Engineering Physics Important Questions
Engineering Physics Important Questions
A blackbody is a body which absorbs all radiation falling on it, reflecting or transmitting none. It
is a hypothetical object which is a “perfect” absorber and a “perfect” emitter of radiation over
all wavelengths. A black body in thermal equilibrium (that is, at a constant temperature) emits
electromagnetic radiation called black-body radiation.
The spectral distribution of the thermal energy radiated by a blackbody (i.e. the pattern of the
intensity of the radiation over a range of wavelengths or frequencies) depends only on its
temperature.
A perfectly black body emits radiation of all possible wavelength. The graph between
intensity of radiation Eλ vs λ for various temperature represents black body spectra.
Blackbody radiation curves at several different temperatures
● The total energy emitted (per second per unit area (spectral radianncy) E
increases rapidly with temperature ie. E = σT4 (Stefan’s law)
● At a particular temperature the spectral radiancy is maximum at a particular
wavelength λm .
● The wavelength λm for maximum spectral radiancy decreases with increase in
temperature
ie. λmT=constant (Wien’s displacement law)
Quantum Explanation: The explanation was given by Compton which was based on quantum
theory of light. According to quantum theory when photon of energy hυ strikes with the
substance some of the energy of photon is transferred to the electrons, therefore the energy (or
frequency) of photon reduces and wavelength increases.
Various assumptions were made for explaining the effect these were:
(i) Compton Effect is the result of interaction of an individual particle and free electron
of target.
or
..............(1)
According to the principle of conservation of linear momentum along and perpendicular to the
direction of incident photon (i.e., along x and y axis), we have
or
..........(2)
and
or
..............(3)
or
or
……..(4)
……………………
………..(6)
or
or
.........(7)
………..(8)
To find the relation in term of wavelength, let us substitute and, we thus
have
Compton shift
.........(9)
From above equations (8) and (9) following conclusions can be drawn
The wavelength of the scattered photon λ’ is greater than the wavelength of incident photon λ.
Δ λ have the same value for all substance containing free electron
Ques 3. Derive time independent and time dependent Schrodinger’s wave equation? Give the
physical significance of wave function. What conditions must it fulfill?
Ans 3. Schrodinger’s time independent wave equation : – describes the situation when force
acting on a particle or potential energy does not depend upon time but vary with the position of
particle. If a moving material particle has a wave associated with it, then its periodic
displacement in space and time should be given by a definite wave equation. Consider a system
of stationary waves to be associated with the particle. Let ψ be the periodic displacement for
the matter waves at any position (x, y, z) at any instant t, the differential equation of motion of
the wave is given by
2 1 ∂2ψ
∇ψ=
u2 ∂t2
2 1 ∂2ψ
∇ ψ- =0 …(1)
u2 ∂t2
where u is the velocity of matter wave. Ψ is the wave displacement function. The solution of eqn.
(1) is given by
⃗
⃗ ( )
ψ r ,t = ψ0 ( r) e-iωt …(3)
∂ψ
= -iω ψ0 e-iωt = - iωψ …(4)
∂t
Differentiating again
2
∂ψ
= (-iω)2 ψ0 e-iωt = - ω2ψ …(5)
∂t2
2
∂ψ
Put the value of in eqn. (1), we get
∂t2
2 ω2
∇ψ+ ψ=0 …(6)
u2
2πu
But ω = 2πν = , Eqn. (6) becomes
λ
2 4π2
∇ψ+ ψ=0 …(7)
λ2
h
Introducing the deBroglie’s concept of wavelength, i.e. λ = , eqn. (7) can be written as
mv
2 4π2m2v2
∇ψ+ ψ=0 …(8)
h2
2 m2v2 h
∇ψ+ ψ=0 …(9) where ħ =
ħ2 2π
2 m2v2
∇ψ+ ψ=0 …(10) where mv = p linear momentum
ħ2
1
The total energy of a particle is given by E = K + V = mv2 + V
2
∴ p2 = m2v2 = 2m (E - V)
Schrodinger’ time dependent wave equation: – describes the situation when energy depends
upon time.
2 1 ∂2ψ
∇ψ=
u2 ∂t2
2 1 ∂2ψ
∇ ψ- =0 …(1)
u2 ∂t2
where u is the velocity of matter wave. Ψ is the wave displacement function. The solution of eqn.
(1) is given by
-i(ωt-kx)
ψ (x,t) = ψ0 (x)e …(2)
where ψ0 is the amplitude of the wave at any position (x,y,z). It is independent of time.
∂ψ -i(ωt-kx) E i
= -iω ψ0 e = - iωψ = - i ψ × …(4)
∂t ħ i
∂ψ E
= ψ
∂t iħ
∂ψ
Eψ = iħ …(5)
∂t
∂ψ -i(ωt-kx) p
= ik ψ0 e = ikψ = i ψ
∂x ħ
ħ ∂ψ
pψ = …(6)
i ∂x
ħ⃗
In 3-dimension, pψ = ∇ψ …(7)
i
1 p2
The total energy of a particle is E = mv2 + V = + V
2 2m
p2ψ
Eψ = + Vψ …(8)
2m
Substituting the values from eqn. (5) and (7) in eqn. (8), we have
ħ2 ⃗
2
∂ψ
iħ = - ∇ ψ + Vψ …(9)
∂t 2m
Physical significance of wave function The quantity whose variations builds up matter
wave is called wave function. It is denoted by symbol ψ. According to Max Born ψ itself has no
physical significance but I ψ I2 represents probability density, it means it represents probability
of finding the particle at that point and at any given moment.
Conditions for acceptable wave function: For a wave function to be acceptable over a specified
interval, it must satisfy the following conditions:
Ques 4. A particle is in motion along a line between x = 0 and x = a with zero potential energy.
At points for which x ≤ 0 and x ≥ a, the potential energy is infinite. Solving Schroedinger’s
equation, obtain energy eigen values and normalized wave function function.
The time independent Schroedinger wave equation for a free particle (V = 0) in three dimension
is
2 2m E
∇ψ+ ψ=0 …(1)
ħ2
0r
2 2 2
∂ψ ∂ψ ∂ψ 2m E
2 + 2 + 2 + ψ=0 …(2)
∂x ∂y ∂z ħ2
d2ψ 2m E
+ ψ=0 …(3)
dx2 ħ2
d2ψ
+ α2ψ = 0 …(5)
dx2
2 2m E
From eqn. (4) and eqn. (5) we get α = …(6)
ħ2
0 = A sinsin αa or sinsin αa = 0
Or sinsin αa = sinsin nπ or αa = ± nπ where n = 1,
2, 3, ………..
nπ
Or α= ± …(8)
a
n2 π2 h2 n2 h2
Put the value of α in eqn. (6), we get En = = …(9) where n = 1, 2, 3, …..
2 m a2 8 m a2
Eqn. (9) represents the permitted energy values known as eigen values of the particle confined
in a one dimensional potential box. The wave function ψ corresponding to each eigen value are
called eigen function.
nπx
ψn(x) = A sinsin ( ) …(10)
a
The probability of finding the particle per unit length is unity i.e. according to condition of
normalization, we have
+∞
∫ -∞
|ψ (x)|
n
2
dx = 1
| nπx 2
|
a
∫ 0
A sinsin (
a
) dx = 1
| nπx 2
|
a
A2 ∫ 0
sinsin (
a
) dx = 1
A2
[ ]
a
2nπx
2 ∫ 0
1- coscos
a
dx = 1
A2
(a) = 1
2
2
A=
a
Put the value of A in eqn. (10) the normalized wave function of the particle moving along a line
between x = 0 and x = a with zero potential energy, at points for which x ≤ 0 and x ≥ a, is given by
2 nπx
ψn(x) = sinsin ( ) …(11)
a a
Ques Explain the concept of Maxwell’s displacement current and show how it led to the
modification of the Ampere’s law?
Ques 5. Prove that the velocity of plane electromagnetic wave in vacuum is given by
c = 1/ (µ0ε0)1/2
where ɛ0 is the permittivity of free space, µ0 is the permeability of free space, ρ is the
charge density, and is the current density.
With three spatial components for each field, we have six separate wave equations.
However for plane waves propagating along , several of these wave equations vanish,
and we have
Ans 6. Poynting Vector: Poynting vector S is defined as the cross product of electric field
vector and magnetic field vector. The magnitude of Poynting vector represents the
electromagnetic energy passing through per unit area per unit time.
S=EXH
Statement: The time rate of E. M. energy within a certain volume plus the time rate of energy
flowing out through the boundary surface is equal to power transferred into the electromagnetic
field.
According to Maxwell’s equation
∂H
∇ X E = -μ0
∂t
------------1
∂E
∇ X H = J + ε0
∂t
-----------2
Take scalar product of H with equation 1 and E with equation 2.
∂H ∂ 1
H.(∇ X E) = -μ0H = - ( μ0H2)
∂t ∂t 2
----------------------------3
∂E ∂ 1
E.(∇ X H) = E.J + ε0E. = E.J + ( ε E2)
∂t ∂t 2 0
-----------------4
Subtracting equation 3 by equation 4
∂ 1 1
∇.( H X E) = E.J + ( ε E2 + μ0H2)
∂t 2 0 2
∂ 1 1
-∇.( E X H) = E.J + ( ε E2 + μ0H2)
∂t 2 0 2
Since E X H = S
∂ 1 1
-∇.S = E.J + ( ε E2 + μ0H2)
∂t 2 0 2
∂ 1 1
-E.J = ∇.S + ( ε0E2 + μ0H2)
∂t 2 2
--------------5
Using Gauss divergence theorem
∫ v
(∇.S)dv = ∫ A
S.dA
-----------------6
From equation 5 and equation 6
∂ 1 1
- ∫ (E.J)dv = ∫ S.dA +
∂t ∫ (
2
ε0E2 + μ0H2)dv
2
Ques7.Discuss the phenomena of interference of light due to thin films and find the
conditions of maxima and minima. Show that the interference patterns of reflected and
transmitted light are complementary.
Ans 7. Thin film of uniform thickness:
(a) Reflected Pattern: Let us consider a thin film of thickness t, refractive index µ and a ray AB of
monochromatic light of λ is falling on it at an angle i. This ray is partly reflected and partly refracted
as shown in Figure given below.
LKD = LNDE = r
BD=DK
Then path difference = µ(BD + DG) = µ(KD + DG)
= µ KG = µ KB cos r
Δ = 2 µt cos r
Now, here since reflection from denser medium is taking place by one ray so additional path
difference of λ/2 is taken into account. Thus the total path difference is
ΔT = 2 µt cos r – λ/2
2 µt cos r = (n + 1) λ
2 µt cos r = nλ n = 0, 1, 2
when cos r is kept constant and thickness increases gradually, the path difference becomes λ /2, λ,
3 λ /2, 2 λ, 5 λ /2, . . . and as a result the film will appear dark (t = 0), bright, dark and so on. On the
other hand if t is constant and r is varied we again get a series of maxima and minima.
(b) Transmitted Pattern: Here the path difference two rays DR and MS will be
Δ= µ (DE + EM) – DH
= 2 µt cos r …
In this case there will be no additional path difference so the total path difference
ΔT = 2 µt cos r
Δ = 2 µt cos r = nλ n = 0, 1, 2, 3, ….. .
We find that the conditions for maxima and minima are found in case of transmitted pattern are
opposite to those found in case of reflected pattern. Under the same conditions of the film looks
dark in reflected pattern it will look bright in transmitted pattern. Thus the interference patterns
of reflected and transmitted light are complementary.
Ques 8. Describe formation of Newton’s ring in reflected monochromatic light. Prove that in reflected
light, the diameters of the bright rings are proportional to the square root of odd natural numbers.
Ans 8. When a plano convex lens is placed on a plane glass plate, a wedge shaped film is
formed between the lower surface of the lens and upper surface of the glass plate. When a
monochromatic light beam is made to fall normally on this film and the film is observed in
reflected light alternate bright and dark rings are seen concentric round the point of contact of
the lens and the glass plate.
Figure shows the experimental arrangement of the same. Light beam from a monochromatic
source is allowed to fall on a glass plate inclined at an angle of 45° to the horizon. After
reflection from this plate light falls on the wedge shaped film formed between the lower surface
of the lens and upper surface of the glass plate from which light beam is again reflected. The
incident and reflected beams interfere to give bright and dark fringes which can be observed
with the help of a microscope.
λ
Path difference, δ = 2μtcoscos (r+θ) +
2
r=0
θ≈0
λ
Hence, Path difference, δ = 2μt +
2
For maxima, δ = nλ
λ
Therefore, 2μt + = nλ
2
Or,
λ
2μt = (2n-1) …………….. (1)
2
λ
For minima, δ = (2n-1)
2
Hence,
λ λ
2μt + = (2n-1)
2 2
2μt = nλ …………..(2)
Eqn. (1) and (2) are the conditions for bright and dark Newton’s rings.
Applying the theorem of chords for the chords OD and PQ in the adjacent figure:
NP×NQ = NO×ND
r×r = t×(2R-t)
Where r is the radius of the ring, t is the thickness of the film and R is the radius of curvature of
plano convex lens.
r2 = 2Rt - t2
r2 = 2Rt
r2
t= ……. (3)
2R
r2
2μ = nλ
2R
nλR
r n2 =
μ
Or,
4nλR
D n2 =
μ
4nλR
Dn = ………..(4)
μ
This shows that diameters of the dark rings are proportional to the square root of natural
numbers.
Ques 9 .Discuss Fraunhofer diffraction at single slit. Show that the relative intensities of the
successive maximum are nearly 1:4/9π2:4/25 π2:4/49π2 …………...
The diffracted beam is focused at the screen XY by convex lens. The diffraction pattern
consists of central bright band followed by alternate dark and bright bands of decreasing
intensity on either side of central maximum.
P – the point at which all the beams diffracted at an angle θ are focused.
Path difference between the rays emerging from extreme points of the slit
Δ = BN = ABsinsin θ = esinsin θ
2π
And corresponding phase difference = esinsin θ
λ
Let slit AB is divided into n equal parts, each part having same amplitude a, thus the phase
1 2π
difference between the two successive parts is δ = esinsin θ ………………(1)
n λ
Resultant amplitude
nδ
2
R=a
δ
2
R=a
sinsin (πesinsin
λ
θ
)
(πesinsin
nλ
θ
)
sinsin α
R=a
()
α
n
πesinsin θ
where = α ……………(2), and If n → ∞, a →0 and na = A (finite)
λ
sinsin α sinsin α
R = na =A ……………(3)
α α
( )
2
sinsin α
I = R2 = A ……………(4) I varies with α.
α
R=A
sinsin α A
α
=
α [
α3 α5 α7 α2 α4 α6
α- + - + …………… = A 1- + - + ……………
3! 5! 7! 3! 5! 7! ] [ ]
πesinsin θ
R is maximum if the negative terms vanish in the above eqn i.e. α = 0 or = 0 or θ = 0
λ
πesinsin θ
= ± mπ
λ
The values of m gives the directions of first, second, third …………….order minima
y= α and y = tantan α
3π 5π 7π
The points of intersections are α = 0, ± , ± , ± , ……….
2 2 2
( )=A
2
sinsin α 2
For Principal maxima, α = 0, Io = A
α
[ ( )
]
2
3π
sinsin ±
( )
2
3π sinsin α 2 4 A2
For Ist secondary maxima, α = ± , I1 = A = A = =
2 α 3π 9 π2
±
2
A2 I
= o
22 22
[ ( )
]
2
5π
sinsin ±
( )
2
5π sinsin α 2 4 A2
For IInd secondary maxima, α = ± , I2 = A = A = =
2 α 5π 25 π2
±
2
A2 I
= o
62 62
[ ( )
]
2
7π
sinsin ±
( )
2
7π sinsin α 2 4 A2
For IIrd secondary maxima, α = ± , I3 = A = A = =
2 α 7π 49 π2
±
2
A2 I
= o
112 121
4 A2 4 A2 4 A2
Io : I1 : I2 : I3 :……………… = 1 : : : :……………
9 π2 25 π2 49 π2
Ques 10. What do you mean by resolving power of grating? Explain Rayleigh criterion of
resolution. Derive an expression for resolving power of grating.
Statement: Two sources are resolvable by an optical instrument when the central
maximum of one diffraction pattern falls over the first minimum of the other diffraction
pattern and vice versa.
The resolving Power of a diffraction grating represents its ability to form separate
spectral θ lines for wavelengths very close together
Derivation
Let the first minima adjacent to the nth maxima be formed in the direction . Then form the
grating equation of minima, we have
Clearly the first minima adjacent to nth principal maxima in direction increasing will be obtained
if m = nN + 1.
According to Rayleigh’s criterion, two spectral lines of wavelength λ and λ + dλ are just resolved
when nth maxima of wavelength λ + dλ falls on first minima of wavelength λ + dλ adjacent to its
nth maxim. For nth maxima of wavelength λ, we have
Ques 11 What are the requirements for producing laser action? Describe the
construction and working of Ruby laser. What are the drawbacks of Ruby laser?
1. The number of atoms in the higher (excited) energy state must be greater than in lower (ground)
state
(i.e., N2 > N1). The process of achieving a large number of atoms in excited state than ground state
is called “Population Inversion” and the process by which population inversion is achieved is
called “Pumping”.
2. The energy density of stimulated radiation must be large, this makes P21(stim) > P12 (spont) i.e.,
1.Active material: A rod of ruby crystal acts as the active material. Ruby is actually Al2O3 crystal
with 5 % impurity of Cr2O3 which gives it a pink color.
2. Resonant cavity: One end of the ruby rod is made fully reflecting while the other end is
partially reflecting. This is called resonant cavity.
4. Cooling system: Cooling arrangement is done in which water circulates in the glass tube
enclosing the ruby crystal.
Working:
Ruby laser is a three-level system containing energy levels E1, E2 and E3. When a flash is
produced in the xenon tube atoms in energy level E1 are raised to energy level E3 through optical
pumping. E3 is a short-lived state having lifetime 10-8s. So atoms from this state immediately
drop to energy level E2 which is a metastable state. Atoms stay here for a longer time (10-3s). So
population inversion is achieved between E1 and E2. When atoms drop from E2 to E1 they emit
photons of energy E2-E1. These photons keep on reflecting inside the resonant cavity. When the
beam of photons becomes intense enough it escapes the partially reflecting end of the ruby
crystal. Thus a pulse of laser beam is obtained.
3. The laser output is not continuous but occurs in the form of pulses of microsecond
duration.
4. The defects due to crystalline imperfection are also present in ruby laser.
Ques 12. Draw a neat diagram of He-Ne Laser and explain its construction and working.
How is it superior to a Ruby Laser?
Ans 12 Construction of He Ne laser -Helium neon laser used a mixture of 10:1 for its
active medium. It consists of a long and narrow discharge tube of diameter of about 1
cm and about 80 cm long. The mixture is at a pressure of about 1 mm of Hg, the partial
pressure of helium gas being 5 to 10 times that of neon.
Active medium: The gas mixture of He and Ne forms the active medium. Ne act
as active center.
Optical resonator system: A set of mirrors form the optical resonator system.
Working
Working: The laser process in a HeNe laser starts with the collision of electrons from the
electrical discharge with the helium atoms in the gas. This excites helium from the ground state
to a long-lived, metastable excited state. These excited helium atoms then collide with the
ground-state neon atoms, producing excited neon atoms. The number of neon atoms entering
the excited states builds up until population inversion is achieved. Spontaneous and stimulated
emission between the states results in emission of 632.82 nm wavelength light, along with
other emission wavelengths (see figure at right). From these states, the electrons quickly decay
to the ground state. The HeNe laser's power output is limited because the neon upper level
saturates with higher current, while the lower level varies linearly with current.
Helium neon laser is better than ruby laser or most of the four level lasers are better than three
level lasers due to the following reasons:
● The laser output is continuous in the case of helium-neon laser. But it is in the form of
pulse in the ruby laser.
● Ruby laser requires high power pumping source, whereas Helium-neon laser requires low
power pumping source like electric discharge.
● Efficiency of helium-neon laser is more than ruby laser.
● The defects due to crystalline imperfections are also present in the ruby laser. But it is
not so in the helium-neon laser.
Ques 13 What is the propagation mechanism of light inside optical fiber? Explain
acceptance angle and acceptance cone of an optical fiber. What do you mean by numerical
aperture? Derive expression for them .
Ans 13. Propagation of Light in optical fiber
The light in the fiber is guided inside the core of the fibre by the principle of TIR, for this
The following condition must satisfy
1. The refractive index of core, n1 must be greater than the refractive index of the
cladding, n2.
2. At the core-cladding interface the angle of incidence, φ must be grater than the
critical angle defined by
Let us consider that the light is launched from medium of refractive index no and is
incident at an angle θi with respect to the axis. The light undergoes refraction at A. The
ray refracts into the core of fibre at angle ( > ).The ray reaches to core-cladding
interface at B. At B if the angle of incidence φ is greater than the critical angle the light
ray will suffer TIR and reach at D. At D again the ray suffers TIR, thus this ray will stay
within the fibre. Thus in a MMSIF the light follows a zig-zag path.
Snells Law at the launching end of the fibre,
At ;
as then
Generally the light is launched in air, i.e., no = 1
Acceptance Cone: In three dimensions, the ray within the acceptance angle will be
guided in the core of the fibre forms a cone. It is .
The numerical aperture determines the light gathering ability of the fibre. It measures
the amount of light accepted by the fibre.
Fractional Index Difference: It is the ratio of the difference in the refractive index of
core and cladding with respect to refractive index of core.
and
Therefore
Ques 14. What do you understand by attenuation in optical fibre? Discuss the important factors
responsible for loss of power in optical fibre. What are the advantages of optical fiber over copper
wires?
Ans 14. Attenuation in an optical fiber is caused by absorption, scattering, and bending
losses. Attenuation is the loss of optical power as light travels along the fiber. Signal attenuation is
defined as the ratio of optical input power (Pi) to the optical output power (Po). Optical input
power is the power injected into the fiber from an optical source.The following equation defines
signal attenuation as a unit of length:
i. absorption
ii. scattering
iii. bending losses.
ABSORPTION. - Absorption is a major cause of signal loss in an optical fiber. Absorption is
defined as the portion of attenuation resulting from the conversion of optical power into another
energy form, such as heat. Absorption in optical fibers is explained by three factors:
Imperfections in the atomic structure induce absorption by the presence of missing molecules
or oxygen defects. Absorption is also induced by the diffusion of hydrogen molecules into the
glass fiber. Since intrinsic and extrinsic material properties are the main cause of absorption,
they are discussed further.
Intrinsic absorption in the ultraviolet region is caused by electronic absorption bands. Basically,
absorption occurs when a light particle (photon) interacts with an electron and excites it to a
higher energy level.
Extrinsic Absorption. - Extrinsic absorption is caused by impurities introduced into the fiber
material. Trace metal impurities, such as iron, nickel, and chromium, are introduced into the
fiber during fabrication. Extrinsic absorption is caused by the electronic transition of these
metal ions from one energy level to another.
Extrinsic absorption also occurs when hydroxyl ions (OH-) are introduced into the fiber. Water in
silica glass forms a silicon-hydroxyl (Si-OH) bond. The amount of water (OH-) impurities present
in a fiber should be less than a few parts per billion. Fiber attenuation caused by extrinsic
absorption is affected by the level of impurities (OH-) present in the fiber. If the amount of
impurities in a fiber is reduced, then fiber attenuation is reduced.
SCATTERING. - Basically, scattering losses are caused by the interaction of light with density
fluctuations within a fiber. Density changes are produced when optical fibers are manufactured.
During manufacturing, regions of higher and lower molecular density areas, relative to the
average density of the fiber, are created. Light traveling through the fiber interacts with the
density areas as shown in figure. Light is then partially scattered in all directions.
The main source of loss is called Rayleigh scattering. Rayleigh scattering is the main loss
mechanism between the ultraviolet and infrared regions. Loss caused by Rayleigh scattering is
proportional to the fourth power of the wavelength (1/&λ4). As the wavelength increases, the
loss caused by Rayleigh scattering decreases.
If the size of the defect is greater than one-tenth of the wavelength of light, the scattering
mechanism is called Mie scattering. Mie scattering, caused by these large defects in the fiber
core, scatters light out of the fiber core. However, in commercial fibers, the effects of Mie
scattering are insignificant. Optical fibers are manufactured with very few large defects.
BENDING LOSS. - Bending the fiber also causes attenuation. Bending loss is classified
according to the bend radius of curvature: microbend loss or macrobend loss.
Microbends are small microscopic bends of the fiber axis that occur mainly when a fiber is
cabled. Macrobends are bends having a large radius of curvature relative to the fiber diameter.
Microbend and macrobend losses are very important loss mechanisms. Fiber loss caused by
microbending can still occur even if the fiber is cabled correctly. During installation, if fibers are
bent too sharply, macrobend losses will occur.
Ques 15 How does the magnetization vary with applied magnetic field in type I type II
superconductors? Mention a few applications of superconductors.
b) The state between the lower critical magnetic field (Hc1) and upper critical magnetic
field (Hc2) is known as vortex state or intermediate state.
After Hc2, the Type II superconductor will become a conductor.
c) Type II superconductors are also known as hard superconductors because of this
reason that is they lose their superconductivity gradually but not easily.
Applications of Superconductors
Ques 16 What is the Meissner effect in superconductors? Explain how the Meissner
effect proves that superconductors are perfect diamagnet.
Ans 16
Since diamagnetic materials have negative susceptibility therefore in superconducting state
material behaves as ideal diamagnet.
Ques 17 What are nanomaterials? Discuss top down and bottom up approaches in fabrication
of nanomaterials.Explain Chemical vapour deposition and Sol gel technique for synthesis of
nanomaterials.
Ans 17 There are two general approaches for the synthesis of nanomaterials as shown in figure:
Top-down approach:
Top-down approach involves the breaking down of the bulk material into nanosized
structures or particles.
Top-down synthesis techniques are extension of those that have been used for
producing micron sized particles.
Top-down approaches are inherently simpler and depend either on removal or division of
bulk material or on miniaturization of bulk fabrication processes to produce the desired
structure with appropriate properties.
The biggest problem with the top-down approach is the imperfection of surface
structure. For example, nanowires made by lithography are not smooth and may contain
a lot of impurities and structural defects on its surface. Examples of such techniques
are high-energy wet ball milling, electron beam lithography, atomic force manipulation,
gas-phase condensation, aerosol spray, etc.
Bottom-up approach:
The alternative approach, which has the potential of creating less waste and hence the
more economical, is the ‘bottom- up’.
Bottom-up approach refers to the build up of a material from the bottom: atom-by-atom,
molecule-by-molecule, or cluster-by cluster.
Many of these techniques are still under development or are just beginning to be used
for commercial production of nanopowders.
Oraganometallic chemical route, revere-micelle route, sol-gel synthesis, colloidal
precipitation, hydrothermal synthesis, template assisted sol-gel, electrodeposition etc,
are some of the well- known bottom–up techniques reported for the preparation of
luminescent nanoparticals.
Q.18 Discuss Chemical vapour deposition and Sol gel technique for synthesis of
nanomaterials.
A.18
The basis of the sol-gel method is the production of a homogeneous sol from the precursors
and its conversion into a gel. The solvent in the gel is then removed from the gel structure and
the remaining gel is dried. The properties of the dried gel depend significantly on the drying
method. In other words, the “removing solvent method” is selected according to the application
in which the gel will be used. Dried gels in various ways are used in industries such as surface
coating, building insulation, and the production of special clothing. It is worth mentioning that,
by grinding the gel by special mills, it is possible to achieve nanoparticles.
.