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Amines DPP 10 Solutions

The document discusses various reactions and properties of amines, including Hofmann’s bromamide reaction and the reduction of amides to amines. It also covers the distinctions between primary, secondary, and tertiary amines, as well as specific reactions like the carbylamine reaction. Additionally, it includes an answer key for related questions.

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22 views4 pages

Amines DPP 10 Solutions

The document discusses various reactions and properties of amines, including Hofmann’s bromamide reaction and the reduction of amides to amines. It also covers the distinctions between primary, secondary, and tertiary amines, as well as specific reactions like the carbylamine reaction. Additionally, it includes an answer key for related questions.

Uploaded by

Suresh
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© © All Rights Reserved
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Class : XIIth Subject : CHEMISTRY

Date :
Solutions DPP No. : 10

Topic :- Amines
2 (c)
Hofmann’s bromamide reaction is used to convert amide to amine.
𝑅CONH2 + Br + 4KOH→𝑅NH2 + K2CO3 + 2KBr + 2H2O
amide amine
4 (d)
Secondary amides such as N-methylethanamide on reduction with LiAIH4 give secondary
amines.
LiAIH4
CH3CONHCH3 + [H] CH3CH2NHCH3 + H2O
N-methylethanamide 2°amine
5 (d)
HOH
CH3CN CH3COOH
6 (c)
H
|
C2H5NH2 + O = C ― C6H5→C2H5N = HCC6H5 + H2O
Benzaldehyde
(A)
NH2CO NH2 + H NH.NH2 NH2CONHNH2 + NH3
urea hydrazine
(B)
C2H5NH2 + NOCl→C2H5Cl + H2O + N2
(C)
11 (c)
The reaction is believed to follow the mechanism.
𝑅—CONH2 + OBr―⟶𝑅CONHBr + OH―
𝑅CONHBr + OH―⟶𝑅CONBr + H2O
RCONBr R C O + Br- R C O R N C O

N N

R N C O+ 2OH- RNH2 + CO32-


12 (d)
HNO2 reacts to give an alcohol means the compound is primary amine.

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C5H13N means C5H11NH2(primary amine)
Optically active alcohol means C5H11 segment contain a chiral carbon.
H
5 4 3 2|
CH3 ― CH2 ― CH2 ― C ― NH2
|
1 CH3
Pentan-2-amine
13 (b)
LiAIH4
𝑅 ― CN + 4[H] 𝑅 ― CH2NH2
Alkyl nitriles primary amine
14 (d)
Electron donors are bases. In the given choices structure which does not involve resonance
will have electron easily available for donation, hence most basic.
∴ Only in choice (b) electrons are not in conjugation with double bond of adjacent atom.
∴ Compound in choice (b) is most basic.
15 (b)
Reduction
𝑅Br + KCN⟶𝑅CN 𝑅CH2NH2
16 (d)
It is methyl amine which, being basic dissolves in dilute HCI. It with NaNO2 evolves
nitrogen gas leaving behind methyl alcohol which has smell of wood-spirit.
HCI
CH3NH2 CH3NH2.HCI
NaNO2/HCI
CH3NH2 + HNO2 CH3OH + N2↑ + H2O
methyl alcohol
17 (b)
Benzaldehyde condenses with N, N-diamethyl aniline in presence of anhydrous ZnCl2 to
give malachite green
CH3
H N
CH3
C6H5CH O + Anhy.
CH3 ZnCl2
H N
CH3 -H2O

CH3
N
CH3
C6H5CH
CH3
N
CH3
malachite green
19 (b)
This is carbylamine reaction which is used to distinguish 1° amines from other amines. The
reaction is given by 1° amines only.
=
C2H5NH2 + CHCI3 + 3KOH→C2H5N C + 3KCI + 3H2O

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=
𝑅NH2 + CHCI3 + 3KOH→𝑅 ― N C + 3KCI + 3H2O
1°amine chloroform isocyanide
(bad smelling)
20 (b)
NH2CONH2 + HNHCONH2⟶NH2CONHCONH2 + NH3

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ANSWER-KEY
Q. 1 2 3 4 5 6 7 8 9 10
A. C C C D D C A C C C

Q. 11 12 13 14 15 16 17 18 19 20
A. C D B D B D B B B B

PRERNA EDUCATION https://prernaeducation.co.in 011-41659551 | 9312712114

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