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Science Department A 10
September 2022 L c* ‘ L J

SCH4U- Structure and Properties of Matter Assessment [AM] i

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Part A — Knowledge and Understanding [10 markslv \”C‘F\tg@g et W "‘fl'fd' L
Circle the most correct answer on the scantron for the questions below. Only the scantron card will be markeJ

1. Which of the following is NOT a characteristic of London dispersion forces?

a) They are the weakest intermolecular force
bl They increase as the molecular mass of a substance increases
€)) They form as a result of permanent dipoles on a molecule
d) They are weaker than intramolecular forces
e) None of the above

2. A molecule has a central atom with sp? orbitals. If no lone pair of electrons are present on the central atom, the
bond angles are i
a) 180° (b)) 120° ) 109.5° d) 90° e) 107°
‘ 3. Ifn=5, how many possible secondary quantum numbers are there?
a) 2 b) 3 c) 4 @y s e) 6

4. Which orbital describes an electron that has the following set of quantum numbers: n=4,£=2, m{=-1, m;=1/2
a) 4s b) 4p @ ad d) af e) 5d

5. Which of the following could have the valence electron configuration shown to the right? 1l i M
a) 07 d) Na* S_ _?;
b) Ca* (€) Al of the above
c) Ne

a) 1 b) 2 @ 3 d 4 e) 0

7. In the molecule shown to the right, there are: H\ S\-“l El%

a) 3 atoms with sp? hybridization C C'}‘-’i
b) 2 tetrahedral carbon atoms H /{/ \
c) 6 atoms with incomplete octets g‘g%c C‘;l‘L ' H
@i)) 3 trigonal planar carbon atoms // N
e) 10 sigma bonds and 4 pi bonds 56 H
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( .‘8. Which rule / principle is being violated in the diagram to the right?
a).. AUFBAU Principle
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. b)' Pauli Exclusion Principle
@ Hund’s Rule
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d) Heisenberg’s Uncertainty Principle
2p
All of the above
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 . wnich of the following electron configurations represents
an electron in an excited state?
a) [Ar]4s3d"%ap? c) [Ar] 453d™04p? e) [Ar] 4s?3d%%4p*
b) [Ar] 45?3¢04pS @ [Ar] 45%3d%4p35s1

10. Choose the correct set of quan

tum numbers for a n electron in the 3p orbital
3 n=1{=0,ml=-1, m,=-1/2 d) n=2{=1,ml=1, ms=-1/2
b) n=3,[:0,n1£:»1,m5=.1/2
&) n=3,{=2,ml{=-1, m;=+1/2
(@ n=3,t=1,mt=1, m=412
Part B — Thinking and Inquiry [11
marks]

1. For each of the following molecules: [2.5

marks each - 5 marks]
draw them in the correct shape
draw bond dipoles and/or partial charges (IF APPLICABLE!)
name the molecular shape )\S
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state the hybridization of the central atom
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identify the polarity of the molecule
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Hybridization: i(’)q) / Hybridization: i"jl' v 7/

Polarity of Molecule: 7?3“9![7 i / Polarity of Molecule: Do\ar

2. What is the maximum number of electrons in an atom that can be represented by the quantum
numbers
provided below? Note: the at(zy'ray be real or hypothetical. [2 marks]

\ @ n=st=4 B <edvans b) n=3,m=-1 *L\_

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3. :D\leermine the four (4) numerical quantum numbers for the 65th electron found in a lead atom. [0.5 each
- 2 marks] £3th electron (}1 )
9/ h:k\/ K= - mR= -2 S ms _2 )
 Describe the results of two
(2) different experiments/tests that you can perform to determine whether
titanium dioxide, TiO,, isan
ionic solid or a covalent network solid? DO NOT discuss appearance
in your
answer. [2 marks]

Experiment / Test 1
Experiment / Test 2
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Part C — Communication [8 marks]

1. The layout of the periodic table that you have been using since grade 9 is in fact no coincidence and
aligns
specifically with the quantum mechanical model. Use your understanding of the unit
to explain the layout
of the periodic table. [2 marks)
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2. There are many technological devices that are based on the principles of atomic and molecular structures,
each of them having their benefits and costs to society.

Explain how the MRI MACHINE uses concepts of the quantum mechanical model in order to work.
Use proper terminology and concepts learned in class and from the assigned readings. [3 marks]
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 A student says that if two molecules have the same number of bonds, the two molecules will have the
same polarity. Do you agree OR disagree? Provide an explanation for your answer. [3 marks]

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4. Arsenic (As) can have a valence of -3, +3, or +5. Using your understan
three (3) condensed electron configuration for each of these ions. [3 marks]

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