Scribd
Upload
32 views2 pages

Finals Prob Set CHPHY

The document contains a finals problem set for a chemistry course, focusing on thermodynamics and calorimetry. It includes various problems related to heat capacity, heat of combustion, entropy changes, and reactions involving ideal gases. The problems require calculations based on given data and thermodynamic principles.

Uploaded by

euniceannestaana
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
32 views2 pages

Finals Prob Set CHPHY

The document contains a finals problem set for a chemistry course, focusing on thermodynamics and calorimetry. It includes various problems related to heat capacity, heat of combustion, entropy changes, and reactions involving ideal gases. The problems require calculations based on given data and thermodynamic principles.

Uploaded by

euniceannestaana
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
You are on page 1/ 2

CHPHY123P

Finals Problem Set

Problems of Chapter 7

40. The molar heat of combustion of naphthalene (M.W. = 128.17) is –1228.2 kcal/mol. If 0.3000 g of naphthalene
burned in a calorimeter causes a rise in temperature of 2.050 °C, what is the total heat capacity of the calorimeter?

41. If 1.520 g of an organic compound burned in the calorimeter in problem 40 cause the temperature to rise 1.845 °C,
what is the heat of combustion of the compound in calories per gram?

66. Using the heat capacities Cp as functions of T, calculate the amount of heat required to raise the temperature of 200
g of CO2 (g) from 300 to 500 K at (a) constant pressure and (b) constant volume. Assume CP – Cv = R.

72. Find ∆Ho as a function of T for the reaction CO2(g) + C(s, graphite) = 2 CO(g) given that ∆H293K = 41,400 calories.

73. Find the expression for ∆Ho as a function of the temperature for the reaction N2(g) + O2(g) = 2 NO(g) given that
∆H°293 K = 43,000 cal.

75. For the reaction CaO(s) + CO2(g) = CaCO3(s) ∆Ho = –42,500 – 0.66 T + 2.155x10–3 T2 + 4.1x103 T–1. Find ∆U°, ∆C°p,
and ∆C°v as functions of T.

Problems of Chapter 8.

1. A quantity of ideal gas in an isolated system is expanded isothermally and reversibly at 400 K from a volume V1 to V2.
During the expansion the gas absorbs 200 cal of heat from the reservoir in contact with it. Find (a) the entropy change of
the gas, (b) the entropy change of the reservoir, and (c) the entropy change of the whole system.

2. If the gas in problem 1 is expanded from V1 to V2 isothermally but irreversibly at 400 K with an absorption of 100 cal
of heat, what will be the entropy changes for (a) the gas, (b) the reservoir, and (c) the complete

system?

3. Suppose the gas in problem 1 expands freely from V1 to V2 at 400 K. What will be the entropy changes for (a) the gas,
(b) the reservoir, and (c) the entire system?

4. Consider again the processes described in problems 1-3, and determine:

(a) The changes in H and U for the gas involved in these processes;

(b) The work performed by the gas in these processes;

(c) The qualitative relation between the work done by the gas and the entropy change experienced by the isolated
system

(d) The qualitative relation between the degree of irreversibility of the processes and the change in entropy of the
isolated system.

5. Starting with the Clausius equality definition of dS, deduce the following expression for the change in entropy which
will attend the heating or cooling of n moles of an ideal gas from volume V1 at temperature T1 to volume V2 at

temperature T2:

17. The atomic heat capacity of solid Mo is given by the equation CP = 5.69 + 1.88 x 10 –3T – 0.503 x 105/T2 cal mole–1

degree–1 Find the change in entropy which accompanies the heating of 1 mole of Mo from 0 °C to its melting point,
2,620 °C.

21. Calculate the change in entropy experienced by 2 moles of an ideal gas on being heated from a pressure of 5 atm at
50 °C to a pressure of 10 atm at 100 °C. For the gas CP = 9.88 cal mole–1 degree–1 .

27. One mole of an ideal gas at 0 °C and 1 atm pressure is mixed adiabatically with one mole of a different gas at 100 °C
and 1 atm pressure to yield a mixture whose pressure is also 1 atm. If CP for each gas is 2.5R cal mole–1 degree–1 what
is S for the process
33. What is the entropy change involved in transforming 1 g of ice at 0 °C and 1 atm pressure into vapor at 150 °C and
0.1 atm pressure? Assume that the specific heat capacities of liquid and gaseous water are, respectively, 1.0 and 0.45
cal/gּdegree.

37. From the data of standard (absolute) entropies, find the standard entropy changes accompanying the following
reactions at 25 °C:

(a) CO(g) + 2 H2(g)  CH3OH(ℓ)

(b) 2 HgCl(s)  2 Hg(ℓ) + Cl2(g)

(c) MgO(s) + H2(g)  H2O(ℓ) + Mg(s)

You might also like