PVT Fluid Sampling and Characterisation
PVT Fluid Sampling and Characterisation
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Authors’ contributions
This work was carried out in collaboration between all authors. Author JUA designed the study, wrote
the protocol, and wrote the first draft of the manuscript. Author OOA confirmed the cited literatures,
and author SOI reviewed the simulation process, analysis and results. All authors read and approved
the final manuscript.
Article Information
DOI: 10.9734/AIR/2015/16000
Editor(s):
(1) Pradip K. Bhowmik, Department of Chemistry, University of Nevada Las Vegas, Las Vegas, USA.
Reviewers:
(1) Anonymous, Suez Canal University, Egypt.
(2) Anonymous, Inha University, South Korea.
(3) Anonymous, Ladoke Akintola University of Technology (LAUTECH), Nigeria.
Complete Peer review History: http://sciencedomain.org/review-history/10630
st
Received 31 December 2014
Original Research Article Accepted 9th June 2015
rd
Published 23 August 2015
ABSTRACT
When reservoir pressure decreases in gas condensate reservoirs, there is a compositional change
which makes the system difficult to handle. This type of system requires an Equation of State (EOS)
to ensure proper fluid characterization so that the Pressure Volume Temperature (PVT) behavior of
the reservoir fluid can be well understood. High quality and accurate PVT data will help reservoir
engineers to predict the behavior of reservoir fluids and facilitate simulation studies. The aim of this
study is to determine what to do on reservoir fluid before carrying out reservoir modeling.
PVT data were obtained from a reservoir fluid in the Niger Delta which was sampled following
standard procedures. Then the laboratory experiments were critically examined to ensure accuracy,
consistency and validity before PVT analysis. Finally, the results from the PVT experiments were
imported into PVT software and subsequently in a reservoir simulator for simulation studies. These
processes generate the EOS model for reservoir modeling of gas condensate reservoirs.
The mass balance test, Hoffman plot and CCE/CVD (Constant Composition Expansion and
Constant Volume Depletion) comparison plots were used to validate PVT data. From these tests,
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the consistencies of the data were ascertained and the composition added up to 100%. The pattern
of the CCE/CVD comparison plot was observed to reflect that less liquid dropout was experienced
later in the depletion process of the CVD experiment than in the CCE experiment. PVT validation
checks help to confirm the Gas oil ratio of the system and the richness of the gas condensate fluid.
It is imperative to obtain representative reservoir fluid samples and carry out reliable laboratory
experiments to generate PVT data for fluid characterization. PVT fluid characterization and
consistency checks will ensure that accurate results are obtained from reservoir simulation models
leading to proper reservoir management.
Keywords: Fluid characterization; equation of state; retrograde condensate; reservoir modeling; fluid
sampling.
NOMENCLATURES 1. INTRODUCTION
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EOS can be modeled with the following general A fundamental tool for planning the development
procedure: of a field and evaluation of field production
performances is reservoir simulation studies.
a) EOS model is built with an EOS correlation Part of the requirement for any integrated
using available composition at reference reservoir studies is the reservoir fluid PVT model
pressure, temperature and depth. [8].
b) To ensure that the GOR and density
match, the molecular weight or specific
gravity of the pseudo component is 1.1 Fluid Characterization and Gas
changed by 5-10% to get close to the Condensate Fluids
densities.
c) Binary Interaction Parameters (BIP) are
used to match saturation pressure while One way of obtaining representative reservoir
the Pseudo components are split. fluid, is by sampling the fluid just after the
d) Laboratory data is entered and deviation completion of the drilling, since pressure is less
between the calculated and experimental likely to drop below the dew point thereby
values is checked. creating a two phase in the reservoir [10-13]. A
e) The BIPs and critical properties of pseudo mono-phasic condition should be maintained
components are regressed if a large during sampling and transfer to laboratory for
deviation is noticed. analysis. In order to realize this objective, the
f) EOS model is lumped for use in simulation sample drawdown pressure should be controlled
model, after linear regression to reduce the and kept as close as possible to the reservoir
simulation time. pressure and above the dew point [14,15].
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Akpabio et al.; AIR, 5(5): 1-11, 2015; Article no.AIR.16000
Fig. 1a. and 1b. Phase envelopes of rich and lean gas condensate fluids [17]
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2.2 Analysis and Tuning of PVT Data condensate windowed cell. A part of the
recombined sample was changed to the cell and
The results from the laboratory experiments expanded thermally to the reservoir temperature
which are the CCE, CVD, viscosity and separator of 176.6ºF. This experiment is started at a
tests were inputted into the PVTsim software. pressure much higher than the reservoir
The Fluid is characterized by delumping and pressure and reduced stepwise until the dew
lumping of the plus fractions and assigning of point pressure is observed and recorded. Other
individual properties (e.g. Tc, Pc, accentric factor, parameters recorded in this test are the deviation
Mw etc.) to these components using an equation factor, the compressibility factor, the liquid
of state (EOS). The EOS parameters were tuned dropout, gas density and relative gas volumes as
to match experiments’ PVT data of the CCE and seen in Table 3.
CVD tests with the simulation results. The
lumping and delumping of the C7 plus fraction
was necessary to reduce the number of CVD experiment is carried out on the fluid at
components used in the EOS calculations also reservoir temperature of 176.6ºFand dew point
reduce compositional model computing time [20]. pressure which was determined by the CCE
experiment. The experiment involves a series of
2.3 Basic Experiments before Fluid pressure expansions and constant pressure
Characterization displacements to maintain the sample in a
constant volume that was equal to the volume of
Constant Composition Expansion (CCE) and sample at dew point pressure. The process is
Constant Volume Depletion Experiments (CVD) repeated until an abandonment pressure, which
are the two basic experiments carried out on gas was 524 Psia. The well stream was pumped from
condensate fluids before characterization. CCE the PVT cell into a pre-weighed flask submerged
experiment is performed in a high-pressure gas in liquid nitrogen and condensed. The condensed
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Akpabio et al.; AIR, 5(5): 1-11, 2015; Article no.AIR.16000
gas phase is then gradually allowed to return to Hence, the expression for the xi and yi are as
ambient temperature. The gas evolves and the follows:
residual condensate are collected separately,
weighed and analyzed. The quantities that are Lxi Vyi Fzi (5)
recorded during this experiment are liquid
dropout, cumulative produced fluid; gas density
and gas z-factor, see Table 4. Phase and Dividing through by Z
volumetric behavior of mixtures using any of the
EOS models can be predicted by obtaining such Lxi zi V yi zi F (6)
properties as the critical properties (Tc, Pc) and
accentric factor, ɷ for each component in the Dividing through by V will give
mixture.
L V xi zi yi zi F V (7)
2.4 Compositional Consistency
The consistency of the fluid composition can be This translates to
determined by evaluating the PVT data. One
major consistency test is the summation of the yi zi L V xi zi F V (8 )
composition to ensure they add up to 100%. In
modern PVT reports, inconsistencies in
composition are usually very small and are seen This is a straight line equation obtained by
in unnoticeable figures instead of errors [21]. plotting yi zi against xi zi to generate an
Apart from the summation of the composition,
intercept, F/V and a negative slope (L/V); this
other techniques for consistency checks are, the
negative slope is equivalent to the measured
mass balance plot, Hoffman plot and Buckley
GOR. Table 2 is used to generate this mass
plot. While the mass balance plot is a
balance plot. Deviation from the straight line can
quantitative method, the Hoffman and Buckley 2
be seen as mass balance inconsistency. The R
plots are qualitative methods of assessing PVT
value must tend towards unity (Fig. 2). This plot
data.
is sometimes used to identify discrepancies in
2.4.1 Mass balance test the reported compositions. The reciprocal of the
slope may be used to compute GOR and
This test is used to assess the feed composition thereafter compare with the measured GOR. The
and the separator vapour and liquid composition conversion from mole to barrels is necessary
for consistency. The basis for the test is the when the values of the liquid density and
mass balance criteria of the component. One molecular weight are provided. The feed
mole of fluid of composition z is considered at a compositions used in this study yielded a good
certain temperature and pressure (T, P); it can result in terms of consistency. The separator
be split into liquid and vapour of L moles and V liquid and vapour can be mathematically
moles of compositions respectively [22]. An L recombined to obtain the well stream
mole of liquid has the compositions x1, x2, … xn, composition. From the graph, the value of the
and a V mole of vapour has compositions of y1, slope was 0.0083 which gives a GOR of 82201.8
y2, …yn. Then scf/sep. bbl. upon conversion of the reciprocal of
the slope. The difference between the calculated
L V 1 (1) and measured GOR is 0.86%. The measured
GOR is 82918.7 scf/sep. bbl. This result shows
and that the value of the liquid molecular weight and
density are close to the reported GOR. If this
Lxi Vyi Z in (2) difference is large, then the values of the
reported liquid molecular weights and densities
n n n are inaccurate. This will make the tuning by
xi yi zi 1
i 1 i 1 i 1
(3) linear regression of the equation of state difficult.
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Akpabio et al.; AIR, 5(5): 1-11, 2015; Article no.AIR.16000
And R2 is 0.9997
Using some conversion factors, the slope of the mass balance plot can be expressed as GOR.
1.2
y = -0.0083x + 1.0088
1.0 R² = 0.9997
0.8
yi/zi
0.6
0.4
0.2
0.0
0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0
xi/zi
HC Component
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Akpabio et al.; AIR, 5(5): 1-11, 2015; Article no.AIR.16000
1.0
0.0
Log K
-1.0
-2.0
-3.0 0.0 2.0 4.0Tc2/105 6.0 8.0 10.0
Non-HC Component HC component Linear (HC component)
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Akpabio et al.; AIR, 5(5): 1-11, 2015; Article no.AIR.16000
Non-linear regression is used to determine the other before the CVD curve lies beneath the
correlation constants to fit the experimental data CCE curve. (Fig. 5).
from the True Boiling Point (TBP) and Mi is the
molecular weight of heptane plus. This equation 3.2 Linear Regression of Data
was originally generated based on a comparison
of experimental and calculated specific gravity of After the CCE and CVD data are obtained, there
68 samples. is need to use non-linear regression to adjust the
predicted EOS characterization in order to obtain
3.1 CCE and CVD Comparison Plots an acceptable match. Some parameters need to
be selected based on experience because the
Two major experiments for gas condensate fluids
tuning process is usually a trial and error
for determination of the reservoir phase behavior
process. Out of the several non-linear least
are Constant Composition Expansion (CCE) and
squares regression methods being implemented
Constant Volume Depletion (CVD) [25]. These
and tested, the rotational discrimination method
experiments help in tuning the equation of state
is recommended. To obtain a good match
models for modeling reservoirs. Information
between the simulated and experimental data a
obtained from these experiments are imported
set of BIPs need to be adjusted. These BIPs help
into PVT softwares to generate the actual
to predict the capabilities of the EOS used in
reservoir fluid properties. Important information is
Volume Liquid Equilibrium (VLE) calculations of
obtained by plotting the CVD and CCE together.
reservoir fluids .A reasonable match could be
The dew point pressure of the reservoir was
achieved with an error of±(5-10%) then the EOS
4191 psi. and the plot shows the consistency of
can be imported into a simulation model such as
tge two experiments. The plot has an identical
ECLIPSE100, 300, Dynamo/Mores which will
dew point while the liquid dropout of the CCE is
now function as a compositional model.
less than that of the CVD. The CCE test gives a
maximum liquid dropout at a lower pressure than
the CVD test. At the beginning of the retrograde 3.3 Gas Condensate Reservoir Modeling
process, the curves are identical but the CVD will
show greater liquid dropout than the CCE as A compositional simulator tracks each
more liquid condenses. This happens because component of the oil and gas in the reservoir
when retrograde condensation starts, the from the least component to the largest (C1,
composition of the gas phase becomes leaner C2……Cn). By doing this it models fluid near the
than the liquid phase. During CVD experiments, critical point in the phase envelope, where
the composition of gas will be richer than the changes in the pressure and temperature of the
original composition during the CCE experiment compositional system can result in very different
when the leaner gas is removed. More liquid phase behavior. In this system, oil and gas
dropout is experienced because the total CVD phases are represented in multi-component
fluid composition is richer. This is the reason why mixtures while composition and time are
the CCE and CVD curves will initially track each represented by EOS.
8000
7000
6000
Pressure, Psi
5000
4000
CCE Liquid dropout %
3000
CVD Liquid dropout %
2000
1000
0
0 1 2 3
Liquid dropout %
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