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Assignment 5

The document contains a series of thermochemistry problems and their solutions, focusing on calculations of enthalpy changes for various chemical reactions and processes. Key calculations include enthalpy of oxidation, combustion, and formation for different compounds, with specific values provided for each scenario. The document serves as an assignment for board-level students to practice and apply thermochemical principles.

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namanbarnwal27
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2 views

Assignment 5

The document contains a series of thermochemistry problems and their solutions, focusing on calculations of enthalpy changes for various chemical reactions and processes. Key calculations include enthalpy of oxidation, combustion, and formation for different compounds, with specific values provided for each scenario. The document serves as an assignment for board-level students to practice and apply thermochemical principles.

Uploaded by

namanbarnwal27
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Thermo chemistry

Assignment -5

Board level

______________________________________________________________

1. 1.25 g of an organic compound (molar mass 114 amu) on oxidation in bomb


calorimeter increases the temperature from 300 K to 306.73 K. The heat
capacity of the calorimeter is 8.93 kJ/K. Calculate the enthalpy of oxidation of
organic compound.
Ans- 5481 kj/mol
2. Calculate the standard enthalpy change (∆H°) and standard energy change
(∆U°) for the reaction.
OF2 (g) + H2O (g) −−→ O2 (g) + 2HF (g)
∆fH° of OF2 (g), H2O (g) and HF (g) are +23.0, -241.8 and
-268.6 kJ/mol respectively. Ans- -320.88 kj
3. The standard enthalpies of formation of CH4, CO2 and H2O are -74.8, -393.5
and -285.8 kJ/mol respectively. Calculate the enthalpy of combustion of CH4.
Ans- -890.3 kj
4. Calculate the internal energy change at 25℃
2 H2O2 (l) − − −→ 2 H2O (l) + O2 (g)
∆fH° for H2O2 and H2O are -188 and -286 kJ/mol.
Ans- -198.48
5. Molar heat of formation of NH4 NO3, N2O and H2O are -367.54, 81.46 and -
285.8kJ/mol at 25℃ and 1 atm pressure. Calculate ∆U for the reaction.
NH4 NO3 (s) −−→ N2O (g) + 2H2O (l)
Ans- -125.08
6. Heat of formation of C2H4 at constant pressure and at 17℃ is -2710 cal.
Calculate heat of formation at constant volume.
Ans- -2130 cal

7. Calculate the standard enthalpy change for the reaction:


SO2 (g) + 2 H2S (g) − − −→ 3 S (g) + 2 H2O (l)
∆f H° for SO2, H2S and H2O is -295.7, -20.2 and -286.7kJ/mol.
Ans- -237.3 kj
8. Enthalpy of formation of NH3 and H2O are -46 and -286.6 kJ/mol. Calculate
the enthalpy of combustion of NH3 at 25℃.
Ans- -383.9 kj
9. Enthalpies of formation of benzene, water and CO2 at 25℃ are +49, -286 and
-393kJ/mol. Calculate the enthalpy of combustion of benzene.
Ans- -3265 kj
10. Calculate the enthalpy of formation of acetic acid if its enthalpy of
combustion is -867 kJ/mol. Enthalpy of formation of CO2 and H2O are -393.5
and -285.9 kJ/mol.
Ans- -491.8 kj
11. For the reaction Zn + 2H+ = Zn2+ + H2 (g) the value of ∆H is -154.4 kJ/mol.
Due to the formation of 1 mole H2 gas, system expands to 22.4 litre at 1 atm
pressure, calculate ∆U.
Ans- -156.67
12. Heat of formation of CO2, H2O and glucose is -393.5, -286 and -1169.3
kJ/mol. Calculate the heat of combustion of glucose.
Ans- -2907.7 kj/mol
13. The standard molar heats of formation for C2H6, CO2 and H2O are -21.1, -
94.1 and -68.3 kcal respectively. Calculate the standard molar heat of
combustion of ethane.
Ans- -372 kcal/mole
14. Enthalpy of combustion of benzene is -3267 kJ. Enthalpy of formation of
CO2 and H2O are -393.5 kJ and -286 kJ. Calculate the enthalpy of formation of
benzene.
Ans- -48 kJ
15. Enthalpy of formation of CH3COOH , CO2 and H2O is -491.8, -393.5 and -
285.9 kJ/mol. Calculate the enthalpy of combustion of CH3COOH.
Ans- -867 kj
16. Heat produced by the combustion of 1.0 g benzene in bomb calorimeter is
41.8 kJ at 298 K. What is the enthalpy of combustion of benzene?
Ans- -3264.1 kj
17. 4 Fe + 3O2 −−→ 2 Fe2O3. Enthalpy of formation of Fe2O3 is -825kJ/mol.
What is the enthalpy change for the above reaction?
Ans- -1650 kj
18. ∆f H° for CO2 ,CO and H2O is -393.5, -110.5 and -241.8 kJ/mol
respectively. Calculate the enthalpy change for the reaction CO2 + H2 = CO +
H2O.
Ans- 41.2 kj
19. 2 A2 (g) +5 B2 (g) = 2 A2B5 (g). For this reaction heat change at constant
volume is - 37.689 kJ at 27℃.Calculate ∆H°.
Ans- -50.16 kj
20. C2H4 on combustion gives CO2 and H2O. Enthalpies of formation of CO2,
H2O and C2H4 are -393.5, -241.8 and +52.3 kJ/mol. Calculate the enthalpy of
combustion of C2H4.
Ans- -1322.9 kj/mol
21. The heats of formation of carbon dioxide and sulphur dioxide are -394.55 kJ
and -297.06 kJ respectively. The heat of combustion of carbon disulphide is -
1071.52 kJ. Calculate the heat of formation of carbon disulphide.
Ans 82.85 kj
22. Proceeding from the heat of formation of gaseous carbon dioxide (∆f H° = -
393.5 kJ mol-1) and the thermochemical equation :
C (Graphite) +2 N2O (g) − − −→ CO2 (g) + 2 N2 (g),
∆H°= —-557.5 kJ. Calculate the heat of formation of N2O (g).
Ans- 82 kj/mol

23. Calculate the heat of transition for diamond to graphite. Given that :
CDiamond + O2 − − −→ CO2, ∆H = -94.3 kcal
CGraphite + O2 − − −→ CO2, ∆H = -97.6 kcal
Also calculate the heat required to change one gram diamond to one gram
graphite. Ans- 0.275 kcal
24. Enthalpy of combustion of C, H2 and C2H6 is -394, -286 and -1560 kJ.
Enthalpy of formation of C2H2 is 227 kJ. Calculate the enthalpy change for the
hydrogenation of C2H2 to C2H6. Ans- -313 kj
25. When 2 moles of C2H6 are completely burnt, 3129 kJ of heat is liberated.
Calculate the heat of formation of C2H6 given that ∆f H for CO2 and H2O is -395
and -286 respectively. Ans- -83.5 kj
26. Heats of combustion of C2H4, C2H6 and H2 are -1409.5, -1558.3 and -285.6
kJ respectively. Calculate the heat of hydrogenation of ethylene.
Ans- -136.8 kj
27. Enthalpy of combustion of graphite, H2 and ethanol is -94 kcal, -68.4 kcal
and -327 kcal. Calculate the enthalpy of formation of ethanol.
Ans- -66.2 kcal
28. Enthalpy of combustion of graphite, H2 and sucrose (C12 H22O11) is -94, -
68.4 and -1349 kcal/mol respectively. Calculate the enthalpy of formation of
sucrose. Ans- -531.4 kcal
29. Enthalpy of combustion of acetic acid is -867 kJ/mol. Enthalpy of formation
of CO2 and H2O is -393.5 and -285.9 kJ/mol respectively. Calculate the
enthalpy of formation of acetic acid.
Ans- -491.8 kj
30. The combustion of one mole of benzene takes place at 298 K and 1 atm.
After combustion, CO2 (g) and H2O (l) are produced and 3267.0 kJ of heat is
liberated. Calculate the standard enthalpy of formation ∆fH°of benzene.
Standard enthalpies of formation of CO2 (g) and H2O (l) are -393.5kJ mol-1 and
-285.83 kJ mol-1 respectively.
Ans- 48.51 kj/mol

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