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GOC

The document discusses various aspects of chemical structures, focusing on inductive effects, aromaticity, and stability of compounds. It highlights the importance of bond lengths, resonance, and the ortho effect in determining acidity and basicity. Additionally, it provides insights into the stability of different molecular configurations and their implications in chemical reactions.

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0% found this document useful (0 votes)
16 views10 pages

GOC

The document discusses various aspects of chemical structures, focusing on inductive effects, aromaticity, and stability of compounds. It highlights the importance of bond lengths, resonance, and the ortho effect in determining acidity and basicity. Additionally, it provides insights into the stability of different molecular configurations and their implications in chemical reactions.

Uploaded by

rborole2008
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
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Prony lane + Gensel. eee confugaked £12 — fanulro we \ sl waits adh whofe aa Jee Aanatonernsa J At ition: poaitions : probe. # taut * ONE PART OF MALECULE Ie —_ panmatic, Moreur€ (8 froma, > * Cyedebu bastion wo dimasg. Ah daont with native wool | to gttain otfe mokitity *) Ton > ta nautrol / iw) By Ra > Non=0g., om Fs nen) 9) A> AA * iat. aolwee | ws ae Aca Waite wd Lp. ay in ar Neat colons, XT, Shunea , WS precgitozion ap semeved, ae holide isn prodiata, AROMATIC Ch, dE prelpihdes. ly) EN af atom T, is & . Jy € Reg: order oun. Benygre > tysidine > t > Fux Thiophene 7 Byrom anger * UE AR CT Rormadl, ro prt. da oes en Rarnafhs + Poke. boned Mi Ada aan eee | ARE Bengane y Nogbraine i ath einem 7 fudwrotente Ais Sayestorotion | Coc ateleiibyy, compare RVG: Pde Mine fee net: founad. aiRe, ae Zindividus® af in find | nye 2 a Os bptnnde es RE 00 Ne. pk bangensidl » Robot snreay mented | Nivgs in the, ay URL, * More yp. a R.8 wrare atobitely al deeds af Pactoka. APPECTING RD. = Osterortion lus C4 TRMO A. iy RE eaten of tontugadtion et eee Extended y Creed * (Bri) Ww 4 Stability ) oH 2 fe daokdene ¥ rong -bubent ‘ \ orn \ Forms ‘ [Pcoxkonion > 2°caxbond” se CARROCATION ton: BM0 - . {nkeraction cr Ait * Dus ‘b Re afteck in oMhansd , cae took mayne double bord cha | LCEC bord seapire CHO singh bond, Alot, , Afr Te. © CTY -G-De-CH for 1 ORY > eT (am Even 2b ove -vodom a pees, apa 4 centiclrred ab HHgraip & No dk KH 1 ehaniiby of ortiin & porn. 4 Cg: Guretivaltng , imstn~ iseekrg . YP Artke, EAR. nd. a WOR Kre.ty # Note Gxeke [act] dn mark See RR? Brdgehend dom con't be dp? itt ona THY 4 3 - marnbered , SF Oeby for ppidychosd \eyetic come, powsibe ok bri > Reso. Hoefer con't we Aprons st pridgehiod at | "ae, AGitn T dn. we. ak Co \yx\ y be Ke cork, shot p>] years Kf it th be at stig yoattton. a ht bridgchaocl poattion , ~ye A potsibse. but ne te Heat af, hydtoganakion: BOND LENGTH: i) g.0. «'/B.L- W) BL EP KY yp FR) BL. xe No. ab x8 WS) BL. 0¢ Resonance r for domme Means (zor T chord k poduct on WySd-)> 0 Ab pre oll Ry pen Coon om Toes) aM * frobility: por TT bd 4 Stanidi Seat a ated » dolosed > Cumulative Crt rCu # ford iS Git ol tee eat (Hoc! ey a Ring stain o¢ (ool 4 Greatt® vo, ofs Por bord, | Koren wild be (HOC. | % REMEMBER * 4 Ina worse ot, | & wom | rece wo rC odors of ct: a gtagwury oF me tM, +H, tT mag, oa, \ «Os Bsnsity vlog Stability v Boake, bordling * Bombo dome podod, EN, & compart 5 Lesy feng Ct mpc, Grobility. aa NN, Lome . periol: orbit Bigg. de ry. _2p-ap > Pep | obra: orto + | WE Ragonentes Ou Aromatic cation? CT T yego, > ROXMaL Yeo, Thy eyctoperyl Bbdg-A > pba > bd, aAK~H > Primony ! Coxbon'4 Ct on veonaklrg, syste, ‘W) Rodononte « No. of RG a meaty Atobility 09 NO. oe He NOTE! Fast: A> Pct vsith de R Lg atct Ww) Hobislibt +7 He GTagWUTY oF Co. 1 OY = Pret Ce casks) oC aM, HH, AL « Reobitity. i ) DBs. J aR wath No No. aly Ba. V) Aromat cation (> 85S 9 No. ah «-H-C.g, . Wi) 3g — who, OX \[ Ske Boe Ware N) [oo oese, ODE & Vetgbifi oC ND) Notmad te0, Vil He aftet | wi viii) E- * cH ~ + > — » Wolo , stability Tripdat 7 Ki shsuddl By 0c ap. “Stone Ee gabe & compara oti g| SO) dant TRastOnge, oe igi: % More troinal ings | : 2 EE AENONS HF ACIDIC QTRENGTH (EWS) g > HET (2056), > het Be > Cyc > = (Roa. ? “Wal > a oft, K Srbility 2k CB | babing Ah eA KEN eo od Resnante * cug-o Pumoric Yo, & # ORTHO EFFECT: Moat anidic: Osubraditeeted Wmus the QTOUP. Ort feo % A a « EWG | Eo, i h> 27 3>J j AH Imp. ot . ow ON “hy oO) oe ® | ., Noe fo | \ Crofakton NO, BOD volatife, “ ou OW.. ov oH CHO oO” Ko & Or odd pda. Ho) » Picric of =: ON NO, - | id 2 pKaz 0.44 ook Te blag ai Sounds , [7a >Aainane eel f# Ka, orden. Oxalic > Moalanic > Surelnicy : Grytexic > Adipic 4 ! “Comaaa| = Ka, ordasg, * | Oxeic + Glubuxic > Adipic > Guarini. > Mollonie * \ ‘ _| *Eecaption aert | eon x04 Gm 4 earth, ain 8 ¥dndoluble fn NooM WR) NMCDg Ziat: More aridic thon Ha e036) ave affpureatunne. AO? = ROM, POH : © th 2, ke dinitrophanal 1 D — Rierie, sqporic, ll cordoorsfite rida YO Lessinger nen oererey Hons * For oridicity Muse Yemove one At from Wandin — positions 2 cheek, Aboloillity of CB Lhe wwe Adsl tp die. | CHLOH (Nek phancf) | 4» Pieric , 0-84 phy #No H-bond dn cn ak orto eon 2 BA PRCOOK AZ | (Dome a. bie HEL), #o 5 eee wor.n? H Susmanansg + Hy Ody: 6B + Sk WOME | Bia So tonic > PAO | Conbonsgcc, (Methanoie) # Tear FoR AciDity: | >. oF, COM cee si ‘y Na motel Tak: coho’, | _—ve De phonol, cevcbo niflio ocids, stirs, ) Ao dubillity Jy Naby: U—~ c voodee bral ‘ae foe ok Se tea | Secafens ean soluble an Nod, eid) | |) RSF Rlbone > Athan > Reco > Kas > 9 Hi) ee eWwoy K-o-87 H BAQICITY: oC atehibty ok pKa \P>d’> NHS * R= CHg | 2 > (Pp a > NHg 1 28> ghd (0 ents city A 98 | a Ectot gp coo. 7, Bosiahy L > Amides : prcdaa, thon ania becouse wy Yeap, Ne Brepilinas a Dakem. ¢ fos aya eno Nv TNE — Ortho | nie ope aE Goaie atrength due bo | IR: Ne pontetpei ART, Boaiaty t 44 2,4, ¢~ tinh? anit Freartokion is Panter’ Sus te K-bo Bs x ok Saint S % weeping aes Rye ak R Rg RNeR ® ent Erporked ordax : 3>2> “ey dex ’ Actual or 273>| % Gaaie strength 0 (/Aymine ino ic, oundred “i jemi AW NY ba ab apo Hing B Bacon Ay Ban | Aron P37 Fi ay w nSondy Re. Alows | babbO boabity ( |\ hae Xp pork af cues “e ‘guano Wn 47 0 hae. ane Gen, oe 3s | boat” st Str Mibu Shand Ave a bridaghand,

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