EXERCISE - 1 [A]

Structural Isomerism
Part - A

1. B 2. D 3. D 4. D 5. D 6. D 7. B

8. A 9. D 10. D 11. D 12. A 13. C 14. D

15. A 16. B 17. A 18. C 19. B, C 20. D 21. A

22. A, C, D 23. A 24. A, C, D 25. B 26. A, B 27. C 28. B

29. B 30. B 31. D 32. D

Part - B
-
1. (a) (b) (c) (d)
O
|
H

2. (a) Tautomers (b) Resonating pairs (c) Tautomers (d) Tautomers (e) Tautomers

O
O
3. (a) , , (b)
H
CH3
CH 3

CH3
|
(c) CH3  C  C  COOEt (d) CH2  C  C  CH2
| | |
OH OH OH

(e) CH2 = C = N – H (f) CH2  N  OH


O
(g) CH2  CH  CH  N  OH (h) CH3 – CH2 – C  N

O

4.

5. (a) 2; (b) 2; (c) 1; (d) 1; (e) 1 6. (a)2; (b) 2; (c) 2; (d) 2; (e) 2

7. (a) 1; (b)1; (c) 2; (d)1; (e) 2; (f) 1; (g) 1 8. (a) 2; (b) 2; (c) 2; (d) 1; (e) 2

9. (a) 3>1>2; (b) 4>2>1>3; (c) 4>1>3>2; (d) 1>3>4>2; (e) 3>2>4>1

10. 3>1>2
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 EXERCISE - 1 [B]
Confonmational Isomerism
Part - A

1. C 2. B 3. B 4. A 5. C
6. D 7. B 8. C 9. C

Part - B

1. (i) (ii)

2. (i) (ii)

3. (i) trans (e, e) (ii) Cis (a, e) (iii) trans (e, e) (iv) trans (e, e)

4. (i) Conformers (ii) Conformers (iii) Positional isomers

(iv) geometrical isomers or diastereomers (v) Identical
5. Structural (Chain isomerism).

6. (C) both 7. False 8. IV > III > I > II

EXERCISE - 1 [C]
1. 5 2. 3 3. 4 4. 6 5. 4
6. 2 7. 8 8. 7 9. 5 10. 8
11. 8 12. 4 13. 4 14. 6 15. 4
16. 5 17. 4 18. 4 19. 0

JEE Main : PYQ

1. A 2. D 3. D 4. B 5. B
6. C 7. A 8. C 9. C 10. B
11. A 12. B 13. A 14. A 15. D
16. A 17. D 18. B 19. C 20. A
21. C 22. B 23. C 24. D 25. C
26. C 27. D 28. 5 29. 6

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 EXERCISE - 2 [A]
Geometrical Isomerism
Part - A
1. B 2. D 3. B,C 4. B 5. D
6. A 7. B 8. C 9. A,C 10. D
11. B 12. D

Part - B
1. b, c , e , f , g , i
2. (i) CH3 – CH = CH – CH3 (ii) CH3 – CH = CH – CH2 – CH3

(iii) CH3 – CH = CH – CH2 – CH2 – CH3 , CH3 – CH2 – CH = CH – CH2 – CH3

CH3
|
,
CH3  CH  CH  CH  CH3

(iv) CH3 – CH = CH – Cl
(v) CH3  C  C  H , Cl  CH2  C  C  H
| | | |
Cl Cl H Cl

3. (i) 4 (ii) 4 (iii) 4 (iv) 4 (v) 6 (vi) 10

4. (a) Z (b) Z (c) Z (d) Z

5. (i) (ii)

EXERCISE - 2 [B]
Optical Isomerism
Part - A
1. D 2. C 3. C 4. D 5. D 6. D
7. C 8. B 9. C 10. B 11. B 12. B
13. C 14. C 15. A 16. A 17. D 18. D
19. B

Part - B
1. a, b, c, e, g, h

2. (a) 2, (b) 1 ,

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 (c) 5,

(d) 1, (e) 1, (d, and )

3. (a) 6, structural isomers = 4, stereoisomers of (c) = 3

H Cl H Cl
| | | |
HC CF (optically inactive) H  C  C  Cl (optically inactive)
| | | |
Cl F F F
(A) (B)

H H H Cl
| | | |
F  C  C  Cl (d, l, meso) F CCH (optically inactive)
| | | |
Cl F F Cl
(C) (D)

(b) 14, Structural isomers = 7, Stereoisomers = 14

F Br F F
| | | |
Cl  C  C  C  Br Cl  C  C  C  F Cl  C  C  C  I Br  C  C  C  Cl
| | | |
I I Br I

4. (a) (b) (c) (d)

5. (a) S (b) R (c) R, S (d) S, S

6. (i) Diastereomer (ii) Enantiomer (iii) Diastereomer

7. 8, yes 8. (i), (ii), (iii), (iv).

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9. (i), (ii), (iii), (iv), (v), (vii) & (viii) are optically inactive species and (vi) is optically active.

10. Two, mirror images i.e. object and its mirror image.

11. These are not same compounds these are positional isomers.

12. (i) P is sp3 hybridised and chiral.

(ii) N is chiral and inversion is not possible in ring structure. one C of cyclopropane ring is
also chiral.

13. (C)

14. 22 = 4 stereoisomers. All are optically active.

15. (7)
CH3
CH3 CH3 H3C CH3
*
*
CH3
1 1 3 1 1

16.

17. (a) or (b)

18. (i) 3 (ii) 3 (iii) 4(cyclic)

Cl Cl
Cl Cl Cl Cl

R Cl S Cl Cl Cl Cl Cl (iv) 6
Both are optically active Optically inactive (presence of plane of symmetry)
Both are diastereomers

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 EXERCISE - 2 [C]
Only One Option Correct :
1. D 2. D 3. D 4. C 5. B
6. B 7. A 8. D 9. D 10. D
11. A 12. B 13. B 14. A 15. C
16. A 17. D 18. B 19. D 20. B
21. C 22. C 23. C 24. D 25. B
26. A 27. D 28. D 29. C 30. A
31. D 32. D 33. D 34. C 35. C
36. B 37. C 38. D 39. D 40. A
41. B 42. D 43. D 44. B 45. D
46. B 47. B 48. A 49. D 50. C
51. C 52. D 53. D 54. C 55. C
56. B 57. A
One or more options may correct :
58. B, D 59. B, D 60. A, D 61. A, B, D
62. B, C 63. A, B, D 64. A, B, C, D 65. A, C
66. A, C 67. A, B, C 68. A, B, C, D 69. A, B
70. B, C, D
Comprehension Type
71. D 72. B 73. C 74. D 75. C
76. C 77. D 78. D 79. C 10. D
Matrix Match Type
81. (A) - 3 ; (B) - 1, 2 ; (C) - 1 ; (D) - 1, 3, 4
82. (A) - 1, 2, 4 ; (B) - 1, 2, 3 ; (C) - 3, 4 ; (D) - 4
83. (A) - 1, 2, 3, 4 ; (B) - 1, 3, 4 ; (C) - 1, 2, 3, 4 ; (D) - 1
84. (A) - 2, 4 ; (B) - 3 ; (C) - 2 ; (D) - 1
85. (A) - 3, 4 ; (B) - 4 ; (C) - 1 ; (D) - 1, 2, 3, 4
86. (A) - 3 ; (B) - 4 ; (C) - 2 ; (D) – 1
87. (A) - 2 ; (B) - 1, 4 ; (C) - 3 ; (D) – 1
Assertion Reasoning Type
88. C 89. C 90. A 91. D 92. B
93. B 94. A 95. C 96. B

JEE Advanced : PYQ

1. B 2. D 3. D 4. AC 5. B
6. C 7. D 9. D 10. A 14. B
15. B 16. C 17. C 18. AD
19. BCD 20. AD 21. 7 22. BD 23. 5
24. BC 25. 8 26. AB 27. D 28. C
29. ACD 30. C 31. 7

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