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Test On TTC

The document contains a series of exercises related to thermodynamics, focusing on concepts such as state functions, adiabatic processes, enthalpy changes, and heat calculations. It includes multiple-choice questions and problems requiring calculations of internal energy, enthalpy, and entropy changes for various chemical reactions. The exercises aim to reinforce understanding of thermodynamic principles and their applications.

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Rohinish Dey
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9 views3 pages

Test On TTC

The document contains a series of exercises related to thermodynamics, focusing on concepts such as state functions, adiabatic processes, enthalpy changes, and heat calculations. It includes multiple-choice questions and problems requiring calculations of internal energy, enthalpy, and entropy changes for various chemical reactions. The exercises aim to reinforce understanding of thermodynamic principles and their applications.

Uploaded by

Rohinish Dey
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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182 CHEMISTRY

EXERCISES

6.1 Choose the corr ect answer. A thermodynamic state function is a


quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work

d
(iv) whose value depends on temperature only.
6.2 For the process to occur under adiabatic conditions, the correct

he
condition is:
(i) ∆T = 0
(ii) ∆p = 0

pu T
(iii) q = 0

is
(iv) w = 0
re R
6.3 The enthalpies of all elements in their standard states are:
(i) unity

bl
(ii) zero
E
(iii) < 0
(iv) different for each element
0 0
6.4 ∆U of combustion of methane is – X kJ mol–1. The value of ∆H is
be C

0
(i) = ∆U
(ii) > ∆U 0
o N

0
(iii) < ∆U
(iv) = 0
6.5 The enthalpy of combustion of methane, graphite and dihydrogen
at 298 K are, –890.3 kJ mol–1 –393.5 kJ mol –1, and –285.8 kJ mol–1
©

respectively. Enthalpy of formation of CH 4(g) will be


(i) –74.8 kJ mol–1 (ii) –52.27 kJ mol–1
(iii) +74.8 kJ mol–1 (iv) +52.26 kJ mol–1.
6.6 A reaction, A + B → C + D + q is found to have a positive entropy
change. The reaction will be
(i) possible at high temperature
(ii) possible only at low temperature
(iii) not possible at any temperature
tt

(v) possible at any temperature


6.7 In a process, 701 J of heat is absorbed by a system and 394 J of
work is done by the system. What is the change in internal energy
no

for the process?


6.8 The reaction of cyanamide, NH 2CN (s), with dioxygen was carried
out in a bomb calorimeter, and ∆U was found to be –742.7 kJ mol–1
at 298 K. Calculate enthalpy change for the reaction at 298 K.

3
NH2 CN(g) + O (g) → N2 (g) + CO2 (g) + H2O(l)
2 2
THERMODYNAMICS 183

6.9 Calculate the number of kJ of heat necessary to raise the temperature


of 60.0 g of aluminium from 35°C to 55°C. Molar heat capacity of Al
is 24 J mol–1 K–1.
6.10 Calculate the enthalpy change on freezing of 1.0 mol of water
at10.0°C to ice at –10.0°C. ∆fus H = 6.03 kJ mol–1 at 0°C.
Cp [H2O(l)] = 75.3 J mol–1 K–1
Cp [H2O(s)] = 36.8 J mol–1 K–1
6.11 Enthalpy of combustion of carbon to CO2 is –393.5 kJ mol–1. Calculate

d
the heat released upon formation of 35.2 g of CO2 from carbon and
dioxygen gas.

he
6.12 Enthalpies of formation of CO(g), CO2 (g), N2 O(g) and N2O 4(g) are –110,
– 393, 81 and 9.7 kJ mol–1 respectively. Find the value of ∆r H for the
reaction:
N2 O4 (g) + 3CO(g) → N2 O(g) + 3CO2(g)

pu T
6.13 Given

is
N2 (g) + 3H2(g) → 2NH3(g) ; ∆rH 0 = –92.4 kJ mol–1
re R What is the standard enthalpy of formation of NH3 gas?

bl
6.14 Calculate the standard enthalpy of formation of CH3 OH(l) from the
following data:
E
3 0
CH3OH (l) + O (g) → CO2 (g) + 2H2O(l) ; ∆r H = –726 kJ mol–1
2 2
be C

0
C(graphite) + O2 (g) → CO2(g) ; ∆c H = –393 kJ mol–1

1 0
O (g) → H2 O(l) ; ∆f H = –286 kJ mol–1.
o N

H 2(g) +
2 2
6.15 Calculate the enthalpy change for the process
CCl4 (g) → C(g) + 4 Cl(g)
and calculate bond enthalpy of C – Cl in CCl4(g).
©

0
∆vapH (CCl4 ) = 30.5 kJ mol–1.
∆fH 0 (CCl4 ) = –135.5 kJ mol–1.
0 0
∆aH (C) = 715.0 kJ mol–1 , where ∆aH is enthalpy of atomisation
0
∆aH (Cl2 ) = 242 kJ mol–1
6.16 For an isolated system, ∆U = 0, what will be ∆S ?
6.17 For the reaction at 298 K,
2A + B → C
tt

∆H = 400 kJ mol–1 and ∆S = 0.2 kJ K–1 mol–1


At what temperature will the reaction become spontaneous
considering ∆H and ∆S to be constant over the temperature range.
no

6.18 For the reaction,


2 Cl(g) → Cl2(g), what are the signs of ∆H and ∆S ?
6.19 For the reaction
2 A(g) + B(g) → 2D(g)
0 0
∆U = –10.5 kJ and ∆S = –44.1 JK–1.
0
Calculate ∆G for the reaction, and predict whether the reaction
may occur spontaneously.
184 CHEMISTRY

6.20 The equilibrium constant for a reaction is 10. What will be the value
0
of ∆G ? R = 8.314 JK–1 mol–1, T = 300 K.
6.21 Comment on the thermodynamic stability of NO(g), given

1 1 0
N (g) + O (g) → NO(g) ; ∆rH = 90 kJ mol–1
2 2 2 2

1 0
NO(g) + O (g) → NO2 (g) : ∆rH = –74 kJ mol–1

d
2 2
6.22 Calculate the entropy change in surroundings when 1.00 mol of
0
H 2O(l) is formed under standard conditions. ∆f H = –286 kJ mol–1.

he
pu T
is
re R
bl
E
be C
o N
©
tt
no

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