,C4 Doi 79. Sound travels in a mixture of two moles of helium and n moles of hydrogen. Ifrms speed of gas molecules inthe mixture is > times the speed of sound, then the value of» willbe: [25 July, 2022 (Shift-I)] @t (2 3 a 80. Avessel contains 14 g of nitrogen gas ata temperature of 27°C. The ‘amount of heat to be transferred to the gas to double the m.s speed of its molecules will be: Take R = 8.32.3 mole" k', (28 July, 2022 (Shi (a) 22295 (b) 56163 (c) 9360) (a) 13,1045 81. Assmall object is placed at the center of a large evacuated hollow spherical container. Assume that the container is maintained at OK. At time 7'= 0, the temperature of the object is 200 K. The temperature of the abject becomes 100 K at ¢= f, and at 50 K, Assume the object and the container to be ideal black bodies. The hheat capacity ofthe object does not depend on temperature. The ratio (yi [JEE Adv. 2021] 82. Consider two ideal diatomic gases A and B at some temperature 7. Molecules of the gas 4 are rigid, and have a mass m, Molecules ofthe 205 B have an additional vibrational mode and have mass m/4. The ratio of the specific heats (C} and C¥) of gas A and B, respect is: 19 Jan, 2020 (SI @3:5 5:7 7:9 5:9 83. Considera mixture of moles of helium gas and 2n moles of oxygen gas (molecules taken to be rigid) as an ideal gas. ItC/C, value will D1 & 1x a wn 6421 @ ems tors 84. Twormoles ofan ideal gas with Se. $ are mixed with 3 moles of srter ia a with & 4 The ct SE fr ise is: {7 Jan, 2020 (Shift-1)} (a) 142 (6) 1.47 (©) 145 @ 1.50 ‘Match the C,/C, ratio for ideal gases with different typeof molecules [4 Sep, 2020 (Shift-D] ‘A. | Monoatomi US B | Diatomie rigid molecules C. | Diatomic non-rigid molecules Dy | Triatomie rigid molecules (@) A,B,C 1,D+1V () A-rIV,B—1, C1, Dll (© A+V,B+1,.C1, Di () ASMLBSIV,C— 1, D1 86, To raise the temperature of @ certain mass of gas f 87. 88. 89, 90. on. 2. 93, 0 constant pressure, 160 calories of heat is required, Whey, Ha mas gasis cooked by 100°C at constant volume, 2p eats leased How many egrets of freedom doseage ofthis gas have (assume gas to be ideal)? [3 Sep, 2029 (i 1 (@) 6 7 ©. 2 . os mixture consists of 3 moles of oxygen ang 5 and the oxygen bond to be rigid, the total intemal gat inunits of R7) of the mixture is Sepa (@ 13 () 15 (©) 20 @u Consider a gas of tritomic molecules. The molecules are to be triangular and made of massless rigid rods whose yen, are occupied by toms. The internal energy ofa mole afte gas temperature Tis 13 Sep. 200 ae @ ser) Bar) Bert Sar Molecules of an ideal gas are known to have three tase! degrees of freedom and two rotational degrees of freedom. Ths is maintained at a temperature of T. The total internal enerey, Ut mole ofthis gas, and the value of 4 CP are given respective, fe fe ty [6 Sep, 2020 (sti (@) U=sRTand y=2 (6) U= Sprandy=8 5 2 3 6 5 1 (© U=sarend (© v=Seracay=2 5 Arndt ‘An ideal gas occupies a volume of 2 m’ at a press 3% 10*Pa. The energy ofthe gas is: {42 Jan, 2019 (Sif (@) 9105 (b) 6 10F (©) 10s @ 3% 10) ‘An unknown metal of mass 192 g heated to temperature of 17° was immersed into a brass calorimeter of mass 128 g conuis#t 240 g of water at a temperature of 8.4°C. Calculate the specifcte! of the unknown metal f water temperature stabilizes at 15°. (Specific heat of brass is 394.3 kg! K-!): 10 Jan, 2019 (Shift (@) 458 kg K+ (6) 12325 kg K" (© 916 Seg! K-! ( 6544 kg* Ke A gas mixture consists of 3 moles of oxygen and 5 #918 oF argon at temperature T, Considering only transla! and rotational modes, the tc inter ergy of the system» aT Jan 20 @ASRT WRT) aRT (a 208T AIS g mass of nitrogen gas is. enclosed in a vessel at atempeo™ 27°C. Amount of heat transferred to the gas, so that rs ve molecules is doubled, is about: (Take R = $.3 1K mole] {9 Jan, 2019 Sait! wae 09 6 OW Mean Free Path } Oger molecules ina closed ch closed chamber frequency of the same system at 10S April, 2024 (Shift-1) irre cllision frequency ofhyd Migr is Z then the collision iarcis Br 2 @ @ 2 OF isthe number density anise dameterofhe molecule. ten % ” st Caleulat the value of mean fice path (2 for oxygen molecules at | fesegedisane covered anelestetee tn aes iMoron (ic. ean fee path is represented by. J0$ Apel Yond (Gbitt-D1 al () Bona? i © Tone 1 © Ponnal™ ‘The mean fe path of molecu fa cern gas at ST 150, here dis the diameter ofthe gas molecules, While maitanng thestandad pressure, the msn ee pathof the molecules at 3K i pproximately: 113 Apr 2025 (Shiny GTB) ZHI (e) 750d Wd) L3UOd ‘The number of air molecules per cm increased from Je10" 210". Theraioacolision feqncyo nr moles before and afte th increase in number respectively is 106 Ap, 203 (Shit (a) 050 (125 (4) 025 (@) 05 temperature 27°C and pressure 1.01 «10° Pa. Assume the moleculat diameter 0.3 nm and the gas is ideal (k= 138 «102K (a) S8nm (6) 86nm [16 March, 2021 (Shift-1)| (© 320m (eh 102, 99, 100, 01 25 * 10m? volume cylinder 1s filled with 1 mol of O, rontaineris slowly heated. As its emperarare ements are true? {2 Sep, 2020 (Shift-AD] the molecules decreases. lecules decreases. ‘An ideal gas inaclosed c increases, which of the following state A. The mean fe patho 1 The mean olson ime between the m0 remain unchanged remains vchanged (o) BandC (d) AandB ice time (me “he plot that depts the Bei of the meas fs time Pace oe cin colin) forte molecules ofa Ha iy is (raps ae res font of emprature (7). quakes we and nt daw see) 0 (#4482020 Sbi-DI ©. The mean free pat D. The mean collision time (a) Cand D (6) AandD (at 4 (ot a it a r on N a LO iF ‘Two gases argon (atomie radius 0.07 nm, atomic weight 40) and enon ftom radius 01 nm, atomie weight 140) have the same ime temperature, The ratio of theit 19 Jan, 2020 (Shift-ID] (a 467 number density and are atthe sa respective mean free times is closest 10: (a 183 (623 fo) 367 room temperature (300 K), The molecular diameter of its oot mean square speed, are found to be 0.3 nm and 200 mvs. respectively What i the average collision rat (per second) ©, molecule? 110 April, 2019 ( (@) 10) fo ~108 @) ~10" () =10" L® 2@ 3H 4 SO MG 12, (150) 1B (0500) 14 6] ISO Le 2~@ BM MH BO We sy 3) HO a) M093) a @ HD Shi 52) SR) SESE 1. (ay 62. (b) 63. (0) 64. (eo) (a) 16) om pay 7) TH (d) Mp a Bh (0) We) 9 a 9) HE o (02. (a) 6. (250) 7) BM 9% 10. (26), 6) IF) BH) 1 «) 26. (b) 27 (0) YD, 30. (e) 36. (6) 37) 3B, [HOO] 39, 40. (e) 46.6) AT) BD 1. (a) 56. () ST. (a) $8. [3600] 59. (266.67) 66. (0) 67 (a) 8. (8D. wey (a) 77.) TR) 80. (c) 86 (a) 87 (5) BK (a) 8, 90. (*) 9%. (6) Tb) (99, 100. () — 1. (@) By using ideal gas equation PV = nT N—Total no, of molecules P= xr 1.38 «101 « 10° = 2 108 1.38 102 «7 Lowx10 2 2. (a) Using Ideal Gas Equation =500K 3. (6) For ideal gas, P= RT oo nett 7 Jw M (Where m is mass of gas and M is ‘molecular mass of gas) For same temperature P, > P, > P, Sop,>P,> py 4. (d) PT= constant, Using PY = nRT RT. a RT. ve 37 =KV Pr? = "BT 7? = constant a so, 4 (xy)=37? ak") 5. (c) No of moles of H, = 8 moles No of moles of O, = 4 moles Total moles = 12 moles ALSTP I mole occupy = 22.4 ¢ 10m? 12 moles will occupy 12 22.4 x 10'em? = 26.8 * 10'em? 6. [250] P= nRT APV.=nRAT 1. Py = nat 5,300 3 x2 +n, «32=0.76 (0.08 m2 +n, 32) 0.76 n=0.02 0.06 8. (@) Let as suppose, Initial load, M, 185kg. Initial temperature, 7, = 27°C = 300K, Initial Pressure, 45 em, We have to calculate final load of ballon at 45 em of Hg pressure. '6em, Final Pressure, P= se0008s oo ay = 2S | 716x266 23.54 9. (0) The ool pes of te mize of esenteeeeleneeaes PreucescaedbyO,* Presse a by Hs Pena oxesedty CO Paby tintin MRT myRT | myRT yy poBT(16 Vv \32 tw (26) The common equilibrium pressure ‘existing inthe mixture R a 11, (©) Wehave given, 2 94165 10 P=P, 25.5x10" aim T.,-?forn= | a wv ap P ‘ad¥ Cn integrating, we get fp #2 aP (Given) P Also, we know, PV = nRT (Pe Lor.) =4/ a0 e*y}-o =o hre}=0 Sex a) te) Sal + New=0 ‘ack ~aP at =nalar w(g en Pane* [150] From ideal gas equation PV=nRT So, PAV+VAP=0= aV Now, PAV = — nkaT mRaT P av Equation (i) and (ii) we get arsape mR Comparing with |A7)= CMF ¥ ee 150 Kiam, 22, (e) The rms speed of a gas motectte 1S | riven by fa \ Vue | Vg = WT \ far far aE (08) \ aM M x ws , 3x22 Soa xe nr wo aS rt 25) cre ae (1.25) gt xa 2o00 7x8 ao=! ear 250k OTS, #050, 128 nj mnates 2A vi vy _ [200 4, fo] Assuming temperature te sta 0 a 800 Foon Pe Lette temperature at which he velocity way fe) flav of hyrogen is equal to the veloity of | 28, (a) Formula of root mean square speed a oxygen al °C be T of a molecule of gas, v= at | 26, (b) Statementet T,=-2¥'C= 200K 27°C = 800K (8) d= me “GG... " BRT, q (b) Given, rms speed eae 2 nsemeed Lia ar : wn st zt Jen oy PRE _ [ores [ORE 5 Pees Statement (OI), » [cee sane PV =nRT ; Bar Fro 160 WW. (DV AS|Vp ne whereas, Translational A! ¥= 259 Distance = 442% 6m (False), 8.) Aspistonis stationary. So using FED ofthe piston, 2. PAPA yy 0.5 kis 21, (6) Rams speed ofa gas molecule, >M.> ete He May Ma Moos Crm) neon = 20-17 ginat C1938. 48 pinot HE = 146.46 ginot So correct relation is, ak 4 CPP Pat mT) (PLAYS 490 = 651.7 avs Vn. (tnon0) > tia) > V_¢poty) 2B. (6) Mya, 29. (b) y,, “ary, on 30. (0) (@) V,., = Ny (7 bonly are comet 31. (0) Given, m= 5 « 10°" kg, k= 1.38 * 10 se V,,, = PAE = [ox138x10 x300 pees io eee = Sms 32, [12] F, speed of the molecule of a gas, BRr Vn, = Pee and Vg a =e 400K mss = 0.056Kg = 56g T,=4T,=4% 400= 1600 3 =2x5x2«1200 2 =12* 10° cal= 12 kal BO, Atconstant 7; ¥,., Mg 1M 16M, iain Ya ooo =F ee La on Therefore Hy >1> Noy 34, (c) Root mean square speed is given as, ey will energy corresponds to each degree of freedom 36. 37. 38, 39, 2. (b) We know that, ‘when temperature, Tis constant, = 10° Nim? On comparing with = 400. 4 [25] Mean fie path, ms", we get x (a) The ratio of rms speed of helium and organ vas, CM, =atomie mass ‘ows (of Argon gas and M, hhetium gas) fe Aiea in iS atomic mass of 43. (6) =7*4,=7 «529-9995 Rounding of 03 sinc pg, ‘A=37.0cm? 4. (ORMS sPEe8 of moe, | BRT M Vig ®VE ¥,_ [i _ fara Vi V2274273 200 i v= 100V5m/s 48. (a) Density of molecules of gsm). "Total number of molecule Jooar = fue sar de “= Number of total molecules is dine proportional to n,e-* 46. (6) Given: Y= per Pet 37-288 p= 2x2x107 x10%6400%10 3x8314 10" Kelvin 47. (c) We have given that, mass = 15g, T=27°C. Amount of heat transferred tothe es.) 7 (0000 J 48. (d) Here we have, RT Mean free path= we~foat 49. (0) ¥ Hydrogen and oxygenare dixon => Ratio= 1:1 50. (a) Average KE per molecule of 12 > og ey Tomstaonal KE ofa molec» 3 , Twhich i independent of nature, 2 peesute and volume, but depends on 15, (9 Theaverage momentumofamolecule inthe sample of an ideal gas is zera ocouse the average velocity i zero, Therefore average momentum of a molecule in a sample of an ideal gas is independent of temperature Gar 3a T YN GT * 46, (6)On the basis of kinetic theory of molecule: suffer change in momentum . ses, the gas exerts pressure because its ‘when impinge onthe walls of container. 51. (0) Given, P= ie= 1x 10m, P=2atm= 21.013 x 10° Nim KE = 2107 J/molecule, Let no. of molecule be N. 10, of motes (n) = NIN, NenN, From, Pi py aT "= 300K, [: K, — Boltzman constant] Formula of mean Kinetic energy ke=2K,r 2 4x10" kr ‘Number of molecules N=", Py WaKreN = PY 2x1 013x10" x10" KT Aso" 3 Sco" pao" 58. [600] ax.E= au Liat .C, ma 2 pte are Me 30380 Tee 89. (i) Pr = ser 3 E=3,y 7 (Paine 60. (2667) ( ve vain )(005x3 e400} 2 2 3 015x287, hy (20+ 20)*0.15 7, 62, (Formostoniemolee ee oder avin sni02 3xL38x10™ : x duns oct L ont oT 6. (AS Kinetic energy 1x81 «300 5= 62325 5 64. (6) Degree of recom of polyatomic gas, fms Degree of feedom of monoatomic gam, fe jth fay For stom gas ,=5 WV0)4 2X9) s N+2 SN+10=6N #6 N ‘65. (a) The parameter that remains the same for molecules of all gases at a given temperature is kinetic energy. is given 66, (c) Total internal energy. U= 8,7 BURA GT HAGE ma tcrootbar -28t 67. (aC, formonostomicanidistomiceses | fe 32 Rand $2 R respectively aC, #825 Cv ray ~ Sasaxd rx2Rs6xSR 9 26 3 « 68. (#) DOF of CH, [Non-Linear polyatomic Moteule | Translational DOF =3 Rotational D.O.F =3 69. (@) DOL Y)=5 +20) Jr 5420 de) 170. (c) The required ratio of specific heat at constant volume, ‘11. (6) Kinetic energy ofthe gas molecules, 38°C = 273 + [78°C] = 195K To double the K.E energy temperature of the particle also become double T,= 390K = 117 72, [121] Atconstant pressure, work done W= na 66 Internal energy, AU MC) AT 1G, +2, Cw acdarde 602121) 7B. (©) Fora monoatomie 28 y, Fora diatomic as at low temperature . inet Th ry f se - oie, | s We3 2 ° 72 5 74, (d) A diatomic gas molecule has three translational degree of freedom, two Fotatonal degree of freedom & given in the question that it has one vibrational mode so there are two additional degrees of freedom corresponding to one vibrational mode, s total degrees of freedom =7 sc 2 75, (d) Internal energy of oxygen (diatomic) 0, Sener =Seyer= sar Internal energy of argon (monoatomic) 3 3 Uy = Soe T= Uy = Ser =3a)R7 = 6RT Total energy U= U,+U, U=S ATs 6RT=11.RT 76, (a) Q= nC AT ras nx Rar 2 o Since diatomic gas has degree of freedom =s au from equation () suas Sears x 105 = 525 71. (by yisindependet of temperature 78. (© pearance Teer ona airy er fue ayer ty Rms speed of gas molecules, (a) Ber oma a Moles: ‘According to question, G ‘ma *Vivee PEE & ‘ (Gmc _2C, +n, afr ya Gime Cenc uD Using, 7=14+— Seg = LEMS XI 2450 Soa zen otra 84, (2) Given, n,=2andn.=3 6458 Cp *mCa 1 _Tns10 tl 37 65m 80, (c) Wehave,m,,= 14g, Vong AT To double the V,, T,= 47,= 4 » 300= 1200K Q=nc, aT =(3}$e-c200-s00 28 = 1125R = 1125 « 832 93601 81. () oart= sondt thay fon p= Sy ec 37 hw Yl 3 io0? Gel Mono ya o fo (etree) atomic | > Ae x) ° ee (Bere tee 1 _( 2008-50" Jio0" Ria 11 { 200°=100" J50" rig 2 1 aoe ee 82, (#) Molar heat capacity of 4 at constant More volume = 5 Pos | 3 | 3 | than z tomic L Molar heat capacity of B at constant 1k ict ile,n,=2& Molesof Hen = ont) Motes of Ie. = L Gis fer Speed of sound ina gas, v, = fH Diving born SF = 2 3x3r 2 Triatomie For Diatomic 86. (a) 160 = nC, 50 “ 240 = nC, 100 9 From (/and (i), 87. (6) £=3« Serssedxar =i 88, (a) U= RT F> 6 (for triatomic) = U=3RT fe 5 eypata inslclent. Degree of fcedom jg not given. (o Heat loss = Heat gain yp? «5 (100 ~21.5) 12 128 394 x (215-84) +240 x 4200 x@s-84) 252916 Ske" K" 1p, (0) Total energy ofthe system is Us Unven * Uine _eSKAT , SXOXRT Fu 2 om($3)= SRT 2. (g We have given that, mass = 15g, Te2Tc. Amount of heat transferred tothe gas, 40 = £nkaT 2 5 espe 5am) eel faved Ax [i _ foo tan (Here, 7, and 7, is in X] 2 wr (©) Mean free path= he 1 Tada (©) Formuts of Mean fee path of a molecule ofthe gas aoa AT Tina? PN, Sher 300d _ 273 3B A= 2089.4 97. (b) Collision frequency, au ry Y . Sind*im, * frequency is ditcetly proportional to numberof air molecules 98. (d) Mean fre path Vind" P 1.3810 300 Lax3.14x (0.3107) x1 0110" R= 102 am pendent of 49, (Mean fre path inp one an rnin ce as temperature increase. 100, (d) As mean free time L t So, graph (d) depicts the right behaviour. l 101, (a) Mean fee time = 5 5 stn if OLY, [8 21.09 007) *Vieo Hence, the nearest answer is 1:83. 102. (a ve Rr. Viro* o=2*03%107 ae noslives's., [E 25x10" 1768 « 10sec ~ 10” Hence, option (a) is correct answer. a eed

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