1

Weekly-08 [Practice Set] (Engineering)

wm‡jevm: †hvMRxKiY, Pj Zwor , Zwor imvqb
c~Y©gvb: 400 Set-01 mgq: 2 NÈv


1. hw` f(x) dvskbwU f(x) + f( – x) = 2 †K wm× K‡i Z‡e  0
f(x)
3. y = 3 –x –
1
– |x + 1| Ges x Aÿ Øviv mxgve× †ÿ‡Îi †ÿÎdj
sinx dx = ?  2
 KZ?
[Let f(x) be a function satisfying f(x) + f( – x) = 2, then 
[The area of the bounded region enclosed by the curve y = 3
0

– x – – |x + 1| and x axis is–]

f(x) sinx dx  ?] 1
  2
mgvavb: I =  0
f(x) sinx dx ..... (i) mgvavb: Y  3
 0 2
= f( – x) sin( – x) dx
0 – 7 0 5 0
  4  4 
= f( – x) sinx dx ....... (ii) [3 Marks] X
0 (– 1, 0) 1 0
(i)  (ii) 2 

2I =  0
[f(x) + f( – x)] sinx dx
2x + 2 ; x < – 1
7
 
 2I =  0
2 sinx dx = 2  0
sinx dx [3 Marks]
y = 2 ; – 1 ≤ x ≤ 2 
3 1
[3 Marks]

= 2[– cosx]
0 5 – 2x ; x > 1 
= – 2(– 1 – 1) 2 2
y = 3 – x –
= 22 1
– |x + 1|
 I = 2 [4 Marks]  2
QvqvK…Z As‡ki †ÿÎdj
1
3+ 
3 3
=
2. x = b †iLvwU y = (1 – x)2, y = 0 Ges x = 0 Øviv Ave× †ÿ·K 2 2 2
R1(0 ≤ x ≤ b) Ges R2(b ≤ x ≤ 1) Ask؇q wef³ K‡i †hLv‡b R1 – 27
=
8
eM© GKK [7 Marks]
1
R2 = | b Gi gvb =?
4
[The line x = b divided the region bounded by y = (1 – x)2, y 4. hw` x = r2 – y2 eµ‡iLv‡K y A‡ÿi PZzw`©‡K Nyiv‡bv nq, Zvn‡j
= 0 and x = 0 into two parts R1(0 ≤ x ≤ b) and R2(b ≤ x ≤ 1) Drcbœ Nbe¯‘i AvqZb wbY©q Ki|
1 [If the curve x = r2 – y2 is rotated about the y axis, find the
where R1 – R2 = . Find the value of b.]
4 volume of the solid generated by curve.]
mgvavb: y = (1 – x)2

r
mgvavb: V = x2 dy (0, r)

b
 R1 = y dx –r
x = r2 – y2

0 r
= 2
(r – y ) dy 2

=
b
(1 – x)2 dx –r
(r, 0)

0 r
2 2
(1 – x)  3 = 2 (r – y ) dy
= –
b 2 2 2
0 x +y =r
 3 0 3 r (0, – r)
= 2 r2y –
y
(1 – b)3 1
=–
3
+
3
[3 Marks]  3 0
r
r3
  = 2r3 –
1 1
R2 = y dx = (1 – x)2 dx  3 0
[4 Marks]
b b
(1 –  x)3 1 2r3
= – = 2 .
 3 b 3
(1 – b)3 4 3
=
3
[3 Marks]  V = r [6 Marks]
3
2(1 – b)3 1 1
R1 – R2 = – + =
 log x dx  I n‡j, cÖgvY Ki †h, I = e – m.I
3 3 4 e
m
2 1 5. e m m m–1
 – (1 – b) = –
3 1
3 12
[If  log x dx  I then prove that I = e – m.I
e
m
1 e m m m–1]
 (1 – b) =
3 1
8
1 mgvavb: †h‡nZz,  log x dx =  (log x) .1 dx e
m
e
m

b= [4 Marks]
2
 nd
2  Chemistry 2 Paper Chapter-4


= (logex)m dx –  (logex)m dx dx   
d x+1
8. hw` dx = f(x) 2x – 1 + c; †hLv‡b c aªæeK Z‡e f(x)
dx  2x – 1

1 mgvb?
= (logex)m.x m(logex)m–1. .x dx
x

x+1
[If dx = f(x) 2x – 1 + c; where c is a constant, then
= x(logex)m – m (logex)m–1 dx  [5 Marks] 2x – 1
f(x)  ?]

e
Im = (logex)m dx mgvavb: awi, 2x – 1 = t  2x – 1 = t2  2dx = 2t.dt [2 Marks]
1


x+1

e
= [x(logex)m] – m
e
(logex)m–1 dx dx
1 1
2x – 1
2
= e – mIm–1 [5 Marks] t +1
+1

2
= t dt
x4 + 1
x
t
6. 6 dx = ? 2


+1 t +3
= dt
mgvavb: x6 + 1 = (x2)3 + 1 = (x2 + 1)(x4 – x2 + 1) [2 Marks] 2
3
=  + 3t
x4 + 1 †hLv‡b, x3 = z

1 t
 6 dx 2 3 
x +1  3x2 dx = dz
4 2 2
x –x +1+x t 2
= (x4 – x2 + 1)(x2 + 1)
dx = (t + 9) + c
6
2x – 1 + 9
= 2x – 1 
2

 
dx 1 3x dx
= 2 +
x + 1 3 (x3)2 + 1  6 +c
= 2x – 1 
x + 4
 
dx 1 dz
= 2 +
x + 1 3 z2 + 1
[3 Marks]  3 +c
1 x+4
= tan–1x + tan–1z + c  f(x) = [8 Marks]
3 3
1
= tan–1x + tan–1(x3) + c [5 Marks]
(2x – 1) cos (2x – 1)2 + 5

3
9. dx Gi †hvMRxKiY = ?
4x2 – 4x + 6
1 2
7. y = ax2 + bx eµ‡iLvwU (1, 2) we›`yMvgx| x Aÿ x = 4 mij‡iLv [The integral (2x – 1) cos (2x – 1) + 5 dx is equal to –]
I eµ‡iLvwU Øviv mxgve× †ÿÎwUi †ÿÎdj 8 eM© GKK n‡j a I b Gi
2
4x – 4x + 6 
(2x – 1) cos (2x – 1)2 + 5

gvb =?
mgvavb: dx
1 4x2 – 4x + 6
[The curve y = ax2 + bx passes through the point (1, 2). Find
the values of a and b if the area bounded by x axis, x = 4 and
g‡b Kwi,
the curve is 8 square units.]  (2x – 1)2 + 5 = t2
1  2(2x – 1).2 dx = 2t dt
mgvavb: y = ax2 + bx ....... (i)  2 t2 – 5 dx = t dt [4 Marks]
(i) bs †iLvwU (1, 2) we›`yMvgx n‡j, 2 = a.1 + b.1 2
t – 5 cost

1
 a + b = 2 ............ (ii) myZivs, dt = sint + c
2 t2 – 5 2
Avevi (i) bs †iLvwU (0, 0) we›`yMvgx| 1
 (i) eµ‡iLv x Aÿ, x = 4 mij‡iLv Øviv mxgve× A‡ji = sin (2x – 1)2 + 5 + c [6 Marks]
2
†ÿÎdj

 y dx
4

 acosx – bsinx  ?
dx
= 10.
0

=  (ax + bx) dx mgvavb:  acosx – bsinx

4 1 dx
2 [3 Marks]
0

=
4 dx
 x2 x2
3

= a  + b  
1 – tan 2  2tan 2 
x 2 x
 3 2
a
x
– b
 2 0 x
 2 1 + tan 2
2 2
2a 3 b 1 + tan
=  42 +  42
3 2 x
16a sec2 dx

= + 8b [3 Marks] 2
3 = [2 Marks]
a1 – tan2  – 2btan
x x
=8  2 2
16a


+ 8b = 8 ................(iii) 2dz awi,
3 =
a (1 – z2) – 2bz x
(ii) I (iii) n‡Z,  tan = z

1 2dz 2
 a = 3, b = – 1 [4 Marks] =–
a 2 b x
z +2 z–1  sec2 dx = 2 dz
a 2
 3

 
1 2 dz 1 2 dz
=– =–
log
a – sin

2
d = ? ;  > 0
2 2 2 2 2
a
z +  – 2 – 1
b b a
z +  – b +2 a 
b 12.  a + sin
 a a  a  a  –
2

[4 Marks] mgvavb: f() = log

a – sin 

1 2 dz
=–
a b  b + a 
2 2 2 2  + sin
a
–
z + a   a  f(– ) = log
a + sin
a – sin 
z + ba – 
a2 + b 2
= – log
a – sin 
ln
a
+c
1 2
=– × a + sin
a a2 + b 2 b a2 + b 2
2×
a z + a + a  = – f() [6 Marks]
[2 Marks]  f() AhyM¥ dvskb

1  az + b + a2 + b2
 –  log
a – sin 
ln  +c 
2
= 2 = 0 (Ans.) [4 Marks]
a + b2  az + b – a2 + b2 a + sin
2

 
x
atan + b + a2 + b2

2

1
13. y = ln(x + e), x = ln  Ges x Aÿ Øviv Ave× †ÿ‡Îi †ÿÎdj
= 2 2 ln + c (Ans.) 1
x
y
 
a +b atan + b – a2 + b2
2
KZ?
[2 Marks]
[Find the area of the region enclosed by the curves y = ln(x + e),
x = ln  and x axis.]
4 1

x +1
11. 3 2 dx  ? y
x (x + 4)
mgvavb: x = lny
1
x4 + 1 Ges y = ln(x + e)

mgvavb: x3(x2 + 4) dx
1
 ln1 = ln(x + e)
4
x +1 A B C Dx + E  =e x
[x A‡ÿ y = 0, ln1 = 0]
awi, x3(x2 + 4)  x + x2 + x3 + x2 + 4 y
x=1–e [4 Marks]
 y = e–x
 x + 1  Ax (x + 4) + Bx(x + 4) + C(x + 4) + x (Dx + E)
4 2 2 2 2 3

Y
 x4 +1  Ax4 + 4Ax2 + Bx3 + 4Bx + Cx2 + 4C + Dx4 + Ex3 y = e– x
y = ln(x + e)
 x4 + 1  (A + D)x4 + (B + E)x3 + (4A + C)x2 + 4Bx + 4C
mnM mgxK…Z K‡i, (0, 1)
A+D=1
B+E=0 X
(1 – e, 0)
4A + C = 0
4B = 0  B = 0


 
0
1  †ÿÎdj = e–x dx
4C = 1  C = 1–e
ln(x + e) dx + [4 Marks]
4 0
=1+1
 B = 0 n‡j E = 0 [B + E = 0]
= 2 eM© GKK (Ans.) [2 Marks]
 4A + C = 0 C = 1
 4 sin–1 x – cos–1 x
A=–
1 14. 
sin–1 x + cos–1 x
dx  ?
16
sin–1 x – cos–1 x
A+D=1 mgvavb: 
sin–1 x + cos–1 x
dx

D=
17 A = – 1  
16  16 – 2cos–1 x
2 ⸪ sin–1x + cos–1x = 
x4 + 1
–
1
16 0 4 16
1 17
x+0
=  
dx
 2
 3 2 = + 2+ 3+ 2 2
x (x + 4) x x x x +4
 
4
4
x +1 1 17x 1 = dx – cos–1 x dx [2 Marks]
 3 2 = + – [6 Marks] 
x (x + 4) 4x3 16(x2 + 4) 16x –1 . 1
= x – cos–1 x.x – x dx

4
x4 + 1  
I= 
3 2
x (x + 4)
dx 1–x 2 x
awi, x = z

4 2 x
= x – xcos–1 x – dx
  
1 17x 1  
= dx + dx – dx 1–x 1
4x3 16(x2 + 4) 16x  dx = dz

4 2 z.2z dz 2 x
= x – xcos–1 x –

1 17 2x 1  
= + dx – lnx 1 – z2  dx = 2z dz
4(– 2)x2 16  2 x2 + 4 16
4 1 – (1 – z2)

4
1 17 1 = x – xcos x –
–1
dz
=– 2+ ln|x2 + 4| – ln|x| + c (Ans.) [4 Marks]   1 – z2
8x 32 16
 
4 4 dz 4
= x – xcos–1 x – 2+ 1 – z2 dz
  1–z
 nd
4  Chemistry 2 Paper Chapter-4
4 4 4 z 1 – z 1 –1 
2
I1 =
V
=x– xcos–1 x + cos–1z + + sin z + c
   2 2  P+Q
V
[†hLv‡b, z = x ] I2 =
R+S
(Ans.)
I1 R + S 500 + 50
[8 Marks] = = =5
I2 P + Q 100 + 10
15. 10  †ivahy³ GKwU Zvi Øviv 10 cm cwiwa wewkó| GKwU ev, I1 = 5I2 [2 Marks]
†MvjvKvi AvswU ˆZwi Kiv n‡jv| Gi †Kv‡bv `ywU weš‘‡Z ˆe`y¨wZK cÖevnhy³  wb‡Y©q AbycvZ,
2 2 2 2
cwievnx †hvM Ki‡j †mB `yBwU we›`yi g‡a¨ †h DceZ©bx nq Zvi Zzj¨‡iva = I1P : I1Q : I2R : I2S [4 marks]
= (5I2)  100 : (5I2)2  10 : I2  500 : I2  50
2 2 2
1 | we›`y `yBwUi Ae¯’vb †ei Ki|
[A round ring is made with a wire whose circumference is = 2500 : 250 : 500 : 50
10 cm and resistance is 10 . A sub circuit is made in this = 50 : 5 : 10 : 1 [4 marks]
ring with two individual points of this ring and it's
equivalent resistance is 1 . Find the position of these two 17. GKwU ˆe`y¨wZK evwZi `y-cÖv‡šÍi wefe cv_©K¨ 1% n«vm †cj| Gi
points.] d‡j †iv‡ai cwieZ©b bMb¨ n‡j, evwZi ÿgZv KZ kZvsk e„w× ev n«vm
mgvavb: †MvjvKvi AvswUi A I B we›`y‡Z cÖevnhy³ cwievnx †hvM Kiv cv‡e?
n‡q‡Q| [Potential difference is dropped by 1% of a lamp. If the
cÖkœvbymv‡i, R1 + R2 = 10 ..... (i) changes in resistance is ignorable then the changes in power
A I B we›`y‡Z R1 I R2 GB `ywU Ask GKwU mgvšÍivj mgevq ˆZwi is–] 2
K‡i‡Q, hvi Zzj¨ †iva 1. mgvavb: P = V [1 marks]
R
R1
myZivs, lnP = 2lnV – lnR
dP dV
 = 2 [†h‡nZz R = aªæeK dR = 0] [4 marks]
P V

A B
kZ©g‡Z, dP = – 1% = – 1 [3 marks]
P 100
R2 myZivs, dP = – 2 = – 2%
R1R2 P 100
myZivs, =1
R1 + R2  evwZwUi ÿgZv 2% n«vm cv‡e| [2 marks]
R1R2
ev, =1
10 18. 5  †iv‡ai GKwU Zvcb KzÐjx‡K GKwU Zwor †Kv‡li m‡½ hy³ Kiv
10
ev, R2 = [2 Marks] n‡jv| †KvlwUi Af¨šÍixY †iva 20 | Kx gv‡bi mv›U hy³ Ki‡j H Zvcb
R1
(i) G gvb ewm‡q cvB, ZviwU‡Z e¨wqZ kw³ Av‡Mi gv‡bi 1 Ask n‡e?
9
10
R1 + = 10 [4 marks] [A heat horoscope of 5  resistance is connected with a cell.
R1
2 Internal resistance of the cell is 20 . If shunt is added and
ev, R1 – 10R1 + 10 = 0 1
as a result spent energy becomes to previous one, then find
10  102 – 4.1.10 9
R1 =
2 the value of shunt.]
= 5  15 = 5  3.873 mgvavb: S
 R1 = 8.873 ev, 1.127 [2 marks] R
R2 = 10 – R1 = 1.127 (ev, 8.873)
†h‡nZz, 10 cm `xN© Zv‡ii †iva 10 | ZvB 1 cm `xN© Zv‡ii †iva I1
E, r
1 | myZivs, R2 I R2 †ivawewkó Ask `ywUi ˆ`N©¨ n‡jv 8.873 cm
I 1.127 cm. [2 marks] r = 20; R = 5
mv›U hy³ bv K‡i, I1 = E
16. GKwU ûBU‡÷vb weª‡Ri mvg¨e¯’vq PviwU evû‡Z h_vµ‡g 100 , 10 R+r

2
, 500  I 50  †iva Av‡Q| weª‡Ri wewfbœ kvLvq e¨eüZ ÿgZvi t mg‡q R 1 †iv‡a e¨wqZ kw³, W1 = I1Rt
AbycvZ wbY©q Ki| E2rT
= [1 mark]
(R + r)2
[A balanced wheatstone bridge has been formed with
S mv›U‡K eZ©bx‡Z hy³ Kiv n‡j, cÖevngvbÑ
resistance of 100 , 10 , 500  and 50 . Find the ratio of
spent power in each resistance.] E E(R + S)
I2 = = [2 Marks]
mgvavb: I1 I1 RS RS + r(R + S)
+r
R+S
P = 100 Q = 10
S ES
G  R †iv‡a cÖevngvÎv, IR = I2 = [1 Mark]
I Ig = 0 I R + S RS + r(R + S)
A B
 t mg‡q R †iv‡a e¨wqZ kw³,
I2 I2 S = 50 2 E2S2Rt
R = 500 W2 = I1Rt = [2 marks]
[RS + r(R + S)]2
VA – VB = V n‡j, kZ©g‡Z,
 5
W
W2 = 1 [1 marks] length of each copper layer is 1 cm and sum of lengths of
9 consecutive carbon and nickel leyers is also 1 cm. Find the
ev, W1 = 9W2 length of each nickel segment.
2
9E2S2Rt Given  = resistivity,  = temperature coefficient of
ev, E Rt 2 =
(R + r) [RS + r(R + S)]2 resistivity]
9S2 (Cu) = 1.7  10–8 ohm/m
ev, 1 2 = (C) = 5  10–5 ohm/m
(R + r) [RS + r(R + S)]2
(Ni) = 1  10–6 ohm/m
ev, R + r = RS + rR + rS
3S (Cu) = 3.9  10–3 C
rR 20  5 (C) = – 5  10–4 C
ev, = =2 [3 marks]
2(R + r) 2(20 + 5) (Ni) = 4  10–4 C
Cu C Ni Cu C Ni
19. Zwor”PvjK ej E Ges Af¨šÍixY †iva r wewkó †Kv‡bv Zwor
†Kv‡li `yB cÖvšÍ kU© Ki‡Z cwievnx Zvi e¨eüZ nq hvi ˆ`N©¨ l Ges mgvavb: awi, ïiæ‡Z A_©vr cÖv_wgK ZvcgvÎvq †iva Ro Ges ZvcgvÎv T
cÖ¯’‡”Q` †ÿÎdj A| Zv‡ii Dcv`v‡bi Av‡cwÿK †iva, NbZ¡ Ges †gvjvi cwigvY cwieZ©b n‡j †iva RT|
fi h_vµ‡g , d Ges M| †Kv‡li abvZ¥K cÖvšÍ †_‡K FYvZ¥K cÖvšÍ ch©šÍ Avgiv Rvwb,
†cuŠQv‡Z GKwU gy³ B‡jKUª‡bi cÖ‡qvRbxq mgq KZ? ivwkgvjv wn‡m‡e RT = ROCu(1 + CuT) + ROC(1 + CT) + RONi(1 + NiT)
cÖKvk Ki| [2 Marks]
[A conducting wire of length l and cross sectional area A is  R OCu + R OC + RONi = ROCu (1 + Cu T) + ROC (1 + CT)
used to short the terminals of a cell having emf of E and + RONi (H  NiT)
internal resistance r. The resistivity, density and molar mass  ROCu Cu + RCC + RONiNi = 0
of the material of the wire are , d and M respectively. Cu lCu.Cu C lC.C NilNi.Ni
 + + =0
Calculate the average time needed for a free electron to A A A
travel from positive of the cell to its negative terminal.]  CulCuCu + ClCC + NilNiNi = 0 [3 Marks]
mgvavb: Avgiv Rvwb, hw`, Ni Gi ˆ`N©¨ lNi = x cm Z‡e,
l C Gi ˆ`N©¨ lC = (1 – x) cm
†iva, R = A Avevi, lCu = 1 cm
E
Zv‡ii ZworcÖevn, I = R + r =
E
[1 Mark] (i) Gi gvb emvB 
l  (1.7  10–8  1  3.9  10–3) + {5  10–5  (1 – x) 
+r
A (– 5  10–4)} + (1  10–6  x  4  10–4) = 0
I
cÖevn NbZ¡, j = A =
E
[1 Marks]  6.63  10 – 2.5  10–8 = (– 4  10–10 – 2.5  10–8)x
–11

l + r  A [3 Marks]
E cÖevnNbZ¡ j = neVd 249.33
 nevd = x= = 0.98 cm [2 Marks]
l + r  A e = B‡jKUª‡bi PvR© 254
E vd = Zvob †eM
 vd =
ne(l + r  A) [2 Marks] 21. GKwU Amxg †iv‡ai †bUIqvK© cÖ`Ë wPÎ Abymv‡i ˆZwi Kiv n‡q‡Q|
Avevi, n = cwievnxi cÖwZ GKK AvqZ‡b cigvYyi msL¨v| cÖwZwU †iv‡ai gvb R| A Ges B we›`yi g‡a¨ Zzj¨ †iva wbY©q Ki|
d
 n = NA [2 Marks]
M
EM
 Zvob †eM, vd = [2 Marks]
edNA(l + r  A)
 gy³ B‡jKUª‡bi `~iZ¡ AwZµ‡g †h mgq jv‡M:
l ledNA(l + r  A)
t= = [2 Marks]
vd EM

20. GKwU wmwjÛvi AvK…wZi cwievnK‡K Gfv‡e ˆZwi Kiv nq hv‡Z Gi

†iva ZvcgvÎvi Dci wbf©ikxj bv nq| GwU wP‡Îi gZ K‡qK ¯Íi ¯Íi
Zvgv, Kve©b Ges wb‡Kj Øviv mvwR‡q wmwjÛvi AvK…wZi cwievnK evbv‡bv
n‡q‡Q| cÖwZwU Zvgvi ¯Í‡ii ˆ`N©¨ 1 †mw›UwgUvi Ges cici Kve©b I
wb‡Kj ¯Íi؇qi ˆ`‡N©¨ †hvMdjI 1 †mw›UwgUvi cÖwZwU bvB‡µvg ¯Í‡ii ˆ`N©¨
wbY©q Ki|
[†`Iqv Av‡Q: p = Av‡cwÿK †iva, a = †iv‡ai DòZv mnM]
A
(Cu) = 1.7  10–8 ohm/m B
(C) = 5  10–5 ohm/m [An infinite network of resistances has been made as shown
(Ni) = 1  10–6 ohm/m in the Figure. Each resistance is R. Find the equivalent
(Cu) = 3.9  10–3 C resistance between A and B.]
(C) = – 5  10–4 C mgvavb: c‡q›U 1 Ges 2 mgwefe m¤úbœ| ZvB `ywU c‡q›U‡K GK‡Î hy³
(Ni) = 4  10–4 C Kiv hvq| c‡q›U 3, 4, 5 Ges 6 mgwefe| GB ¸‡jv‡KI GK‡Î hy³
[A cylindrical conductor is made so that its resistance is Ki‡ev| Gfv‡e Pj‡Z _vK‡e| [3 Marks]
independent of temperature. It is done by stacking layers of
copper, carbon and nichrome as shown in Figure. The
 nd
6  Chemistry 2 Paper Chapter-4
3 2 k
1 I = 2 mA 1 mA 1 mA

4 5 k 3 k

5 †fvëwgUvi mn:
2 KVL e¨envi K‡i cvB 
4I1 – 5I2 = 0 [2 Marks]
6 4I1 = 5I2
I1 2 k

2 mA I2
R 5 k 3 k 6 k
R
R
R Ges I1 + I2 = 2 mA
R R 10
 I1 = mA
9
R 10 20
 V = 2  = Volt [3 Marks]
9 9
R R R
% ÎæwU = 
V – V
R 2 4 8  V  100
 20
†h‡nZz †kÖwY‡Z ZvB Zzj¨ †iva n‡e  [3 Marks] 3–
9
R R R a =  100
R0 = R + + + +............ avivi mgwó S = 1 – r 3
2 4 8 7
†hLv‡b, a = cÖ_gc` =  100 = 25.9% [3 Marks]
= R 1 + + + + ......... 
1 1 1 27
 2 4 8  r = mvaviY AbycvZ
=R  = 2R
1 2
[4 Marks] 23. GKwU 5 †mwg ˆ`‡N©¨i Zvgvi Zv‡i j = 1 A/mm cÖevn Nb‡Z¡i3
1 – 1 we`y¨r cÖevwnZ n‡”Q| Zvgvi NbZ¡ I AvYweK fi h_vµ‡g 9000 kg/m
 2 Ges 63 g/mol–1| cÖwZwU Zvgv cigvYy GKwU B‡jKUªb‡K gy³ B‡jKUªb
 Zzj¨‡iva 2R wn‡m‡e Z¨vM Ki‡Z cv‡i| Zv‡ii ZvcgvÎv 27C| Zvgvi Zv‡ii GK cÖvšÍ
†_‡K Ab¨ cÖv‡šÍ †h‡Z GKwU gy³ B‡jKUª‡bi AwZµvšÍ Mo `~iZ¡ wbY©q
22. wZbwU †iva R1 = 3k , R2 = 2k  Ges R3 = 5k  wP‡Îi g‡Zv
Ki| a‡i bvI †h B‡jKUª‡bi Zvcxq MwZ GKwU Av`k© M¨v‡mi AYyi MwZi
GKwU we`y¨r Dr‡mi mv‡_ hy³ Av‡Q †hB Drm aªæe nv‡i we`y¨r mieivn Abyiƒc|
Ki‡Z cv‡i| we`y¨r DrmwU eZ©bx‡Z I = 2 mA mieivn K‡i| RV = 6 [A copper wire of length 5 cm carries a current of density j
k Af¨šÍixY †iv‡ai GKwU †fvëwgUvi R1 Gi `yB cÖv‡šÍi wefe cv_©K¨ = 1 A(mm)2. The density and molar mass of copper are 9000
cwigvc Kivi Rb¨ mshy³ Kiv nq †hgb fv‡e wP‡Î †`Lv‡bv n‡q‡Q| kg m–3 and 63 g mol–1. Each copper atom contributes one
†fvëwgUv‡ii mmxg †iv‡ai wefe cv_©K¨ (V) cwigv‡ci kZKiv ÎæwU KZ free electron. The temperature of the wire is 27C. Estimate
n‡e? the (average) distance travelled by a free electron during the
b time it moves from one end of the copper wire to the other
end. Assume that thermal motion of electrons are similar to
I R2
that of molecules of an ideal gas.]
R3 R1 RV Vmgvavb: GLv‡b,
cÖwZ GKK AvqZ‡b gy³ B‡jKUª‡bi msL¨v = cÖwZ GKK AvqZb
cigvYyi msL¨v
[Three resistors R1 = 3 k, R2 = 2 k and R3 = 5 k have GKK AvqZ‡bi fi
n=  NA
been connected to a constant current source as shown in †gvjvi fi
figure. The current source supplies current I = 2 mA to the 9000
=  6.02  1023
circuit. A voltmeter with Rv = 6 k internal resistance is 63  10–3
connected, as shown, to measure the potential diference = 8.6  1028 m–3 [2 Marks]
across R1. Find the percentage error in the measurement of Avgiv Rvwb,
potential difference (V) across. R1 caused due to finite j
resistance of the voltmeter.] Zvob †eM, Vd = ne
mgvavb: †fvëwgUvi Qvov: 1  106 A/m2
R1 Gi `yB cÖv‡šÍi wefe cv_©K¨: =
8.6  1028  1.6  10–19
V = (3 k)  (1 mA) = 7.2  10–5 ms–1
= 3 Volt [2 Marks] 5 cm `~iZ¡ AwZµ‡g cÖ‡qvRbxq mgq
 7
5  10–2 hv 20 wgwbU mgq e¨eav‡b 20  †_‡K 40  ch©šÍ mgnv‡i e„w× cvq Ges
t= = 965 s [2 Marks]
7.2  10–5 Zvic‡i Gi gvb w¯’i n‡q hvq| †`Lv †M‡Q †h myBP eÜ nIqvi ci cÖ_g
B‡jKUª‡bi Zvcxq MwZkw³ cÖvq 2 kT Gi mgvb †hLv‡b 20 wgwb‡U †KvlwU Zvi †gvU mwÂZ kw³i 10% nvwi‡q‡Q| †KvlwU KZÿY
3
we`y¨r kw³ mieivn Ki‡Z cvi‡e?
K = 1.38  10–23 Jk–1 hv wKbv †evëRg¨vb aªæeK| R()
1 3
 mv2 = kT R
2 2 40
–23
3kT 3  1.38  10  300
v= =
m 9.1  10–31 20
= 1.17  105 ms–1 [2 Marks] t(min)
S O
 t = 695 s mg‡q B‡jKUª‡bi AwZµvšÍ `~iZ¡: E 20
s = vt [A chemical cell of emf E has negligible internal resistance.
= (1.17  105  695) m It is connected to a variable resistance (R) which changes
= 8.1  104 km [2 Marks] linearly from 20  to 40  in 20 minute and thereafter
becomes constant. After switching off, it lost 10% of energy
24. wP‡Î †`Lv‡bv eZ©bx‡Z a Ges b Gi g‡a¨ Zzj¨ †iva Rab Ges a in first 20 minutes. How long will the energy in the cell last?]
Ges c Gi g‡a¨ Zyj¨ †iva Rac| Zzj¨‡iva؇qi AbycvZ Rab : Rac †ei mgvavb: cÖ_gt 20 wgwb‡Ui g‡a¨ †gvU PvR© cÖevn wnmve Kwi:
t = 20 t = 20

  
Ki| E E
Q0 = idt = dt = dt
R 20 + t
a 10  0 0 0

 Q0 = E ln 
d 20 + 20
200   20  = E ln (2) [4 Marks]
b 10  20 min ci †iva 40  G aªæeK _v‡K Ges Zwor cÖevnI aªæeK n‡q
E
160  50  I= nq|
40
50   cieZ©x t mg‡q PvR© cÖevn:
c
Et
Q = It = [2 Marks]
40  40
[In the circuit shown in the figure the equivalent resistance Avgiv Rvwb, GKwU †Kv‡li nviv‡bv kw³ Zvi g‡a¨ w`‡q cÖevwnZ
between a and b is Rab and the equivalent resistance Pv‡R©i mgvbycvwZK|
between a and c is Rac. Find the ratio Rab : Rac.] AZGe:
mgvavb: a Ges b Gi g‡a¨: Q 9
40  Ges 160  †kÖwY‡Z e‡j Zzj¨‡iva 200  Q0 1
= [2 Marks]
200  I 50  mgvšÍiv‡j e‡j Zzj¨‡iva Et
50  200 40
= 40   =9
50 + 200 E ln2
40  Ges 50  †kÖwY‡Z _vKvq Zzj¨‡iva 90   t = 360 ln2
90  Ges 200  mgvšÍiv‡j e‡j Zzj¨‡iva   †KvlwU ¯’vqx _v‡K T = (20 + 360 ln2) min [2 Marks]
90  200 1800
= 
90 + 200 29 26. wP‡Î †`Lv‡bv eZ©bx‡Z `ywU †iva R1 Ges R2 GKwU Av`k© †Kv‡li
1800
GLv‡b, 10 , 29  Ges 10  †kÖwY‡Z _vKvq Zzj¨‡iva mv‡_ wmwi‡R mshy³ Kiv n‡q‡Q| hLb GKwU †fvëwgUvi R1 Gi `yB cÖv‡šÍ
mshy³ Kiv nq, Gi cvV V1 = 4.0 Volt nq Ges hLb GKB †fvëwgUvi
2380
Rab =  [4 Marks] R2 `yB cÖv‡šÍ mshy³ Kiv nq ZLb Zvi cvV V2 = 6.0 volt| hLb GwU
29 †m‡ji `yB cÖv‡šÍ mshy³ Kiv nq ZLb cvV V3 = 12.0 †fvë| mvwK©‡U R1
GLb, Gi `yB cÖv‡šÍi cÖK…Z †fv‡ëR †ei Ki|
a Ges c Gi g‡a¨:
V3
b Gi mv‡_ hy³ 10  †ivawU I‡cb mvwK©U eZ©bx‡Z AšÍf©y³ bq|
d Ges c Gi g‡a¨ GKwU mvg¨ve¯’vq _vKv ûBU‡÷vb weªR †`Lv hvq|
†h‡nZz 40 = 160
50 200

 50  †iva Zwor hvq bv e‡j Zv ev` †`qv hvq| R1 R1

50  Ges 40  †kÖwY‡Z ˆZwi K‡i = 90 
160  Ges 200  †kÖwY‡Z ˆZwi K‡i = 360 
V1 V2
90  Ges 360  mgvšÍiv‡j ˆZwi K‡i = 72 
72  Ges 10  †kÖwb‡Z ˆZwi K‡i = 82  [4 Marks] [In the circuit shown in the figure, two resistors R 1 and R2
 Rac = 82  have been connected in series to an ideal cell. When a
Rab 2380 1 1190 voltmeter is connected across R1 its reading is V1 = 4.0 Volt
 =  = [2 Marks] and when the same voltmeter is connected across R 2 its
Rac 19 82 1189
reading is V2 = 6.0 Volt. The reading of the voltmeter when
it is connected across the cell is V3 = 12.0 volt. Find the
25. GKwU Zwor ivmvqwbK †Kv‡li Zwor”PvjK ej E hvi Af¨šÍixY actual voltage across R in the circuit.]
1
†iva bMY¨| GwU GKwU cwieZ©bkxj †iva (R) Gi mv‡_ mshy³ Kiv nq,
 nd
8  Chemistry 2 Paper Chapter-4
mgvavb: †fvëwgUv‡ii wiwWs m¤ú~Y© mwVK n‡e hLb GwU e¨vUvwii `yB cÖv‡šÍ mgvavb: we›`y A, B, C, D, E Ges F mgwefe we›`y|
hy³| C 2 B
†m‡ji emf = 12 volt
awi †fvëwgUv‡ii †iva R Ges Zwor cÖevn I
12 V 3 1
R Q

D S P A
I O
R1 R2 U
T
4 6
R

12 RR E F
 V1 =  1 5
R1R R1 + R cÖwZmgZvi Rb¨, P, Q, R, S, T Ges U mgwefe we›`y Ges 1, 2, 3,
+ R2
R1 + R 4, 5, Ges 6 mgwefe we›`y| [4 Marks]
R2 (R1 + R) eZ©bxwU cybivq wb‡Pi gZ K‡i AvuKv hvq,
1+ =3
R1R
R2(R1 + R) P A
 =2
R1R O
R2 R2
 + = 2 ....................(i) [4 Marks]
R R1
GKBfv‡e,
12 RR
V2 =  2
R2R R2 + R
+ R1
R2 + R
1
12
6=
R1(R2 + R)
1+
R2R
R1R2 + R1R eZ©bxwU mij K‡i cvB:
 =1
R2R R R
R1 R1 6 6
 + = 1.................... (ii) [4 Marks] O P A
R R2
mgxKiY (i) Ges (ii) n‡Z d
R R [4 Marks]
cÖwZ¯’vcb K‡i cvB 
12 1 12
R1 2
=
R2 3 R
myZivs O Ges A Gi g‡a¨ Zzj¨ †iva Req = 4 [2 Marks]
 R1 Gi `yB cÖv‡šÍ cÖK…Z wefe:
12.R1 12 12
V1 = = = 28. 25C ZvcgvÎvq †Kv‡bv GKwU cwievnx †Kv‡li ZworØvi `ywUi
R1 + R2 R2 3
1+ 1+
R1 2 ga¨eZx© `~iZ¡ 0.95 cm Ges cÖwZwUi cÖ¯’‡”Q‡`i †ÿÎdj n‡jv 1.8 cm2|
24 cÖwZ wjUvi `ªe‡Y 29.25 g NaCl `ªexf~Z K‡i `ªeYwU Øviv H †KvlwU‡K
 V1 = = 4.8 volt [2 Marks]
5 c~Y© Kiv n‡j †KvlwUi †iva nq 7.25 ohm| H `ªe‡Yi Av‡cwÿK
cwievwnZv I Zzj¨ cwievwnZv wbY©q Ki|
27. wP‡Î, wÎfzR¸‡jvi cÖwZwU evûi †iva R Ges e„‡Ëi cwiwa‡Z e¨eüZ [A conducting cell at 25°C has a distance between two
Zv‡ii †iva bMY¨| we›`y O Ges A Gi g‡a¨ Zzj¨ †iva wbY©q Ki| electrodes of 0.95 cm and a cross-sectional area of each of
1.8 cm2. If the cell is filled with a solution containing 29.25 g
of NaCl per liter of solution, the resistance of the cell is 7.25
ohm. Determine the relative conductivity and the equivalent
conductivity of that solution.]
1 l
mgvavb: Av‡cwÿK cwievwnZv,  = R  A
A 1 0.95
O = 
7.25 1.8
= 7.279  10–2 ohm–1 cm–1
[5 Marks]
1000
Zzj¨ cwievwnZv, e =   Ce
1000
=  
[In the figure, each segment (side of small triangle) has w 
e
resistance R and wire used in the circumference of the circle V
has negligible resistance. Find equivalent resistance between
point O and A.]
 9
1000 cathode during 25 min, determine the average value of the
= 7.279  10–2 
29.25 1000 current and the current produced in the fuel cell. (H =
1
 1.008)]
–1 2 –1
= 145.58 ohm cm (g eqv) [5 Marks] mgvavb: nvB‡Wªv‡Rb dz‡qj †m‡ji †ÿ‡Î:
A¨v‡bvW ZworØv‡ii RviY Aa©-wewµqv:
29. cvwbi Zwor we‡køl‡Yi †ÿ‡Î mvgvb¨ GwmW †hvM Kivi cÖ‡qvRb c‡o 2H2(g) + 4OH–(aq)  4H2O + 4e–
†Kb? K¨v‡_vW ZworØv‡ii weRviY Aa©-wewµqv:
[Why is it necessary to add a little acid in electrolysis of O2(g) + 2H2O(l) + 4e–  4OH–(aq)
water?] mgMÖ dz‡qj †mj wewµqv : 2H2(g) + O2(g)  2H2O(l)
mgvavb: cvwbi Zwor we‡køl‡Y `yB-Pvi †duvUv GwmW A_ev Ab¨ †Kv‡bv 1
ev, H2(g) + 2 O2(g)  H2O(l)
B‡jK‡UªvjvBU †hvM Kivi cÖ‡qvRb c‡i| Avgiv Rvwb, weï× cvwbi
pH gvb 7| weï× cvwb‡Z H+ Avq‡bi NbgvÎv I OH– Avq‡bi myZivs, †Kvl wewµqv n‡Z †`Lv hvq, cÖwZ †gvj H2 wewµqv K‡i 2
NbgvÎv mgvb| 25C ZvcgvÎvq G gvb [H+] = [OH–] = 1.0  10– †gvj e– cÖevn Z_v 2 F Zwor Avavb Drcbœ K‡i|
7
mol L–1| H+ Avqb I OH– Avq‡bi NbgvÎv mgvb _vKvq weï× 12.6 g H2 =
12.6
mol H2 = 6.25 mol H2
cvwb‡Z B‡jKUªb cwievwnZ n‡Z cv‡i bv| weï× cvwb‡Z hLb mvgvb¨ 1.008 × 2
GwmW Z_v H+ Avqb †hvM Kiv nq ZLb cvwb‡Z H+ Avq‡bi NbgvÎv  6.25 mol H2 wewµqv K‡i Drcbœ K‡i = (2 × 6.25)
†e‡o hvq| `ªe‡Y H+ Avqb I OH– Avq‡bi NbgvÎvi cv_©‡K¨i = 12.5 F
Kvi‡Y ZLb B‡jKUªb Z_v Zwor cÖevwnZ nq| [10 Marks]  Drcbœ Zwor 12.5 F| [5 Marks]
Avgiv Rvwb, Q = I × t
Q
30. GKwU A¨vjywgwbqvg wk‡í ˆ`wbK 20 ton A¨vjywgwbqvg avZz Drcv`b I=
t
nq| hw` ˆ`wbK 30000 sec mgq Kvh©Ki nq Z‡e G‡Z ˆ`wbK KZ
12.5 × 96500
d¨viv‡W we`y¨r I KZ Amp we`y¨r kw³i cÖ‡qvRb n‡e? =
25 × 60
[In an aluminium industry, 20 ton aluminium metal is = 804.167 A
produced. If it works for 30000 sec, then what amount of
 ZworcÖev‡ni Mo gvb 804.167 A| [5 Marks]
current (in faraday and ampere unit) is needed?]
mgvavb: Avgiv Rvwb,
F = ne 33. 0.75 A Zwor cÖevn 1 wgwbU 20 †m‡KÛ mgqe¨vcx Pvjbv Ki‡j H+,
20  1000 Ni2+ I Al3+ Avq‡bi cÖwZwUi KZwU cigvYy‡Z iƒcvšÍwiZ n‡e?
= 3 [How many atoms of each of H+, Ni2+ and Al3+ ions will be
27  10–3
converted if a current of 0.75 A is applied for 1 min 20 s?]
= 2.222  106 F [4 Marks]
Avevi, mgvavb: Q = neF
Q It
Q n= =
I= eF eF
t
ItNA
F  96500  N= [2 Marks]
= eF
t
 H Avq‡bi cigvYyi msL¨v,
+
2.22  106  96500
=
30000 0.75  80  6.023  1023
N H+ = wU
1  96500
= 7.15  106 A [6 Marks]
= 3.745  1020 wU [2 Marks]
31. jNy NaCl `ªe‡Yi Zwor we‡køl‡Y Kx cwigvY we`y¨r cÖev‡ni d‡j  Ni Avq‡bi cigvYyi msL¨v,
2+

1 NÈv mg‡q Pt K¨v‡_v‡W cÖgvY Pvc I ZvcgvÎvq 0.112 L H2 0.75  80  6.023  1023
NNi2+ = wU
Drcbœ n‡e? 2  96500
[What amount of current in the electrolysis of dilute NaCl = 1.87  10 wU
20
[3 Marks]
solution will produce 0.112 L of H2 in 1 h at the Pt cathode  Al3+ Avq‡bi cigvYyi msL¨v,
at standard pressure and temperature?] 0.75  80  6.023  1023
mgvavb: It = neF [3 Marks] NAl3+ = wU
3  96500
PV
 e F = 1.25  1020 wU [3 Marks]
RT
I=
t
1  0.112 34. 200 mL †Wwm‡gvjvi NaCl `ªe‡Yi g‡a¨ w`‡q 2.5 amp Zwor
  96500 4 wgwbU 38 †m‡KÛ mgq a‡i cÖevwnZ Kiv n‡jv| hw` cÖevwnZ Zwo‡Zi
0.0821  273
=
3600 Kvh©ÿgZv 90% nq, Z‡e Zwor we‡køl‡Yi ci Drcbœ `ªe‡Yi pH
= 0.268 A [7 Marks] gvb wbY©q Ki|
[A 2.5 amp current is passed through 200 mL of decimolar
32. †Kv‡bv GKwU nvB‡Wªv‡Rb dz‡qj †mj-G A¨v‡bv‡W cÖweó 12.6 g H2 NaCl solution for 4 min 38 s. If the efficiency of the flowing
hw` 25 wgwbU mg‡q K¨v‡_v‡W cwiPvwjZ Aw·‡R‡bi mv‡_ wiW· wewµqv electrolyte is 90%, determine the pH value of the resulting
solution after electrolysis.]
K‡i, Z‡e H dz‡qj †m‡j Drcbœ Zwor I Zwor cÖev‡ni Mo gvb wbY©q
mgvavb: 2NaCl  2Na+ + 2Cl–
Ki| (H = 1.008)
2Cl– + H2O  Cl2 + H2 + OH–
[If 12.6 g of H2 at the anode in a hydrogen fuel cell
It (0.9  2.5)  (4  60 + 38)
undergoes a redox reaction with oxygen conducted at the n= =
eF 1  96500
 nd
10  Chemistry 2
Paper Chapter-4
–3
= 6.482  10 mol [3 Marks] 2
 I2 =  I = 0.2436 A [1 Mark]
 200 mL `ªe‡Y OH– Avq‡bi cwigvY 6.482  10–3 mol 2+3+6
6.482  10–3 [CuSO4 I ZnSO4 Gi ga¨ w`‡q cÖevwnZ Zwor I2]
 200 mL `ªe‡Y OH– Avq‡bi NbgvÎv =
200  10–3 wAg =
MAgI1t
= 0.03241 M [4 Marks] eAgF
 `ªe‡Yi pH = 14 – pOH 107.87  1.0964  t
 1.45 =
= 14 – [– log(0.03241)] = 12.51 [3 Marks] 1  96500
 t = 1183.11 sec [2 Marks]
35. we`y¨rcÖev‡ni Kvh©ÿgZv 50% n‡j 12.3 g bvB‡Uªv‡ebwRb‡K A¨vwbwj‡b MCuI2t
weRvwiZ Ki‡Z KZ cwigvY Zwo‡Zi cÖ‡qvRb? hw` ZworØvi؇qi wefe wCu =
eCuF
cv_©K¨ 3 V nq, Zvn‡j KZ kw³ LiP n‡e? 63.5  0.2436  1183.11
 wCu =
[How much current is required to oxidize 12.3 g of 2  96500
nitrobenzene to aniline at 50% electrical efficiency? If the wCu = 0.09482 g [2 Marks]
potential difference between the two electrodes is 3V, how MZnI2t
much power will be consumed?] wZn =
eZnF
mgvavb: bvB‡Uªv‡ebwR‡bi weRviY wewµqv: 65.38  0.2436  1183.11
wZn =
NO2 NH2 2  96500
 wZn = 0.09763 g [2 Marks]
+ 6H+ + 6e– + 2H2O
37. Pb(s) / Pb2+ (aq) || Ag+(aq) / Ag(s); GB †m‡ji jeY †mZz
1 †gvj 6F wn‡m‡e wb‡Pi †Kvb¸‡jv Dchy³ bq, KviYmn e¨vL¨v Ki|
¦AvYweK fi = 123 K2SO4, KNO3, KCl
123 g bvB‡Uªv‡ebwR‡bi weRvi‡Y 6 F Zwor cÖ‡qvRb [Pb(s) / Pb2+ (aq) || Ag+(aq) / Ag(s); Which of the following is
6  12.3 not suitable as a salt bridge in this cell, explain with reasons.
 12.3 g bvB‡Uªv‡ebwR‡bi weRvi‡Y 123 K2SO4, KNO3, KCl]
–
= 0.6 F Zwor cÖ‡qvRb mgvavb: GLv‡b, K2SO4 I KCl Dchy³ bq| KviY, SO2– 4 Avqb I Cl
2+ +
[2 Marks] Avqb Pb I Ag Gi mv‡_ AgCl, Ag2SO4, PbSO4, PbCl2 jeY
†h‡nZz wewµqvq cÖevwnZ Zwo‡Zi Kvh©ÿgZv = 50% MVb K‡i hv ¯^í`ªve¨ Ges Aat‡ÿc Gi m„wó K‡i| Zwor we‡køl‡Yi
 50 F ZworcÖevn †c‡Z n‡j 100 F cÖevngvÎvi cÖ‡qvRb| †ÿ‡Î Aat‡ÿc †hb bv c‡o GiKg e¨e¯’v wb‡Z nq| NO3– RvZxq
 0.6 F ZworcÖevn †c‡Z n‡j cÖ‡qvRbxq cÖevngvÎv jeY mvaviYZ `ªeYxq n‡q _v‡K d‡j Aat‡ÿc c‡o bv| ZvB,
100  0.6 KNO3 e¨envi Dchy³| [10 Marks]
=
50
= 1.2 F 38. Pb / Pb2+ Ges I2/I–, Pt Gi cÖgvY B‡jK‡UªvW wefe h_vµ‡g
= 1.2  96500 C – 0.126 V Ges + 0.536 V; GLb c„_Kfv‡e 0.1 †gvjvi Mvp‡Z¡i Avqb
= 115800 C [3 Marks] wb‡q GKwU M¨vjfvwbK †Kvl MVb Kiv n‡j Pt B‡jK‡UªvW‡K K¨v‡_vW
 e¨wqZ Zworkw³ = wefe cv_©K¨  cÖevwnZ Zwo‡Zi cwigvY wn‡m‡e aiv nq| †KvlwUi g‡a¨ Kx cwigvY wefe m„wó n‡q‡Q?
2+ –
= 3  115800 = 347400 J [5 Marks] [Standard electrode potentials of Pb/Pb and I2/I , Pt are –
0.126 V and + 0.536 V respectively; Now, if a galvanic cell is
36. E = 2.2 V formed with ions of 0.1 molar concentration individually,
the Pt electrode is considered as the cathode. What amount
of potential is generated in the cell?]
mgvavb:
K¨v‡_v‡W wewµqv: I2 (s) + 2e  2I–(aq) (weRviY)
Ag2SO4 A¨v‡bv‡W wewµqv: Pb (s) – 2e  Pb2+(aq) (RviY)
mgMÖ †Kvl wewµqv: Pb(s) + I2(s)  Pb2+(aq) + 2I–(aq)
2 0 0 0
Ecell = Ecathode + Eanode = (0.536 + 0.126) = 0.662 V
bvb©‡÷i mgxKiY Abymv‡i,
CuSO4 ZnSO4 0 0.059 [Pb][I2]
Ecell = Ecell + log
3 6 n [Pb2+][I–]2
log  2+ – 2
1.45 g Ag Rgv n‡j, KZ MÖvg Cu I KZ MÖvg Zn Rgv n‡e? 0 0.059 1
= Ecell + [3 Marks]
[If 1.45 g of Ag is deposited,how many grams of Cu and Zn will
2 [Pb ] [I ] 
accumulate?] [ ∵ KwVb c`v_©¸wji MvpZ¡ =1]
18 0.059 1
mgvavb: Req = {( 3+ 6)–1 + 2–1}–1  = 11  = 0.662 + log
2 (0.1) (0.1)2
E 2.2
I= = A = 1.34 A [2 Marks] [∵ [Pb2+] = 0.1 M; [I–] = 0.1 M]
Req 18
0.059
11 = 0.662 + × 3 log 10
2
3+6
 I1 =  I = 1.0964 A [1 Mark] = 0.662 + 0.0885
2 + 3 +6
= 0.7505 V [7 Marks]
[Ag2SO4 Gi ga¨ w`‡q cÖevwnZ Zwor I1]
 11
39. wb¤œwjwLZ wewµqvwUi mvg¨aªæeK wbY©q Ki: K‡i GKwU nvB‡Wªv‡Rb ZworØvi cÖ¯‘Z Kiv nj| ZworØviwUi RviY
Fe2+ + Ce4+ ⇌ Fe3+ + Ce3+ (298 K) wef‡ei gvb wbY©q K‡iv|
[E0Ce4+/ Ce3+ = 1.61 V; E0Fe3+/ Fe2+ = 0.77 V] [A platinum plate is partially immersed in HCl solution at
[Determine the summation of the following charge: pH= 10 Pure hydrogen gas at atmospheric pressure is used
to produce hydrogen electrode.]
Fe2+ + Ce4+ ⇌ Fe3+ + Ce3+ (298 K) mgvavb: nvB‡Wªv‡Rb ZworØv‡ii †h weRviY wewµqv msNwUZ nq
[E0Ce4+/ Ce3+ = 1.61 V; E0Fe3+/ Fe2+ = 0.77 V]] †mwU n‡jv,
mgvavb: Fe2+ ⇌ Fe3+ + e– [ e = 1] 1
H+(aq) + e–  H (g)
Ce4+ + e– ⇌ Ce3+ 2 2
mvg¨ve¯’vq, Ecell = 0 0 0.059 [H+]
ERed = EH+/ H +
1 log 1
d‡j, Q = k 2 2 1
0 0 0 (PH2)2
Ecell = (EFe2+/Fe3+) + (ECe4+/Ce2+) 1
= (– 0.77 + 1.61) = 0.84 0 0.059 (PH2)2
0 RT  ERed = EH+/1 H – log [3 Marks]
Ecell = Ecell – lnQ [3 Marks] 2 2 1 [H+]
eF
0 RT cÖkœvbymv‡i, PH2 = 1 atm Ges E0H+/1 H2 = 0
 0 = Ecell –
2
lnk 1
eF
2
RT 0.059 (1) 1
0
 Ecell = lnk  ERed = 0 – log = – 0.059 log +
eF 1 [H+] [H ]
0 eF  ERed = – 0.059 {log1 – log[H+]} [2 Marks]
 lnk = Ecell  = – 0.059 {0 + (– log[H+])}
RT
0.84  1  96500 = – 0.059 pH {∵pH = – log [H+]}
 lnk =
8.314  298 ERed = – 0.059  10 [∵ pH = 10]
 k = e(32.717) = 1.61738  1014 [7 Marks]  ERed = – 0.59 V
myZivs, EOx = – ERed = 0.59 V [5 Marks]
40. GKwU cø¨vwUbvg cvZ‡K pH = 10 G HCl `ªe‡Y AvswkK wbgw¾Z
Kiv n‡jv Ges H `ªe‡Y 1 evqygÐjxq Pv‡c weï× nvB‡Wªv‡Rb M¨vm Pvjbv

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