5 Sample Paper

Solved

CHEMISTRY
Time Allowed: 3 hours
Maximum Marks: 70
General Instructions: Same instruction as given in Sample Paper 1.

SECTION - A 16 Marks
(The following questions are multiple-choice questions with one correct answer.
Each question carries 1 mark. There is no internal choice in this section,)

1. ldentify the correct order of decreasing 5. IEj of Nis greater than O due to:
stability of the following cations?
) CHg-CH - CH,
2500
(10) CHg -CH - OCH3 mol')
AH(KJ
Ne
(uI) CH3 -CH - CH, - OCH3 2000 (2080)
Options: F
(1681)
(a) (1) > ()> () (b) (1) > (u) > ) 1500
(1402)
(c) (u) > )> () (d) () > () > (1) 1
Be
(1314)
2. ldentify the INCORRECT statement. 1000 (899) C

(a) 2-Perntanone can exhibit tautomerism. (1086)

L B
(b) Tropolone is a non-benzenoid aromatic (520) (801)
500
compound. 2 4 6 8 10
(c) Naphthalene and benzoic acid can be Atomic number (Z)
separated using sublimation.
(d) None of these. 1 (a) half-filled 2p orbitals in N
(b) fully filled 2p orbitals
3. Choose the correct statement.
(c) empty 2p orbitals of N
(a) The correct bond angle order is 1
H,0> NHg > CO, > CH4 (d) fully filled 2p orbitals of O
(b) Be, Ca* and Cl are isoelectronicspecies 6. For the reaction A+ 2B C+D, the equilibrium
(c) CF4 and SF4 has same shape constant K, is 0.10 at a certain temperature.
(d) The C molecules has only -bonds If the concentration of A at equilibrium is
according to MOT 1 0.2 M, the concentration of B is 0.3 M and
the concentration of D is 0.018, what is the
4. Which of the following elements does not
show disproportionation tendency? concentration of Cat equilibrium?
(b) Br (a) 0.05 M (b) 0.10 M
(a) Cl 1
(c) F (d) I 1 (c) 0.15 M (d) 0.20 M

44 EduCart Chemistry Class XI

 work function of
the metal 11. The judge in the court suspected that the
the 101s- document has some changes. To check that,
thresholdfrequencyis 5.2
is
What
7 whose the judge asked the forensic department to
check the ink used at two different places.
10-20J
10-19 (b) 3.44 x Which technique is suitable to detect?
344* (a) Distillation
(a) 10-20J 1
(c) 2.59 10-19) () 2.59 x (b) Solvent extraction

(P) on
alcohol
dehydration gives an (c) Column chromatography
1
An Alkene( ) on ozonolysis
gives (a) Thin-layer chromatography
8. alkene(). AL
acetaldehyde and one
molecule of 12. In an electrophilic substitution reaction of
name of (P) nitrobenzene, the presence of nitro group:
one
of acetone. TheIUPAC
molecule
() deactivates the ring by an inductive effect
is:
(a)2-butanol () activates the ring by an inductive effect
at ortho
(U) decreases the charge densityrelative
()2-pentonol and para position of the ring to
(c) 3-methyl-2-butanol meta position by resonance
() 2-methyl-2-butano. 1 (IV)increases the charge density at meta
para
position relative to the ortho and
Column-l with Column-l position of the ring by resonance.
Q. Matchthe
Column-I
Column-ll Options:
(b) () and (I)
(a) Only )
(d) only (i) 1
(c) () and (11i)
A2NH3g) N20) +3H2(9) ) RT statements labelled as
Given below are two most
Select the
H + lh 2HI |0) Kp =Kc(RT) Assertion (A) and Reason (R).
givenbelow:
(B) appropriate answer from the options correct
true and (R) is the
CGHsg)|() Kp =Kc (a) Both (A)and (R) are
()CzH29) +H2g) explanation of (A).
the
are true but (R) is not
Kc (b) Both (A) and (R)
(D CoCO36) CaOs) |() correct explanation of (A).
RT
+ CO29) is false.
(c) (A) is true but (R)
true.
(d) (A) is false but (R) is
of CCl,
Options: 13. Assertion (A): Dipole moment
(M), (D) - ()
(a) (A) - ),(B)- (I), (C) - (D) - ()
molecule is zero.
- (), Symmetrical species even
(b) (A) - ), (B) - (), (C) Reason (R): has zero
(),(D)- ) with polar bonds
() (A)- (u),(B) - (), (C) - 1 dipole moment. 1
(C) - ),(D) - (V)
(0 (A)-(),(B) - (), nitric
represented in the Assertion (A): The conjugate base of
10. ldentify the law which is 14. acid is N03.
graph. Conjugate base of a strong
Reason (R): strong. 1
acid is also very
Potential
Energy
(k) 4H,+4H, is impossible to determine
15. Assertion (A): It
the exact position and exact
electron
+
4H, momentum of an
=
4H, simultaneously.
electron in an
Step 3 Reason (R): The path ofan 1
defined.
atom is clearly
Significant figures for 0.200
Step1 16. Assertion (A): for 200 it is 1.
is 3 whereas
Step2 or right of
AH, Reason (R): Zero at the end significant
are
a number they are not
provided that
side of the
Reaction Coordinate on the right 1
(b)Newton's law decimalpoint.
(a) Kerb's law 1
(d)Hess's law 45
(c) Ohm's law Sample Paper5
 SECTION - B 10 Mark 28. An
(This section contains 5 questions with internal choice in two questions. (A)
The following questions are verus short answer type and carry 2 marks each)
17. Arrange the following elements according to
thermometer
property given in brockets: (Any two)
to sink
(A) NO, F, Cl (Oxidising property)
condenser
(B) B, Mg, K, Al (Metalic character) RB. flask
(C) Be, B, C, Li (Melting Point) 2 water
inlet
18. Give reason:
29.
liquid
(A) The shape of water should be substance
tetrahedral but it is found to be angular
or bent shape. (A) Which process is shown in the given
image. What is its principle?
(B) The H-O-H bond angle in water is (B) Name any mixture which can be
separated using the above technique. 2
reduced to 104.5° from 109.5°. 2
20. What is the major product formed when
19. Establish a procedure for converting: ethene reacts with bromine water?

(A) Phenol to benzene 21. What willbe the wavelength of the spectral
ine obtained in the spectrum of Li* ion
(B) Sodium acetate to methane when the transition takes place between
two levels whose sum (i.e., nË + n) is 4 and
difference (i.e., n1- n) is 2. 2
OR (A) 1.3 x 10-8 (B) 2.5 x 10-8
(C) 1.5 x 10-8 (D) 3x 10-8
On the basis of given image, answer the
Justify you answer with complete
questions that follows: calculation.

SECTION -C 21 Marks
(This section contains 7 guestions with internal choice in one question.
The following questions are short answer type and carry 3 marks each.)
22. (A What do you understand by (B) On moving from top to bottom in
disproportionation reaction? group, the ionisation enthalpy
decreases.
(B) MnO, undergoes disproportionation
reaction in acidic medium but MnO, 25. Inthe given reactions, identify Xand Y:
does not. Give reason. 3 (A) CH3CH,OH + Conc. H,SO4’ X+ H,0
(B) CH3CH = CHCH3 + KMnO4 + H*’Y 3
23. (A) The entropy change in the conversion of
water to ice at 272 K for the system is 26. Calculate average atomic mass of hydrogen
-21.85 JKmol and that of surrounding using the following data:
is +21.93 JKmol. State whether the
process is spontaneous or not? Natural
lsotope Abundance %
Molar mass
B) Answer the following questions in one
sentence. H 99.985
e What are the conditions for the
spontaneous reaction under any 0.015 2
temperature? 27. Aphoton with wavelength 200 nm strikes
() Considering system(s) thermody
criteria the metal surface, if the work function of the
namic parameters give the metal is 3.5 eV.
for the spontaneity of any, process. 3 Then calculate:
24. Give reason: (A) energy of the photon (in e)
periodic
(A) On moving from left to right in a element (B) kinetic energy of the emission
table, the electronegativity of (C) the velocity of the photoelectron.
 questions: OR
thefollowingtitration with different
Answer
performs a titer values of 25.2 (A) Why are atomic masses the average
28. Riya found values? Give two examples.
(A)burettesand and 25.0 mL. What is
25.25 mL based upon the (B) 0.3475 g of an organic compound gave
mL, average titer value on combustion 0.4950 g of CO, and
rounding
the offprinciple?
massof 0.2025 g of H,0. Calculate the %of Cand
Calculatethe magnesiunm H in it. 3
B) atomsof
n 2.5gatomofS.
G) 1.5g 8 Marks
SECTION -D
are case-based questions. Each
question has an internal choice and
questions the questions that follow,)
(The
following
marks each. Read the passage carefully and answer
s4(1+1+2) substitution reactions under certain conditions.
carries frequently used to
effect is Ozonolysis and Oxidation reactions are also
Commonion average. H,O)
29, Compounds with high
purity
chloride ic vividly displayed. HX (HBr, HBr, HI, and addition
sodium and alkenes undergo two types of
get
Saturated solution of Concentration of reactions: Markovnikov and anti-Markovnikov.
A increased
precipitated due to dissociation of The MarkovnikoV reaction
occurs when HX is
availatble from the with H-bonding
chlorideion make the Sodium chloride of added to an alkene or alkyne,substituted carbon
H whichhelp to to the double bond's less
the other double
greaterpurity. helps to finish atom and X bonding toan ionic mechanism.
ion effect also bonded carbon atom via
The common as sparinglu H,O) is introduced
When HBr (not HCL, HÊ, orattaches to the less
particular ion precipitated solubilitu
the with very low value of to an alkene or alkyne,
Br
carbon, whereas H
soluble water,
gravimetric estimation. Thus. we substituted double-bonded
product for chloride atom, resulting in the
silver ion as silver
as links to the other carbon
can precipitate hydroxide and barium ion anti-markovnikov reaction.
ferric ion as its
quantitative estimation,
The product in the given
(A) What is the major
its sulphate forsolute a particular solvent reaction?
solubility of a concentration that mau be ’P
maximum CH -CH= CH, + HBr
is the given conditions when the (a) 2-Bromopropane
achieved under equilibrium. When a (b) 1, 2-Dibromopropane
dissolution process is atequal to its solubility, (c) 1-Bromopropane
is
solute's Concentration be saturated with that above
1
solution is said to (d) None ofthe
the effect ofcommon reaction:
few uses or in the given
solute. Here are given below:
solubility (B) ldentify Xand Y
ion effect on CH = CH Nal, X
water fromaquifers Y: But-2-yne
"Toobtain drinking (a) X: CH = CNa*,
CNat, Y. Propyne
" In the treatment
of water (b) X: CHa-CH = Y: Propyne
(c) X: CH = CNa,
CNat, : But-2-yne
" Salting out ofsoaps depending () X: CHg-CH=
(A) Differentiate the solutions 1
solubility ofthe salt. OR
upon the is it given reaction:
What is salting out of soap? How (B) ldentify X
and Yin the
(B) effect? X+Y
achieved by common ion 2-Methyl pent-2-ene
OR Y: Propanone
(a) X: Propanal,Y: Butanone
B) Give reason: NaOH (b) X: Butanal, Y: Butanone
soluble in aqueous (c) X:
Propanal, 1
CO, is more 1
Butanal, Y: Propanone
than in water. (d) X: productin the
solubility of PbBr is would be the major
following reaction
() The molar (C) What figure, if the
certain temperature.
2.17 x 1o3 M at a 2 given Markovnikovrule?
obeys
Calculate Ksp for PbBr2.
weakly held
30. are made up of a lot of
Akenes They displau gddition reactions
due
* bonds. Electrophiles Br
such bonds.
ne presence of added to the CH,-C=ChH
species) are CH-CH=CHBr 2
(Electron-seeking
molecules in
this reaction,
double-bonded production product.
of a new radical
resultingin the free
undertake 47
It also has the ability tto Sample Paper 5
 SECTION -E 15 Marka
(The following questions are long answer type and carry 5marks each.
All questions have an internal choice)
31. Answer the following questions: (B) Calculate the H,for the given reaction
Give IUPAC of the given compound CgHeg) +502(9) ’ 3CO2(9) 4H,0
Given: B.E. (C- C) = 347 kJ/mol
B.E. (C- H) = 414 kJ/mol
B.E. (C - O) = 741 kJ/mol
(B) Write the number of o and bond in B.E. (0- O) = 498 kJ/mol
pent-2-en-4-yne. B.E. (0- H) = 464 kJ/mol
(C) Observe the given data and answer the OR
question that follows:
(A) Derive an expression for an isothermal
Alkane Boiling point (in K) expansion of an ideal gas during o
CH4 111.0 reversible, irreversible and an adiabatir
processes?
CaH1o 272.4
(B) A0.5 moles of gas at temperature 300K
CH16 371.4
expands isothermally from an initial
CioH22 447.1 volume of 2L to 6L then what is the
Why on increasing the number of carbon work done by the gas?
atoms, the boiling point of the alkane is 33. (A) What is a dipole moment? Write its
increasing?
significance.
(D) Out of the given compounds, identify the
benzenoid and non-benzenoid aromatic (B) Observe the given data and answer the
compournds: question that follows:

Molecule Dipole Moment

HBr 0.79

() Give resonating structures of phenol. NH3 1.47

OR NF3 0.23
(A) Give reason why SO3 act as an CCl4
electrophile.
NE, has lower dipole moment than NH3
(B) Arrange the following carbocation in though fuorine is more electronegative
increasing order of stability:
than hydrogen, Give reason.
(CH3),C, CHg, (CH3)2CH, CH,CH;
() Why water is not used in paper OR
5
chromatography.
(A) Write the postulates of VSEPR theory.
32. (A) Answer the following giving reason:
(B) Arrange the following in increasing
0 Does first law of thermodynamics order of bond angle:
apply welon human body?
NO; SiF4 PH3
) qand w are not state function but 5
) (0) ()
(q + w) is a state function.
 Sample Paper
6 self-Assessment
CHEMISTRY
hous
Maximum Marks: 70
AMood3
Time

Instructions:: Same instructions as givenin Sample Paper 1.

General.
SECTION -A 16 Marks

questionsare multiple-choice questions with one correct answer.

(Thefollowing carries 1 mark. There is no internalchoice in this section)
Eoch question
that methane 5. The reduction potential of elements M,
researching scientists find interacting N and O are +2.46 V, -1.13 V, and -3.13 V
1, On also form hydrates on respectively. Based on these values find out
onn high pressure and low the correct order regarding their reducing
under
with water conditions. If they take 1 mole
temperature many property?
methane for reaction then, how molecule (a) 0>N> M (b) M>0>N
of hydrogen this
arom atoms of (c) M>N>0 (d) O> M> N 1
contains?
atoms of hydrogen. 6. Which of the following graphs is incorrect?
(a) It contains 4g hydrogen. and
(6) It contains 3 g
atoms of
hydrogen. (Where v= velocity, Z = atomic number
atoms of
(c) t contains 6.022 x 10 atoms ofcarbon. 1 n= number of shel)
x 104 (b)
(d) It contains 1.83 (a)
expands from a volume of1.0 Lto 3.0 L V
2. Agas external pressure of 2.0
against a constant
volume is accompanied
atm. The change in 100J of heat from the
by an absorption of done by the 1/n
surroundings. What isthe work
gas during this process?
n

(b)300 J (d)
(a) 200 J 1 (c)
(d) 500J
(c) 400J
orbital
path of electron in
3. "The exact determined." is
This statement
cannot be
based upon:
(a) Aufbau principle 1
(6) Heisenberg's uncertointy principle
(c) Hund's rule 1 with column-ll.
(4) Pauli exclusion principle Match the column-l Column-ll
7.
Fahrenheit Column-! (Species)
measured temperature on
be on
reading (Hybridisation)
Scale is 200°F. What will this (1) MnO,
the celsius scale? P)sp°d
) 40°c (b) 94°C
(c) 93.3°C (d) 30°C SamplePaper6
87
Date

(a) 3-Methylbutanoic acid

(2) PCl, (b) Pentanoic acid
() dsp?
(c) 2-Methylbutanoic acid
(R) s (3) ICL,
acid
(S) sp'? (4) [Ni(CN)j? () 2-Methyl Pentanoic
12. The given reaction is an example o6
Options:
+ C,AlCI
R

(a) (2) (4) (3) (1) (a) Nucleophilic aromatic substitutias

(3) (b) Electrophilicaromatic substitutio
(b) (2) (4) (1)
(c) Free radical mechanism
(c) (1) (3) (2) (4) (d) Nucleophilic addition
1
(d) (1) (3) (4) (2) 1 Given below are two statements labellaa
Assertion (A) and Reason (R). Select the
8. ldentify the molecule with linear geometry.
(a) BClg (b) BeCl, appropriate answer from the options given below
(c) HS (d) PHg 1 (a) Both (A) and (R) are true and (R) is the corea
explanation of (A).
9. Correct order of stability of carbocation of (b) Both (A) and (R) are true but (R) is not the
compounds (P), (@), (R) and (S) is:
P) HcO correct explanation of (A).
(c) (A) is true but (R) is false.
(H,co (d) (A) is false but (R) is true.
(R) OCH3
13. Assertion (A): Butane and 2-methyl butorg
are chain isomer.
Reason (R): Butane is a straight-chain
(S) alkane while 2-methy
Options: butane is a branched-choin
() P>Q> R>S (b) P>Q> S> R alkane. 1
(c) Q> P> S> R (d) S> R>Q>P 1
14. Assertion (A): All exothermic reactions
10. The IUPAC names of the products X and Y, are accompanied by decrease
formed in the given reactions are: in randomness.
OH A reaction which
Reason (R):
Br,
spontaneous and accompanied
X
CS, < 5°C by decrease of randomnes
must be endothermic.
NH2
Br, 15. Assertion (A): The three elements in ato
CS,, < 5°C have the same atomic mas
gaps.
4-bromophenol and Y thot tN
(a) X = Reason (R): The reason for this is
2,4,6-tritbromoaniline properties of the elements
2-bromophenol and Y
(b) X atriad are comparable.
2,4-tribromoaniline expansion
3-bromophenol
(c) 2,4,5-tribromoaniline
X
and Y 16. Assertion (A): During isothermal ener
heat
of an ideal gastransferredto
and Y
() X =
6-bromophenol is completely
2,4,5-tribromoaniline 1 work.
isothermalprocess
Reason (R): Duringan
following sequence of internalener
11, ldentify C in the the change in decrease
to
of gas due nullHfed by th
reactions:
pressure is
CH,CH,-CH -Br
Mg.Et,0 CO,B H,0,c change due to
increase
volume.
 SECTION-B 10Marks
contains S questions with internal choice in two questions.
(This sectionquestions are very short answer type and carry 2 marks each)
Thefollowing
observe from the below graph?
19. Arrange the following sets of elements in
What doyou increasing order of first ionisation enthalpy
with brief explanation.
(A) F,O, Nand (B) Mg, P, Ar 2
20. 6.12x 10: kg of washing soda is dissolved in
Irtensity water to obtain a 1L solution. The density of
this solution was found to be 105.66 kg/m.
Calculate:
(A) Molarity
(a) 0.0213 (b) 0.0214
(c) 0.0314 (d) 0.0121
(B) Mole fraction of Na,CO3 in solution. 2
mos 1000 2000 3000 Justify your answer with complete
Aow. Wavelength à (nm) calculation.
Tec Wavelength-intensity relationship 2 21. Answer the following Any two):
the of (A) Draw the hyperconjugative structures of
(& HAO, is also used in the manufacture
CH3 - CH = CH,
explosives. Why? (B) In the given conversion, identify the
OR reagent (giving reason) as electrophile/
nucleophile:
Riya take dimethyl ether and water for CHCOCl + OH ’ CHCOOH + HCI
maling a solution for her experiment. (C) Write the correct order for the rate of
While doing experiment she observes reaction for the electrophilic attack of
the given compounds.
that in both water and dimethyl ether OH NH,
CH-0-CH3, an oxygen atom is a central
atom yet they have different bond angles.
Which one has a greater bond angle? Give a ) (I)

reason. 2 2

SECTION -C 21 Marks
(This section contains 7 questions with internal choice in one question.
The following questions are short answer type and carry 3 marks each.)
22. (A) Two itres of an ideal gas at a pressure (B) How do solar panels generate electricity
using the photoelectric effect? 3
of 10 atm expands isothermallyat 25°C
into a vacuum until its total volume is 24. Find out the ionisation constant of 0.01 M
10 litres. How much heat is absorbed solution of acetic acid which is 1.34% ionised
and how much work is done in the at 298K.
expansion? (degree of dissociation = 0.0134) 3
(B) How much work is done if the expansion OR
is conducted at 298K. If the overall gas pressure is increased
(C) Also calculate heat absorbed during the3 from 1 atm to 1Ôatm, then in which of the
process in B. following reactions would there be a rise
in the amount of product at equilibrium?
23. (A) Suhana buys an incandescent light bulb Describe.
from the market for some decor in her
yellowish colour (A)SO29) +Clag) S0,Clag)
house. She observes the
lght coming from the bulb when it (B) N29) +O9) 2NO9)
glows. State why do these Incandescent (C) SOxg) +O9) SO3g)
ight bulbs emit a yellowish light? 2
2S, Consider the glven 28. First and second ionisation
reaction:
SA) 2w4C t 3D;)
When 7moles of Aand 4 moles of B are
mixed together, Then
(in kJfmol) of few elements
Elements IE,
are given
enthabipeelncw
(A) Which one is the limiting regent? 520
(B) Caleulate the amount of Cformed. 900 7300
(C) Calculate the excess amount of reactant 1760
left. 3 R 1680
26. Answer the following S 2372 3380
quentlons:
(A) Draw molecular orbital 5251
diagram of 0;
and calculate Its bond order. Answer the following questions:
(B) Explain why the bond order of N, is (A) Which of the given element
greater than N'. alkalimetal? could be on
(C) Give reason: H, and H, have the (B) Which of the given
bond order but H;' Is more stabl. same3 noble gas?
elerment could
27. (A) Explain the oxidatlon (C) Which of the above two
number (by glving
structures) of glven underlined form the halide of the formulaelement wil.
species: MX.3
H,SO,,H;S;O, Cros (D) How many valence electrons are
(B) () Balance the
following reaction:
xl, + yOH ’ l0; +xl+ 2H,0
in P? present
(i) ldentify Xand Yin the given (E) Which of these is a non-metal?
And also reaction.
balance the reaction. (F) Which of the given element
Fe,03) +COlg)X +Y has only two
3 valence electrons?
3

SECTION -D 8Marks
(The following questions are case-based questions. Each
question
carries 4 (1+1+2) marks each. Read the passage carefully and has an internal choice and
answer the questions that follow)
29. When hydroqen reacts with
heat is evolved.
gaseous iodine, the value of the equilibrium
constant, from
67.5 at 357°C to S0.0 at 400°C.
H2g) + l2g) 2Hlg), AH =-9.4kJ (exothermic) (A) When l, dissociates to it's atomic fom
Because this reaction is exothermic, we can the following reaction occurs:
write it with heat as a product.
"29) t'9) 2HI +heat 29) 2,o;AH= +150kJ
The reaction is favoured at high or low
Increasing the temperature of the reaction
increases the internal energy of the system. temperature?
Thus, increasing the temperature has the effect (B) Agas is in equilibrium with water at a
of increasing the amount of one ofthe products certain temperature and pressure. What
of this reaction. The reaction shifts to the left will happen if temperature of the gass
to relieve the stress, and there is an increase
increased?
in the concentration of H, and l, and a
reduction in the concentration of HI. Lowering OR

the temperature of this system reduces (B) Write the equilibrium constant expresso
the amount of energy present, favours the for the given reaction in terms of actviy
production of heat, and favours the formation simplifying where appropriate.
of hydrogen iodide. When we change the PA(9) +502(g) P0109)
temperature of a system at equilibrium, the expectel
equilibrium constant for the reaction changes. (C) In which direction equilibrium is the
in
to shift on temperature
Lowering the temperature in the Hl system increasing
increases the equilibriumn constant: At the following reaction?
new equilibrium the concentration of HI has
increased and the concentrations of H, and l,
2CO2(9) 2c0, +O2g)
AH=+212kcol
decreased. Raising the temperature decreases
 are orgoniccompounds nitrogen, or sulfur. They are also called
polycyclic aromatics or arenes. The best examples are
mono- and member
Anown
as
The parent toluene and benzerne and some are given with
hydrocarbons closely related.
Heteroarenes are their resonance energies in the table given
of -CH group
carbonatom below.
one oxygen,
least
of the heteroatoms
buone
Resonance en Formulae Names Resonance en
Names ergy, kJ/mol ergy, kJfmol
formuloe
151
Pyridine 96
Benzene

255 Pyrrole 89
Naphthalene

349 Thiophene 120

Anthracene

Phenanthrene 382 Furan 66

rule. (a) Styrene

Aromatics require satisfying Huckel's
Plants and micro-organisms have an exclusive (b) Vaniline
route to benzene-ring compounds. The great (c) Charvical
majorits of aromatic compounds in nature,
(d) All of these
therefore, are produced by plants and micro
organisms, and animals are dependent upon OR
plants for many aromatic compounds either electrons in
directly or indirectly. (B) ldentify the number of pi
tropone.
(A) ldentify the non-benzernoid aromatic (a) 4re
(b) 6ne
compound. (d) 7re 1
(c) 3re
(a) Furan of.
(C) Write the structural formula
(b) Tropolone () TMS (tetramethylsilane)
() Pyridine (i) Isobutanol (2-methylpropan-1-o)
1 (ii) 2,3-Dibromo-1-phenylpentane
(4) Thiophene
(iv) 4-Ethyl-1-fluoro-2-nitrobenzene 2
(B) Aromatic compound which are present in
plants is:
15 Marks
SECTION -E
carry 5 marks each.
questions are long answer type and
(Ihe following internal choice)
an
Allquestions have N

2CH, -CH -C ory ether

31, Answer the following questions: C
you con
the alkene formed reagent by which
(A)Write the structure of a propene and propyne. Give
(C) Name
distinguish
of 1-bromo-1
by dehydrohalogenation alcohollc KOH. reaction too.
Cyclopentadienyl anion is
methyl cyclohexene with reason:
(D)Glve stablethan allylanion,
following
product of the more
(B) Find the 91
reaction: Sample Paper 6
 OR
(A)But-2-en-1-ol
(B) 2-Aminoethan-1-ol
(A) Write the product obtained on ozonolysis
of following compound: (C) 2, 4-Dimethylhexan-3.
(D) 2, 3 Dibromopentanal
(E) 4-Ethyl-2-4-dimethylhexane
(B) How will you convert ethyne to benzene? 33. (A) Which of the following sets of quontu
(C) What is the major product in the numbers is/are not possible,
following reaction? ()n=2, l= 0, mË =0, m,= + 1/2Give reaw
i) n = 1, l= 1, m= 0, m, =-1/2
+ CH,- CH- CH, CI Anhy AlClg,
(iii) n = 4, l= 3, m=- 4, m, = +
CH, 1/2
(B) Arrange the following
(D) ldentify X, Y, Z, and W. increasing order of energy:orbitals in the
CH3-CH,-Br lc KOH x Ch/CC Y NaNH2 Z () n=4, l= 0, () n=4,l=2
(II) n= 3, l= 2 (IV) n=3,l=1
OR
W Given figure shows howthe
electron occurs when light is transition
5
Incoming photon energy inccident onit
32. There are three students. Manish, Ramesh,
and Rajni. They were given a task to identify
the additional elements in an organic
complex provided by their teacher. They Excited stote
energy level 1
made Lassaigne's extract by fusing the
chemical with sodium metal on their own.
They next mixed a part of the extract with
solid iron sulphate and dilute sulphuric acid. Ground stote
Manish and Rajni received prussian blue, but energy level, 0
Ramesh received only red. Ramesh tried the
test again with the same extract, but this
time further he only obtained red colour. (A) What are the frequency and wavelength
They then taken a back and went to their of photon emitted during a transtun
teacher to inform him of their discovery. The from n = 6 state to n = 3 state in th
teacher asked them to consider why this hydrogen atom? (h=6.626 x10
observation was made. Write the chemical
(B) The threshold frequency for ametal ?
equations to explain the formation of is 1.5 x 1013 -1
different colours.
Calculate the kinetic energy of
OR electron emitted when radiation ß
strikes the
Write the structure of the following given frequency 1.0 x 1014 s-1
compounds. metal.
 7 Sample Paper
Self-Assessment
TimeAllowed: 3
hours CHEMISTRY Maximum Marks 70

General Instructions: Same instruction as given in Sample Paper 1.

SECTION - A 16 Marks
Thefollowing questions are multiple-choice questions with one correct onswer.
Fgch question carries 1 mark. There is no internal choice in this section.)
verify the lavw of (a)
4 In the experiment to the:
conservation of mass, weighing of
(a) reactants are
only required
required
(b) products are only products are must K.E
(c)reactants and the
essential 1
are not
() contents
increases from
temperature of a system
2, The absorbs heat of 10 kJ (b)
27°C to37°C when it value ofAUis:
volume. The
ot constant
(a) 100kJ
(b) OkJ
(d) 1 kJ 1 K.E
(c) 10kJ
is
threshold frequency of potassium
3. The of the
then the work function
C0g5.0 x 10 Hz,
potassiunm will be:
(c)
10-15 (b) 4.3 x 10-14
(a) 33.13x 10-20 1
(c) 4.8x10-19 (d) 33.13x
number of electrons, K.E
4, On observing the in a species, a student
neutrons and protons which is
proper symbol of that species V
gets correct electrons,
o . Then, choose the
respectively: (d)
neutrons and protons
() 10, 8 and 9 (b) 8, 10 and 8
1
(d) 16, 8 and 8
(c) 10, 8 and 8
Einstein's photoelectric K.E
5. According to
energy
equation the graph between kinetic
frequency
of photoelectrons ejected and the
of the incident radiation is:
Sample Paper 7
 3
6. Which of the following is not a correct
1

statement regarding the intermediates form (C) Nz0)*,Hxg) ()

K,
during various mechanisms? ’ NHg)
(a) Tertiary corbocations are more stable
than secondary carbocation.
(b) Secondars free rodicol are more stable Options:
than primary free radicals. (a) A-(), 8-(), C-() (b). A-(V),
(c) Primary carbonium ions are more stable
(c) A-(), B-(I), C-(1) (d) A-(0),, ,8-(), C-
than secondary carbonium ions.
(d) None of the above 1 11, Which of the following reactions
involve neither oxidation nor
8-(0),Cdoes-(ln,
7. Astudent was given a compound X for (a) Vo*V,0, reduction? t
(b) Na Na'
identifying the type of functional group (c) Cro’Crz0 (d) Zn2, Zn
present in it. Compound Xon reacting with
sodium metal gives 4, 5-dimethyl octane 12, Which one is the correct statement
then, the correct IUPAC name of compound
X should be: (a) The uncertainty principle is AE.At, h
(a) 2-bromobutane (b) 2-bromopentane 4
(c) 3-bromobutane () 3-bromopentane 1 (b) de-Broglie wavelength is given
n where his Planck's
8. Consider the following sequence of reaction: 4T constant
(c) The uncertainty principle states
ConcHyso4, Alkene
Y »2 Molecules of possible to determine the exact thati
Alcohol Zn |H,0
acetaldehyde and momentum of the electron. positig
(d) The effect of Heisenberg's
ldentify Xand Y. principle is significant for theuncert
motoioinnt
X Y macroscopic objects.
(a) 1-Butanol 1-Butene Given below are two statements labelled..
(b) 1-Pentanol 1-Pentene Assertion (A) and Reason (R). Select the m
appropriate answer from the options given be
(c) 2-Butanol 2-Butene (a) Both (A)and (R) are true and (R) is the coren
() 2-Hexanol 2-Hexene explanation of (A).
1 (b) Both (A) and (R) are true but (R) is not the
correct explanation of (A).
9. Correct increasing order of charges of (c) (A) is true but (R) is false.
fundamental particles which are present in (d) (A) is false but (R) is true.
atom is:
(a) electron < proton < neutron 13. Assertion (A): In the dissociation of PQ.
at constant pressure and
(b) proton < electron < neutron . temperature addition
(c) electron < neutron < proton of helium at equilibrium
() neutron < proton< electron 1 increases the dissociation of
PCls.
10. For the reaction: Na9) + 3H2(9) -’ 2NH3(9) Reason (R): Helium reacts with Cl, and
hence shifts the equilibrium
in forward direction.
Equilibrium constant K =
14. Assertion (A): Violet colour is the mos
deviated one.
Some reactions are written below in Reason (R): The shorter is the wove
Column I and their equilibrium constants length, the greater is th
in terms of K, are written in Column Il. deviation.
Match the following reactions with the
corresponding equilibrium constant.
15. Assertion (A): 22.4 LH, and 11.2 LC,
mixing produces 22.4 L
HCl gas.
Column II Reason (R): Here Cl, is acting as limity
Column I(Reaction) (Equilibrium
reagent.
Constant) effect increaseso
16. Assertion (A): Shielding
(A) 2N2g) +6H2g) ) 2K, group.
we go down thenumber
4NH3 (g) Reason (R): Higher the penultima
electrons in the will bethe
(B) 2NH3g) -’ N2g) + () K shell, lesser
3H2g) shielding.
 SECTION -B
section contains
5questions with internal
followingquestions are veru short answer typechoice
The(This in two2 marks eoch ) 10 Marks
and corry questions
andher
friends went on a camping 20. Observe the following figure and
Radhya propane stove to cook. The
and used
trËp burns with
flame. Why is
a clean questions that follow. answer the
stove and what makes
used| for this,
was
propane goodchoice for camping stoves ?
olkanesa
OR
experiment identify
doing an alkenes in toa given
wWas
Ritika and
alkanes reaction of bromine water
the
compounds. On
observes that the orange
alkene she water disappears while
with bromine
colourof when bromine water Attempt any two:
there isno changealkane. Give the reason
with an
mixed
behindherobservation. 2 (A)What is the shape of the
is
given in the figure? compound
total number of moles of
Calculate the product at equilibrium, (B) Why lone pairs acquire axial position in
18. reactant and fraction of HI dissociated at
is the H, + ,
preference of equatorial?
if aa
equilibrium in the reaction 2HI
2 (C) What is the hybridisation of the
the initial moles of HI is 2 mole.
and
molarity of NaOH in the compound given in the figure?
Calculate the 4 g in
19. solution prepared by dissolving solution. 21. (A) How would you convert propene to
to form 25 m of the
enough water (b) 3 M
succinimide?
(a)2 M (B) How would you convert PhC-H to ether
(d) 4 M 2
(c) 4.5M soluble salt which is blood red in colour.
answer with complete
your 2
Justify
calculation.
SECTION -C 21 Marks
with internal choice in one question.
(This section contains 7 questions
anSwer type and carry 3 marks each)
The following questions are short
NaCl is 25. In a lab, you have two solvents: heptane
density of the 3M solution of and pentane. How would the boiling point,
22, The molality of the
1.25 g ml, Calculate the
3 evaporation rate, and solubility of each
one
solution. solvent affect your reaction, and which
chlorine would be better for your needs? 3
oxidation state of
23. (A) Why the in the reaction
changes from +5 to +1 with 26. You have been provided the following data.
of potassium chlorate (KCIO3)
hydrochloric acid (HC). Molecule
Enthalpy (kJ/mol)
Zn metal, gives |AH,=-393.5
(B) When H,SO4 reacts with HN03, NO is CO29)
hydrogen gas while with |AHj=-285.83
of hydronium ion. Why?
reduced instead H,O0
OR |sHj=-3267
Cgle)
(A) The ion MnO42- undergoes
acidic the given data
calculate the
disproportionation reaction in an Give On the basis of formation of benzene.
does not. standard enthalpy of 3
medium, while MnO
of
reason. 0.001 M solutionare
reducing and oxidising 27. If equal
volumes of solutions
(B) ldentify the balanced redox reaction: AgNO and 0.001
M NaCl
we be able to
agents in the 3 mixed together. Then wil
Clzlog) + 2Br (gd) ’ 2Cl (ag) + Br2(aq) observethe precipitation? 3
of different isomers =1.8x10-1)
24. Write structures (Given:Kgp(AgC) molecular formula
member of lkyne
corresponding to the fifth names of all the compound P, with
bromine dissolved
in
IUPAC
series. Also write the isomerism is exhibited 28. (A) A decolourises
of CgHy2
Isomers. What tupe
isomers? 95
by different pairs of SamplePaper 7
 (B) ldentify Xand Yin the
carbon tetrachloride. When P reacts with
alkaline KMnO, it yields only Q which is
potassium salt of an acid. ldentify P and () 3[Fe(CN)|J + 4Fe fol owing t,
Q. Give their structure and IUPAC name.
Also write the reactions involved. Y

SECTION - D
has an internal choico
(The followingquestions are case-based questions. Each question
and answer the questions
carries 4 (1+1+2) mnarks each. Read the passage carefully that
29. In 1927 bå the Germnan physicist Werner 30. While we are exercising we burnfollow,
Heisenberg. said that the more precisely the When we intake the food it out co,
position of some particle is determined, the oxidation process and
and H,0. First the transform underge,
less precisels its momentum can be predicted
from initial conditions, and vice versa. This was carbohydrates
simple sugar and then to CO, and
called the uncertainty principle. Heisenberg's the energy is changed in the

iminpideepsere .
pathway, that the Hess
uncertainty principle states that for particles Law
means that through burning
exhibiting both particle and wave nature, it
amount of energy is
the food era
will not be possible to accurately determine released.
both the position and velocity at the same mention that the higher the Gym instrc
time. Heisenberg's principle applies to all work out. As oxygen leads to the oxygen
hig
matter waves. The measurement error of any food. Thus, we are burning calories. OXIdator
Thergi.
two conjugate properties, whose dimensions Weshould always breathe while exercisng
happen to be joule sec, like position Process
momentum, time-energy will be guided by Food Intake Food is
Description
undergoesconsumed
Heisenberg's value. But, it will be noticeable .
and of significance only for small particles
digestor
like an electron with very low mass. A bigger Carbothydrates
broken
particle with a heavy mass will show the error
down into simpe
Sugars.
to be very small and negligible. Oxidation Simple sugars are furte
Oxidised to produ:
CO, and H,0, relecsr:
energy.
Energy release The total energy relecse
(Hess's Law) from food oxidation isr
same, regardless of te
pathway taken.
(A) What is entropy?
(B) Name the process by which we
Electron Electron calculate the Hess's Law.
particle position Wave nmomentum
(a) By reversing the equation
(A) Write the Correct expression for (b) Through adding the two equatiors
Heisenberg's uncertainty principle. 1
(C) Through multiplying the equatiot
(B) What are the limitations of Heisenberg's a constant
uncertainty principle? (d) Bath (a) and (c)
OR
OR
(B) The error in measurement of the lifetime
(B) Who discovered the appication
theenthos
of an atom is 4x10* sec. What is the law of thermodynamics to
minimum uncertainty in its energy in eV? change?
(b)JulesHenri
1 (o) Boyle
(d) Boltzmann
(C) How will you represent the uncertainty (c) Hess l
ofHess's
in velocity, if the uncertainty in position (C) What are the applications
and momentum are equal? Write any two.
 SECTIC carry 5 marks each.
long answer type and
questionsare internal choice)
following have an
(The Allquestions following figure.
that (B) Consider the
is more than 2500
angle ofH,O
bond reason.
than
I isgreater (2080) Ne p
Give
ofF,0. momentoffNH3 enthalpy
lonisation
2000
dipole Give reason.
moment of NF3. (1681)Fo
thedipole
FHF
of is higher than HCL mol
H/kJ
A
moment 1500 (1402) Ng
Dipole
oGivereason. Oo(1314)
Be-H bonds are
polar, still
Although the
dipole moment. 1000 (899) Be
Pc(1086)
have zero
BaH,molecule B(801)
Givereason.
OR
500 (520)
1 2 3 4 5 6 7 8 9 10
in
C-0 bonds are equivalent Atomic number of elements
A) All the
cO.Givereason. Explain the deviations in ionisation
given figure, (SF4) the lone pair of enthalpy observed in certain elements
B Inthe equatorial position
electrons occupy the compared tothe general trend, using the
position. Give data presented in the figure?
in preference to the axial
reason. 33.(A) On complete combustion of 0.246 g of
F an organiccompound it will give 0.198 g
of carbon dioxide and 0.1014 g water.
Determine the percentage composition of
carbon and hydrogen in the compound.
(B) Write IUPAC names of the given
compounds:
() Using molecular orbital theory explain ) (CH,)CH-CH =CH-CH,-CH
the non-existence of Be, molecule. 5
CHy-CH-CH
32.(A) What are Periods and Groups? C,Hs
(B) What did Dobereiner's law of Triads?
What are the limitations of the triads?
(G) CH,=C(CH,CH,CHh
(C) Consider the following table:
Atomic Number
Element CHy-HCH =-CH-HO,
A 12 CH3

carry out the following

19 (C) How would you
conversions?
C 29
Cgtis-CgHs
D 36 () CeHs

Write their electronic configurations and

identify the group of the periodic table for OR
each element. carbanion in the
Arrange the following stability:
OR (A) increasing
carbon order oftheir
(A) Why first ionisation enthalpy of second
atom is greater than boron while CH,-CH,, F-CH, -CH
CH, -C=C.
ionisation enthalpy of boron is greater
than cartbon. le Paper 7
97
Date

compound
(C) An organicC13H12 formswith
(B) 0.45 g of an organic
compound gave
50 cm of moist dinitrogen at
288 K
formula
carbocation X on reaction with
ethereal
molet
Calculate the which gives
and 755 mm pressure.
percentage of nitrogen in the
given Y when it reacts
molecules. Then find the compouondth
with its
organic compound. (Given
tension at 288K = 12.7 mm)
aqueous
and Y. compounda
 8 Sample Paper
Self-ASsessment
CHEMISTRY
hours Maximum Marks.: 70
Time Allowed: 3

Ceneral instructions: Same instruction as given in Sample Paper 1.

SECTION - A 16 Marks
The following questions are multiple-choice questions with one correct answer.
Fach question carries 1 mark. There is no internal choice in this section)
following
1, The correct stability order of the (a) 0.526
cal
(b) 5.26
cal
resonance structure is: mol K mol K
() HC N'=N (W) H,C - N=N
cal cal
(V) H,C= N'=N (c) 10.52 (d) 21.04 mol K 1
(u) H,C - N'=N mol K
Select the correct option: 5. ldentify the correct statenent.
(a) ) > (un > () > (IV) (a) The first ionisation enthalpy of Al is more
(b) ) > (Q) > () > ((V) than the first ionisation enthalpy of Mg.
(c) )> (u) > () > () (b) The second ionisation potential of Mg is
1
() ()> () > () > ) greater than that of Na.
sulphur (c) The first ionisation potential of Na is
2. in which of the following compounds
+6? more than the first ionisation potential
will have an oxidation state of
(b) Na,S406 of Mg.
(a) Na,S,03 (d) The third ionisation potential of Mg is
1
(c) Na,sO3 (d) Na,S04 greater than that of AL 1

3. In the following graphical representation, 6. Find out the products X and Y obtained by
attained at:
equilibrium condition will be the reaction:
HOCL XY
CH =CH 0°C
2-dichloroethanal
A (a) X= carbocation, Y= 1,
Conc. 2-dichloroethanal
(b) X= enol form, Y= 2,
2,2-dichloroethanal
(c) X= carbocation, Y=
2-dichloroethanal 1
(d) X= enol form, Y=1,
T

tË t2 t3 ta
Time molecular orbital theory
7. On the basis of these given
(a) tË (b) t2 observe the bond orders of
(c) t3 1 species.
(d) t4 () NO*
What is the molar entrops change for
() CN
melting of ice at 0°C, if AHe= 1.435 kcal/mol? () O,
 10.
),(D)-()
)-() (o)
(b) Options: (D) (C) (B) (A) Match (a) work
(d) (c) 10J(b) isothermal 8.
reversible An (d) (c) (b) (a)above table:
the
Choose
Particle X,
Y
protons, The ()Options:
cannot would would Particle
Particle ParticleX,
(a) Which
Column I the done ideal Y Y X ond 0) ()
be
and the
glven and and of
following: be be by gas Z.
neutrons
X X Y these
determined less more the is and are Zhasincorrect Proton
Number
Number (01) (00)
OH receives an 15
toble
OH than 15 15
than gas: atom. particlesZ a have
have positive and
Butanal() 10 expansion. show
Ethanol(11)Pentan-2-o(ne0) Propanoic ) 10 Then,the 10 statement Electron
Neutron electrons
(d) (b) ldenticol
J zero
J 17 16 16 (1) (1)
Column Il J of ion
the
of charges. same ond and bond
heat in
number (1M) ()
acid element. regarding porticles order?
15 18 15
in
1 a 1 of 1

14. 13. (d) (c) ) Assertion

(a)
(bappropriate Given
12. 11.
(A ) correct
(A)explanation
Both (A).of Both
Reason(R): Assertion Reason(R): Assertion (d) (c) (b)
observations? Two ()Mendeleev's (la)w (A)-(),(B)-(M)(C)-).XD)-(0)
is is below conclusion can following
(a) contains of Dobereiner's la(cw) (b) during chemistry
tA)-).(B)-(V)(C)-().(D)-
his.other element
wayobserved
studentWhile (d) () ()
false true (A) (A) The
multiplereciprocal proportion.
definite
Theconservation
The mass.ofThe carbon None
explanation (A) gaseous
Newlands'
and and
answer data data two.
weights
between studying
but and are data data of
(A): (A): but 30% and
results. had
(R) (R) proportion. the State
(R) (R) two proportion. is is is is
In
is oxidised.
itself
get Cu Zn) + protons.
In chemical
propertes
an The lsotopes
chemical
properties
same ar e Reason
from carbon 3.5g samples above Octaves dbou
weight
ised
lectrons
reductanadnt isfalse. is are in in in in you the an the
reduced a aelements true. of truestatementsaccordance t he atomic
reaction: (A). true the accordance accordanceaccordance draw ofOne table,
perlodic
SNO
redox Zn and
oxygen. laatomic
w
CusONoq) and (). containg
sample on law
by is of options
but based 70% analysis Swastikob
losing reaction, a an (R ) Select that
aceptby depends element (R) Oxygen. other
sam
iy reductont isgiven labelled with with with with the on
rmid he
is the the gave
low low lo. law
el ctrons oxidom on ha#
not comc: belog
mog Wte th
45. Friedel-Crafts alkylati
AsSertion (A: 22 corat gold is a 16. Assertion(A): not produce
alkyl benzene.
Reoson (R: A
mirture. olkyl halides
Comnpound has a fixed Reason (R): The reactivity of of acyl
that
composition of the elements is lower than 1
present in t. 1
haides.

10 Marks
(This section contains5
SECTION -B
in two questions.
The following questions arequestions
very shortwithanswer typechoice
internal and carry 2marks each.)
47. Draw the
structural
folowing compounds: formulas of the 2Mg + O,’ 2Mg0, if
AHe(MgO) = -601kJ
(A) 3,4, 4, 5 -
Tetramethylheptane
(B) 2, 5 - Dimethylhexanal
2

2
19. Attempt any two:
48. (A) The enthalpy of atomisation for the (A) When two isomers of alkene like fumaric
reaction CH4g) Cg) + 4Hg) is 1665 kJ and maleic acid are heated, one of them
mol. What is the bond energy of C-H loose water and forms anhydride and
other does not. Then, identify the acids
bond?
that convert into anhydride by loosing
(B) When an ideal gas is compressed in a water.

cyinder with constant external pressure (B) How would you convert chlorobenzene
as seen in figure, then how much work to biphenylene?
will be done on it? (C) Hydrogenation of an alayne with Pd-C
and H, gives the alkane
Per HgC-=CH, HCCHy-CHy CH,
V Describe the mechanism involved in the
above reaction. 2

20. 100 g of CaC, reacts with water producing

acetylene (CH). Calculate the volume of
CaC2 produced at STP.
(a) 35 L (b) 30 L
(d) 10 L 2
(c) 25 L
answer with complete
Justify your
calculation.
compounds in
OR
21. Arrange the following for manganese.
increasing oxidation number
enthalpy for the
What is the change in MnClz, MnO, Mn(OH)3,
KMnO4
following reaction?
21 Marks
SECTION -C
question.
questions with internal choice in one
7 each)
(This section contains answer type and carry 3 marks
questions are short
The following
(A) PCls) PCly)
number of moles of reaction
Ll Does the
increase, decrease or
products
remain
equilibria
+CO19 CaCO
(B) CaO
following 4H,O)e,O49,+429)
same when each of the +
pressure by (C) 3Fe,
is subjected to a decrease in
increasing the volume? Sample Paper 8 10
 the followinu.
23. 26. Glve reason for
The ond noble gses lika
wes obtained when A)Fluorne the avidernt
these following
different
dete
oxides of lead were onalysed neon are
electronegivnytaward the lat
tobla
Colour ef Amount of Amount bottom of the perlodic
oxlde oxide of lead order of their
(1) (0)Increasing
Red 1.22g s0,(OH); « 0,(CF),4
(2) Yellow 6.42 g of
(3)
Here wavelengths
27. A) ore varnous
Brown 2.30 g 2.07g given:
Show that this doto lustrate law o
by 300Opm
multiple proportlons. 3
Arrange thess radiations
24. (A) Bromine monochloride, BrCl, increasingorder of their energies
decomposes Into bromine and chlorine slectrons in
and reaches the equlbrlum 2BrCl) (B) How many
have the following quanturn
Br0) + Chio for whlch K 32 at
SOOK. If initially pure BrCl Is present at a 1
nurritierg
() n 4, m,
concentration of 3.30 10- mol litre';
what is its molar concentration In the () n 3, l s 0
mixture at equilibrlum? OR
(8) A sparingly soluble salt of the formula (A) Calculate the energy of a mae
AX has solubility product 2.5 x 10" at photons with a frequency of5104
298K. Calculate its solubilty. (B) Swastik went to Nanital hill statlon u
their family. Their he took a ride f t
25. (A) Write names of the products obtained air balloons, Swastik asked the rider he
by addition reactlon of hydrogen how and which gas uplifts this balloon
bromide with hex-1-ene: alr. Rider says thatit is Helium gas whis
() In the absence of peroxlde uplifts the hot air balloon air. State wh
(6) Inthe presence of peroxide. onlyHelium gas used in hot air balbors
(B) Give mechanism for reactlon and in airships?
(C) Give resonating structures of prop-2 28. Glve the shapes of the folowing covdet
ene-al. Also write the order of rolative molecules using VSEPR theory:
stability of these resonating structures. 3 (A) AsFs (B) BE, (C) XeOF;

SECTION -D 8 Mars
(The following questions are case-based questions. Each question has an internal choice and
carries 4(1+1+2) marks each.Read the passage carefully and answer the questions that follow)
29. Bohr proposed the following three postulates nh
L, where n =1,2,3..
of Bohr 's model: 2n
(1) The negative electron moves around the This postulate saus that the electrO
positive nucleus (proton) in acircular orbit. angular momentum is quantised Der
the rodus
All electron orbits are centered at the by r, and v, respectively.
the nth orbit and the electron's spee
nucleus. Not all classically possible orbits Condition con b
are available to an electron bound to
the it, the first quantisation
nucleus. expressed explicitly as
first nh
(2) The allowed electron orbits satisfy the the
quantisation condition: In the n" orbit, 20 tronstos
can (3) An electron is allowed to make is E
angular mormentum L, of the electron energy
from one orbit where its
take only discrete values:
 mother obit where s ene 8
(n otm When possesses the nost enerqs efficient packing
obsorbs photon, the electron structure, which is close to the theoretical
makes a tonsition to a higher energy
orbit maximum of the model and that the graphite
When Gn Gto emits aphoton, the
electron possesses packing which is sgnificantly less
tronsits to a lower-energs orbit. Electron
(ransitions with the smultaneous photon efficient. This can be interpreted as the most
efficient carbon-carbon bonding in diamond
absorption or photon emission take place has an average bond order of one and in
instantaneously The allowed electron Energy
density
(kJcc)
graphite it is something greater than one.
transitions satisfy the second quantisation
Energy Densits (kJ/cm)
condition 8 50
- |E,-Eml = n
where n is the energy of either an emitted
or an absorbed photon with frequency f -50
The secOnd quantisation condition states
that an electron's change in energy in the 100
= C+0, diamond structure
hydrogen atom is quantised = N+N, diamond structure

1 4

Emission of'energy Principal Bond Length (¢)

Absoption,ofengrgy Specific Energy (kJ/g) h6Ysd_
(6/)
Electron
-40

-40% below
Free Atom Limit
20

n=2 nucleus Reported p-C0->

n=3 n=1
Energy levels
1 2 3 4
Answer the following questions: Principal Bond Length (¢)
(A) What is the necessary condition for being (A)The bond order of carbon-carbon bonds
a hydrogen-like an ion? in graphite is:
(a) 1 (b) 1.3
OR
(c) 2 (d) 3 1
(A)What will be the trend of radius when (B) Which of the following statements is
the n volue (principal quantum number) true about the bond length in diamond?
increases? 1 (a) lt is shorter than the bond length in
graphite.
(B) Using Bohr's frequency rule calculate the (b) It is longer than the bond length in
energy of radiation where the frequency graphite.
of the radiation is 5 x 1014 g-1 1 (c) It is the same as the bond length in
graphite.
on the
(C) Find the energy value for the second (d) It varies depending
2 temperature.
stationary state.
OR
30. Astudent of eleventh standard is searching for a result of
his/her project which is on RECENT RESEARCH (B) The bond length in diamond is
which type of hybridisation?
ON THE BOND LENGTH OF C-C IN DIAMOND (b) sp?
(a) sp 1
AND GRAPHITE. On searching he/she finds (c) sp (4) sp'd
the bond length of C-C for diamond is 1.54 A, bond order
whereas for graphite the intra-graphene you have idea, why
(C) () Do diamond than the bond
in is less
aromatic bond length is 1.42 Å and the order in graphite?
inter-graphene bond length is 3.35 A. These bond enthalpy.
stationary points are depicted in given figure (G) Definebond orderand 2
correlation?
(n orange) emphasising that the diamond What is their
 SECTION-E
carry 5 marks each
long answer type ond
(The following questions are choice)
questions have an internal
All Carius method of estimation
31. (A) 32. (A) In
Sana observe some thermodynamic halogen, 0.15 g of an organic
gave 0.12 g of AgBr. Find
processes at her home, While observing
she found that refrigerator works percentage of bromine in the
Isothermalls ond ropidls pumping d
into a blcycle tire is a gdiabatic
process.
Differentiate between isothermal and
(B) Calculate number
pi bonds ( )inthe
of
sigma compag
followingbondstructu
(B)
adiabatlc process.
Classify them as extensive or intensive
properties: Temperature, Mass, Gibbs
energy, Molar heat capacity. () CH, =C(CH,CH,CHa),
(C) Glven;
(GiI) CH,CH,CH;CH,
Nao) +3 H,0) ’ 2NH3(g) CH-CHCH =
AH, =-92.4 kJ/mol
Calculate the standard enthalpy of OR
formation of ammonia gas.
(D) The heat of (A) An inorganic salt gave
combustion of andlfyolsiowsire
naphthalene percentage composition on
is -5133 kJ/mol at constant volume, Ng = 29.11, S = 40.11, O = 30. 3%
what will the value of enthalpy change? Calculate empirical formula of the cx
OR (B) ldentify the electrophilic centre in the
(A) Explain giving reason which has
more following: CHyCH =0, CHg-CN, CHh
entropy, H,0 (298 K, 1 atm) or Ha0 (C) Write the bond line
condensed formula for structure
(330K, 1atm). compounds in the table.
the give
(B) For the reaction
Molecular Bond line
4Fe, +30a9) ’ 2Fe,0, formula structure
Con
AS =-549.4JK-mol-1
densed
structur
It is spontaneous reaction though its (a) 2,2, 4-Trimeth
entropy change is negative (AH, =-1648 yl pentane
x 10 J/mol) explain. (b) 2-Hydroxy-1, 2,
(C) Justify that reaction with negative value 3- propanetri
of AG will always have equilibrium carboxylic acid
constant greater than 1. (c) Hexanedial
P(atm)

33. An alkene p' with theirC -C single bonds

eight C-Ho bonds and one C-Cr bond.
b on ozonolysis gives two moles of aldeny
2.0 -
(0) with molar mass 44u.
Aldehyde (0) on reacting with alcohol
an S
an
magnesium bromide (R) form
’ V(«10-)m? on dehydration (S) gives back (P) oa allthe
0.20 down
ldentify (P) to (S) and write
5 reactions.
 OR
the
Predict the major products of
(A) following reactlons:
townds om tectuoghe
HBr
CH- CH, () Chlooh4d6n6, uorsbanere i4
()) CH, -CH = (PhCOO),
HBr (i) Benzsne, touene,p ierobenne
CH,
(G) CH,- CH = (PhCOO), (C) Cotvsrt hexone to b4mzane
 Time
It is Management
for the3
extremely important
theprescribed time limits
to
Complete all33 QS or reviewgiven
hours paper
complete each
below. Else,Section of the paper
you may run
difficult/unattempted
within
os. out of time to

CHEMISTRY
Section Questions Time to be Spent Total Time
(maximum)
Reading Time (Mandatory): 15 min
12Q (MCOs) ~ 15 minutes
SECTION A (per Question)
( mark) 30 minutes
4Q (AR) ~ 2 minutes (4 minutes extra given)
(per Question)
SECTIONB
5Q (VSA) ~3 minutes 20 minutes
(2 marks) (per Question) (5 minutes extra given')
SECTION C ~ 4 minutes
(3 marks) 7Q (SA) 35 minutes
(per Question) (7 minutes extra given")

SECTIOND ~ 10 minutes
2Q (Case-based) 25 minutes
(4 marks) (per Question) (5 minutes extra given")

SECTION E ~ 15 minutes 50 minutes

3Q (LA)
(5 marks) (per Question) (5 minutes extra given")

Revision Time 20 minutes

TOTAL TIME: 180minutes

~means approximate time (1minute +/- is okay) * Extra time for competency-based Qs is suggested.

IMPORTANT:
b The mandatory 15 minutes Reading Time should be used to skim through the
paper and decide which Os to attempt at the end (difficult Qs).
Revision time isamust to have (at the end) to achieve three things:
sure about
Attemptthe guestionsyou have left or are not 100%
-Check if anyquestion (sub-part) is left unattempted Objective section
DOuble check.if the correct options are picked in the