EXERCISE-01 CHECK YOUR GRASP

SELECT THE CORRECT ALTERNATIVE (ONLY ONE CORRECT ANSWER)

1. 
In a reaction PCl5   PCl3 + Cl2 degree of dissociation is 30%. If initial moles of PCl5 is one then total
moles at equilibrium is
(A) 1.3 (B) 0.7 (C) 1.6 (D) 1.0
2.  
For reaction HI  ! ½ H2 + ½ I2 value of Kc is 1/8 then value of Kc for H2 + I2   2HI.
1 1
(A) (B) 64 (C) (D) 8
64 8
3. 
In a equilibrium reaction H2(g) + I2(g)  2HI(g)
H = – 3000 calories,
which factor favours dissociation of HI :-
(A) Low temp. (B) High Pressure (C) High temp. (D) Low pressure.
4. 
N2 + 3H2   2NH3
If temp. of following equilibrium reaction increase then -
(A) Shift Right side (B) Shift left side (C) Unchanged (D) Nothing say.
5. 
C(s) + H2O (g)   H2(g) + CO(g)
by increasing pressure following equilibrium
(A) Unaffected (B) Proceed in backward direction
(C) Proceed in forward direction (D) Unfixed
6. Unit of equilibrium constant Kc for following homogenous reaction :-
4NH + 5O   4NO + 6H O is
3 2 2

(A) (Conc n) -1 (B) (Conc n) +1 (C) (Conc n) +10 (D) Have no unit
7. 
Which of the following factor shifted the reaction PCl3 + Cl2   PCl5 at left side.
(A) Adding PCl5 (B) Increase pressure (C) Constant temp. (D) Catalyst.
8. In which of the following process reaction is fastest complete.
(A) K = 10 (B) K = 1 (C) K = 103 (D) K = 10–2
9. At 298 K equilibrium constant K1 and K2 of
following reaction SO2 (g) + ½ 
O2(g)  SO3(g) ----- (1)

2SO3(g)   2SO2(g) + O2(g) -------- (2)
The relation between K1 and K2 is
(A) K1 = K2 (B) K2 = K12 (C) K2 = 1/K12 (D) K2 = 1/K 1
10. 
In the following reaction PCl5 (g)  PCl3(g) + Cl2(g) at constant temp. rate of backward reaction is increase by :
(A) Inert gas mixed at constant volume (B) Cl2 gas mixed at constant volume
(C) Inert gas mixed at constant pressure (D) PCl5 mixed in constant volume.
11. Some gaseous equilibrium are following :

K

CO + H2O  CO2 + H2

K1

2CO + O2  2CO2

K2

2H 2+ O 2   2H 2O
then find out the relation between equilibrium constants :-
(A) K = K1K2 (B) K = (K 1K2)2 (C) K = (K1K2)–½ (D) K = (K1/K2)½
12. 
For the equilibrium process x + y  n
 xy. If the conc . of x and y is doubled, then equilibrium constant.
(A) Become twice (B) Become half (C) Unchanged (D) Become thrice
13. Two moles of PCl 5 were heated in closed vessel of 2 litre capacity, at equilibrium 40% of PCl 5 was
dissociated into PCl3 and Cl2. The value of equilibrium constant is :
(A) .267 (B) .53 (C) 2.67 (D) 5.3
14. 
The reaction A(g) + B(g)   2C(g) is occur by mixing of 3 moles of A and 1 mole of B in one litre
1
Container. if  of B is , then KC for this reaction is :-
3
(A) 0.12 (B) 0.25 (C) 0.50 (D) 0.75
15. 
Reaction 2BaO 2(s)  2BaO(s) + O 2 (g) ;  H = + ve. At equilibrium condition, Pressure of O2 is
depends on :-
(A) Increase mass of BaO2 (B) Increase mass of BaO
m
(C) Increase temp. at Eq . (D) Increase mass of BaO 2 and BaO both
16. 
Consider the following equilibrium in a closed container N2O 4 (g)   2NO2 (g). At a fixed temperature,
the volume of the reaction container is halved. For this change, which of the following statements held true
regarding the equilibrium constant (K p) and degree of dissociation () :-
(A) Neither Kp nor  changes (B) Both Kp and - changes
(C) Kp changes, but  does not change (D) Kp does not change, but  - changes
17. 
C(s) + CO2(g)  2CO(g)
According to above reaction, partial Pressure of CO2 & CO are 4 & 8 respectively then find out Kp of the
above reaction :-
(A) 6 (B) 2 (C) 16 (D) 32
18. 
For the reaction, A+B  C + D, Kc = 9. If A and B are taken in equal amounts, then amount of C at
equilibrium is :-

(A) 1 (B) 0.25 (C) 0.75 (D) None of these

19. At equilibrium 500mL vessel contains 1·5 M of each A, B, C, D. If 0·5M of C and D expelled out
then what would b e the K C :-
1 4 5
(A) 1 (B) (C) (D)
9 9 9
20. The following equilibrium are given

N2 + 3H2  2NH3 -------------- K1

N2 + O2  2NO -------------- K2
1
H2 + O  H O -------------- K3
2 2  2
The equilibrium constant of the reaction
5
2NH3 + 
O  2NO + 3 H2O, in terms of K1, K2 and K3 is :
2 2
K1K 2 K 1 K 23 K 2 K 33
(A) K3 (B) (C) (D) K 1K 2K 3
K2 K1

21. 
The reaction A + B   C + D is studied in a one litre vessel at 250°C. The initial concentration of
A was 3n and that of B was n. When equilibrium was attained, equilibrium concentration of C was found
to the equal to the equilibrium concentration of B. What is the concentration of D at equilibrium :
(A) n/2 (B) (3n – 1/2) (C) (n – n/3) (D) n
 k
22. 
In a reversible reaction A 
1

 B , the initial concentration of A and B are a and b in moles per litre and
k 2

the equilibrium concentration are (a – x) and (b + x) respectively ; express x in terms of k1, k 2, a and b :
k1a  k 2 b k1a  k 2 b k1a  k 2 b k1a  k 2 b
(A) k1  k 2 (B) k1  k 2 (C) k1k 2 (D) k1  k 2
23. The value of K p for the reaction

2H 2 O (g) + 2Cl 2O (g)  4HCl (g) + O 2 (g)
is 0.03 atm at 427°C, when the partial pressure are expressed in atmosphere then the value of K C for
the same reaction is :
(A) 5.23 × 10 –4 (B) 7.34 × 10 –4 (C) 3.2 × 10 –3 (D) 5.43 × 10 –5
1
24. The equilibrium constant of the reaction SO2 (g) + 
O (g)  –3 –1/2
 SO3 (g) is 4 × 10 atm . The equilibrium
2 2

constant of the reaction 2 SO 3 (g)  2 SO 2 (g) + O 2 (g) would be :
(A) 250 atm (B) 4 × 10 3 atm (C) 0.25 × 10 4 atm (D) 6.25 × 10 4 atm
25. When alcohol (C 2H5OH) and acetic acid are mixed together in equimolar ratio at 27°C, 33% is converted
into ester. Then the K C for the equilibrium :

C 2 H 5 OH () + CH 3 COOH ()  CH 3COOC 2H 2 () + H 2 O ()
(A) 4 (B) 1/4 (C) 9 (D) 1/9
26. 
2 moles each of SO3, CO, SO2 and CO2 is taken in a one lit. vessel. If KC for SO3 + CO  SO2 + CO2
is 1/9 then :
(A) total no. of moles at equilibrium are less than 8
(B) n (SO 3 ) + n(CO 2 ) = 4
(C) [n(SO 2 )/n (CO)] < 1
(D) both (B) and (C)
27. An equilibrium mixture in a vessel of capacity 100 litre contain 1 mol N2, 2 mol O 2 and 3 mol NO. No.
of moles of O 2 to be added so that at new equilibrium the conc. of NO is found to be 0.04 mol/lit :
(A) (101/18) (B) (101/9) (C) (202/9) (D) None of these
28. Ammonia gas at 15 atm is introduced in a rigid vessel at 300 K. At equilibrium the total pressure of the
vessel is found to be 40.11 atm at 300 C. The degree of dissociation of NH 3 will be :
(A) 0.6 (B) 0.4 (C) unpredictable (D) none of these
29. The degree of dissociation of SO 3 is  at equilibrium pressure P 0 :

Kp for 2SO 3 (g)   2SO 2 (g) + O 2 (g)
(A) [(P 0 )/2(1 – ) ]
3 3
(B) [(P 03)/(2 + )(1–) 2 ] (C) [(P 02)/2(1 – ) 2] (D) none of these
30. 
For the reaction CO(g) + H 2O (g)  CO 2 (g) + H 2 (g) at a given temperature the equilibrium amount
of CO 2 (g) can be increased by :
(A) adding a suitable catalyst (B) adding an inert gas
(C) decreasing the volume of container (D) increasing the amount of CO (g)
31. For the reaction :
PCl 5 (g)  PCl 3 (g) + Cl 2 (g)
The forward reaction at constant temperature is favoured by
(A) introducing an inert gas at constant volume (B) introducing chlorine gas at constant volume
(C) introducing an inert gas at constant pressure (D) increasing the volume of the container
(E) introducing PCl 5 at constant volume