Atomic masses : [H=1,D= 2, Li =7, C= 12, N= 14, O=16, F= 19, Na =23, Mg = 24, Al =27, Si =28,

P=31, S = 32, CI = 35.5, K= 39, Ca= 40, Cr =52, Mn = 55, Fe = 56, Cu = 63.5, Zn= 65, As =75,
Br=80,Ag = 108, I= 127, Ba = 137, Hg =200, Pb =207]
SECTION -I
Straight Objective Type
This section contains 15 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which OLY ONE 0s correct. Each question carry (3, - 1) Marks.

1. The students of a class were divided inic two groups: Group B(of boys) and Grcup G (of girls). Both the
groups were asked to perform one experiment each. Group B observed a photon of wave number
8x 10 m, while group G observed photon of energy 1.8 x 10-1" joule. Both the groups claimed that their
photon has greater momentum. What do you say: Use h =6.625 x 10 Js.
(A) Photon of group Bhas greater momentum.
(B) Photon of group G has greater momentum.
(C) Photons of both groups have same momentum.
(D) Nothing can be said with certainty.
2 A red hot sample of atomic hydrogen in a tube was subjected to electrical discharge. The approximate
voltage at which the first indication of current flow was observed was:
(A) 13.6 V (8) 10.2 V (C) 1.51 V (D) 1.89 V

3. Light of wavelength . strikes a metal surface with intensity X and the metal emits Y electrons per
second, of average kinetic energy Z. What will happen to Yand Z, if Xis doubled keeping , constant:
(A) Y will decrease; Z will decrease (B) Y will increase; Z will kemain same
(C) Y will remain same;Z will increase (D) Y willincrease: Z will increase
4. Nodal plane(s) for d,2,2 orbital islare :
(A) YZ plane (B) ZX plane (C) Both (A) and (B) (D) None of these
5 The set giving INCORRECT representation of electronic configuration of Carbon atom with the rule violated is:
()11L| 1
1s 2s 2p 1s 2s 2p

(ii) 1L111|L
1s 2s 2p 1s 2s 2p

1s 28 2p
(A) i, ii &iv; Hund's rule of maximum multiplicity.
(B) ii&v; Hund's rule of maximum multiplicity.
(C) i, ii&iv; Pauli exclusion principle.
(D) ii& v;Pauli exclusion principle.
6. Let the value of angular momentum in Bohr orbit, orbital angular momentum and spin angular momentum for
h h
the last electron in Sulphur atom (2= 16) be n,,Jn 4 and Jn3 Find the value of (n, +n, +n,) :
(A) 17 (B) 8 (C) 11 (D) 14
7. Which of thefollowing statements is INCORRECT:
(A) Minimum possible atomic number of element containing atleast one electron in orbital represented by
P.. is 31.
(B) Majority of the lines of Balmer series in Hydrogen spectrum lie in ultraviolet region.
(C) Zeeman effect and Stark effect (spliting of spectral lines into finer lines on applying electric and magnetic
field respectively) are failures of Bohr model.
(D) The number of neutrons in the daughter nuclei left after emission of 1a-particle from gU5 is 144.
8. Aprotonand an a-particle, both initially at rest, are supplied with same potential difference and are projected
from infinity towards a thin gold foil. What can be said about their closest distance of approach from the gold
nucleus:
(A) a-particle willreach closer to the gold nucleus than proton.
(B) Proton will reach closer to the gold nucleus than a-particle.
(C) Both proton and a-particle willhave same value of closest distance of approach from the gold nucleus.
(D) Nothing can be said with certainty.
9. Electrons in a Be sample make transition from n =7 upto I excited state producing photons with all
possible wavelengths. From these, the photons of second maximum wave number are incident upon a He
ion sample, in which the electrons jump from n, orbit to n, orbit as a result of it. Find the value of n, & n,:
(A) 1, 2 (B) 1, 3
(C) i, 0 (D) No electron jump in He ion takes place
10) According to Heisenberg's uncertainty principle, on decreasing the wavelength of light used to locate a
microscopic particle, uncertainty in measurement of momentum of particle:
(A) Increases (B) Decreases
(C) Remains unchanged (D) Cannot be predicted
11. Only 30% of incident photons produce photoelectrons when UV light of 662 nm and intensity 1 W/m? is
directed at a metal of surface area 1 cm². The magnitude of photo current in microampere is:
[Use Plank's constant h = 6.62 x 10-34,Js]
(A) 16 (B) 8 (C) 32 (D) 24
12 Which of the following statements is INCORRECT:
(A) de Broglie wave length of electron in the 1st orbit of He* ion is equal to that in 2nd orbit of Be*ion.
(B) The maximum possible number of electrons in an atom with (n + =7) is 32.
(C) Maximum number of isoelectronic species among the following is six.
N,, CN, Si, NO-, Co, 0,2*, Cy2, C,H, CH,*
(D) Fourth line of Brakett series in He* spectrum lies in infrared region.
13. A sample of hydrogen atoms absorbs radiations of wavelength o and consequently emits radiations of
maximum ten different wavelengths upon back-transition, of which only five wavelengths are longer than
Choose the INCORRECT alternative:
(A) The highest orbit occupied by the electron is the 5th orbit.
(B) The initial orbit number of the electrons is 2.
(C) Among the emitted radiations, four wavelengths are shorter than o
(D) Among the emitted radiations, one wavelength belongs to Pfund series.
14. Which of the following statements is/are INCORRECT:
(A) AH-atom sample having electrons in 5th orbit can emit 3 photons in infrared region upon back
transition.
(B) We cannot use two photons successively of 1240 Åand 2000 Åwavelength in order to ionise a Hatom
from ground state.
(C) According to Bohr model, binding energy of nth orbit is always less than excitation energy of nh orbit for
all H-like species.
(D) Asingle isolated H-atom having its electron in 4th orbit can emit 2 photons in visible region upon
back-transition.
15. Which of thefollowing statements is correct:
(A) In Liion, the ratio of series limit wavelength of Humphry series and wavelength of 2nd line of Paschen
series is 3136:325 respectively.
(B) The d orbital has two nodal planes,xz and yz planes, and two additional angular nodes.
(C) The ratio of time period of revolution of electron in 1 orbit of He* ion and 2nd orbit of Be ion is 1 :2
respectively.
(D)Canal rays is the other name for anode rays and the positively charge particles traveling in it are one of
the fundamental particles of an atom - protons.

SECTION- I|
Multiple CorrectAnswer Type
This section contains 5 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/are correct. Each question carry (4, 0) Marks.

16. For a hypothetical Hlike species which follows Bohr's model, some spectral
lines were observed as shown in figure. If it is known that line 'E' belongs to
the visible region, then the line(s) possibly belonging to infrared region will C
be :[Given : n,, n,, ng and n, are consecutive orbits &n, =3] D B
(B) C A
(A) D
n.
(C) B (D)A
17. In which of the following conditions, the de Broglie wavelength of a charged particle Awill be less than that of
another charged particle B? Given that particle Ais heavier than particle B:
(A) Linear momentum of these particles is same.
(B) Both particles move with same speed.
(C) Both particles have same kinetic energy.
(D)Same potential difference has been applied across both the particles from rest.
18. Select the correct statement(s) :
(A)n/p ratio increases during a-emission.
(B) In B-emission from a nucleus, the atomic number of the daughter element decreases by one.
(C) Correct order of ionisation power is a >B>y.
(D) Lesser the value of binding energy per nucleon for a nucleus, greater is the stability of nucleus.
19. Which of the following statements is/are correct for orbitals related to the given diagrams:

() (II)

(A) Orbital corresponding to (I) diagram has non-zero value of orbital angular momentum.
(B)Orbital corresponding to (II) diagram has no spherical node.
(C)Orbital corresponding to (II) diagram has one nodal plane.
(D)Orbital corresponding to (I) diagram is 3s orbital.
20. Which of the following statements is/are correct for orbitals related to the given diagrams:

(1) (u)

(A) Orbital corresponding to (I) graph may be 2p, orbital.

(B) Orbital corresponding to (Il) graph may be 3p, orbital.
(C) Orbital corresponding to () graph may be 2s orbital.
(D)Orbital corresponding to (I) graph may be 1s orbital.
 SECTION - ||
Comprehension Type
This section contains 1 paragraphs. Based upon each paragraph, there are 2 questions. Each question has
4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct. Each question carry (3, 0) Marks.

Paragraph for Question Nos. 21 to 22

The famous alien Jadu on his visit to our planet earth brought a sample containing 100 identical H-ike atoms
(hypothetical atoms, Z can be fractional) from his planet. He gave these atoms to Rohit (Hritik Roshan)
asking him to analyze them. He further gave Rohit the following informations:
1. Out of the given atoms, some are in ground state and some others are in a higher energy level (n =x) and
the potential energy of electron in the ground state of given atom is -192 eV.
2. When the sample is exposed to radiations of wavelength 155 nm, the electrons jump to another higher
energy level (n =x+3). Upon back-transition upto ground state, a maximum of 10 differentspectral lines are
produced.
Now answer the following two questions that Jadu asked Rohit: (Take hc = 12400 eV Å.)
21. What is the final state in which the electrons move, after absorbing photons of wavelength155 nm ?
(A) 6 (B) 5 (C)7 (D) 8
22. What is the maximum number of atoms which had their electron in ground state initially ?
(A) 93 (B) 94 (C) 95 (D) 96

SECTION - IV
Matrix- Match Type
This section contains 1questions. Each question contains statements given in two p q r st
columns, which have to be matched. The statements in Column- are labelled
A, B, C and D, while the statements in Column-ll are labelled p, q, r, s and t. Any AO000
given statement in Column- can have correct matching with ONE OR MORE B 9 0 O
statement(s) in Column-ll. The appropriate bubbles corresponding to the answers
to these questions have to be drakened as illustrated in the following example. D|@00
If the correct matches are A-p, s and t; B-q and r; C-p and q; and D-s and t; then the correct darkening of
bubbles will look like the following: Each question carry (3, 0) Marks.

23. Column Column-ll|

Species Characteristics
(A) Co3+ (p)Minimum possible number of electrons with (n + ¬+ m =4)
and clockwise spin is 2.
(B) Cut (q) The value of magnetic moment (spin only) is greater than
or equal to /8 BM.
(C) T2+ () Total number of fully filled orbitals is 10 or more.
Sc3+
(D) (s) Number of electrons with (m, = 0) may be 11.
(t) Value of total spin is zero.

SECTION -V
Integer Answer Type
This section contains 7 questions. The answer to each of the questions is a whole number. Each question
carry (4, 0) Marks.
24. Determine the sum of fully filled and half filled orbitals, which have number of radial nodes less than the
number of angular nodes, in ground state of Fe ion.

25. What is the change in de Broglie wavelength (in ¢) of an electron making a transition from an orbit, where
electron forms 2 waves per revolution to another orbit, where electron forms 4 waves per revolution in Li?ion?
9
Report your answer by multiplying it with and rounding it off to the nearest whole number.
10
Given: de Broglie wavelength of electron in first orbit of H-atom = A.

26. How many of the following particles when emitted in single number from a nuclie will result in the production
of an isotope or an isobar or an isotone ?
Electron, Proton, B' particle, Neutron, Positron, a-particle, B particle, nucleus of H-atom, nucleus of He
atom.

5RC
27. Electron in He* is in a state with directional character and has total 1 node. Photons of frequency9
cause the electron to jump into a higher state. The higher state in which electron jumps finally is associated
with five possible orientations in space. What is change in (n +) values corresponding to two states ?
(R= Rydberg's constant, c =speed of light)
28 The energy needed for Lig) ’ Li (9) + 3e is 2 x 10 kJ mol-,If the first ionisation energy of Liis
620 kJ molH, calculate the second ionisation energy for Li (in MJ per mole). Round off your answer to the
nearest whole number. Take kinetic energy of electron in 1st orbit of H-atom is 2.2 x 10-18 Jlatom and
NA=6 * 1023,
29. AH-atom sample contains electrons in n excited state. When electrons from this energy level make transition
upto a lower state producing all possible spectral lines, the line corresponding to minimum wavelength was
3.4
observed to result from a photon of energy 3.0225 eV. Find the value of n. (Take :3.0225 = ).

30 An electron is allowed to move freely in a closed cube shaped box of side 5/3 cm. Calculate the minimum

h
uncertainty in it's velocity (in m/s) ? (Mass of electron =9x 1031 Kg. 0.54 x10-34 Js)
4n
Report your answer as (A + B), where (Av)=Ax 10 m/s.
 (A,C)
(B) (A) (C)
t). 8
-p,
15. 20. 28.
5. 10. (D
s):
q,
(C-p,
(C,D)
(D) (B) (D)
t): 2
(B-r,
14. 19. 27.
4. 9.
s)
,
q,
(A,C)(A-p,
(B) (C) (D)
STRUCTURE 7

3. 13. 18. 23. 26.

8.

ATOMIC
(B,C)
(C) (C) (D) (D)
2 8
:TOPIC
7. 12. 17. 22. 25. 30.
2.

(B.C,D)
(B) (A) A) (A)
8 5

6. 11. 16. 21. 24. 29.

1.