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Roll No.
~-~Code
:! Q.P. ~56 /2/3 1
1
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,-·-·-· -·-·-·- ·-·-·-· -·-·-·- ·-·-·-· -·-
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! Candidates must write the Q.P. Code
! on the title naee of the answer-book.
··-·-·-·-·~----·-·-·-·-·-·-·-·-·-·-·-·-
fl\
l.
2.
~/NO TE
(I) cf,44 1~~~ ~TI= rm-~ -ij~~ 23~ I
111111111111 HI I
Please check that this questio n paper contain s 23 printed pages.
r (II) cf,441 ~~~~~m-~-ij 33 ~~ I
3.
Please check that this questio n paper contain s 33 questions.
(III) ~-lp f-q- ~~ 3m:~~ ~-~cf >Tsq; t qtl~"3 ffi-3~c fil ~~-~TR~
I

Q.P. Code given on the right ha.nd side of the questio n paper should be
writte n on the title page of the answer-book by the candid ate.
S. (IV) f441 ~c6T' 3m ~&.fl ~~- U~, '3'ffl:-~ ifii 'q~~'C RWJc nT ailiiifi 31q~
7.
fffli I
Please wrjte down the serial _nqmber .of the questi on in the answe r~
book at the given place before attemp ting it.
(V) ~ ~-~·q ;). ~ ~ ~ 15 ~ ~-~ ~ ~ i I ~-"tl3f ct>T ~d(UI ~ -q 10.15
( ~~ ~1((•11 I 10.15 ~'U 10.3Q~ c,q;1:ft t~cfic:R 1 ~-"tl3 fq,1~ ~~ ~~
"$R~ ~-;~c fil 'CR~ ~~ Ri~~ I
I
2
15 minute time has been allotte d to read this questio n paper. The questio n
paper will be distrib uted at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
I

candid ates will read the questio n paper only and will not w:rite any answe r
on the answer -book during this period.

fq~ l.:t (~4iRti:t>)

(ti lll.:t

s
f.t!ilfJa R7llT: a °E/UZ'
Time allowed : 3 hours
~HE MIS TRY (The ory) •
~JP n:70
Maximum Marks : 70

1 P.T.O .
56/2/3

I
 --==: ::---- ..... •• I [l{/P"

SEC'JJION - A
~- 16 X 1: 16

Question No. 1 to 16 are Multiple Choic,e type questions carrying 1 mark each.
1. Which among the following is a false statem ent ?
(A) Rate of zero order reaction is independent of initial concentration of
reactant.
(B) Half-life of a zero order reaction is inversely proportional to the rate
constant.
(C) Molecularity of a reaction may be zero.
(D) For a first order reaction, t 112 = 0.693/k.

I !

2. The charge required for the reduc~ion of 1 mol of MnO 4 to MnO 2 is

(A) 1F (B) 3 F
(C) 5F (D) 6 F

3. The element having [Ar]3d104s1 electronic con.figu_ration is

(A) Cu (B) Zn
(C) Cr (D) Mn

4. The numbe i of molec·uies that react with each other in an elemen tary
reaction is• aimeasu re of the :
(A) activation energy of the reaction (B) stoichiometry of the reactio n
(C) molecularity of the reaction (D) order of the reactio n

5. The diamagnetic species is :

(A) [Ni(CN)4]2-- (B) [NiClJ2--
(C) [Fe(CN)aJ3- (D) [CoFaJ3-

[At. No. Co = 27, Fe =26, Ni =28]

6. The complex ions [Co(NH ) (NO ) ]
2

+ and [Co(NH 3
)

5
(ONO)] 2

+ are called
2
3 5

(A) Ionization isomers (B) Linkage isomers

(C) Co-ordination isomers (D) Geometrical isomers

56/218 P.T.O.

rl
 ·'·
...

,r--L
• .Jo·•

...........~---...: C --- L

ii -••
7. What will be formed- after oxidation ~eaction of secondary alcohol with·.
chromic anhydride (CrOs)? • ' · ·.' ·- •• • -~· •

(A) Aldehyde (B) Ketone

(C) Carboxylic acid (D) Ester

8. Which is the correct IUPAC name for •

CH3

Cl
(A) Methylchlorobe~zene (B) Toluene
(C) 1-Chl or~M ethyl benze ne (D) 1-Methyl-4-Chl<;>robenzene

9. Which of the following is/are examples or'den aturat ion of protei n?

(A) Coagulation of egg white (B) Curdling of milk
(C) Clotti ng of blood (D) Both.(A) and (B)

pheno.l to salicyl. ic acid can be accomplishe d by

.· of
10. The conversion (
.•. -·.· •. .

(B) Friedel-Crafts' reacti on

(A) Reime r-Tiem ann reacti on
. . . ' '
r •
(C) Kolbe reacti on (D) Coupling·reaction

11. . Scurv y is cause d due to deficiency of • , ..

(A) Vitam in B 1 (B) Vitam in B2
(C) Ascorbic acid (D) Glutam ic acid

12. Nucleotides are joined togeth er by • •

(A) Glycosidic linkag e (B) Peptid e linkag e . '

(C) Hydrogen· bondi ng (D) Phosp hodie ster linkag e

6612/8 , . . P.T.O.
- 7 -
.'
'•

i
1
 For questions numbe r i~ to 16, two statem ents are given ..:..-one iabeiled as •• , •
Assertion (A) and th~ other labelled as Reason (R). Sele.ct th.e ~orrect
answer to these questions from the codes (A}°, (B), (C) ~nd (D) , as. given
below: • :

(A) Both Assertion {A) and Reason (R) are true and Reason (R) is the
correct explanation of the Assertion (A).
(B) Both Assertion (A) and Reason (R) are true, but Reaso~ (R) is not the
. correct explanation of the Assertion (A). .
(C) Assertion (A) is true, but Reason (R) is false.
(D) Assertion (A) is false, but Reason (R) is true.

13. Asser tion (A) : Cu cannot liberate H2 on reaction with dilute .mineral
acids. ...
Reaso n (R): Cu has positive electrode potential.
• I

14. Asser tion (A) : In a first order reaction, '

if the
.
concentration of the
reacta nt is doubled, its half-life is also double d.
•
Reaso n (R.) : The half-life of a reaction does not depend upon the initial
concen tration of the reacta nt in a first order reaction .

. . '•,

15. Asser tion (A): Vitam in D cannot be stored in our body.

Reaso n (R) : :Vitam in D is fa·t soluble vitami n and is not excreted from\.
the body in urine.

16. Asser tion (A) : Aroma tic prima ry amine s cannot be prepar ed by Gabriel
Phthal imide synthe sis.
Reaso n (R) _: Aryl halide s do not undergo nucleophilic substit ution
reactio n with the anion formed by phthal imide. •
P.T.O.
56/2/3 - 9 -
 •
·■
•

...
SECTION-B
17. Name the following coordination compounds according to IUPAC norms! 2 x 1
(a) [Co(NH3)iH2O)Cl]Cl2
(b) [CrCl2 (en)2] Cl

18. What is meant by the Rate law and Rate con~tant of a reacti~n. Identify
the order of a reaction if the units of its Rate constant are : 2
(a) . s-1 •

(b) moI-1 L s-1

19. Complete and balance the following chemic~! equations : 2xl

- 2-
(a) 8MnO 4 + 3S2O 3 _ + H2O ~
2-
(b) Cr2O 7 + 3Sn2+ + 14H+ ~

20. (A) The rate constant for a zero order reaction A ➔ P is 0.0030 mol L- s- •
1 1

How long will it take for the initial concentration of A to fall from
0.10 M to 0.075 M? 2
OR •
(B) The decomposition of NH8 ~? platinum surface is zero order reaction.
1 1
What are the rat.es of production ofN2 and H2 ifk = 2.5 x lo-4 mol L- s- ? 2

21. Give reasons for the following observations : 1+1

(a) p-Chloronitrobenzene reacts with (aq)NaOH at 443 K to give
p-nitrophenol whereas chlorobenzene reacts with the same reagent
at 623 K and 300 atm.
(b) Main product obtained when chloroethane reacts with KCN is
propane nitrile while with Ag CN it is ethyl isocyani~e.

P.T.O.
66/2/3 - 11 -
 ,. - • ~ t , I " f"i'\.MAIII••• • - - .. .,. I ♦ • •--V"'l.1,/\f fW .,:;:v~••••" •--
............ - • • • - . ------ -----~- -,. .

II
SECT ION-C
22. Henry's law constant for CO2 in water•is 1.67 x 10 Pa at 298 K. Calculate
8

the number of moles of C_O2 in 540 g of soda water when packed under
3.34 x 105 Pa at the same temperature. 3

23. Give reasons: 3x1= 3

(a) Fuel cells are preferred for production of electrical energy than
thermal plants.
(b) Iron does nof rust even if zinc coating is broken in a galvanized pipe.
I
: I ,- ("

(c) In the experimental determination of electrolytic conductance, Direct

Current (DC) is not used.
, I

24. (a) E (Mn 2+/Mn) is -1.18 V. Why is this value highly negative in
comparison to neighbouring d-block elements? 3x1= 3
(b) What is lanthanoid contraction?
(c) Zn, Cd and Hg are soft metals. Why ?

25. (a) Using valence bond theory, explain the hybridization and magnetic
behaviour of the following : 2 + 1=3
(i) [Co(NHa)a)Cl3
(ii) !½[NiClJ
[At. no. : Co =27, Ni =28]
5
(b). Write the electronic configuration of d ion when L10 > P.

26. (a) Define. the following : 2 +1 =3

(i) Enantiomers
(ii) Racemic mixture
(b) Why is chlorobenzene resistant to nucleophilic substitution reaction?

68/2/3 P.T.O.
- 13 -
 II
27. (A) Explfll:11 the following reactions and write. chemical equation involved : - :
. . . ... . . . . .
• ( '
3x1=3 I t .. , I

(a) Wolff-Kishner reduction

(b) Etard reaction
(c) Cannizzaro reaction
ORi i • .
.
(B) Write the structur~~ of A, B , ~:qd 9 in t~~ following sequence of
reactions : • • t • • • 2 x 1½ = 3
1
. (a) ~H~COOH 80Cl2 A H2, P4-Baso·4 • B H2N-NH2 C

(b) CHaCN 1.(DIBAL-H) A Dil. NaOH. • B ·; •· •d

C
2. H20 :_, 1- •

28. Define the following terms : ' ' • 3

(a) Native protein
(b) Nucleotide
(c) Essential amino acid

SECTION-D
29. The spontaneous flow of the solvent through a semipermeable membrane
from a pure solvent to a solutio~ • or from a dilute solution to a
concentrated solution is called osmosis. The phenomenon of osmosis can
l l • ~ • •

be •demonstrated by taking two eggs of the same size. In an egg, the

'membrane below the shell 'and around the egg:material is semipermeable.
The ·outer hard shell· can be removed by :puttin_g the egg in dilute
hydrochloric. acid. After removing the hard shell, one egg is placed in
distilled water and the other in a saturated salt solution. After some time,
. ' .' • •

the egg ·placed in distilled water swells-up while the egg placed in salt
solution shrinks. The external pressure applied to stop the osmosis is
termed as osmotic pressure (a colligative property). Reverse osmosis takes
place when the applied external pressure becomes larger than the osmotic
pressure.

56/2/3 - 15 -
P.T.O.
 II.
(a)
. . . - be· used in. the
Define reverse os~osis. Name' one 8PM'. which can
process of reverse osmosis.
. • t I
2

(b) (i) What do you 'expect· to happen when red blood corpuscles
(RBC's) are placed in 0.5% NaCl solution ? 1

OR
(b) (ii) Which one of the following-will have higher osmotic pressure in
1 M KCl or 1 M urea solution. Justify yo_ur answer. 1

(c) Why osmotic pressure is a colligative property? 1

' .
I '

30. •Amines have a lone pair· of electrons on nitrogen atom due to which they
' • I

behave as Lewis base. Greater the value of Kb 'or s~aller the value of pKb,
stronger is the base. Amines are more basic than alcohols, ethers, esters,
etc. The basic ~haracter ·of aliphatic amines sho~d increase with the
• ~ "' • •• • I

increase of alkyl substitution. But it does not occur in a regular manner as

a secondary aliphatic amine is unexpectedly more basic than a tertiary
amine in aqueous solutions. Aromatic ~mines are weaker bases than
ammonia and aliphatic amines. Electron releasing groups such as -CH3,
-OCH3, -NH2,,; .etc., increase the basicity while electron-withdrawing
.
substituents' such as -NO2, -CN, halogens
. . the basicity of
etc., decrease
..
amines. The effect of these substitute is more at p- than at m- position.
(a) Arrange the following in the increasing order of their basic character.
Give reason : I I ''
2
NH2 NH2 • NO2

f
6 '
NO2 CH3
(b) Why pKt, of aniline is more than that of methylam~e ? 1

. 66/2/3 - 17 - P.T.O.
 XX!XX/XXXX School No. ovu.. - - - • ••
11689119 Date ofBinh
rw.~r:f!Y NINE ONLY__ - ----
TWO CRORE SIXTEEN LAKH EIGHTY NINE nmy~ ~D ~o HUJIDRF
.D
..
words)

II
- (c) (i)
• •

Arrange the following in the increasing orde r

character in an aqueous solution:
'
• • # •
of. their basic
1

(CHs) 3N, (CH3) 2NH, NH3, CH3NH2

OR .
(c) (ii) Why ammonolysis of alkyl halides is not a good ·method to 1
prepare pure amines ?
-
SEC TIO N-E
the following
31. (A) (a) Calculate the standard Gibbs energy (~G j of
reaction at 25 °C : 3+2
Au(s) + Ca2+(iM) ➔ Au3+(1M) + Ca(s)
0 0

E Au3+/A u = + 1.5 V, E Ca2+1ca = .... 2.87 V •,

. . ' •

Predict whether the reaction will be spo~t, aneous or not at 25 °C.

[1 F = 96500 C mol-1]
•
(b) T~h ed silver contains Ag2S. Can this· tarni sh be remo
ved by (

placing tarnished silverware ·in an aluminium p~ containing

an inert electrolytic solution such as NaCl ? The stand ard
electrode potential for half reaction :
Ag2S(s) + 2e--➔ 2Ag(s) + S2-is -0.71 V and for. •.
''""· f t

AJ,3+ + ae--➔ 2Al(s) is-1. 66 V

OR
2+3
31. (B) (a) Define the following:
(i) Cell potential
(ii) Fuel cell
(b) Calculate emf of the following cell at 26 °C: •
2+ 2+ ,
Zn(s) I Zn(O.lM) 11 Cd(O.OlM) I Cd(s)
..
I
0

Given: ECd2+/Cd =-0. 40 V

0

Ezn2+fln :..;.0.76 V
[log 10 = 1]

68121a P.T.O.
- 19 -

•
 ---------. -·- ------- --- ....

32. (A) An organic compound 'A', molecular formula C2H 60' oxidises with
CrOs to form a compound 'B'. Compound 'B' on warming with iodine
and aqueous solution of NaOH gives a yellow precipitate of
compound 'C'. Wh~n compound 'A' is h~ated with cone.. H2S04 at 413
K giy~s a compound . on reaction, with excess HI gives
. . 'D', which
compound 'E'. Identify compounds 'A', 'B', 'C', 'D' ~nd 'E' and write
chemical equations involved. 5

OR
82. (B) (a) Write chemical equations of the following reactions : 8+1+1=5
(i) Phenol is treated with cone. HN08·;
(ii) Propane is treated with B2H8 followed by oxidation by
H20z'~H-~
. (iii) Sodium t-butoxide is ·treated with CH3Cl.
(b) Give a simple chemical test to distinguish between butan-1-ol
and butan-2-ol.
(c) Arrange the following in increasing order of acid stre1:1gth :
phenol, ethanol, water

33. (A) (a) Give IUPAC name of CH8 - CH - CH - CHO. 1

(b) Give a simple chemical test to dis~inguish between propanal

and propanone. 1
(c) How will you convert the following : 8
(i) Toluene to benzoic acid
(ii) Ethanol to propan-2-ol
(iii) Propanal to 2-~ydroxy propanoic acid
OR

18/1/8 P.T,O.
~
. 'material,
Co mp le"te. ea ch sy nth esi s by •giving missing starting·.
33. (B) 5 x 1 =5
rea ge nt or pro du cts :

(b)
? (i) 03 •
• (ii) Zn - H2O 2
0 =O •
0

OH SOCl2 . .
(c) 0 ~

OH

CHO
(d)
CX COOH
NaCN/HCl

G8J2t3 - 28 -