Module 4
Module 4
Module 4
• Advantages
– It is a renewable source.
– It can be stored and used as per the requirement.
– It helps in waste management.
– It is an indigenous source of energy.
– It helps in economic development of rural areas.
– It helps in improving sanitation in rural areas and towns.
– It helps in providing fertilisers.
– It provides economical use of various types of wastes and residues.
• Disadvantages
• It has low energy density.
• It is a labour intensive energy source.
• Its production requires large land area.
BIOMASS CONVERSION TECHNOLOGIES
– A liquid in the form of oil such as acetic acid, acetone, methanol, oil
and tar
– A pure carbon char
• If pyrolysis is carried out at higher temperature (above l000°C),
maximum amount of gaseous product is formed. This high
temperature pyrolysis is called gasification. This process is generally
used to produce charcoal and it is also called carbonization.
• Liquid product from biomass is obtained by catalytic liquefaction
process at low temperature (250–450°C) and high pressure (270
atm).
Biomass to Ethanol Production-
• Biochemical
• The conversion of biomass is carried out using
metabolic action of microorganism or bacteria.
The process produces liquid and gaseous fuel.
The major biochemical processes for the
conversion of biomass are as follows:
• Anaerobic digestion or fermentation. The
biomass in the presence of water is converted
into biogas by the action of anaerobic bacteria.
The methane and carbon dioxide are the two
main components of biogas
• The biomass used includes animal manure, algae,
kelp, hyacinth, urbane waste (garbage+ sewage)
and industrial waste.
• Ethanol fermentation. It is formed due to the
alcoholic fermentation of simple hexose sugars
(six carbon atoms per molecule such as C6Hl2O6)
in aqueous solution by the action of a enzyme
present in yeast (act as catalyst) in the acidic
conditions (pH valuebetween 4 and 5).
• The chemical reaction can be given as:
1.Urban waste to Energy Conversion-
• waste, aqua waste and forest waste. Agricultural crops include rice,
wheat and cereals while agricultural wastes include wheat straw,
sugarcane biogasses, groundnut shell, coconut shell and rich husk.
Animal wastes include cow dung, horse manure, sheep manure and
poultry waste. Urban wastes include paper, leftover food, plastic,
rubber, wood and textile. Aqua wastes include water plants
(hyacinth), algae and waste from fishery. Forest wastes include
waste from sugar mill, tannery, fruit processing industry and paper
mill.
Factors affecting the performance of a
digester
• The factors affecting the performance of a digester are as follow:
• Temperature. Anaerobic bacteria grow and work best in the
temperature range of 20–65°C.
• Pressure. A pressure of 6–l0 cm of water column is
considered ideal for proper functioning of the digester.
• Water. The presence of water helps in better mixing of various
constituents of the biomass, hydrolysis of biomass, movement of
bacteria and faster digestion process. The optimum solid content
of biomass is 9–l0%.
• pH value. The pH value in the acid forming stage of digestion
process should be about 6 (acidic). During methane forming stage,
the pH value should be about 6.5–7.5 as anaerobic bacteria do not
grow in acidic solution.
• Feeding rate. A uniform feeding rate should be maintained. In case
of faster feed, acids will accumulate to stop digestion process. In
case of slow feed, the digestion progresses slowly due to non-
availability of sufficient biomass.
• Presence of nutrients. Carbon, nitrogen and other nutrients are
essential for digestion. Carbon and nitrogen are main nutrients for
anaerobic bacteria and their presence in proper ratio is essential to
ensure the maximum microbiological activity. Selected raw
materials should added to maintain the proper concentration of
nutrients in digestion solution of bacteria.
• Seeding. To start or accelerate the digestion process, it is customary
to add a small amount of digested slurry containing methane
forming bacteria to the freshly charged digester. This process is
called seeding of bacteria.
• Mixing and stirring. Mixing and stirring of digester slurry helps to
mix the floating masses of biomass in the slurry for bacterial action
so as to speed up the methane forming process in the slurry.
• Retention time. It is the duration for which the biomass slurry
remains in the digester. The digesters are designed to keep biomass
for the retention period ranging from S0 to 50 days depending on
the region (climatic temperature) and type of biomass. Retention
time is optimised to get atleast 70–80% of digestion of the slurry.
• Toxic substances. The presence of pesticides, detergents and
ammonia in the biomass affects the digestion process.
• Type of biomass. The digestion process also depends on the type of
biomass. The biomass can be cow dung, poultry manure, sheep
manure, night soil, rice husk, algae and water hyacinth and these
have a different rate of biogas yield per unit mass
types of biogas plants
• Biogas plants can be classified as batch type and continuous type. The
continuous type biogas plants can be further classified as (i) floating drum
or constant pressure type plant and
• fixed dome or constant volume type plant.
• Batch type plant
• A batch type plant consists of a number of digesters which are charged,
used and emptied one by one in a synchronous manner to maintain
regular supply to gas holder or storage tank. Each digester is charged with
fresh biomass and it starts supplying biogas after 8–l0 days. The digester is
now capable of supplying biogas for about 40–50 days till its biomass is
completely digested. Afterwards, this digester is emptied and recharged
with fresh biomass. Hence, each digester should be charged in about at
the interval of 50–60 days. Digesters in a batch biogas plant is shown in
the Figure 5.2. The installation and operation of batch type plant is both
capital and labour intensive
Continuous type biogas plant
• It has constant volume but varying pressure inside the digester as it has no
movable type gas holder but a fixed dome at the upper portion of the
digester as shown in Figure 5.5. The biomass and water are mixed into
slurry in inlet mixing tank, which is fed into the digester through the inlet
pipe. A stirrer is provided in the digester tank to mix the slurry inside the
digester, which also helps in mixing of scum floating on the slurry. The
generated biogas accumulates in the fixed dome of the digester and it is
taken out by an outlel pipe. The residual digested slurry is taken out from
an opening in the digester. In the modified fixed dome type biogas plant, a
displacement tank is also provided which is connected to the digester. As
the pressure of gas in the fixed dome increases, the level of the slurry
inside the digester goes down and it forces the slurry to rise in the
displacement tank. This arrangement helps in maintaining a constant
pressure inside the digester about l m of water column and the removal of
digested slurry from the displacement tank
• Advantages and disadvantages of fixed drum type biogas plant
• The advantages are as follows:
• It has lower cost.
• It has no corrossion problem.
• It has better heat insulation.
• It requires no maintenance. The disadvantages are as follows:
• Gas production per cubic meter of the digester is less.
• It has variable pressure of biogas.
•
• It has more risk of leakage due to higher pressure of gas.
• It has more risk of explosion.
• It involves complex installation.
KVIC and Janata model-
• These plants are commonly known as KVIC (Khadi Village and Industrial
Commission) plants and were standardized in 1962 and are used widely
even now. These plants have an underground well-shaped digester having
inlet and outlet connections through pipes located at its bottom on either
side of a partition wall. An inverted drum (gas holder) made of mild steel
is placed in the digester which rests on the wedge shaped support and the
guide frame at the level of the partition wall and moves up and down
along a guide pipe with the accumulation and use of gas. The weight of
the drum applies pressure on the gas to make it flow through the pipelines
to the points of use. The different components of KVIC biogas plants are
shown in Fig. 6.1.
• The gasholder alone is the costliest component which accounts for about
40% of the total installation cost of biogas plant. It also needs to be
painted regularly for protecting it against corrosion. These plants can be
of any size to cater the needs of the users.
• Janta model biogas plant
• This is the first fixed-dome biogas plant was introduced in the form
of the Janta Model Biogas Plant by Gobar Gas Research Station,
Ajitwal in 1978. The main feature of this model is that the digester
and the gas holder are integrated parts of brick masonry
structure. The digester is made of a shallow well having a dome-
shaped roof on it. The inlet and outlet tanks are connected with
the digester through large chutes which are called displacement
chambers. The gas pipe is fitted on the crown of the masonry
dome and there is an opening on the outlet wall of the outlet
displacement chamber for the discharge of spent digested slurry.
The size of these plants is limited to 15 m3 par day. The different
components of Janta Model Biogas Plant are shown in Fig. 6.2.
Deenbandhu model biogas plant
• Deenbandhu model biogas plant was developed by AFPRO (Action for Food
Production, New Delhi) in 1984. The world Deenbandhu is meant as the friend of
the poor. This plant is designed on the principle that the surface area of biogas
plants is reduced (minimized) to reduce their installation cost without sacrificing
the efficiency of the plant. The design consists of segments of two spheres of
different diameters, joined at their bases. The structure thus formed act as the
digester as fermentation chamber as well as the gas storage chamber. The higher
compressive strength of the brick masonry and concrete makes it preferable to go
in for a structure which could always be kept under compression. A spherical
structure loaded from the convex side will be under compression and therefore,
the internal load will not have any residual effect on the structure.
• The digester is connected with the inlet pipe and the outlet tank. The upper part
above the normal slurry level of the outlet tank is designed to accommodate the
slurry to be displaced out of the digester with the generation and accumulation of
biogas and is called outlet displacement chamber. The size of these plants is
recommended up to 6 m3 par day. The different components of Deenbandhu
Model Biogas Plant are show in Fig. 6.3.
Biomass Energy Programme in lndia