Solution
Solution
1103CJA101021250020 JA
PHYSICS
SECTION-I
1) A semicircular ring having charge density +λ on first half and –2λ on second half is kept as shown
(A)
(B)
(C)
(D)
2) A ring having charge +Q and radius R and a long thin rod having charge density +λ are kept as
(A)
(B)
(C)
(D) Zero
3) A insulating cylindrical rod of diameter d and length ℓ (ℓ >> d) has a uniform surface charge
density such that the electric field just outside the curved surface of the cylinder at point M is E0.
Find the electric field due to charge distribution at point P (r >> ℓ).
(A)
(B)
(C)
(D)
4) There is a uniform electric field in X-direction. If the work done by external agent in moving a
charge of 0.2 C through a distance of 2 metre slowly along the line making an angle of 60° with x-
direction is 4 joule, then the magnitude of E is :
(A)
(B) 4 N/C
(C) 5 N/C
(D) 20 N/C
5) The variation of potential with distance x from a fixed point as shown in figure. The electric field
at x =13m is
6) Three charges Q, +q and +q are placed at the vertices of a right angle triangle (isoscles triangle)
as shown. The net electrostatic energy of the configuration is zero, if Q is equal to :
(A)
(B)
(C) –2q
(D) +q
7) Two rods each of length 6L carry charge Q are placed as shown in figure. Find magnitude of
electric field at point P, which is at a distance of 5L from centre of each rod.
(A)
(B)
(C)
(D)
8) A point charge 25 µC is located in the XY plane at the point of position vector . What
(A)
(B)
(C)
9) The figure below shows the forces that three charged particles exert on each other. Which of the
four situations shown can be correct?
(A) all of these
(B) none of these
(C) II, III
(D) II, III and IV
10) If two electric charges q and –2q are placed at distance 6a apart, then locus of point in the plane
of charges, where electric potential is zero is : (Take charge q at origin and –2q lies on positive x-
axis)
11) In the electrostatic field of a point charge q from point 1 (Figure) we moved one and the same
charge to points 2, 3, 4. Compare the work done on the charge during the each movement in each
case.
12) The maximum electric field intensity on the axis of a uniformly charged ring of charge q and
radius R will be :-
(A)
(B)
(C)
(D)
13) A small charged ball 'q' of mass 'm' is suspended on an insulating string of length ℓ. Another
identical charged ball is slowly moved by a student towards the first one from a large distance.
Eventually, the second ball is placed at the original location of the first one as shown in figure. At
that moment, the first ball is elevated a small distance h above its original position and remains at
rest. Then
cosα =
(A)
(B)
cosα =
(C)
cosα =
cosα =
(D)
14) The charge per unit length of the four quadrant of the ring is and respectively.
The electric field at the centre is:
(A)
(B)
(C)
(D) None
15) A particle is attached at one end of massless rod whose other end is fixed at O as shown in
figure. A particle is given minimum velocity at lower most point to complete vertical circular motion
about O. Find net force on the particle when it is at position P. Length of rod is ℓ. .
(A)
(B)
(C)
16) A constant force F is pushing the block A of mass 5kg which is connected with block B of mass
10 kg by a light spring till the block B will slide. If 0.4 and 0.5 are the coefficient of friction between
A and ground and B and ground respectively. (where k = stiffness of the spring)
(A)
The maximum compression of the spring is equal to
(B) The minimum magnitude of F to move the block B is 45N
(C) The minimum magnitude of F to move the block B is 70N
(D) At maximum compression force F equals force of spring.
17)
In the Figure, the ball A is released from rest when the spring is at its natural length. For the block
B, of mass M to leave contact with the ground at some stage, the minimum mass of A must be :
(A) 2 M
(B) M
(C) M/2
(D) A function of M and the force constant of the spring.
18) The kinetic energy of a particle moving along a circle of radius R depends on the distance
covered S as K.E. = KS2 where K is a constant. Find the force acting on the particle as a function of
S :-
(A)
(B)
(C)
(D)
19) A particle P will be in equilibrium inside a hemispherical bowl of radius 0.5 m at a height 0.2 m
from the bottom when the bowl is rotated at an angular speed of ( g = 10 m/sec2)
(A) 10 / rad/sec
(B) 10 rad/sec
(C) 10 rad/sec
(D) rad/sec
20) A particle A moves along a circle of radius R=50 cm so that its radius vector r relative to the
point O (figure) rotates with the constant angular velocity ω = 0.40 rad/s. Then modulus of the
velocity of the particle, and the modulus of its total acceleration will be
SECTION-II
1) Two point charges q1 = 2µC and q2 = 1µC are placed at distances b = 1 cm and a = 2 cm from the
origin of the y and x axes as shown in figure. The electric field vector at point P(a,b) will subtend an
angle θ with the x-axis given by tanθ = K. Find value of K.
2) Electric potential in a particular region of space is V=12x–3x2y + 2yz2. The magnitude of electric
field at point P (1m, 0, –2m) is found to be x (in N/C). Write value of x/13.
3) Two charge particles of opposite sign and magnitude Q each are projected directly away from
each other with the same speed where r is the initial distance between the
particles. Their masses are m and 2m. Find the maximum distance between them. Express answer in
terms of nr and fill n in OMR sheet.
4) A particle starts moving on a circle with a constant tangential acceleration. At a certain instant
magnitude of radial acceleration of particle is found to be 88 times the magnitude of its tangential
acceleration. Find number of revolutions completed till this instant.
5) A very small ball of mass 'm = 5 kg' is suspended from point A through an inextensible thread of
length ℓ = 4 m. It lies on the surface of a fixed smooth sphere of radius R = 3 m. The ball is moving
in a circular path with a constant speed v = 1 m/s so that it always maintains contact with the
surface of sphere. Find the normal reaction 'N' (in Newton) acting on the ball. Fill in OMR
sheet. (g = 10 m/s2)
CHEMISTRY
SECTION-I
if
the correct reaction between k1, k2 and k3 is :-
(A) k1 = k2 = k3
(B) 2k1 = k2 = 3k2
(C) 4k1 = k2 = 3k2
(D)
(A) 100
(B) 43.44
(C) 150
(D) 140
3) Select the rate law that corresponds to the data shown for the following reaction A + B → C :-
Initial rate
Exp. [A] [B]
(mol L–1.min–1)
4) If half-life of a second order reaction is 1 h. After what time the amount of reactant will become
25% of the initial amount ?
(A) 1.5 h
(B) 2 h
(C) 2.5 h
(D) 3 h
5)
6)
log[conc] are plotted: Among the following, the correct sequence for the order of
the reactions is:
9) The half life period of a radioactive element is 70 days. After 210 days, one gram of the element
will reduce to :-
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
11) N2(g) + 3H2(g) 2NH3(g)
Initially the molar ratio of N2 and H2 was 1 : 3. At equilibrium 50% of each reactant has reacted. If
the equilibrium pressure is P then the partial pressure of NH3 at equilibrium is :-
(A)
(B)
(C)
(D)
12) The vapour density of N2O4 at a certain temperature is 36. What is the percentage dissociation of
N2O4 at this temperature ?
(A) 53.3%
(B) 106.6%
(C) 20.7%
(D) 27.78%
13)
Which of the following is the correct major product ?
(A)
(B)
(C)
(D)
14)
(A)
(B)
(C)
(D)
15)
The electrophile, E⊕ attacks the benzene ring to generate the intermediate σ–complex. Of the
following, which σ–complex is of lowest energy ?
(A)
(B)
(C)
(D)
16) Which of the following compounds will significant amont of meta product during mono-nitration
reaction?
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
(A) o-xylene
(B) p-xylene
(C) both
(D) m-xylene
(A)
(B)
(C)
(D)
20) For the electrophilic substitution reaction involving nitration, which of the following sequence
regarding the rate of reaction is true?
SECTION-II
1)
At which place nitration will mainly take place ?
is expressed as ℓn k =
Calculate activation energy for formation of COCl2(g) from CO(g) and Cl2(g) at same temperature
(Kcal/mol).
4) 10 gram mixture of two gases A2(mol.wt. = 20) and B2 (mol. wt. = 30), which decompose by first
order kinetics, was taken in a vessel. The half life of decomposition of A2 and B2 are 2 and 3 hours
respectively. After 6 hours weight of mixture of A2 and B2 is found to be 2 gram. Find the weight of
A2 in the initial mixture-
5) In a one-litre flask, 6 moles of A undergoes the reaction A(g) ⇌ P(g). The progress of product
formation at two temperatures (in Kelvin), T1 and T2, is shown in the figure:
MATHEMATICS
SECTION-I
(A) A ∪ B ∪ C
(B) A ∪ (B ∩ C)
(C) A ∩ B ∩ C
(D) A ∩ (B ∪ C)
2) If f(x) be a polynomial function satisfying f(x).f = f(x) + f and f(4) = 65 then value of f(6)
is:
(A) 217
(B) 215
(C) 216
(D) 65
3) Range of
(A)
(B)
(C)
(D)
(A) 18
(B) 6
(C) 4
(D) 0
(A) (i),(ii),(iii),(iv),(vii)
(B) (i),(ii),(iv),(v),(vii)
(C) (i),(ii),(iv),(v),(vii),(viii)
(D) (i),(ii),(iii),(v),(vii),(viii)
(A) T1 = 2T2
(B) 2T1 = T2
(C) T1 = T2
(D) T1 = 4T2
7) If ; then range of f(x) = cos[x] is:
(where [.] is G.I.F.)
8)
Suppose for . If is the function whose graph is the reflection of the graph of
f(x) with respect to the line y = x, then g(x) equals
(A)
(B)
(C)
(D)
(A) 23
(B) 4
(C) 80
(D) 8
10) Domain of is -
12)
Let f : R B is defined as which of the following is correct
(A) [1, ]
(B) [1, ∞)
(C) [– , –1] ∪ [1, ]
(D) (–∞,–1] ∪ [1,∞)
2012
14) If 3 f(x) – = 4logex for x > 0; then f(e ) is equal to :-
(A) e2012
(B) 1
(C) 2012
(D) loge(2012)
(A) One-one
(B) Many-one
(C) odd
(D) neither even nor odd
16) If A = {2, 3, 4, 8, 10}, B = {3, 4, 5, 10, 12} & C = {4, 5, 6, 12, 14} then (A ∩ B) ∪ (A ∩ C) equals
:-
17) If f(x) = sin2x + sin2(x + ) + cos x cos(x + ) and g( ) = 1 then graph of y = g(f(x)) is :-
(A) circle
(B) straight line
(C) Parabola
(D) None
18) Period of function ƒ(x)=min{sinx, |x|} + (where [.] denotes greatest integer function) is -
(A) π/2
(B) π
(C) 2π
(D) 4π
(A) One-one
(B) Many-one,
(C) odd
(D) neither even nor odd
20) Let [x] denote the greatest integer less than or equal to x. Then, the values of x ∈ R satisfying
the equation [ex]2 + [ex + 1] – 3 = 0 lie in the interval :
(A)
SECTION-II
1) Given the relation R = {(1, 2), (2, 3)} on the set A = {1, 2, 3}, the minimum number of ordered
pairs which when added to R make it an equivalence relation is 2k. Then the value of k is
is
4)
If A and B are two sets such that A = {1, 2, x}, B = {3, 4, y} and {1, 3} × {2, 4} ⊆ A × B then the
value of x + y is
5) Number of non negative integers in domain of function f(x) = n(7 – 3[x]) is: (where [.] denotes
greatest integer function)
ANSWER KEYS
PHYSICS
SECTION-I
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A B D C B A B C B C C C A C B C C A D
SECTION-II
Q. 21 22 23 24 25
A. 2 1 2 7 5
CHEMISTRY
SECTION-I
Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D D B D D C D C C D A D A B B C A D D C
SECTION-II
Q. 46 47 48 49 50
A. 4 6 3 4 8
MATHEMATICS
SECTION-I
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A D C B C C D B B D B A C B A B C B D
SECTION-II
Q. 71 72 73 74 75
A. 3.50 6 19.00 5.00 3.00
SOLUTIONS
PHYSICS
1)
2)
Net force
electric field due to a long straight wire of charge density λ at one of its end is given by
3)
So Ep =
4)
W=4J
d = 2m
q = 0.2 c
θ = 60°
W = Fdcosθ
⇒
5) E = – = = 5 volt/meter
6)
∴
7)
E due rod.
8)
Position of charge
Position of point
9)
10)
11) Uf = same
W = ΔU ⇒ same work.
12) Emax at
13)
14)
15)
∴ gl = – + 2gℓ
∴ v2 =
Fnet = =
16)
Fx – – µ1m1gx = 0
Kx = µ2 m2g
17)
to leave "M" from ground
kx ≥ Mg
Now
WET
kx = 2mg
⇒ 2mg = Mg
18)
K.E.=kS2
....(i)
Differenciation w.r.t. S
as
FT = 2KS
FC =
Put value of mV2 from eq. (i)
⇒ Fnet
19)
tan θ = ⇒ θ = 37°
N sin θ = mg ⇒ N =
&
N cos θ = m.ω2r
Put value of N from (i)
g cot θ = ω2r
22)
24)
θ = 44 radians
25)
N cos53 + T cos37 = mg ....(i)
CHEMISTRY
26)
Rate of reaction =
or
27) k =
= = (A')2/3 .
On comparison with Arhenius Eq :
Ea = [Ea1+ Ea2–Ea3]
⇒ Ea = [180 + 80 – 50] = 140 kJ
28)
⇒y=2
29)
kt =
k×1=
k×t=
t = 3h
30)
r = K2 × [N2O2] × [H2]
keq =
∴ r = k × [NO]2 × [H2]
31)
K1 = K2
1015e–3000/T = 1014e–1000/T.
10 = e–1000/T + 3000/T
10 = e2000/T
ℓn10 =
T=
= 868.58
34)
3ℓn2 = ℓn
210 = 3
For a first order reaction
35)
a–x b–x
At Eq r f = rb
K1(a – x) = K2(b – x)
K1a – K1x = K2b – K2x
(K2 – K1)x = K2b – K1a
(K2 – K1)x = K2b – K1a
x =
37)
Dt =
n=2
α=
α (in % = 27.78%
39)
40)
41) On direct nitration of aniline meta product is obtained in significant amount (47%).
42)
43)
44)
46) Nitration will take place at 4th position due to +M effect of 2º amine.
47)
48) ln k = ℓn A –
after 6 hr.
X = 4 gram
Y = 6 gram
50)
MATHEMATICS
51)
53)
for
for
for
=
=
Range =
54)
Let S = (A × B) ∩ (B × A)
If (α, β) ∈ S then (α, β) ∈ (A × B) and (α, β) ∈ (B × A)
⇒ α ∈ A and β ∈ B as well as α ∈ B and β ∈ A
⇒ α, β ∈ (A ∩ B)
A ∩ B = {2, 3}
S = {(2,2), (2,3), (3,2), (3,3)}
Number of elements in S is 4.
55)
=3–
⇒ T1 = and T2 =
57)
if
if
if
if
So, that Range =
58)
60)
1 – e(1–x) > 0 and x > 0
⇒ e(1–x) < 1 ⇒ (1 – x) < 0
⇒ x > 1 ⇒ x ∈ (1,∞)
61)
62)
∈ [0, π/4]
f(x) ∈ [1, ]
Now, y = g(f(x)) =
∴ y = 1 Which is a straight line
68)
period 'π'
LCM of 2π & π = 2π
72)
|3 – x| > 0
|3 – x| ≤ 1, x ≠ 3
|x – 3| ≤ 1
–1 ≤ x – 3 ≤ 1
2 ≤ x ≤ 4, x = 2, 4
Sum = 6
73)
= =1
so,
= = 19
74)
{1, 3} × {2, 4} ⊆ A × B
⇒ {(1, 2), (1, 4), (3, 2), (3, 4)} ⊆ {(1, 3), (1, 4), (1, y), (2, 3), (2, 4), (2, y), (x, 3), (x, 4), (x, y)}
⇒ y = 2, x = 3