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GOCDPP-2 NexusCrashCourse

The document is a crash course on General Organic Chemistry for JEE Main 2025, containing a series of questions (Q-1 to Q-22) related to basicity and acidity of various compounds. Each question provides multiple-choice answers, followed by an answer key and solutions explaining the reasoning behind the correct answers. The content focuses on understanding the concepts of acidity, basicity, and the effects of different functional groups on these properties.

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5 views17 pages

GOCDPP-2 NexusCrashCourse

The document is a crash course on General Organic Chemistry for JEE Main 2025, containing a series of questions (Q-1 to Q-22) related to basicity and acidity of various compounds. Each question provides multiple-choice answers, followed by an answer key and solutions explaining the reasoning behind the correct answers. The content focuses on understanding the concepts of acidity, basicity, and the effects of different functional groups on these properties.

Uploaded by

mpghorse15
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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NEXUS CRASH COURSE

JEE MAIN 2025

General Organic Chemistry

DPP-2
Q-1: The strongest base is :
(a)

(b)

(c)

(d)

Q-2:

The correct order of decreasing basicity of the above compounds is :


(a) I > II > III > IV
(b) II > I > IV > III
(c) III > IV > II > I
(d) II > I > III > IV

Q-3: Give the correct order of increasing acidity of the following compounds.

(a) II < I < IV < III


(b) IV < II < I < III
(c) I < II < IV < III
(d) IV < I < II < III
Q-4: Write the order of basic strength :

(a) Q > R > S > P


(b) P > R > Q > S
(c) R > P > S > Q
(d) P > Q > R > S

Q-5: Which of the following has the most acidic hydrogen?

(a)

(b)

(c)

(d)

Q-6: The decreasing order of acidity of the following phenol derivatives is

(a) S > P > Q > R (b) R > S > P > Q


(c) S > Q > P > R (d) P > Q > R > S
Q-7: The decreasing order acidity of following benzoic acid derivatives is

(a) P > Q > R > S


(b) Q > P > S > R
(c) S > R > Q > P
(d) R > S > P > Q

Q-8: Arrange the following in decreasing acidic strength.

(a) A>B>C>D
(b) B>A>C>D
(c) D>C>A>B
(d) D>C>B>A

Q-9: Which of the following σ -bonds participate in hyperconjugation ?

(a) I and II
(b) I and V
(c) II and V
(d) III and IV
Q-10: Correct basic strength order is :

(a) r > q > p > s


(b) r > p > q > s
(c) q > r > p > s
(d) r > q > s > p

Q-11: The increasing basicity order of the following compounds is

(a) (D) < (C) < (B) < (A)


(b) (A) < (B) < (C) < (D)
(c) (A) < (B) < (D) < (C)
(d) (D) < (C) < (A) < (B)

Q-12: For the series of bases shown below, the correct order of basicity from
strongest to weakest :

(a) d > b > c > a


(b) b > d > c > a
(c) d > b > a > c
(d) a > b > c > d
Q-13: Which of the following compounds would you expect to be strongest
carbon acid ?

(a)

(b) CH2(CO2 Et)2

(c)

(d) CH3COCH2COOC2H5

Q-14: In sets a – d, only one of the set is incorrect regarding basic strength.
Select it :

(a)

(b)

(c)

(d)
Q-15:

Identify most acidic hydrogen in given compound.


(a) a
(b) b
(c) c
(d) d

Q-16: Consider the hydrogen atoms attached to three different carbon


atoms (labeled 1, 2 & 3). Rank the attached hydrogen atoms in order from
most acidic to least acidic.

(a) 2>1>3
(b) 1>2>3
(c) 2>3>1
(d) 3>2>1

Q-17: Arrange the following in increasing order of their pKa values.

(a) y<x<z
(b) x<y<z
(c) y<z<x
(d) x<z<y
Q-18:

Decreasing order of acidic strength of different (–OH) groups is :


(a) w>x>y>z
(b) w>z>x>y
(c) z>w>x>y
(d) z>x>w>y

Q-19: Among the following compounds, the most basic compound is :

(a)

(b)

(c)

(d)
Q-20: Rank the following compounds in order of decreasing acid strength
(most acidic → least acidic) .

(a) 2 > 4 > 1 > 3


(b) 1 > 3 > 4 > 2
(c) 3 > 1 > 2 > 4
(d) 3 > 1 > 4 > 2

Q-21: Order of basic strength:

(a) A>B>C>D
(b) B>A>C>D
(c) C>B>A>D
(d) C>B>D>A

Q-22:

Compare basic strengths of the above compounds:


(a) A>B>C
(b) B>A>C
(c) C>A>B
(d) C>B>A
Answer Key

1 2 3 4 5 6 7 8 9 10 11

(b) (b) (b) (b) (d) (c) (a) (a) (b) (b) (d)

12 13 14 15 16 17 18 19 20 21 22

(a) (d) (c) (a) (a) (b) (a) (d) (d) (c) (c)
Solutions
Solution -1 :

Guanidine is highly stabilise after accepting H⊕, so it is most basic amine.

Solution -2 :
+M groups increases basicity while —M decreases basicity.

Solution -3 :
Carboxyllic acids are more acidic than phenol and alcohols.

Solution -4:
S is least basic as it is aromatic and lp is delocalised P is most basic as it is
aliphatic amine.
Solution -5:

Solution -6:
-M and -I groups will increase acidity while +M and +I groups will decrease.

Solution -7:
Withdrawing group will increase acidity while donating groups will decrease
acidity.

Solution -8 :
The correct order of acid strength is

Solution -9 :
α ‘H’ atoms w.r.t. C = C bond take part in hyperconjugation.
Solution -10 :

Solution -11 :
pKb values
(A) EtNH2 3.29
(B) (Et2)NH 3.00
(C) Me3N 4.22
(D) Ph - NH- Me 4.7
So, order of basic strength
(B) > (A) > (C) > (D)

Solution -12 :
Solution -13:

Solution -14 :

Solution -15 :

is the most acidic ‘H’ because the resulting anion has


2-equivalent R.S.
Solution -16 :

Solution -17 :
Stability order is

So Acidic strength order is x > y > z


So pKa is z > y > x.

Solution -18:
Solution -19 :

Solution -20 :

Solution -21 :
Solution -22 :

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