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Solid State Concept

The document provides a comprehensive review of the solid state chemistry concepts, including types of crystalline solids based on bonding, unit cell structures, and various packing arrangements. It covers important topics such as voids in unit cells, non-stoichiometry defects, and specific crystal structures like NaCl and ZnS. Additionally, it includes calculations related to lattice points, magnetic moments, and defects in crystals.

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20 views169 pages

Solid State Concept

The document provides a comprehensive review of the solid state chemistry concepts, including types of crystalline solids based on bonding, unit cell structures, and various packing arrangements. It covers important topics such as voids in unit cells, non-stoichiometry defects, and specific crystal structures like NaCl and ZnS. Additionally, it includes calculations related to lattice points, magnetic moments, and defects in crystals.

Uploaded by

pranavreddy802
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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GNREDDY IIT JEE CHEMISTRY CLASSES

SOLID STATE
CONCEPT REVIEW
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TYPES OF CRYSTALLINE SOLIDS BASED ON BONDING
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SIX FOLD AXIS OF SYMMETRY


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2D CLOSE PACKING LAYERS


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3D SPACE LATTICE
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HCP UNIT CELL


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RANK OF THE UNIT CELLS=EFFECTIVE LATTICE POINTS CALCULATION
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RANK OF THE HCP UNIT CELL=EFFECTIVE LATTICE POINTS CALCULATION
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SEVEN CRYSTAL SYSTEMS


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2D CLOSE PACKING LAYERS

C.NO OF SQUARE CLOSE PACKING 2D LAYER= 4


C.NO OF HEXAGONAL CLOSE PACKING 2D LAYER= 6
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3D PACKINGS

1.SIMPLE CUBIC CLOSE PACKING


2.BODY CENTRED CUBIC CLOSE PACKING
3.HEXAGONAL COLSE PACKING(H.C.P)
4.CUBIC CLOSE PACKING(C.C.P) (OR)
FACE CENTRED CUBIC CLOSE PACKING(F.C.P)
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3D CLOSE PACKING BY SQUARE CLOSE PACKING 2D LAYERS


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1. SIMPLE CUBIC CLOSE 3D PACKING
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2. BODY CERNTRED CUBIC CLOSE 3D PACKING


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3D CLOSEST PACKING BY HEXAGONAL CLOSE PACKING 2D LAYERS


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3. HEXAGONAL CLOSEST 3D PACKING


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4. CUBIC CLOSEST 3D PACKING (OR) FACE CENTRED CUBIC CLOSEST 3D PACKING
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OCTAHEDRAL VOID
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LIMITING RADIUS RATIO CALCULATION


1. TRIGONAL VOID
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2. TETRAHEDRAL VOID
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3. OCTAHEDRAL VOID
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4. CUBIC VOID
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VOIDS IN FCC OR CCP UNIT CELL

FACE CENTRED CUBIC UNIT CELL


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TETRAHEDRAL & OCTAHEDRAL VOIDS
REPRESENTATION IN HCP PACKING
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RANGE OF LIMITING RADIUS RATIO


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VICE-VERSA CONCEPT
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NaCl STRUCTURE
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ZnS SHALARITE STRUCTURE


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DIAMOND STRUCTURE
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FLUORITE STRUCTURE: CaF2


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ANTIFLUORITE STRUCTURE: Na2O
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CsCl STRUCTURE
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CORUNDUM(Al2O3 )TYPE STRUCTURE
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Which of the following has both Schottky and Frenkel defects.


A) AgBr B) ZnO C) NaCl D) KCl
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NaCl is doped with 10-3 mol percent SrCl2 .The concentration of cation vacancies per mole of
NaCl will be
A) 6.02x1015 B) 6.02x1018 C) 6.02x1020 D) 6.02x1023
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NON STOICHIOMETRY DEFECTS


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In FeO crystal lattice, 4% of cationic sites are vacant and electroneutrality is maintained by
oxidation of same Fe(III). The number of Fe(III) ions present per hundred of O2- ions are
A) 6.5 B) 7 C) 8 D)9.5
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MAGNETIC MOMENT CALCULATION


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