Reactions of Amines =

Method

"" " " - - - ← -

1 to Form Amines
- ←
:

==← ←←¥ From halogenoalkar.es Reaction from Year 1 ! Recap :

M 6 Nucleophilic substitution of Halogen alkane with NH3

]
.

( conditions :
Heat halogen alkane with excess NH3 dissolved

⑦
"" """ "" " " " "" " " "
"
" :
NH3
:[ - ✓
H

µ
1HG #
s'
-
H

" "
l
TH
R -
c-
H s R -
C -
N -

H + :X
-

I \
I H
H
H

✓
H
" ,
. / .
,
j
.

R -
C -
+ H - N -
H , ,

T¥
1
H

of
Disadvantage method 1

'

Amine has lone pair of electrons hence it act as

nucleophile it react with
group a can a , so
may
halogen alkane molecules itself ,
giving a mixture of products .

Excess NH3 makes haloalkane used

all
gets
•

sure
up
.

Method 2 to Form Amines : From nitrites ¥

WE- - - - ← - - ← ← ←← -← %
( non - aromatic)

Aliphatic be produced by
amines
reducing nitrite
reducing LIA /
-

can a to an amine using a

strong agent such as
H4 in

ether, followed by dilute

dry acid .

1 LiAlH4
CH }C=_ N 4 [H ] CH> CH2
.

t > NH2
2. Dilute Acid
Ethane nitrite Ethyl amine

catalytic Hydrogenation

Platinum used of
or nickel
catalyst is instead expensive LiAlHy in
industry
•

Ni
( H3C IN +
ZH2 & pressure
>
CH3 CH2 NH2
High Temp
Ethane nitrite Ethyl amine