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Chem DPP - 11

The document contains a set of questions and answers related to atomic structure and spectral lines, specifically focusing on the Paschen and Lyman series in hydrogen and helium ions. It includes calculations for wavelengths, energy transitions, and spectral line possibilities. An answer key is provided at the end for reference.

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43 views2 pages

Chem DPP - 11

The document contains a set of questions and answers related to atomic structure and spectral lines, specifically focusing on the Paschen and Lyman series in hydrogen and helium ions. It includes calculations for wavelengths, energy transitions, and spectral line possibilities. An answer key is provided at the end for reference.

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abc9xyz01
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1

ARJUNA JEE 2023


Atomic Structure DPP-06
1. What is the shortest wavelength line in the Paschen 6. Find the value of wave number (v) in terms of
series of Li2+ ion? Rydberg’s constant, when transition of electron takes
R 9 place between two levels of He+ ion whose sum is 4
(1) (2)
9 R and difference is 2.
8R 32R
1 9R (1) (2)
(3) (4) 9 9
R 4 3R
(3) (4) None of these
4
2. The shortest wavelength in H spectrum of Lyman
series when RH = 109678 cm–1 is.
7. What is the maximum wavelength line in the Lyman
(1) 1002.7 Å
series of He ion?
(2) 1215.67 Å
1
(3) 1127.30 Å (1) 3R (2)
(4) 911.7 Å 3R
4
(3) (4) None of these
3. Which of the following electron transitions in a 4R
hydrogen atom will require the largest amount of
energy? 8. The given diagram indicates the energy levels of a
certain atom. When the system moves from 2E level
(1) From n =1 to n = 2
to E level, a photon of wavelength  is emitted. The
(2) From n = 2 to n = 4 wavelength of the photon emitted during its transition
(3) From n = 5 to n = 1 from 4E/3 level to E level is
(4) From n = 3 to n = 5

4. The emission spectrum of hydrogen is found to


satisfy the expression for the energy change. ΔE (in
1 1 
joules) such that E = 2.1810−18 − J
 n2 n2  (1) /3 (2) 3/4
 1 2
where n1 = 1, 2, 3…… and n2 = 2, 3, 4… ...... The (3) 4/3 (4) 3
spectral lines correspond to Paschen series to
(1) n1 = 1 and n2 = 2, 3, 4 9. the energy difference will be minimum of which of
the following energy levels of H – atoms?
(2) n1 = 3 and n2 = 4, 5, 6
(1) n = 2 and n = 3 (2) n = 3 and n = 4
(3) n1 = 1 and n2 = 3, 4, 5 (3) n = 1 and n = 2 (4) n = 1 and n = 4
(4) n1 = 2 and n2 = 3, 3, 5
10. When electron jumps from the fourth orbit to the
5. The number of possible spectral lines in Brackett second orbit in He+ ion, the radiation emitted out will
series in hydrogen spectrum, when the electrons fall in
present in the ninth excited state return to the (1) ultraviolet region
ground state, is (2) visible region
(1) 36 (2) 45 (3) infrared region
(3) 5 (4) 6 (4) radio wave region
2

Answer Key
1. (3) 6. (2)
2. (4) 7. (2)
3. (1) 8. (4)
4. (2) 9. (2)
5. (4) 10. (1)

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