JEE–MAIN EXAMINATION – JANUARY 2025

(HELD ON THURSDAY 23rd JANUARY 2025) TIME : 9:00 AM TO 12:00 NOON

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A 1  x  11 
2/13
Ix   C
 e4 loge x 2 1
1
 4  x  15 
1 e  dx is
1. The value of 
x   loge x 2 1  2/13 2/13
  6loge x 2 1
1 1

 1  26  1  13 
e2
e e  I  37   I  24       
4  52  4  39 
(1) loge2 (2) 2
1 1 1 
(3) 1 (4) e2 =  2/13  2/13 
4 2 3 
Ans. (3)
1 1 1 
dx =   
Sol. Let lnx = t   dt 4  41/13 91/13 
x
1
 b = 4, c = 9
4
e 1 t 2 3(b + c) = 39
I 1
dt
2
1
2
3. If the function
2 1  6  t 
e1 t e
2
1  sin  k1  1 x  sin  k 2  1 x , x  0
4
e  
1 6 t
2
x
I dt 
1 1
f (x)   4 , x0
2 2 
e    e 1t  2  k1 x 
1 6 t 2
 2
log e   , x0
4  x  2  k2x 
2I   dt   t 2 = 4 – 2 = 2
4

2 is continuous at x = 0, then k12 + k22 is equal to

I=1 (1) 8 (2) 20

dx (3) 5 (4) 10
2. Let I(x)   .
11 15
Ans. (4)
 x  1113  x  1513
Sol. lim
2
sin  k1  1 x  sin  k 2  1 x  4
1 1 1  x  0 x
If I(37) – I(24) =  1  1  , b, c  , then
4  13   2(k1 + 1) + 2(k2 – 1) = 4
b c13 
 k1 + k2 = 2
3(b + c) is equal to
(1) 40 (2) 39 2  2  k1x 
 lim ln  4
(3) 22 (4) 26
x 0 x  2  k2x 

Ans. (2) 1  k  k  x 
 lim ln 1  1 2   2
dx x 0 x
 2  k 2x 
Sol. I(x)   11 15
 x  11  x  1513 13 k1  k 2
 2
x  11 2
26
Put t  dx  dt
x  15  x  5
2  k1 – k2 = 4
 k1 = 3, k2 = – 1
1 dt 1 t 2/13
Ix   11/13
 . k12  k 22  9  1  10
26 t 26 2 / 13

1
4. If the line 3x – 2y + 12 = 0 intersects the parabola 1 6e2x
7  e2x   7  32x 2
 y.  dx
4y = 3x2 at the points A and B, then at the vertex of
the parabola, the line segment AB subtends an
angle equal to y 3
 C
 11   3 7e 2x
7  e 2x
(1) tan 1   (2)  tan 1  
9 2 2 5 3
(0, 5)   C C=1
8 8
4 9
(3) tan 1   (4) tan 1  
5 7  y = – 3 + 7 + e2x
Ans. (4) y = e2x + 4
k=8

Sol. B(4,12) x 4  2x 3  3x 2  2x  2
6. Let f(x) = logex and g(x) 
2x 2  2x  1
. Then the domain of fog is
A(–2, 3)
(1)  (2) (0, )

–4 O (3) [0, ) (4) [1, )

3x – 2y + 12 = 0 Ans. (1)
2
4y = 3x Sol. f(x) = lnx
 2(3x + 12) = 3x
2

x 4  2x 3  3x 2  2x  2
x – 2x – 8 = 0
2 g(x) =
2x 2  2x  1
 x = – 2, 4
Dg  R
mOA = – 3/2, mOB = 3
Df  (0, )
 3 
 2 3 9 For Dfog  g(x) > 0
tan    
 1 9  7 x 4  2x 3  3x 2  2x  2
 2  0
2x 2  2x  1
9
  tan 1   (angle will be acute)  x4 – 2x3 + 3x2 – 2x + 2 > 0
7
5. Let a curve y = f(x) pass through the points (0, 5)  Clearly x < 0 satisfies which are included in option
and (loge2, k). If the curve satisfies the differential (1) only.
equation 2(3 + y)e dx – (7 + e2x)dy = 0, then k is
2x

7. Let the arc AC of a circle subtend a right angle at

equal to
the centre O. If the point B on the arc AC, divides
(1) 16 (2) 8
(3) 32 (4) 4 length of arc AB 1
the arc AC such that  , and
Ans. (2) length of arc BC 5

Sol.
dy 2  3  y  .e

2x
OC  OA  OB , then   2  
3  1  is equal
dx 7  e 2x
to
dy 2y.e2x 6.e2x
 
dx 7  e2x 7  e2x (1) 2  3 (2) 2 3
2x
2e
  7  e2 x dx 1 (3) 5 3 (4) 2  3
I.F.  e 
7  e2x

2
Ans. (1) Sol. a = 3
Sol. 1
S4 = (S8 – S4)
B 5 5
1
 5S4 = S8 – S4
A C  6S4 = S8
4
 6.  2  3   4  1  d 
15° 2
75° 8
 =  2  3   8  1 d 
2
 12(6 + 3d) = 4(6 + 7d)
  18 + 9d = 6 + 7d
c  a  b ….(1)
 d=–6
a.c  a.a  b.a 20
 S20 =  2  3   20  1 6  
0 =  +  cos 15° ….(2) 2 
= 10 [6 – 114]
 b.c  a.b  b.b = – 1080
cos75° =  cos 15° +  ….(3) 9. Let P be the foot of the perpendicular from the point
x  3 y  2 z 1
(2) & (3) cos75° = –  cos215° +  Q(10, –3, –1) on the line   . Then
7 1 2
cos75o 1 2 2 the area of the right angled triangle PQR, where R is
  
2
sin 15o
sin15o
3 1 the point (3, –2, 1), is
(1) 9 15 (2)
 
30
 cos15o  3  1
(2)     (3) 8 15 (4) 3 30
sin15o 3 1   Ans. (4)

 3  1 a   2 2  b
Q(10,–3,–1)
 Sol.
 c  
 3  1  3  1 
Now

 3  1  2  
P() =(10,1,–3)
 3  1 .2 2
 2  3 1   
 3  1 3 1
R(3,–2,1)

  x  3 y  2 z 1
2
 3 1   
= 4 7 1 2
2
 7 + 3, –  + 2, – 2 – 1
3  1  2 3  8 dr’s of QP 
=
2 7 – 7, –  + 5, – 2
= 2 3 Now
8. If the first term of an A.P. is 3 and the sum of its (7 – 7) . 7 – (– + 5) + (2).2 = 0
54  – 54 = 0   = 1
first four terms is equal to one-fifth of the sum of
 P = (10, 1, – 3)
the next four terms, then the sum of the first
PQ  4jˆ  2kˆ
20 terms is equal to
PR  7iˆ  3jˆ  4kˆ
(1) –1200 (2) –1080
i j k
(3) –1020 (4) –120 1
Area  0 4 2 = 3 30
2
Ans. (2) 7 3 4

3
 z i 1 12. The number of words, which can be formed using
10. Let  , z  , be the equation of a circle
2z  i 3 all the letters of the word “DAUGHTER”, so that all
with center at C. If the area of the triangle, whose the vowels never come together, is
vertices are at the points (0, 0), C and (, 0) is 11 (1) 34000 (2) 37000
square units, then  equals
2

(1) 100 (2) 50 (3) 36000 (4) 35000

121 81 Ans. (3)
(3) (4)
25 25 Sol. DAUGHTER
Ans. (1) Total words = 8!
z i 1
Sol.  Total words in which vowels are together = 6! × 3!
2z  i 3
words in which all vowels are not together

z i 2 = 8! – 6! × 3!

i 3 = 6! [56 – 6]
z
2 = 720 × 50
i = 36000
3|x – iy – i| = 2 |x – iy + |
2
2 2 2 2 Ans.(3)
9(x + (y+1) ) = 4 (x + (y – 1/3) )
2 2 2 2
9x + 9y + 18 y + 9 = 4x + 4y – 4y + 1 13. Let the area of a PQR with vertices P(5, 4), Q(–2, 4)
5x2 + 5y2 + 22y + 8 = 0 and R(a, b) be 35 square units. If its orthocenter
22 8  14 
x2 + y 2 + y+ =0 and centroid are O  2,  and C(c, d) respectively,
5 5  5 
11 then c + 2d is equal to
centre  (0, – )
5
7
0 0 1 (1) (2) 3
1 3
0 11 / 5 1  11
2 8
 0 1 (3) 2 (4)
3
2
 11 
      11 2  Ans. (2)
2

 5  P(5, 4)
  = 100
2
Sol.
11. Let R = {(1, 2), (2, 3), (3,3)} be a relation defined
O(2, )
on the set {1, 2, 3, 4}. Then the minimum number
of elements, needed to be added in R so the R
Q(–2,4) R(a,b)
becomes an equivalence relation, is :
(1) 10 (2) 8 Equation of lines QR = 5x + 2y + 2 = 0
(3) 9 (4) 7 Equation of lines PR = 10x –3y – 38 = 0
Ans. (4)  Point R (2, –6)
Sol. A = {1, 2, 3, 4}
52 2 4 46
Centroid =  , 
For relation to be reflexive  3 3 
R = {(1,2), (2, 3), (3,3)}
5 2
Minimum elements added will be =  , 
3 3
(1,1), (2,2), (4,4) (2,1) (3,2) (3,2) (3,1) (1,3)
5 4
 Minimum number of elements = 7 c + 2d =  3
3 3
Option : (4)

4
  3  12 5  17. Let the position vectors of the vertices A, B and C
14. If x , then cos 1  cos x  sin x  is
2 4  13 13  of a tetrahedron ABCD be ˆi  2jˆ  kˆ , ˆi  3jˆ  2kˆ
equal to
–1 4 –1 5
and 2iˆ  ˆj  kˆ respectively. The altitude from the
(1) x – tan (2) x – tan
3 12 vertex D to the opposite face ABC meets the
–1 4 –1 5
(3) x + tan (4) x + tan median line segment through A of the triangle
5 12
Ans. (2) ABC at the point E. If the length of AD is
110
 3 3
Sol. x
2 4 805
and the volume of the tetrahedron is , then
 12 5 
cos 1  cos x  sin x  6 2
 13 12 
the position vector of E is
cos–1(cosx cos+sinx sin)
cos–1(cos(x–))
 
(1)
2

1 ˆ ˆ
i  4 j  7kˆ  (2)
12

1 ˆ ˆ ˆ
7i  4 j  3k 
 x –  because x –   (– , )
2 2
5
(3)
6

1 ˆ
12i  12ˆj  kˆ  (4)
6

1 ˆ
7i  12ˆj  kˆ 
  x – tan–1 .
12
Ans. (4)
15. The value of (sin70°)(cot10°cot70° – 1) is
(1) 1 (2) 0 D
(3) 3/2 (4) 2/3
Ans. (1)
Sol. sin70º (cot 10º cot70º – 1)
cos 80  Sol.
 1
sin10 C(2,1,–1)
16. Marks obtains by all the students of class 12 are A(1,2,1
presented in a frequency distribution with classes ) E 3 3
F  ,2,  
of equal width. Let the median of this grouped data 2 2
be 14 with median class interval 12-18 and median
class frequency 12. If the number of students B(1,3,–2)
whose marks are less than 12 is 18, then the total
number of students is
(1) 48 (2) 44 1
Area of ABC = AB  AC
(3) 40 (4) 52 2
Ans. (2) 1 ˆ ˆ ˆ 1
 5i  3j  k  35
N  2 2
 2 F
Sol. medain     h volume of tetrahedron
 f 
 
1 805
N  = × Base area × h =
3 6 2
 2  18 
 12     6  14
 12  1 1
 35  h 
805
  3 2 6 2
N 
 2  18  23
 6  2 h
 12  2
 
13 13
N AE 2  AD2  DE 2   AE 
 18  4  N = 44 18 18
2

5
  ˆi  5kˆ  Ans. (2)
AE  AE .  
 26  Sol.    1 x    4 y  z  5
13  ˆi  5kˆ  x     1 y     4  z  7
 . 
18  26 
   1 x    2 y    2  z  9
13  ˆi  5kˆ  ˆi  5kˆ For infinitely many solutions
 . 
18  26  6  1   4 
ˆi  5kˆ D   1 4 0
P.V. of E 
6
1
6

 ˆi  2ˆj  kˆ  7iˆ  12ˆj  kˆ    1   2    2

18.
–1
If A, B and (adj(A ) + adj(B )) are non-singular
–1
( – 3) (2+ 1) = 0
matrices of same order, then the inverse of 5 4 
–1 –1
A(adj(A ) + adj(B )) B, is equal to –1
Dx  7   1 4 0
–1
(1) AB–1 + A B (2) adj(B–1) + adj(A–1) 9   2    2

1 AB1 BA 1 2(3 – ) (23 2) = 0

(3) (adj(B) +adj(A)) (4) 
AB A B =3

Ans. (3)  2 + = 9 + 3 = 12

1
20. One die has two faces marked 1, two faces marked

     
1
1 1
Sol.  A adj A  adj B .B 2, one face marked 3 and one face marked 4.
 
Another die has one face marked 1, two faces
1
    adjB .A
B . adj A 1 1 1
marked 2, two faces marked 3 and one face marked

adj  A  A  B  adj  B  .A

4. The probability of getting the sum of numbers to
B1 1 1 1 1 1

be 4 or 5, when both the dice are thrown together,

1 1 1 1
B A I  B IA is

B1 A 1 1 3
 (1) (2)
A B 2 5

2 4
adjB adjA (3) (4)
  3 9
BA A B
Ans. (1)
1
  adjB  adjA  Sol. a = number or dice 1
A B

19. If the system of equations b = number on dice 2

( – 1)x + ( – 4)y + z = 5 (a,b) = (1,3), (3,1), (2,2), (2,3), (3,2), (1,4), (4,1)
x + ( – 1)y + ( –4)z = 7 Required probability
( + 1)x + ( + 2)y – ( + 2)z = 9 2 2 1 1 2 2 2 2 1 2 2 1 1 2
             
has infinitely many solutions, then  +  is equal 2
6 6 6 6 6 6 6 6 6 6 6 6 6 6
to 18 1
 
(1) 10 (2) 12 36 2
(3) 6 (4) 20

6
 SECTION-B r1 r2 r 3
21. If the area of the larger portion bounded between 6 0 0
1 4 0 2
the curves x2 + y2 = 25 and y = |x – 1| is (b + c),
4 2 0 4
b, c  , then b + c is equal to ________ 0 0 6
3 3 0
Ans. (77)
1 3 2
(–3,4)
y = x–1 0 6 0
y = –x+1
Sol. (4,3
) 6 6 6 6
sum =  (3) + (3)2  (3)3
600 402 204 006
0 1 5
6 6 6
+ (2)  (2)1 (3)1  (2)2
330 132 060

= 1 + 45 + 135 + 27 + 40 + 360 + 4 = 612

2 2
x +y =5 23. Let the circle C touch the line x – y + 1 = 0, have
x + (x – 1) = 25  x = 4
2 2
the centre on the positive x-axis, and cut off a
x2 + (–x + 1)2 = 5  x = – 3 4
chord of length along the line –3x + 2y = 1.
4 13
1 1
A  25   25  x2 dx   4  4   3  3
2 2 x 2 y2
3 Let H be the hyperbola   1 , whose one of
 2 2
4
25  x 25 x the foci is the centre of C and the length of the
A  25   25  x 2  sin 1 
2 2 2 5  3 transverse axis is the diameter of C. Then 22 + 32
25  25 4 25 3 is equal to ________
A  25   6  sin 1  6  sin 1 
2  2 5 2 5 Ans. (19)
1 25 
A  25   . 1
2 2 2
75 1
A 
4 2 M
Sol.
1 C
A  75  2  (,0)
4 –1
r
b = 75, c= 2
b + c = 75 + 2 = 77
22. The sum of all rational terms in the expansion of
1/3 1/2 6
(1 + 2 + 3 ) is equal to _______
Ans. (612) x–y+1=0
6
 1 1
 p=r
Sol.  1  2 3  3 2 
 
   – 0 1
= r  ( + 1) = 2r .... (1)
2 2

6 2r
r 2
= (1) r1 (2) 3 (3) 3
r1 r2 r3 2

7
 2 2
 3  0  1   2  2
now     r
 9  4   13  10
y =f(x)
 (3 + 1) + 4 = 13 r ......(2)
2 2

(  1)2 –1 1
(1) & (2)  (3 + 1)2 + 4 = 13
2
–10 y =f(x)
182 + 12 + 2 + 8 = 132 + 26 + 13
5 – 14 –3 = 0
a(–10,10)

5 – 15 +  – 3 = 0
 = –10,  = 10
5 – 15 +  – 3 = 0
 – 2 = 10 + 20 = 30
1
  ,3 25. If the equation a(b – c)x2 + b(c – a)x + c(a – b) = 0
5
36
has equal roots, where a + c = 15 and b  , then
 r= 2 2 5
a2 + c2 is equal to ________
How e = 3 and 2 = 4 2 Ans. (117)
2
Sol. a(b – c) x + b (c – a) x + c(a – b) = 0
e =9 = 2 2  =8
2 2 2

x = 1 is root  other root is 1

 2  +=–
b(c  a)
2
2  1  2   9
a(b  c)
  
 – bc + ab = 2ab – 2ac
2 + 2 = 9
 2ac = ab + bc
 =1 2
 2ac = b(a + c)
 22 + 32 = 2 (8) + 3(1) = 19  2ac = 15b ... (1)

24. If the set of all values of a, for which the equation  36 

 2ac = 15   = 108
3
5x – 15x – a = 0 has three distinct real roots, is the  5 
interval (, ), then  –2 is equal to ________
 ac = 54
Ans. (30)
Sol. 5x3 – 15x – a = 0 a + c = 15

f(x) = 5x3 – 15x a2 + c2 + 2ac = 225

f'(x) = 15x2 – 15 = 15(x–1)(x + 1) a2 + c2 = 225 – 108 = 117

8
 JEE–MAIN EXAMINATION – JANUARY 2025
(HELD ON THURSDAY 23rd JANUARY 2025) TIME : 9 : 00 AM TO 12 : 00 NOON

PHYSICS TEST PAPER WITH SOLUTION

SECTION-A 28. Given below are two statements:
26. Regarding self-inductance : Statement-I : The hot water flows faster than cold
A : The self-inductance of the coil depends on its water.
geometry. Statement-II : Soap water has higher surface
B : Self-inductance does not depend on the
tension as compared to fresh water.
permeability of the medium.
In the light above statements, choose the correct
C : Self-induced e.m.f. opposes any change in the
answer from the options given below
current in a circuit.
(1) Statement-I is false but Statement II is true
D : Self-inductance is electromagnetic analogue of
mass in mechanics. (2) Statement-I is true but Statement II is false

E : Work needs to be done against self-induced (3) Both Statement-I and Statement-II are true
e.m.f. in establishing the current. (4) Both Statement-I and Statement-II are false
Choose the correct answer from the options given Ans. (2)
below: Sol. Hot water is less viscous then cold water.
(1) A, B, C, D only (2) A, C, D, E only Surfactant reduces surface tension.
–30
(3) A, B, C, E only (4) B, C, D, E only 29. A sub-atomic particle of mass 10 kg is moving
6
Ans. (2) with a velocity 2.21 × 10 m/s. Under the matter
Sol. Self inductance of coil wave consideration, the particle will behave
–34
 N2 A closely like ______. (h = 6.63 × 10 J.s)
L= 0
2R (1) Infra-red radiation (2) X-rays
27. A light hollow cube of side length 10 cm and mass (3) Gamma rays (4) Visible radiation
10g, is floating in water. It is pushed down and Ans. (2)
released to execute simple harmonic oscillations. h 6.63  10 34
–2 Sol.  =  –30
The time period of oscillations is y × 10 s, p 10  2.21  10 6
where the value of y is –10
= 3 × 10 m
2
(Acceleration due to gravity, g = 10 m/s , density Hence particle will behave as x-ray.
3 3
of water = 10 kg/m ) 30. A spherical surface of radius of curvature R,
(1) 2 (2) 6 separates air from glass (refractive index = 1.5).
(3) 4 (4) 1
The centre of curvature is in the glass medium. A
Ans. (1)
point object ‘O’ placed in air on the optic axis of
Sol. a2x g = manet
the surface, so that its real image is formed at ‘I’
L2g inside glass. The line OI intersects the spherical
x  a net
m
surface at P and PO = PI. The distance PO equals
m
T = 2 to-
L2g
(1) 5R (2) 3R
where m = 10g, L = 10 cm, = 1000 kg/m 3
(3) 2R (4) 1.5R
Ans. (1)

1
 =1.5 32. Identify the valid statements relevant to the given
Sol. =1
air glass circuit at the instant when the key is closed.
O P I

R Key
A
PO = u = –x air B 5V
PI = v = x
PO = PI A. There will be no current through resistor R.
 2 1  2  1 B. There will be maximum current in the
 
v u R
connecting wires.
1.5 1 1
  C. Potential difference between the capacitor
x x 2R
plates A and B is minimum.
5 1
 D. Charge on the capacitor plates is minimum.
2x 2R
X = 5R Choose the correct answer from the options given

31. A radioactive nucleus n2 has 3 times the decay below :

constant as compared to the decay constant of (1) C, D only (2) B, C, D only
another radioactive nucleus n1. If initial number of (3) A, C only (4) A, B, D only
both nuclei are the same, what is the ratio of Ans. (2)
number of nuclei of n2 to the number of nuclei of Sol. Initially capacitor behave as a short circuit.
n1, after one half-life of n1?
So current will be maximum.
(1) 1/4 (2) 1/8
Charge on capacitor will be zero.
(3) 4 (4) 8
Potential difference across capacitor will be zero.
Ans. (1)
Sol. N2 = N0e–3
t 33. The position of a particle moving on x-axis is

N1 = N0e–t given by x(t) = A sin t + B cos2t + Ct2 + D, where t

N2 ABC
 e 2 t is time. The dimension of is-
N1 D
3 –2
ln 2 (1) L (2) L T
t half lifeofN1 t  1
(3) L2 T–2
2
 (4) L
n

N0 Ans. (3)
 N 0 et
2 Sol. Dimension [x(t)] = [L]
t = ln2 [A] = [L]
ln 2 [B] = [L]
t

[C] = [LT–2]
ln 2
2 
e  [D] = [L]

 ABC   L  L  LT 
N2 1 –2
  D  
2 –2
 = [L T ]
N1 4    L 

2
34. Match the List-I with List-II Choose the correct answer from the options given
List-I List-II below :
A. Pressure varies I. Adiabatic (1) A, B only (2) A, D, only
inversely with volume process (3) B, D, E only (4) A, B, E only
of an ideal gas.
Ans. (1)
B. Heat absorbed goes II. Isochoric
Sol. (A) = C[ML2T–2] = [C][1]
partly to increase process
internal energy and  BNA
(B) C.S =  ;
partly to do work. I C
C. Heat is neither III Isothermal BNA
absorbed nor released . process V.S. = [R also depends on ‘N’]
RC
by a system
NAB
D. No work is done on or IV Isobaric (C) V.S.  R → NR
CR
by a gas . process
Choose the correct answer from the options given (D) False [Theory]
below : (E) E [False] C.S  N
(1) A–I, B–IV, C–II, D–III NAB
(2) A–III, B–I, C–IV, D–II  C.S. 
C
(3) A–I, B–III, C–II, D–IV
36. A point particle of charge Q is located at P along
(4) A–III, B–IV, C–I, D–II
the axis of an electric dipole 1 at a distance r as
Ans. (4)
shown in the figure. The point P is also on the
1
Sol. A → P  equatorial plane of a second electric dipole 2 at a
V
distance r. The dipoles are made of opposite charge
 PV = constant
q separated by a distance 2a. For the charge
 nRT = const.  T = const.
Hence Isothermal III particle at P not to experience any net force, which
B → IV of the following correctly describes the situation?

W  0, U  0, Q  0 [only isobaric]
P +q –q
C → IQ = 0 Adiabatic Dipole 1

D → II w = 0 Isochoric r
r
III IV I II 2a
35. Consider a moving coil galvanometer (MCG) :
A : The torsional constant in moving coil +q –q
galvanometer has dimensions [ML T ]2 –2 Dipole 2
2a
B : Increasing the current sensitivity may not
necessarily increase the voltage sensitivity.
C : If we increase number of turns (N) to its double a a
(2N), then the voltage sensitivity doubles. (1)  20 (2) ~ 10
r r
D : MCG can be converted into an ammeter by
a a
introducing a shunt resistance of large value in (3) ~ 0.5 (4) ~3
r r
parallel with galvanometer.
Ans. (4)
E : Current sensitivity of MCG depends inversely
on number of turns of coil.

3
 37. A gun fires a lead bullet of temperature 300K into
a wooden block. The bullet having melting
 temperature of 600 K penetrates into the block and
Sol. 
melts down. If the total heat required for the

process is 625 J, then the mass of the bullet is ___
grams.

kq kq 2kq (Latent heat of fusion of lead = 2.5 × 104 JKg–1 and

  2 2 cos 
r  a
2
r  a 
2
r  a  specific heat capacity of lead = 125 JKg–1 K–1)
(1) 20 (2) 15
1 1 2a (3) 10 (4) 5
 
r  a r  a 
2 2 3

r 2
a 
2 2 Ans. (3)
Sol. 625 = msT + mL
1 1 2a
  625 = m[125 × 300 + 2.5 × 104]
r  a r  a 
2 2 3

r 2
a 
2 2
625 = m[37500 + 25000]
625 = m[62500]
4ra 2a
 1
r  a2  m
2 3

r  kg
2
2
a 2 2
100
2r 1 M = 10 grams
 
r  a2 
38. What is the lateral shift of a ray refracted through a
2 3

r2  a2 2
2

parallel-sided glass slab of thickness ‘h’ in terms of

4r 2 1 the angle of incidence ‘i’ and angle of refraction

 ‘r’, if the glass slab is placed in air medium ?
r  a2  r  a2 
2 4 2 3

h tan(i  r) h cos(i  r)
(1) (2)
 4r (r + a ) = (r – a )
2 2 2 3 2 2 4
tan r sin r
3 4 h sin(i  r)
 a2   a2  (3) h (4)
4r 1  2   r 8 1  2 
8
cos r
 r   r  Ans. (4)
3 4
 a2   a2  Sol. Formula base
4 1  2   1  2 
 r   r  h sin(i  r)
cos r
Exact value cannot be solved in exam for this
39. A solid sphere of mass ‘m’ and radius ‘r’ is
equation to be true
allowed to roll without slipping from the highest
a point of an inclined plane of length ‘L’ and makes
1  a > r
r an angle 30º with the horizontal. The speed of the
But point charge Q lies between charges of dipole particle at the bottom of the plane is v1. If the angle
of inclination is increased to 45º while keeping L
1 hence electric field cannot be zero.
constant. Then the new speed of the sphere at the
There for it should be bonus. bottom of the plane is v2. The ratio of v12 : v22 is
But by solving from mathematical software we are (1) 1 : 2 (2) 1 : 3
getting a/r  3. (3) 1 : 2 (4) 1 : 3
Ans. (1)

4
 A C
L
Sol. Lsin 4
Sol.
 A
6V D
using WET 4 4
Wg = kf – ki
B
Mg L sin = kf – ki

1 1
2
K.E. in pure rolling mVcm  Icm 2
2 2 4
2
1 1 2 V 6
 mV 2   mR 2 2
2 2 5 R 4 4
7
mV 2
10
7 4
mgL sin   mVf2  0
10 6 6



6
V  sin 
f
2
2
2
 V1  sin 1 sin 30 1
    
 V2  sin 2 sin 45 2
Current through ammeter = 1 A
40. Refer to the circuit diagram given in the figure,
Rnet = 6
which of the following observation are correct?
A C
A. Total resistance of circuit is 6. 1A
B. Current in Ammeter is 1A
6V D A
C. Potential across AB is 4 Volts.
D. Potential across CD is 4 Volts. 0.5A 0.5A

E. Total resistance of the circuit is 8. B

Choose the correct answer from the options given VAB = 0.5 × 4 = 2 volt
below: VCD = 1 × 4 = 4 volt
A C A, B & D are correct
41. The electric flux is  =  + 
4
A where  and  are linear and surface charge
D
E = 6V 
4 4 density, respectively,   represents

(1) charge
B
(2) electric field
(3) displacement
(1) A, B and D only (2) A, C and D only
(4) area
(3) B, C and E only (4) A, B and C only
Ans. (3)
Ans. (1)

5
 Sol.  =  +  1   – 1  R1  R 2  2
 2 2  
[ = [ = [ feq  1  R1R 2  R 2
      2  (2 – 1 )(R1  R 2 )  1R1 
     =  
      R2  1R1 

  Q / L  Area  2  2 R1  2 R 2 – 1R1 – 1R 2  1R1 

    =  
 Q / Area   Length  R2  1R1 

  1 2[2 R1   2 R 2 – 1R 2 ]

  L feq 1R1R 2
 
For same size of image
42. Given a thin convex lens (refractive index 2), kept
u = 2f
in a liquid (refractive index 1, 1 < 2) having
1R1R 2
radii of curvature |R1| and |R2|. Its second surface is u=
 2 R1   2 R 2 – 1R 2
silver polished. Where should an object be placed
on the optic axis so that a real and inverted image
43. The electric field of an electromagnetic wave in
is formed at the same place ?
free space is
1 R1 . R 2
(1) E = 57 cos[7.5 × 10 t – 5 × 10
6 –3
(3x + 4y)]
2  R1  R 2   1 R1

1 R1 . R 2
 4iˆ  3jˆ  N/C.
(2)
 2  R1  R 2   1 R 2 The associated magnetic field in Tesla is-

(3)
1 R1 . R 2 (1) B 
57
3  10 8
–3
 
cos [7.5 × 10 t – 5 × 10 (3x + 4y)] 5kˆ
6

2  2 R1  R 2   1 R1 . R 2
(2) B 
57 6 –3
 
cos [7.5 × 10 t – 5 × 10 (3x + 4y)] k̂
 2  1  R1 3  10 8

(4)
 2  1  (3) B  
57
3  10 8
6 –3
 
cos [7.5 × 10 t – 5 × 10 (3x + 4y)] 5kˆ
Ans. (2)
Sol. 57
(4) B   6 –3
cos [7.5 × 10 t – 5 × 10 (3x + 4y)]
3  10 8
|R1| |R2|
 k̂ 
1 Ans. (3)
Sol. K  3iˆ  4ˆj

2 3iˆ  4ˆj
1 K̂ 
5
1 2 1
 –
feq fL fm 4iˆ – 3jˆ
Ê 
5
| R2 |
fm  – ˆ K
ˆ  Eˆ
2 B
ˆ  –Zˆ
B
1  2  1 1 
  – 1  
fL  1  R1 R 2  E0 57
B0 = 
C 3  108

6
44. The motion of an airplane is represented by 46. A positive ion A and a negative ion B has charges
velocity-time graph as shown below. The distance 6.67 × 10–19 C and 9.6 × 10–10 C, and masses
19.2 × 10–27 kg and 9 × 10
–27
covered by airplane in the first 30.5 second is ____ kg respectively. At an
km. instant, the ions are separated by a certain distance

v(m/sec)
r. At that instant the ratio of the magnitudes of
A
400 electrostatic force to gravitational force is P × 10–13,
where the value of P is ____.
200 B
1
(Take = 9 × 109 Nm2C–1 and universal
4 0
0 2 10 20 30 40 t(sec) gravitational constant as 6.67 × 10–11 Nm kg )
2 –2

(1) 9 (2) 6 Ans. (BONUS)

(3) 3 (4) 12 9  109  6.67  10 –19  9.6  10 –10
Sol.
Ans. (4) 6.67  10 –11  19.2  10 –27  9  10 –27

Sol. Total Area under curve. 1

 10 45
2
45. Consider a circular disc of radius 20 cm with
Charge is not integral multiple of electron.
centre located at the origin. A circular hole of a
47. Two particles are located at equal distance from
radius 5 cm is cut from this disc in such a way that
origin. The position vectors of those are
the edge of the hole touches the edge of the disc.
represented by A  2iˆ  3njˆ  2kˆ and
The distance of centre of mass of residual or
remaining disc from the origin will be- B  2iˆ  2ˆj  4pkˆ , respectively. If both the vectors
(1) 2.0 cm (2) 0.5 cm are at right angle to each other, the value of n
–1

(3) 1.5 cm (4) 1.0 cm is____.

Ans. (4) Ans. (3)

15 Sol. A.B  0
4 – 6 n + 8p = 0

Sol.
1 | A || B|
mass of disc = m 4 + 9n2 + 4 = 4 + 4 + 16p2
m 9n 2 = 16p2
mass of cut part =
16
3
P=+ n
m 4
m0 –  15
Xcom = 16
m 4 – 6n + 6n = 0
m–
16 12n = 4
= 1 cm. 1
n=
3

7
48. An ideal gas initially at 0ºC temperature, is 3H
compressed suddenly to one fourth of its volume.
50.
If the ratio of specific heat at constant pressure to
12V
that at constant volume is 3/2, the change in
temperature due to the thermodynamics process R

is____K. In the given circuit the sliding contact is pulled

Ans. (273) outwards such that electric current in the circuit
3 changes at the rate of 8 A/s. At an instant when R
Sol.  =
2 is 12 , the value of the current in the circuit will
Tv –1 = C be ____A.

V 
0.5 Ans. (3)
273 V00.5  T  0 
 4  LdI
Sol. – – IR  0
dt
T = 273 × 2 = 546
12 – 3 × (–8) – I × 12 = 0
T = 273
I=3
49. A force f  x2 yiˆ  y2ˆj acts on a particle in a plane
x + y = 10. The work done by this force during a
displacement from (0, 0) to (4m, 2m) is _____
Joule (round off to the nearest integer)
Ans. (152)
4 2

 x (10 – x)dx   y dy
2 2
Sol.
0 0

4 2
10x3 x 4   y3  640 8
=      =  64  = 152
 3 4 0  3 0 3 3

8
 JEE–MAIN EXAMINATION – JANUARY 2025
(HELD ON THURSDAY 23rd JANUARY 2025) TIME : 9 : 00 AM TO 12 : 00 NOON

CHEMISTRY TEST PAPER WITH SOLUTIONS

SECTION-A 53. The incorrect statements among the following is
51. The element that does not belong to the same period
(1) PH3 shows lower proton affinity than NH3.
of the remaining elements (modern periodic table) is:
(1) Palladium (2) PF3 exists but NF5 does not.

(2) Iridium (3) NO2 can dimerise easily.

(3) Osmium (4) SO2 can act as an oxidizing agent, but not as a
(4) Platinum reducing agent.
Sol. (1)
Sol. (4)
Palladium 5th period
SO2 can oxidise as well as reduce.
Iridium, Osmium, Platinum  6th Period
Hence it can act as both oxidising and reducing
52. Heat treatment of muscular pain involves radiation
of wavelength of about 900 nm. Which spectral agent.

line of H atom is suitable for this ? 54. CrCl3.xNH3 can exist as a complex. 0.1 molal
Given: Rydberg constant aqueous solution of this complex shows a
5 –1 –34 8
RH = 10 cm , h = 6.6 × 10 J s, c = 3 × 10 m/s)
depression in freezing point of 0.558ºC. Assuming
(1) Paschen series,   3
100% ionisation of this complex and coordination
(2) Lyman series,   1
number of Cr is 6, the complex will be
(3) Balmer series,   2
(Given Kf = 1.86 K kg mol–1)
(4) Paschen series, 5  3
Sol. (1) (1) [Cr(NH3)6] Cl3

 = 900 nm H-atom (Z = 1) (2) [Cr(NH3)4Cl2] Cl

= 9 × 10–5 cm (3) [Cr(NH3)5Cl] Cl2
5 –1
RH = 10 cm
(4) [Cr(NH3)3Cl3]
1  1 1 
Ryderg eq. =  R H Z2   2  2  Sol. (3)
  n1 n 2 
Given : Tf = 0.558°C
1 1 1
  2 2
  R H n1 n 2 K  kg
k f  1.86
mol
1  1 1 
 5 1
 2  2  0.1 m aq. sol.
9  10 cm  10 cm
5
 n1 n 2 
1 1 1  Tf = i × kf × m
 2
 2 
n1 n 2 9  0.558 = i × 1.86 × 0.1
It is possible when n1 = 3, n2 = 
 i = 3
Possible series :  3

1
55. 2.0V
FeO24   Fe3 
0.8V 0.5V
 Fe2   Fe0 57. Given below are two statements:
In the above diagram, the standard electrode Statement I: Fructose does not contain an
potentials are given in volts (over the arrow). aldehydic group but still reduces Tollen‟s reagent

The value of E FeO24 /Fe2
is Statement II : In the presence of base, fructose
(1) 1.7 V (2) 1.2 V undergoes rearrangement to give glucose.
(3) 2.1 V (4) 1.4 V In the light of the above statements, choose the
Sol. (1)
correct answer from the options given below
(1) Statement I is false but Statement II is true
(2) Both Statement I and Statement II are true
(3) Both Statement I and Statement II are false
G  G  G
o
4
o
1
o
2 (4) Statement I is true but Statement II is false
  n 4 FE o4   n1FE10  n 2 FE2o Sol. (2)
  4 E o4  3  2  (1  0.8) CH2–OH CH–OH
C=O C – OH
6.8 –
 E o4  V  HO H OH HO H
4 H OH H OH
H OH H OH
 Eo4  1.7V CH2OH CH2OH
(D. Fructose) (Enediol)
56. Match the LIST-I with LIST-II
CH=O CH=O
LIST-I LIST-II
H OH HO H
Name reaction Product HO H H
+ HO
H OH H OH
obtainable H OH H OH
A. Swarts reaction I. Ethyl benzene CH2OH CH2OH
D-Glucose D-Mannose
B. Sandmeyer‟s reaction II. Ethyl iodide
C. Wurtz Fittig reaction III. Cyanobenzene 58. 2.8 × 10–3 mol of CO2 is left after removing 1021
D. Finkelstein reaction IV. Ethyl fluoride molecules from its „x‟ mg sample. The mass of
Choose the correct answer from the options given CO2 taken initially is
below:
Given : NA = 6.02 × 1023 mol–1
(1) A-II, B-III, C-I, D-IV
(2) A-IV, B-I, C-III, D-II (1) 196.2 mg (2) 98.3 mg

(3) A-IV, B-III, C-I, D-II (3) 150.4 mg (4) 48.2 mg

(4) A-II, B-I, C-III, D-IV Sol. (1)
Sol. (3)
x 10 3
(moles)initial 
LIST-I LIST-II 44
Name reaction Product obtainable
A. Swarts I. 1021
Et-I   Et-F
KF
DMF (moles) removal 
reaction 6.02 1023
B. Sandmeyer‟s II.
PhN 2 Cl  
CuCN/KCN
PhCN +N2
reaction (moles)left  (moles)initial  (moles) removed
C. Wurtz Fittig III.
Ph–Cl + EtCl   Na
reaction ether x 10 3 1021
Ph–Et + Ph–Ph + Et–Et 2.8  10 3  
44 6.02 1023
D. Finkelstein IV.
Et–Cl   Et-I + NaCl
NaI
reaction acetone
 x = 196.2 mg

2
59. Ice at –5°C is heated to become vapor with 60. The d-electronic configuration of an octahedral
Co(II) complex having magnetic moment of 3.95
temperature of 110°C at atmospheric pressure. The BM is :
entropy change associated with this process can be (1) t 62g e1g (2) t 32g e 0g
(3) t 52g e 2g (4) e 4 t 32
obtained from :
Sol. (3)
383K
H melting H boiling Co+2 = (Ar)18 3d7 4s°
(1)
268K
 C p dT 
273

373

H m ,fusion H m,vaporisation 61. The complex that shows Facial – Meridional

273K
Cp,m
(2)
268K
 T
dT 
Tf

Tb isomerism is
(1) [Co(NH3)3Cl3] (2) [Co(NH3)4Cl2]+
373K
Cp,m dT 383K
Cp,m dT (3) [Co(en)3]3+ (4) [Co(en)2Cl2]+
 
273K
T
 
373K
T Sol. (1)
Ma3b3 type complexes show Facial - Meridional
383K
isomerism
q rev
(3)  Cp dT 
T
(i) [Co(NH3)3Cl3] Ma3b3
268K
(ii) [Co(NH3)4Cl2]+ Ma4b2
(iii) [Co(en)3]3+ M(AA)3
H m ,fusion H m,vaporisation
273K
(iv) [Co(en)2Cl2]+ M(AA)2b2
(4)  Cp,m dT 
Tf

Tb
268K a, b, = NH3, Cl–
AA = en
373K 383K
62. The major product of the following reaction is :
 
273K
Cp,m dT 
373K
 Cp,m dT
excess HCHO
alkali
CH3CH2CH=O reflux
?
Sol. (2)
(1) CH3–CH2–CH2–OH
Ice → Ice Water → Water Water → Water
vapour vapour (2) CH3–CH–CH=O
268 K 273 K 273 K 273 K 373 K 383 K CH2–OH
(1) (2) (3) (4) (5)
CH2–OH
(3) CH3–C–CH2–OH
Soverall = S1 + S2 +S3 +S4 + S5
CH2–OH
H m fusion (4) CH3–C–CH=O
S2  Tf = 273 'K'
273 CH2
373 Sol. (3)
C p,m dT
S 3   T
This is an example of Tollen‟s reaction i.e.
273
multiple cross aldol followed by cross Cannizaro
reaction
H m vaporisation
S4  Tb = 373 'K' CH2–OH
373
CH3CH2CH=O  2HCHO
Alkali CH3–C–CHO
383
C p,m dT CH2–OH
S 5  
373
T CH2–OH

Answer = (2) 

HCHO
Alkali
 CH3–C–CH2–OH + HCOO
CH2–OH

3
63. The correct stability order of the following 66. The correct set of ions (aqueous solution) with
species/molecules is : same colour from the following is :
H
(–) (1) V2+, Cr3+, Mn3+ (2) Zn2+, V3+, Fe3+
(–)
(3) Ti4+, V4+, Mn2+ (4) Sc3+, Ti3+, Cr2+
p q r
Sol. (1)
(1) q > r > p (2) r > q > p (1) V2+(Violet), Cr3+(Violet), Mn3+(Violet)
(3) q > p > r (4) p > q > r
(2) Zn2+(Colourless), V3+(Green), Fe3+(Yellow)
Sol. (1)
q is aromatic r is nonaromatic p is antiaromatic (3) Ti4+(Colourless), V4+(Blue), Mn2+ (Pink)
64. Propane molecule on chlorination under (4) Sc3+(Colourless), Ti3+(Purple), Cr2+ (Blue)
photochemical condition gives two di-chloro 67. Given below are two statements :
products, “x” and “y”. Amongst “x” and “y”, “x” is
Statement I : In Lassaigne's test, the covalent
an optically active molecule. How many tri-chloro
products (consider only structural isomers) will be organic molecules are transformed into ionic
obtained from “x” when it is further treated with compounds.
chlorine under the photochemical condition? Statement II : The sodium fusion extract of an
(1) 4 (2) 2
organic compound having N and S gives prussian
(3) 5 (4) 3
Sol. (4) blue colour with FeSO4 and Na4[Fe(CN)6]
*
“X” is CH3–CH–CH In the light of the above statements, choose the
2

Cl Cl correct answer from the options given below

(1) Both Statement I and Statement II are true
Cl
X 
Cl2 *
 CH3–CH–CH–Cl (2) Both Statement I and Statement II are false
hv + CH3–C–CH2–Cl
Cl Cl Cl (3) Statement I is false but Statement II is true
+
(4) Statement I is true but Statement II is false
Cl–CH2–CH–CH2–Cl
Cl Sol. (4)
The sodium fusion extract of organic compound
65. What amount of bromine will be required to
convert 2 g of phenol into 2, 4, 6-tribromophenol ? having N & S gives blood red colour with FeSO4
(Given molar mass in g mol–1 of C, H, O, Br are and Na4[Fe(CN)6]
12, 1, 16, 80 respectively) 68. Which of the following happens when NH4OH is
(1) 10.22 g (2) 6.0 g
added gradually to the solution containing 1M A2+
(3) 4.0 g (4) 20.44 g
Sol. (1) and 1M B3+ ions ?

OH OH Given : Ksp[A(OH)2] = 9 × 10–10 and

Br Br
+ 3HBr Ksp[B(OH)3] = 27 × 10–18 at 298 K.
+ 3Br2
(1) B(OH)3 will precipitate before A(OH)2
Br
(2) A(OH)2 and B(OH)3 will precipitate together
2
Moles of phenol = = 0.021 (3) A(OH)2 will precipitate before B(OH)3
94
 Moles of bromine = 0.021 × 3 = 0.064 (4) Both A(OH)2 and B(OH)3 do not show
 Mass of bromine = 0.064 × 160 = 10.22 g precipitation with NH4OH

4
Sol. (1) 70. Which among the following react with Hinsberg's
Condition for precipitation Qip > Ksp reagent?
NH2 N(CH3)2
For [A(OH)2] (A) (2)

[A2+] [OH–]2 > 9 × 10–10 (C) CH3–NH2 (4) N(CH3)3

H
[A+2] = 1 M N
(E)
– –5
 [OH ] > 3 × 10 M
Choose the correct answer from the options given
 For [B(OH)3] below :
[B3+][OH–]3 > 27 × 10–18 (1) B and D only (2) C and D only
(3) A, B and E only (4) A, C and E only
[B3+] = 1M
Sol. (4)
 [OH–] > 3 × 10–6 M B and D are 3º amine which does not have
So, B(OH)3 will precipitate before A(OH)2 replaceable H on N, So does not react.
SECTION-B
69. Match the LIST-I with LIST-II 71. If 1 mM solution of ethylamine produces pH = 9,
LIST-I LIST-II then the ionization constant (Kb) of ethylamine is
10–x. The value of x is ________ (nearest integer).
(Classification of molecules (Example)
[The degree of ionization of ethylamine can be
based on octet rule) neglected with respect to unity.]
A. Molecules obeying octet I. NO, NO2 Sol. (7)

rule Sol. C2 H5NH2 (aq)  H 2O C2 H 2 NH3  OH

B. Molecules with II. BCl3, AlCl3 C = 10–3 M - -
C(1 - ) C C
incomplete octet
  C = 10–3 =10–5 = 10–5
C. Molecules with incomplete III. H2SO4, PCl5
1  1 
octet with odd electron
 
Given, PH = 9  POH = 5   OH   10 5 M
D. Molecules with expanded IV. CCl4, CO2  
octet [C 2 H 5 NH 3 ][OH ]
Now, K b 
Choose the correct answer from the options given [C 2 H 5 NH 2 ]
below : 10 5  10 5
Kb = = 10–7
10 3
(1) A-IV, B-II, C-I, D-III
72. During "S" estimation, 160 mg of an organic
(2) A-III, B-II, C-I, D-IV compound gives 466 mg of barium sulphate. The
(3) A-IV, B-I, C-III, D-II percentage of Sulphur in the given compound is
______ %.
(4) A-II, B-IV, C-III, D-I
(Given molar mass in g mol–1 of Ba : 137, S : 32,
Sol. (1) O : 16)
(A) A  IV Sol. (40)
466
(B) B  II Millimoles of BaSO4 = = 2m mol
233
(C) C  I 466
 32
(D) D  III %S = 233  100  40%
160

5
73. Consider the following sequence of reactions to  104 P = 0.6(104 – 1)
produce major product (A) P = (6000 – 0.6) × 10–4
CH3 i) Br2, Fe = 5999. × 10–4
ii) Sn, HCl
(A) = 0.59994
iii) NaNO2, HCl, 273 K
NO2 Major Product P
iv) H3PO2, H2O PTotal  0.6 
2
Molar mass of product (A) is ______ g mol–1.
= 0.6 + 0.29997
(Given molar mass in g mol–1 of C : 12, H : 1,
= 0.89997
O : 16, Br : 80, N : 14, P : 31)
= 899.97 × 10–3
Sol. (171)
Ans. 900
CH3 CH3 CH3
Br2
Br
Sn
Br Given by NTA
Fe HCl
NO2 NO2 NH2
Given : 2N2O5(g) → 2N2O4(g) + O2(g)
t=0 0.6 0 0
NaNO2/HCl
t = 100s 0.6 - x x x/2
CH3 CH3
x
Br
H3PO2
Br PTotal  0.6 
2
(A) As given in equation
Molar mass of product (C7H7Br) (A) is 171 g mol–1 Kr = 4.606 × 10–2 sec–1
74. For the thermal decomposition of N2O5(g) at (Here language conflict in question)
constant volume, the following table can be KA
( Kr  not considered)
formed, for the reaction mentioned below : 2
2N2O5(g) → 2N2O4(g) + O2(g) 0.6
K r t  ln
0.6  x
S.No. Time/s Total pressure / (atm)
0.6
1. 0 0.6 4.606 × 10–2 × 100 = 2.303 log
0.6  x
2. 100 'x'
0.594
–3
x = ________ × 10 atm [nearest integer] PTotal  0.6   0.897 atm
2
Given : Rate constant for the reaction is 4.606 × 10–2 s–1.
= 897 × 10–3 atm
Sol. (900)
75. The standard enthalpy and standard entropy of
NTA. (897)
decomposition of N2O4 to NO2 are 55.0 kJ mol–1
–2 –1
KN2O5 = 2 × 4.606 ×10 S and 175.0 J/K/mol respectively. The standard free
2N2O5 (g) 
2N2O4 (g)  O2 (g) energy change for this reaction at 25°C in J mol–1
Pi 0.6 0 0 is _______ (Nearest integer)
P Sol. (2850)
Pf 0.6 – P P
2 H orxn = 55 kJ/mol, T = 298 K
2.303 0.6 Sorxn = 175 J/mol
2 × 4.606 × 10–2 = log
100 0.6  P
G orxn  Horxn  TSorxn
0.6
4 log10
0.6  P  G orxn J/mol – 298 × 175 J/mol
0.6
10 4   G orxn  – 52150
0.6  P
 0.6 × 104 –104 P = 0.6  G orxn J/mol