TAKSHSHILA SCIENCE INSTITUTE

Unit 2 Std 11 : Chemistry Date : 15/07/24

Total Marks : MCQ Time : 0:00 Hour
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [100]

1. The hydrogen electron de-exites from its 3rd excited state. Which are true and false statements for
it. Assign T for true and F for the false.
(i) It emits the radiation giving the lines in the Lyman Balmer and Paschen series.
(ii) It emits radiation of only UV and visible regions and not infrared region.
(iii) It emits the radiation of smallest wavelength giving the line in Lyman series.
(iv) It will emit the radiation of the highest frequency giving line in Pfund series
(A) TFTF (B) FTFT (C) TTFF (D) FFTT
2. How many elements are there having electrons in d-orbital among the elements with atomic number
1 to 100 ?
(A) 30 (B) 60 (C) 80 (D) 20
3.

4.
(A) 10 : 1017 (B) 1 : 1017
SIR
The relative is .......... proportion of the atoms of tritium and protium.
(C) 10 : 107 (D) 1 × 107
X and Y both are moving particles. The uncertainty in measure of momentum of Y is half than that
of X. If uncertainity of position of X is ± 0.05Å than that of Y is .....
(A) 2.5 × 10–10 cm (B) 1 × 10–10 cm (C) 5 × 10–10 cm (D) 1 × 10–9 cm
A species ‘X’ contains 20 protons and 18 electrons.
K
5.
(A) species ‘Y’ contains 18 protons and 18 electrons. What are ‘X’ and ‘Y’ respectively ?
(A) Ca and Ar (B) Ca2+ and S2– (C) Ca2+ and Cl– (D) Ca2+ and Ar
LA

6. Which element has ns2np5 type electronic configuration in its outermost shell ?
(A) Carbon (B) Chlorine (C) Neon (D) Aluminium
7. The correct relationship between quantum numbers n, l and m is :
(B) n > l £ m (C) n > l ³ m (D) n ³ l > m
ZA

(A) n > l > m

The decrease in number of neutrons when X YPb
8. a U changes the b is represented as :
(A) (x – a) + (y + b) (B) (x – a) – (y + b) (C) (x + a) – (y + b) (D) (x – a) – (y – b)
9. In long form of periodic table, an element has electronic configuration 1s2 2s22p63s23p3 Thus what
will be the atomic no. of element ? Which is just below this element in its group ?
(A) 23 (B) 16 (C) 47 (D) 33
10. For the third electron of Lithium atom moving in its premissible orbit, the values of angular
momentum and energy are ....... respectively.
h – 9p 2e4 m 3h +3p 2 me4
(A) Angular momentum , energy = (B) Angular momentum , energy =
2p 2h 2 2p 4h 2
h 3p 2me 4 h – 6p 2e 4m
(C) Angular momentum , energy = (D) Angular momentum , energy =
2p 2h 2 2p 3h 2
11. Match the species of Column - X with the electron configuration of the elements in the Column -
Y and select correct answer.

Column – X Column – Y
(i) 22 Ti2+ (P) (n–1) d4ns2
(ii) 30 Zn (Q) (n – 1) d10 ns1
(iii) 24Cr
Zalak
(R) (n – 1) sir0[MO.9727916425]
d2 ns
(iv) 29Cu (S) (n – 1) d5 ns1
(M) (n – 1) d10 ns2
 Match the species of Column - X with the electron configuration of the elements in the Column -
Y and select correct answer.

Column – X Column – Y
(i) 22 Ti2+ (P) (n–1) d4ns2
(ii) 30 Zn (Q) (n – 1) d10 ns1
(iii) 24Cr (R) (n – 1) d2 ns0
(iv) 29Cu (S) (n – 1) d5 ns1
(M) (n – 1) d10 ns2
(N) (n – 1) d10 ns2

(A) (i) ® M; (ii) ® N; (iii) ® P; (iv) ® Q (B) (i) ® R; (ii) ® N; (iii) ® P; (iv) ® S
(C) (i) ® M; (ii) ® Q; (iii) ® S; (iv) ® R (D) (i) ® R; (ii) ® N; (iii) ® S; (iv) ® Q
12. The introduction of neutron in nucleus of an atom would lead to the change in ........ .
(A) Atomic weight (B) Atomic number
(C) Number of electrons around a nucleus (D) Chemical nature of the atom
13. If there are 13 electrons in M shell and 1 electron in N shell then the number of unpaired electrons
in such atom will be.....
(A) 5 (B) 4 (C) 3 (D) 6
14. Which element of the following possesses half filled valence shell with electron ?

15.
(A) C

shell are .......... .

(A) 7
(B) O

(B) 15
SIR (C) Ne

(C) 14
(D) N
The number of protons in nucleus of an element having maximum unpaired electrons in 2p sub-

(D) 6
16. How many orbitals are associated with n = 4 ?
K
(A) 16 (B) 15 (C) 8 (D) 18
17. What is wavelength of wave associated with electron whose velocity (v) is 108 cm sec–1 ?
LA

(mass of electron = 9.1 ´ 10–31 kg)

(A) 7.27 nm (B) 7.27 ´ 10–8 m (C) 7.27 ´ 10–10 m (D) 7.27 ´ 10–10 Å
18. The product of frequency of light and wavelength is equal to.....
(A) Redberg’s constant (B) Plank’s constant (C) Energy of photon (D) Velocity of light
ZA

19. From the following which pair is isotone and isobar respectively.
(i) 14 14 12 14
6C , 7N (ii) 6C , 6N
(iii) 6C14, 7N15 (iv) 13
6C , 7N
15

(A) (iii) and (i) (B) (i) and (ii) (C) (i) and (iii) (D) (iii) and (iv)
20. The correct electronic configuration of 29Cu2+ is
(A) [Ar] 4s1 3d10 (B) [Ar] 4s2 3d8 (C) [Ar] 4s2 3d9 (D) [Ar] 4s0 3d9
21. Which of the following is the correct formula for one mole of photon energy ?
Nh hc Nhc Nc
(A) (B) (C) (D)
lc l l l
22. How many number of proton, electron and neutron in 55Mn+2 respectively ?
(A) 25, 27, 30 (B) 25, 25, 30 (C) 25, 23, 30 (D) 25, 27, 26
23. Which of the following electronic configuration is not possible ?
(A) 3d2 (B) 2p2 (C) 3f2 (D) 4s2
24. Which of the following represents the correct set of four quantum numbers of 3d orbital electron ?
1
(A) n = 3, l = 3, m = 2, s = + (B) n = 3, l = 2, m = 2, s = 0
2
1
(C) n = 3, l = 2, m = 1, s = + Zalak sir [MO.9727916425]
(D) n = 4, l = 2, m = 2, s = 0
2
 Which of the following represents the correct set of four quantum numbers of 3d orbital electron ?
1
(A) n = 3, l = 3, m = 2, s = + (B) n = 3, l = 2, m = 2, s = 0
2
1
(C) n = 3, l = 2, m = 1, s = + (D) n = 4, l = 2, m = 2, s = 0
2
25. What are the possible values of l when n = 4 ?
(A) 0, 1, 2, 3 (B) 1, 2, 3, 4 (C) 0, 1, 2, 3, 4 (D) 4, 0, 2, 3
26. Spin multiplicity value of oxygen element is
(A) 2 (B) 1.5 (C) 1 (D) 4
32 2 –
27. Give number of protons, neutrons and electrons respectively in 16 S
.
(A) 16, 16, 16 (B) 16, 14, 16 (C) 16, 16, 14 (D) 16, 16, 18
28. According to De-Brogli’s principal, what is the relation between momentum and wavelength of
movable particals ?
(A) Inverse proportion (B) Underroot proportion(C) Same proportion (D) None of these
29. Electron configuration of Molybdenum (Z = 42) is .......... .
(A) [Kr] 4d4 5s2 (B) [Kr] 5s2 5p4 (C) [Kr] 4d5 5s1 (D) [Kr] 4d3 5s2 sp1
30. Give actual proportion (ratio) of photon energy having wavelength of 3000Å and 6000Å respectively.

31.

32.
(A) 2 : 1

(A) photoelectric effect

(B) 1 : 3

(B) Zeeman effect SIR (C) 3 : 1

(C) diffraction
(D) 1 : 2
The splitting of the spectral lines under the influence of magnetic field is called....
(D) interference

In an atom an electron is moving with a speed of 600 ms–1 with an accuracy of 0.005 % certainty
with which the position of the electron can be located is....
(A) 5.10 ´ 10–3 m (B) 3.84 ´ 10–3 m (C) 1.92 ´ 10–3 m (D) 1.52 ´ 10–4 m
K
33. How many ‘nodes’ are there in 3s orbital ?
(A) 3 (B) 2 (C) 1 (D) Zero
LA

34. In Schrodinger’s wave equation V indicates

(A) wave function (B) total enthalpy of electron and proton
(C) velocity of electrone (D) potential energy
ZA

35. Identify the possible set of quantum numbers for outer shell electron in element K.
1 1
(A) n = 4, l = 0, m = 0, s = ± (B) n = 4, l = 1, m = 1, s = ±
2 2
1 1
(C) n = 3, l = 2, m = –1, s = ± (D) n = 3, l = 0, m = 0, s = ±
2 2
36. Bohr’s atomic model could explain the spectrum of .......... .
(A) Atoms or ions which have two electrons.
(B) Only dihydrogen molecule.
(C) He– atom only.
(D) Atoms or ions which contain only one electron.
37. How many electrons in an atom with atomic number 50 can have (n + l) = 5 ?
(A) 10 (B) 12 (C) 18 (D) 25
38. The associate wavelength of a particle with mass 1 gram and velocity 100 m/s is ..........
[h = 6.626 × 1034 Js]
(A) 6.63 × 10–35 m (B) 6.63 × 10–36 m (C) 6.626 × 10–33 m (D) 6.626 × 10–34 m
39. Two electrons of K-shell can be distinguished by
(A) spin quantum number. (B) azimuthal quantum number.
(C) principal quantum number (D) magnetic quantum number
Zalak sir [MO.9727916425]
 Two electrons of K-shell can be distinguished by
(A) spin quantum number. (B) azimuthal quantum number.
(C) principal quantum number (D) magnetic quantum number
40. Which of the following set of quantum numbers of an electron will have the highest energy ?

n l m s
1
(A) 4 2 – 1 –
2
1
(B) 3 2 1 –
2
1
(C) 5 0 0 –
2
1
(D) 4 1 0 –
2

41. When electron enters into the orbital of equal energy subshells, they are arranged in such a way that
the direction of their spins remain parallel or the value of spin quantum number remains maximum.
This statement is known as..
(A) Hund’s rule (B) Heisenberg’s principle
(C) Pauli’s Exclusion principle (D) Auf-bau rule

42. Assertion : The relative proportion of atoms of Tritium and Protium is 1 : 1017
Reason
(A) Assertion is false but reason is true
(B) Assertion is true but reason is false
(C) Both assertion and reason are true
SIR
: The property responsible for the low proportion of Tritium is its non-radioactivity.

(D) Both assertion and reason are true and reason is the correct explanation of the assertion.
K
43. Number of electrons present in P–3 ion having 15 protons are .......
(A) 15 (B) 16 (C) 18 (D) 12
LA

44. Number of total electrons in an orbit of –angular Momentum Quantum Number (l) is .........
(A) l2 (B) 4l + 2 (C) 2l + 1 (D) 2l + 2
45. Number of unpaired electron(s) present in an element having atomic number Z = 24 is ....... .
(A) 6 (B) 4 (C) 0 (D) 5
ZA

46. The correct set of four quantum number for the unpaired electron of the element Z = 21 is
1 1
(A) n = 3, l = 2, m = 1, s = + (B) n = 3, l = 1, m = 0, s = +
2 2
1 1
(C) n = 3, l = 3, m = 2, s = + (D) n = 4, l = 0, m = 0, s = +
2 2
47. What is frequency of first line of Balmer series for H-atom ?
[RH = 2.18 × 10–18J; h = 6.626 × 10–34Js]
(A) 3.29 × 1015 s–1 (B) 8.05 × 1013 s–1 (C) 8.22 × 1015 s–1 (D) 4.57 × 1014 s–1
48. If kinetic energy of an electron is increased by nine times, the wavelength associated with it would
become ......... .
1 1
(A) times (B) times (C) 9 times (D) 3 times
3 9
49. Which of the following electronic configuration is not possible ?
(A) 4d8 (B) 3f14 (C) 3s1 (D) 2p6
50. What is shape of the orbital having l = 1 and m = 0 ?
(A) Triangular planar (B) Dumbbell (C) Square planar (D) Spherical
51. Which of the following series of lines in the atomic spectrum of hydrogen appear in the visible
region ?
Zalak sir [MO.9727916425]
(A) Paschen (B) Balmer (C) Brackett (D) Lyman
 Which of the following series of lines in the atomic spectrum of hydrogen appear in the visible
region ?
(A) Paschen (B) Balmer (C) Brackett (D) Lyman

52. The energy of one mole of photon having frequency 4 ´ 1014 Hz is

(A) 129 kJ mol–1 (B) 159 kJ mol–1 (C) 145 kJ mol–1 (D) 212 kJ mol–1
53. Electronic configuration of an element of the modern periodic table is .......... .
1s2 2s2 2p6 3s2 3p4
What will be atomic number of the element immediately below it, in the same group ?
(A) 18 (B) 34 (C) 48 (D) 24
54. In which one of the following pairs, the two species are both isoelectronic and isotopic ?
(Atomic number Ca = 20, Ar = 18, K = 19, Mg = 12, Fe = 26, Na = 11)
(A) 40Ca2+ and 40Ar (B) 39K+ and 40K+ (C) 56Fe3+ and 57Fe2+ (D) 23Na and 24Na+

55. The shortest wavelength in hydrogen spectrum of Layman series when RH = 109678 cm–1 is
(A) 1002.7 Å (B) 1215.67 Å (C) 1234.7 Å (D) 911.7 Å
56. A 600 W mercury lamp emits monochromatic radiation of wavelength 313.3 nm. How many photons
are emitted from the lamp per second ? (h = 6.626 ´ 10–34 Js, Velocity of light = 3 ´ 108 ms–1)
(A) 1 ´ 1019 (B) 1 ´ 1020 (C) 1 ´ 1021 (D) 1 ´ 1022
57.

58.
m–1 Hence, x is ........... [h = 6.62 ´ 10–34 Js]
(A) 0.25 kg (B) 0.15 kg
Which of the following wave equation is true ?
SIR
A body of mass x kg is moving with velocity of 100 ms–1. Its De-Broglie wavelength is 6.62 ´ 10–35

(C) 0.2 kg (D) 0.1 kg

¶2y ¶2 y ¶2 y 8p 2 m2 ¶y 2 ¶y 2 ¶y 2 8p 2 m2
(A) + + + (E – V )y = 0 (B) + + + (E – V )y = 0
¶x 2 ¶y 2 ¶z 2 h2 ¶x 2 ¶y 2 ¶z 2 h2
K
¶2y ¶2 y ¶2 y 8p 2 m ¶2y ¶2 y ¶2 y 8p 2 m
(C) + + + (E – V )y = 0 (D) + + + (E – V )y = 0
¶x 2 ¶y 2 ¶z 2 h2 ¶2 x ¶2y ¶2z h2
LA

59. What does the electron configuration 1s2 2s2 2p5 3s1 indicate ?
(A) ground state of fluorine (B) excited state of fluorine
(C) excited state of neon (D) excited state of the O –1
2 ion
ZA

60. Which of the following is true for number of electrons, orbitals and type of orbitals present in N-orbit
respectively ?
(A) 4, 4 and 8 (B) 4, 8 and 16 (C) 32, 16 and 4 (D) 4, 16 and 32
61. A metallic ion M2+ has an electronic configuration of 2, 8, 14 and the ionic weight is 56 amu. The
number of neutron in its nucleus is
(A) 30 (B) 32 (C) 34 (D) 42
62. Calculate the wavelength of the light required to break the bond between two chlorine atoms in a
chlorine molecule. The Cl – Cl and bond energy is 243 kJ mol–1.
(h = 6.6 ´ 10–34 Js, C = 3 ´ 108 ms–1, Avogadro’s number = 6.02 ´ 1023 mol–1)
(A) 8.18 ´ 10–31 m (B) 6.26 ´ 10–21 m (C) 4.91 ´ 10–7 m (D) 4.14 ´ 10–6 m
63. Assertion (A) : The probability of finding an electron in a small volume around a point (x, y, z)
at a diatance ‘r’ from the nucleus is proportional to y2 .
Reason (R) : Subatomic particles have both wave and particle nature. The correct choice is
(A) Both (A) and (R) are true and (R) is the correct explanation of (A)
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A)
(C) (A) is true but (R) is not true
(D) (A) is not true but (R) is true

Zalak sir [MO.9727916425]

64. Which set of quantum number is not possible ?
n l m s n l m s
1 1
(A) 3 2 –2 + (B) 4 0 0 +
2 2
1 1
(C) 5 3 0 – (D) 3 2 –3 +
2 2

65. In which one of the following, the number of protons is greater than neutrons but number of protons
is less than the number of electrons
(A) D3O+ (B) SO2 (C) H2O (D) OH–
66. The most probable radius (in pm) for finding the electron in He+ is
(A) 0.0 (B) 52.9 (C) 26.5 (D) 105.8
67. An electron from one Bohr stationary orbit can go to next higher orbit
(A) by emission of electromagnetic radiation.
(B) by absorption of electromagnetic radiation.
(C) by absorption of electromagnetic radiation of particular frequency.
(D) without emission or absorption of electro-magnetic radiation.
68.
second energy level ?
(A) –54.47 ´ 102 erg / atom
(C) –0.5447 ´ 10–12 erg / atom
SIR
The energy of electron in first energy level is –21.79 ´ 10–12 erg / atom. What will be energy in

(B) –5.447 ´ 10–12 erg / atom

(D) –0.05447 ´ 10–12 erg / atom
1
69. How many electrons in 2p orbital have spin quantum number s = – ?
2
K
(A) 6 (B) 0 (C) 2 (D) 3
70. Which orbital is non directional ?
LA

(A) 4p (B) 4d (C) 4f (D) 3s

71. Rutherford experiment prove
(A) Electron (B) Proton (C) Atom (D) Nucleus
72. Give no. of energy state orbital and electrons in N orbit.
ZA

(A) 4, 12, 32 (B) 4, 16, 30 (C) 4, 16, 32 (D) 4, 32, 64

73. Calculate the energy of 1 mole of photon whose frequency is 5 ´ 1014 Hz .
(A) 19.951 kJ (B) 199.51 kJ (C) 39.90 kJ (D) 399.0 kJ
74. Three unpaired electron of nitrogen atom can be explained by.....
(A) Pauli’s rule (B) Aufbau principle
(C) Uncertainity principle (D) Hund’s rule
75. Nuclear theory for atom was given by.....
(A) Rutherford (B) Einstein (C) Neil bohr (D) J. J. Thomson
76. For one atom the energy difference between excited state ground state is 4.4 ´ 10–14 J. Then what
will be wavelength of photon ?
(A) 2.26 ´ 10–12 m (B) 1.13 ´ 10–12 m (C) 4.25 ´ 10–12 m (D) 4.52 ´ 10–12 m
77. Magnitude of K.E. in an orbit is equal to
(A) Half of the potential energy (B) Twice of the potential energy
(C) One fourth the potential energy (D) None of these

78. Isotone of 76
32 Ge is : ..........
(A) 37
32
Ge (B) 77
33
As (C) 77
34
Se (D) 78
36
Sc
Zalak sir [MO.9727916425]
 Isotone of 76
32 Ge is : ..........
(A) 37
32
Ge (B) 77
33
As (C) 77
34
Se (D) 78
36
Sc
79. Which of the following has maximum number of unpaired electrons ?
(A) Fe3+ (B) Fe2+ (C) Co2+ (D) Co3+
80. Which one is not correct ?
(A) n = 4, l = 2, m = 0 (B) n = 4, l = 1, m = 0 (C) n = 4, l = 4, m = 1 (D) n = 4, l = 0, m = 0
81. What is the mass of photon having wavelength 3.6 Å.
[h = 6.6 ´ 10–34 k gm2s–1, c = 3 ´ 108 ms–1]
(A) 8.212 ´ 10–31 kg (B) 5.687 ´ 10–34 kg (C) 6.135 ´ 10–33 kg (D) 7.256 ´ 10–32 kg
82. The nucleus of an element contain 9 protons. Its valency would be
(A) –1 (B) 3 (C) 2 (D) 5
83. Which of the following ion has the highest number of upaired electrons ?
(A) Fe+3 (B) Fe+2 (C) Ni+2 (D) Co+3
84. Calculate mass of a photon having 3.6Å wavelength.
(A) 6.135 ´ 10–29 kg (B) 3.6 ´ 10–29 kg (C) 6.135 ´ 10–33 kg (D) 3.6 ´ 10–27 kg
85. The nature of anode rays depends upon
(A) Nature of electrode (B) Nature of residual gas

86.

87.
(C) Nature of discharge tube

(A) 1 (B) 2
SIR
Which quantum number indicates s, p, d, f orbitals ?
(D) All the above
If magnetic quantum number is –3 then the principal quantum number can be.....
(C) 3 (D) 4

(A) h (B) s (C) l (D) m

K
88. Give number of unpaired electrons in Ni+2.
(A) 0 (B) 1 (C) 3 (D) 2
LA

89. The electron configuration 1s2 2s2 2p6 3s2 3p2 is for .......... element.
(A) C (B) P (C) Si (D) S
90. It n = 6, l = 1, [p orbital] m = 0. Then the max. electrons in p orbital are....
(A) 6 (B) 2 (C) 4 (D) 10
ZA

91. When electron transist from higher energy level to lower energy level then.....
(A) energy absorb (B) energy emits
(C) atomic number increases (D) atomic number decreases
92. Which ion does not possess electron configuration like Ne ?
(A) Na+ (B) F – (C) Mg+2 (D) Cl–1
93. How many unpaired electrons are present in p-orbital of oxygen ?
(A) 0 (B) 1 (C) 2 (D) 3
94. What change occurs in energy of Bohr’s orbit ?
(A) increase away from nucleus (B) does not change away from nucleus
(C) decrease away from nucleus (D) none
95. Which type of spectra obtained if electron transists from M-orbit to L-orbit ?
(A) absorption (B) emission
(C) continuous (D) spectra will not obtain
96. The spectra of He+ is similar as.....
(A) Li + (B) Na (C) He (D) H

Zalak sir [MO.9727916425]

97. The electron configuration of nitrogen is 1s2 2s2 2px1 2py1 2pz1 instead of 1s 2 2s2 2px2 2py1 is
decided by.....
(A) Pauli’s principle (B) Aufbau principle (C) Hund’s rule (D) Ritz rule
98. From the following orbitals of which, electron configuration violates Aufbau principle ?
2s 2p

(A)

(B)

(C)

(D)

99. Which series of lines obtained in ultraviolet region in hydrogen spectra ?

(A) Paschen (B) Balmer (C) Lyman (D) Pfund
100. In hydrogen atom for which change higher energy required ?
(A) n = 3 to n = 5 (B) n = 1 to n = 2 (C) n = 2 to n = 3 (D) n = 2 to n = 1

K SIR
LA
ZA

Zalak sir [MO.9727916425]

 TAKSHSHILA SCIENCE INSTITUTE
Unit 2 Std 11 : Chemistry Date : 15/07/24
Total Marks : MCQ Time : 0:00 Hour
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [100]

1.

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