d80 Msds

Download as pdf or txt
Download as pdf or txt
You are on page 1of 10

Product Name: EXXSOL D80 FLUID

Revision Date: 21Dec2006


Page 1 of 10 ______________________________________________________________________________________________________________________

MATERIAL SAFETY DATA SHEET


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: EXXSOL D80 FLUID Product Description: Dearomatized Hydrocarbons Product Code: Intended Use: Solvent COMPANY IDENTIFICATION Supplier:

EXXONMOBIL CHEMICAL COMPANY P.O. BOX 3272 HOUSTON, TX. 77253-3272 USA 24 Hour Health Emergency (800) 726-2015 Transportation Emergency Phone (800) 424-9300 CHEMTREC Product Technical Information (281) 870-6000/Health & Medical (281) 870-6884 Supplier General Contact (281) 870-6000

SECTION 2

COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS#


DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8

Concentration*
100%

* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION

This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). POTENTIAL PHYSICAL / CHEMICAL EFFECTS Combustible. Material can release vapors that readily form flammable mixtures. Vapor accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an incendiary electrical discharge. POTENTIAL HEALTH EFFECTS Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs.

NFPA Hazard ID: HMIS Hazard ID:

Health: Health:

1 1

Flammability: 2 Flammability: 2

Reactivity: 0 Reactivity: 0

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES

Product Name: EXXSOL D80 FLUID


Revision Date: 21Dec2006
Page 2 of 10 ______________________________________________________________________________________________________________________

INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.

SECTION 5

FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Combustible. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Oxides of carbon, Incomplete combustion products, Smoke, Fume FLAMMABILITY PROPERTIES Flash Point [Method]: >77C (171F) [ ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.6 Autoignition Temperature: 251C (484F) [Approximate ] SECTION 6

UEL: 5.0

ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. U.S. regulations require reporting releases of this material to the environment which exceed the reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National

Product Name: EXXSOL D80 FLUID


Revision Date: 21Dec2006
Page 3 of 10 ______________________________________________________________________________________________________________________

Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required due to toxicity or flammability of the material. See Section 5 for fire fighting information. See Section 3 for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for Personal Protective Equipment. SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do it without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapor; but may not prevent ignition in closed spaces. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.

SECTION 7

HANDLING AND STORAGE

HANDLING Avoid contact with skin. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Loading/Unloading Temperature: Transport Temperature: [Ambient ]

[Ambient ]

Static Accumulator: This material is a static accumulator. STORAGE Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be grounded and bonded. Drums must be grounded and bonded and equipped with self-closing valves, pressure vacuum bungs and flame arresters. Storage Temperature: [Ambient ] Storage Pressure: [Ambient ] Suitable Containers/Packing: Barges; Drums; Tank Cars; Tank Trucks Suitable Materials and Coatings: Carbon Steel; Stainless Steel; Polyethylene; Polypropylene; Teflon Unsuitable Materials and Coatings: Natural Rubber; Butyl Rubber; Ethylene-proplyene-diene monomer

Product Name: EXXSOL D80 FLUID


Revision Date: 21Dec2006
Page 4 of 10 ______________________________________________________________________________________________________________________

(EPDM); Polystyrene SECTION 8 EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive) EXPOSURE CONTROLS / PERSONAL PROTECTION

Source DISTILLATES (PETROLEUM), HYDROTREATED LIGHT

Form Vapor.

Limit / Standard RCP 1200 TWA mg/m3

165 ppm

Note Source Total ExxonMobil Hydrocarbons

NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosionproof ventilation equipment. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: Half-face filter respirator For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly effect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: If prolonged or repeated contact is likely, chemical resistant gloves are recommended. If contact with forearms is likely, wear gauntlet style gloves. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended.

Product Name: EXXSOL D80 FLUID


Revision Date: 21Dec2006
Page 5 of 10 ______________________________________________________________________________________________________________________

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATION Physical State: Liquid Form: Clear Color: Colorless Odor: Mild Petroleum/Solvent Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15.6 C ): 0.798 Density: 798 kg/m (6.66 lbs/gal, 0.8 kg/dm) Flash Point [Method]: >77C (171F) [ ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 5.0 Autoignition Temperature: 251C (484F) [Approximate ] Boiling Point / Range: 200C (392F) - 250C (482F) Vapor Density (Air = 1): 6.2 at 101 kPa Vapor Pressure: 0.023 kPa (0.17 mm Hg) at 20 C Evaporation Rate (n-butyl acetate = 1): 0.1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 1.68 cSt (1.68 mm2/sec ) at 40 C | 2.16 cSt (2.16 mm2/sec) at 25C Oxidizing Properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D Pour Point: -39C (-39F) Molecular Weight: 171 [Calculated ] Hygroscopic: No Coefficient of Thermal Expansion: 0.00074 V/VDEGC SECTION 10 STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.

Product Name: EXXSOL D80 FLUID


Revision Date: 21Dec2006
Page 6 of 10 ______________________________________________________________________________________________________________________

MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 ACUTE TOXICITY Route of Exposure
Inhalation Toxicity: Data available. Irritation: Data available.

TOXICOLOGICAL INFORMATION

Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on test data for structurally similar materials.

Ingestion Toxicity: LD50 > 15000 mg/kg

Minimally Toxic. Based on test data for structurally similar materials.

Skin Toxicity: LD50 > 3160 mg/kg Irritation: Data available.

Minimally Toxic. Based on test data for structurally similar materials. Mildly irritating to skin with prolonged exposure. Based on test data for structurally similar materials.

Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.

CHRONIC/OTHER EFFECTS For the product itself: Vapor/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects including death. Prolonged and/or repeated skin contact with low viscosity materials may defat the skin resulting in possible irritation and dermatitis. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema.

Additional information is available by request. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-3 = IARC 1 5 = IARC 2B 4 = IARC 2A 6 = OSHA CARC

1 = NTP CARC 2 = NTP SUS

SECTION 12

ECOLOGICAL INFORMATION

Product Name: EXXSOL D80 FLUID


Revision Date: 21Dec2006
Page 7 of 10 ______________________________________________________________________________________________________________________

The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. Material -- Not expected to demonstrate chronic toxicity to aquatic organisms. PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be readily biodegradable. Hydrolysis: Material -- Transformation due to hydrolysis not expected to be significant. Photolysis: Material -- Transformation due to photolysis not expected to be significant. Atmospheric Oxidation: Material -- Expected to degrade rapidly in air OTHER ECOLOGICAL INFORMATION VOC (EPA Method 24): 6.659 lbs/gal SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning PRECAUTIONARY LABEL TEXT: Empty containers may retain residue and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. SECTION 14 TRANSPORT INFORMATION

LAND (DOT) Proper Shipping Name: PETROLEUM DISTILLATES, N.O.S. Hazard Class & Division: COMBUSTIBLE LIQUID ID Number: 1268 Packing Group: III

Product Name: EXXSOL D80 FLUID


Revision Date: 21Dec2006
Page 8 of 10 ______________________________________________________________________________________________________________________

ERG Number: 128 Label(s): NONE Transport Document Name:

PETROLEUM DISTILLATES, N.O.S., COMBUSTIBLE LIQUID, UN1268, PG III

Footnote: This material is not regulated under 49 CFR in a container of 119 gallon capacity or less when transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically listed as a hazardous substance. LAND (TDG) : Not Regulated for Land Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport

SECTION 15

REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purpose, this material is classified as hazardous in accordance with OSHA 29CFR 1910.1200. NATIONAL CHEMICAL INVENTORY LISTING: AICS, DSL, EINECS, ENCS, KECI, PICCS, TSCA

EPCRA: This material contains no extremely hazardous substances.

SARA (311/312) REPORTABLE HAZARD CATEGORIES: Fire. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The Following Ingredients are Cited on the Lists Below:* None. --REGULATORY LISTS SEARCHED-6 = TSCA 5a2 11 = CA P65 REPRO 7 = TSCA 5e 12 = CA RTK 8 = TSCA 6 13 = IL RTK 9 = TSCA 12b 14 = LA RTK 10 = CA P65 CARC 15 = MI 293

1 = ACGIH ALL 2 = ACGIH A1 3 = ACGIH A2 4 = OSHA Z 5 = TSCA 4

16 = MN RTK 17 = NJ RTK 18 = PA RTK 19 = RI RTK

Code key: CARC=Carcinogen; REPRO=Reproductive * EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to confirm whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list. SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:

Product Name: EXXSOL D80 FLUID


Revision Date: 21Dec2006
Page 9 of 10 ______________________________________________________________________________________________________________________

Revision Changes: Not Applicable ----------------------------------------------------------------------------------------------------------------------------------------------------PRECAUTIONARY LABEL TEXT: Contains: DISTILLATES (PETROLEUM), HYDROTREATED LIGHT CAUTION! HEALTH HAZARDS Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated and cause lung damage. PHYSICAL HAZARDS Combustible. Material can accumulate static charges which may cause an incendiary electrical discharge. PRECAUTIONS Avoid contact with skin. Use proper bonding and/or grounding procedures. FIRST AID Inhalation: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do it without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Report spills as required to appropriate authorities. Seek the advice of a specialist before using dispersants. ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. -----------------------------------------------------------------------------------------------------------------------------------------------------

Product Name: EXXSOL D80 FLUID


Revision Date: 21Dec2006
Page 10 of 10 ______________________________________________________________________________________________________________________

Internal Use Only MHC: 1A, 0, 0, 0, 2, 0 DGN: 4400220HUS (1007664) ----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Exxon Mobil Corporation, All rights reserved

You might also like