09/07/2020 Basics in Inorganic Chemistry - - Unit 5 - Week 3

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Unit 5 - Week 3

Course
outline Week 3 : Assignment 3
How does an The due date for submitting this assignment has passed. Due on 2020-02-19, 23:59 IST.
NPTEL online As per our records you have not submitted this assignment.
course work?
1) Given the molecular formula of the hexa-coordinated complexes 1 point
Week 0 (i) Co Cl3 (NH3)6
(ii) Co Cl3 (NH3)5
Week 1
(iii) Co Cl3 (NH3)4
Week 2 If the number of coordinated NH3 molecules in (i), (ii) and (iii) respectively are 6, 5 and 4 then the
oxidation state of Co in (i), (ii) and (iii) are respectively
Week 3
+6, +5, +4
Lecture 10 :
Crystal Field +3, +2, +1
Theory: 0, +1, +2
Octahedral vs.
Tetrahedral +3, +3, +3
Complex (unit? No, the answer is incorrect.
unit=12&lesson=14) Score: 0
Accepted Answers:
Lecture 11 :
+3, +3, +3
Application of
CFSE: Spinel 2) Using crystal field theory, identify from the following complex ions that shows same spin 1 point
and J-T
only magnetic moment values
Distortion (unit?
unit=12&lesson=15) (A) [CoF6]3- (B) [IrCl6]3- (C) [Fe(H2O)6]2+
Lecture 12 :
Introduction to
Molecular A and B
Magnetism
B and C
(unit?
unit=12&lesson=16) A and C

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09/07/2020 Basics in Inorganic Chemistry - - Unit 5 - Week 3

Lecture 13 : A, B and C
Problem Solving
No, the answer is incorrect.
Approach (unit?
Score: 0
unit=12&lesson=17)
Accepted Answers:
Lecture 14 : A and C
Magnetism
3) The magnetic moment of an octahedral Co(II) complex is 4.0 BM. The electronic 1 point
(unit?
unit=12&lesson=18) configuration of the complex is
Download
Videos (unit?
t2g5 eg2
unit=12&lesson=62) t2g6 eg1

Weekly t2g3 eg4

Feedback (unit? t2g4 eg3
unit=12&lesson=63)
No, the answer is incorrect.
Quiz : Week 3 : Score: 0
Assignment 3 Accepted Answers:
(assessment? t2g5 eg2
name=66)
4) The crystal field stabilization energy (CFSE), in units of Δ0 for [CoF3(H2O)3] is 1 point
Week 4
0

Text Transcripts 0.4

0.8
1.8
No, the answer is incorrect.
Score: 0
Accepted Answers:
0.4

5) Which one of the following complexes is Jahn-Teller distorted 1 point

[Co(NH3)6]+3
[Cr(H2O)6]+3
[Cu(H2O)6]+2
[Fe(CN)6]-4
No, the answer is incorrect.
Score: 0
Accepted Answers:
[Cu(H2O)6]+2

6) Consider the two complexes (A) [Ni(H2O)6]2+ and (B) [Ni(NH3)6]2+, the right statement is 1 point

Complex (A) is diamagnetic and complex (B) is paramagnetic

Complex (B) is diamagnetic and complex (A) is paramagnetic
Both are paramagnetic
Both are diamagnetic
No, the answer is incorrect.
Score: 0
Accepted Answers:
Both are paramagnetic

7) The correct spinel structure of Co3O4 is 1 point

[Co2+]t [2Co3+]o O4
[Co2+]t [2Co3+ Co3+]o O4

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09/07/2020 Basics in Inorganic Chemistry - - Unit 5 - Week 3

[Co2+ Co3+]t [Co3+]o O4

[2Co3+]t [Co2+]o O4
No, the answer is incorrect.
Score: 0
Accepted Answers:
[Co2+]t [2Co3+]o O4

8) The correct set of electronic configurations for metal ions in octahedral coordination 1 point
geometry for strong Jahn-Teller distortion is

t2g6 eg1, t2g3 eg1, t2g6 eg3

t2g1, t2g3 eg2, t2g6 eg1
t2g3, t2g3 eg1, t2g3 eg2
t2g3 eg2, t2g6 eg2, t2g6 eg3
No, the answer is incorrect.
Score: 0
Accepted Answers:
t2g6 eg1, t2g3 eg1, t2g6 eg3

9) The spin-only magnetic moment of [MnF6]3- is 1 point

3.2 BM
4.0 BM
4.9 BM
5.5 BM
No, the answer is incorrect.
Score: 0
Accepted Answers:
4.9 BM

10)The complex that shows orbital contribution to the magnetic moment is 1 point

[Cu(H2O)6]2+
[Ni(H2O)6]2+
[Co(H2O)6]2+
[Cr(H2O)6]2+
No, the answer is incorrect.
Score: 0
Accepted Answers:
[Co(H2O)6]2+

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09/07/2020 Basics in Inorganic Chemistry - - Unit 5 - Week 3

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