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Tamilnadu 12th Chemistry Lesson 12 – One Marks

Choose the correct answer:

1.
The formation of cyanohydrins from aceton is an example of
A. Nucleophilic substitution
B. Electrophilic substitution
C. Electrophilic addition
D. Nucleophilic addition
ANSWER: D

2.
Which one of the following reduces tollens reagent?
A. Formic acid
B. Acetic acid
C. Benzophenone
D. None of these
ANSWER: A

3.
Which one of the following reaction is an example of disproporationation reaction
A. Aldol condensation
B. Cannizaro reaction
C. Benzoin condensation
D. None
ANSWER: B

4.
Which one of the following undergoes reaction with 50 % sodium hydroxide solution to give
the corresponding alcohol and acid
A. Phenylmethanal
B. Ethanal
C. Ethanol
D. Methanol
ANSWER: A

5.
In which of the following reactions new carbon - carbon bond is not formed?
A. Aldol condensation
B. Friedel craft reaction
C. Kolbe’s reaction
D. Wolf kishner reduction
ANSWER: D

Additional One Word:

1.
Which among the carbonyl compounds cannot be prepared by Rosenmund reduction?

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A. Ketones
B. Formaldehyde
C. Acetadehyde
D. Both a and b
ANSWER: D

2.
Which of the following acids do not exhibit optical isomerism?
A. Lactic acid
B. Tartaric acid
C. Maleic acid
D. Both a and b
ANSWER: C

3.
Schiff’s reagent gives pink colour with
A. Acetone
B. Acetaldehyde
C. Ethyl alcohol
D. Methyl acetate
ANSWER: B

4.
Isopropyl alcohol vapours with air over silver catalyst at 520 K give
A. Tert butyl alcohol
B. Acetaldehyde
C. Acetone
D. 2 - Propanol
ANSWER: C

5.
Methyl ketones are usually characterised by
A. The Fehling’s solution
B. The iodoform test
C. The Schiff’s test
D. The Tollen’s reagent
ANSWER: B

6.
Which of the following compound is oxidised to give ethyl methyl ketone?
A. 2 - Propanol
B. 2 - Pentanone
C. 1 - Butanol
D. 2 - Butanol
ANSWER: D

7.
Formaldehyde polymerises to give

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A. Paraldehyde
B. Paraformaldhyde
C. Formalin
D. Formic acid
ANSWER: B

8.
Tincture benzoin is obtained from
A. Benzoyl chloride
B. Benzoin
C. Benzyl alcohol
D. Benzoic acid
ANSWER: B

9.
The formation of cyanohydrins from a ketone is an example of
A. Electrophilic addition
B. Nuclephilic addition
C. Nuelcus
D. Electrophilic
ANSWER: B

10.
Bakelite is a product of reaction between
A. Formaldehyde and NaOH
B. Phenol and Methanal
C. Aniline and NaOH
D. Phenol and Chlorofom
ANSWER: B

11.
On dry distillation this gives acetophenone.
A. Calcium benzoate
B. Calcium acetate and calcium benzoate
C. Calcium acetate
D. Calcium acetate and calcium formate
ANSWER: B

12.
4 – methyl pent – 3 ebe – 2 – one is the IUPAC name of
A. Mesitylene
B. Mesityl oxide
C. Phorone
D. Chloretone
ANSWER: B

13.
Aldehydes are functional isomers of

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A. Ethers
B. Alcohols
C. Ketones
D. Esters
ANSWER: C

14.
Which one of the following gives oxime with hydroxyl amine?
A. Benzene
B. Phenol
C. Benzaldehyde
D. Benzoic acid
ANSWER: C

15.
Acetaldehyde cyanohydrins on hydrolysis gives
A. Acetic acid
B. Lactic acid
C. Cinnamic acid
D. Mandelic acid
ANSWER: B

16.
Ketones when reduced in the presence of Pt forms
A. Primary alcohols
B. Secondary alcohols
C. Tertiary alcohols
D. Acids
ANSWER: B

17.
The pink colour of Schiff’s reagent is restored by
A. Alcohol
B. Acid
C. Ketone
D. Aldehyde
ANSWER: D

18.
When aqueous solution of formaldehyde is evaporated to dryness it forms a polymer called
A. Paraldehyde
B. Paraformaldehyde
C. Bakelite
D. Polyamide
ANSWER: B

19.
Heating a mixture of sodium acetate and soda lime gives

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A. Methane
B. Ethane
C. Acetic acid
D. Benzene
ANSWER: A

20.
The acid that cannot be prepared by Grignard reagent
A. Acetic acid
B. Formic acid
C. Butyric acid
D. Benzoic acid
ANSWER: B

21.
Acids have higher boiling points due to
A. Pleasant smell
B. Waxy solid
C. Hydrogen bonding
D. Oxygen
ANSWER: C

22.
Acetic acid when heated with HI / P gives
A. Methane
B. Ethane
C. Propane
D. Acetaldehyde
ANSWER: B

23.
It is used as food preservative
A. Sodium benzoate
B. Ammonium benzoate
C. Benzoic acid
D. Formic acid
ANSWER: A

24.
Carboxylic acids are functional isomers of
A. Ethers
B. Alcohols
C. Aldehydes
D. Esters
ANSWER: D

25.
Primary alcohol on oxidation gives

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A. Aldehyde
B. Ketones
C. Both a and b
D. Neither a nor b
ANSWER: A

26.
Oxidation of secondary alcohol gives
A. Aldehydes
B. Ketones
C. Ethers
D. Primary alcohols
ANSWER: B

27.
Lower members of carboxylic acid family are
A. Waxy solids
B. Pleasant smelling liquids
C. Foul smelling liquids
D. Inert gases
ANSWER: B

Fill in the Blanks:

1.
The number of N – N bond in urotropine is ______
A. 6
B. 0
ANSWER: B

2.
Acetone reacting with HCN to form cyanohydrins is ______ type of reaction.
A. Nucleophilic addition
B. Redox
ANSWER: A

3.
The reagent that does not react with both acetone and benzaldehyde is _____
A. Fehling’s solution
B. Hydrazine
ANSWER: A

4.
The number of carbon atoms in a chain can be increased with ______ reaction.
A. Grignard
B. HVZ
ANSWER: A

5.
Ozonolysis of terminal alkenes gives _______ as one of the products.

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A. Water
B. Formaldehyde
ANSWER: B

6.
Esters have a ______ odour.
A. Fruity
B. Fishy
ANSWER: A

7.
Reduction of ketone gives _______
A. Secondary alcohol
B. Primary
ANSWER: A

8.
_______ is used in the manufacture of thermo softening plastic Perspex.
A. Benzophenone
B. Acetone
ANSWER: B

9.
Formic acid contains _____ group
A. Aldehyde and Alcohol
B. Carboxylic acid
ANSWER: A

10.
______ is used for the treatment of gout
A. Formic acid
B. Acetic acid
ANSWER: A

11.
Grignard reagent on addition with dry ice followed by hydrolysis gives ______
A. Only carboxylic acids
B. Only ketones
ANSWER: A

12.
Among the halogen acids, the weakest acid is _____
A. HB
B. HF
ANSWER: B

13.
Propanone is usually characterised by ______
A. Iodoform test
B. Schiff’s test

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ANSWER: A

14.
The compound used in the preparation of triphenyl methane dye is _____
A. Methanol
B. Phenyl methanol
ANSWER: B

15.
Hydrolysis of ______ yields acids.
A. Cyanides
B. Methanol
ANSWER: A

16.
The compound that does not undergo Cannizzaro reaction is ____
A. Formaldehyde
B. Acetaldehyde
ANSWER: B

17.
The compound which does not reduce Fehling’s solution is _____
A. Benzaldehyde
B. Formaldehyde
ANSWER: A

18.
The compound used in the preparation of the tranquilizer, sulphonal is _____
A. Glycol
B. Acetone
ANSWER: B

19.
Benzylhydrol is ___________
A. Diphenyl carbinol
B. Methyl carbinol
ANSWER: A

20.
IUPAC name of phenetole is ____________
A. Propoxy benzene
B. Ethoxy benzene
ANSWER: B

21.
The acid which reduces Tollen’s reagent is _____
A. Formic acid
B. Acetic acid
ANSWER: A

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22.
Weakest acid among the following is _______
A. Acetylene
B. Water
ANSWER: A

23.
The decarboxylating agent is _____
A. Quick lime
B. Soda lime
ANSWER: B

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