ATOMS & MOLECULES

3
CHAPTER

 Laws of chemical combination

CONTENTS The laws of chemical combination played a
significant role in the development of
 Introduction Dalton’s atomic theory of matter.
 Laws of chemical combination There are two important laws of chemical
combination.
 Dalton’s atomic theory (A) Law of conservation of mass
 Law of conservation of mass was given by
 Atoms Lavoisier in 1774. According to the law of
conservation of mass : Matter is neither
 Symbols of elements
created nor destroyed in a chemical reaction.
 Atomic mass The substances which combine together in a
chemical reaction are known as ‘reactants’
 Molecules whereas the new substances formed as a
result of chemical reaction are called
 Ions ‘products’. The law of conservation of mass
means that in a chemical reaction, the total
 Valency mass of products is equal to the total mass of
reactants. There is no change in mass during a
 Chemical formulae chemical reaction.
Ex. Lavoisier showed that when mercuric oxide
 Molecular mass/ Formula mass was heated, it produced free mercury and
oxygen. The sum of masses of mercury and
 Mole concept oxygen was found to be equal to the mass of
mercuric oxide
Mercuric oxide  Mercury + Oxygen
100 g 92.6 g 7.4 g
 Introduction Sol. Mass of the reactant = 100 g
Matter is called ‘padarth’ in Hindi. Kanad Mass of the products = 92.6 + 7.4 g = 100.0 g
was one of the first persons to propose that = 100 g
matter (or padarth) is made up of very small
Since the total mass of the products formed is
particles called ‘parmanu’. John Dalton called
equal to the total mass of the reactants
these particles by the name of atom. The
undergoing reaction, so the data is in
word ‘atom’ means ‘indivisible’ something
which cannot be divided further. The particles agreement with low of conservation of mass.
of matter (atoms or parmanu) normally exist (B) Law of constant proportions
in a combined form. This combined form of This law was discovered by the french
atoms is now called ‘molecules’. All matter is chemists, A. Lavoisier and Joseph Proust. A
made up of small particles called atoms and pure chemical compound always contains
molecules. Different kinds of atoms and same elements combined together in same
molecules have different properties due to
proportion by mass
which different kinds of matter also show
different properties.
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Ex. Pure water obtained from different sources  Drawbacks of Dalton’s atomic theory
such as river, well, spring, sea, etc., always Some of the drawbacks of the Dalton’s
contains hydrogen and oxygen combined atomic theory of matter are given below :
together in the ratio 1 : 8 by mass.
 One of the major drawbacks of Dalton’s
Limiting reagent : - In a reaction having atomic theory of matter is that atoms were
more than one reactant we must identify the thought to be indivisible (which cannot be
limiting reagent “Reagent which is finished divided). We now know that under special
early is known as limiting reagent ”. circumstances, atoms can be further divided
Example : - In Haber’s process to manufacture into still smaller particles called electrons,
NH3, protons and neutrons. So, atoms are
N2 + 3H2  2NH3 themselves made up of three particles :
If we take 2 moles of N2 (56 grams) along electrons, protons and neutrons.
with 3 moles of H2 (6 grams) we can see that  Dalton’s atomic theory says that all the atoms
only 1 moles of N2 (28 grams) is sufficient to of an element have exactly the same mass. it is,
react with 3 moles of H2. It means 1 mole however, now known that atoms of the same
N2 (28 grams) is in excess & H2 will be element can have slightly different masses.
finished when reaction will be completed or  Dalton’s atomic theory said that atoms of
H2 is limiting reagent. different elements have different masses. it is,
however, now known that even atoms of
 Dalton’s atomic theory different elements can have the same mass.
 It failed to explain how atoms of different
On the basis of laws of chemical combination elements differ from each other, i.e., it did not
John Dalton, an English school teacher in tell anything about internal structure of the atom.
Manchester, proposed that behaviour of matter  It could not explain how and why atoms of
could be explained using an atomic theory. He different elements combine with each other to
published his work about atomic theory in 1808. form compound atoms or molecules.
The main points of Dalton’s atomic theory are:  It failed to explain the nature of forces that
 All the matter is made up of very small hold together different atoms in a molecule.
particles called “atoms”.  It did not make any distinction between
ultimate particle of an element that takes part
 Atoms cannot be divided.
in reactions (atom) and ultimate particle that
 Atoms can neither be created nor destroyed. has independent existence (molecule).
 Atoms are of various kinds. There are as
many kinds of atoms as are elements  Atoms
 All the atoms of a given element are identical  All the matter is made up of atoms. An atom
in every respect, having the same mass, size is the smallest particle of an element that can
and chemical properties. take part in a chemical reaction. Atoms of
 Atoms of different elements differ in mass, most of the elements are very reactive and do
size and chemical properties. not exist in the free state. They exist in
 Chemical combination between two (or more) combination with the atoms of the same
elements consists in the joining together of element of another element.
atoms of these elements to form molecules of Atoms are very, very small in size. The size
compounds. of an atom is indicated by its radius which is
called ‘atomic radius’. Atomic radius is
 The “number” and “kind” of atoms in a given
measured in ‘nanometres’. The symbol of a
compound is fixed. nanometre is nm.
 During chemical combination, atoms of 1
different elements combine in small whole 1 nanometre = 9 metre
10
numbers to form compounds.
1
 or 1 nm = m
109
 Atoms of the same elements can combine in or 1 nm = 10–9 m
more than one ratio to form more than one
Hydrogen atom is the smallest atom of all. They
compounds.
cannot be viewed by simple optical
 microscopes. However, through modern following elements are the first letter of the
techniques such as scanning tunneling name of that elements.
microscope it is possible to produce magnified
images of surfaces of elements showing atoms. Element Symbol

 Symbols of elements Hydrogen H

In order to represent the elements, instead of Carbon C

using full lengthy names, scientists use Nitrogen N
abbreviated names. These abbreviated names Oxygen O
of the elements are known as symbols. Thus,
Fluorine F
symbol may be defined as the abbreviation
Phosphorus P
used for the name of an elements.
Sulphur S
Dalton’s symbols of elements
Iodine I
Dalton was the first scientist to use the
symbols to represent elements in a short way.
Some symbols derived from the first two
Element Dalton’s symbol letters of the names of the elements.
Hydrogen Element Symbol
Carbon
Aluminium Al
Oxygen Barium Ba
Phosphorus Lithium Li
Sulphur Beryllium Be
Platinum Neon Ne
Iron Silicon Si
Copper Argon Ar
Silver Calcium Ca
Gold Nickel Ni
Lead
Mercury Some symbols derived from the first and
the third letters of the names of the
Dalton’s symbols for elements were difficult elements
to draw and inconvenient to use. So, Dalton’s
Element Symbol
symbols are only of historical importance.
They are not used at all. Arsenic As
 Modern symbols of elements Magnesium Mg
IUPAC (International Union of Pure and Chlorine Cl
Applied Chemistry) approves names of Chromium Cr
elements. The symbols of elements are Manganese Mn
generally either the first letter or the first two
Zinc Zn
letters or the first and the third letters of the
name of the elements. The symbols of the Rubidium Rb

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 Some symbols derived from the latin Mass of 1 atom of the element
=
names of the elements are given below 1
of the mass of an atom of carbon  12
12
Ex. The atomic mass of magnesium is 24 u which
Element Latin Symbol
indicates that one atom of magnesium is 24
name
1
Iron Ferrum Fe times heavier than of a carbon 12 atom.
12
Gold Aurum Au
Copper Cuprum Cu Atomic Mass of Some Elements
Potassium Kalium K Element Symbol Atomic
Sodium Natrium Na 1 Hydrogen H mass
1u
Silver Argentum Ag
2 Carbon C 12 u
Mercury Hydragyrum Hg
3 Nitrogen N 14 u
Tin Stannum Sn
4 Oxygen O 16 u
Lead Plumbum Pb
Antimony Stibium Sb 5 Sodium Na 23 u
It is important to note that the first letter of 6 Magnesium Mg 24 u
every chemical symbol is capital letter but, if 7 Aluminium Al 27 u
the symbol consists of two letters, the second 8 Phosphorus P 31 u
letter is not capital letter. 9 Sulphur S 32 u
Ex. Symbol for aluminum is Al and not AL 10 Chlorine Cl 35.5 u
Symbol for lead is Pb and not PB 11 Potassium K 39 u
 Significance of the symbol of an element 12 Calcium Ca 40 u
 Symbol represents name of the element. 13 Iron Fe 56 u
 Symbol represents one atom of the element.
14 Copper Cu 63.5 u
 Symbol also represents one mole of atoms of  Gram atomic mass
the element. That is, symbol also represents
Gram atomic mass of an element is defined as
6.022 × 1023 atoms of the elements
that much quantity of the element whose mass
 Symbol represents a definite mass of the expressed in grams is numerically equal to its
element (equal to atomic mass expressed in atomic mass. To find gram atomic mass we
grams) keep the numerical value the some as the

atomic mass, but simply change the units from
Atomic mass
u to g. for example, atomic mass of aluminium
 Atoms are extremely small ; the heaviest is 27 u. Its gram atomic mass is 27 g.
atoms have masses of about 10–22 g. Even an  Gram atomic mass of Isotopes :
ultramicrobalance cannot measure the mass M1X1  M 2 X 2
of a single atom. However, relative masses of X1  X 2
atoms of different elements can be
determined. At first, the mass of the lightest M1 & M2 are relative masses of isotopes and
atom, hydrogen. X1 & X2 are relative % content
In 1961, International Union of chemists Ex. Chlorine contains two types of atoms having
selected the most stable isotope of carbon relative masses 35 and 37 and their relative
(C - 12 isotope) as standard for comparison the abundance is 3 : 1. In such cases the atomic
atomic masses of various elements. Atomic mass of the element is the average of relative
mass of an element tells us the number of masses of different isotopes of the element.
times an atom of the element is heavier than of 35  3  37 1
the mass of an atom of carbon - 12. Atomic mass of chlorine = = 35.5
4
Atomic mass of an element may be defined as
Atoms usually exist in two ways.
the average relative mass of an atom of the
element as compared with mass of an atom of (i) Molecules (ii) Ions
carbon (C - 12 isotope) taken as 12 amu.
Atomic Mass
 the atomicity of hydrogen, nitrogen, oxygen,
 Molecules chlorine, bromine and iodine is 2 each.
 A combination of atoms is called a molecule. Atomicity of some common elements.
The forces which hold the atoms together in a
Type of Name Symbo Atomicity
molecule are called covalent bonds.
element l
A molecule is the smallest particle of a Non-metal Helium He Monoatomi
substance which has the properties of that cMonoatomi
Argon Ar
substance and can exist in the free state.
Neon Ne cMonoatomi
There are two types of molecules. cDiatomic
Hydrogen H2
 Molecules of elements
Chlorine Cl2 Diatomic
The molecule of an element contains two (or
Nitrogen N2 Diatomic
more) similar atoms chemically combined
together. Oxygen O2 Diatomic

Ex. A molecule of hydrogen element contains 2 Phosphor P4 Tetratomic

hydrogen atoms combined together, and it is us
Sulphur S8 Polyatomic
written as H2.
Metals Sodium Na Monoatomi
 Molecules of compounds Iron Fe cMonoatomi
The molecule of a compound contains two Aluminiu Al cMonoatomi
(or more) different types of atoms chemically m cMonoatomi
combined together Copper Cu
c
Ex. Hydrogen chloride is a compound. The
molecule of hydrogen chloride (HCl) contains
two different types of atom. Hydrogen(H) and  Ions
chlorine atom (Cl)
Molecules of some compounds An ion is a positively or negatively charged
atom (or group of atoms). An ion is formed
Compound Combining Formula Ratio by by the loss or gain of electrons by an atom, so
elements mass it contains an unequal number of electrons
Water Hydrogen 1:8 and protons.
H2 O
and Ex. Sodium ion Na+, magnesium ion Mg2+,
oxygen chloride ion Cl–, and oxide ion O2–.
Ammonia Nitrogen NH3 14:3
 There are two types of ions : cations and
and
anions.
Hydrogen
Carbon Carbon CO2 3:8  Cation
dioxide and
A positively charged ion is known as cation.
Oxygen A cation is formed by the loss of one or more
 Atomicity electrons by an atom.
The number of atoms present in one molecule Ex. Sodium atom loses 1 electron to form a
of an element is called its atomicity. sodium ion, Na+, which is cation :
Ex. Noble gases (helium, neon, argon, krypton, Na 
etc.) have one atom each in their molecules Na 1 electron
 
 Sodium ion
such as He, Ne, Ar and Kr. So, the atomicity Sodium
(A cation )
of noble gases is 1.
The ions of all the metal elements are cations.
Ex. Hydrogen (H2), nitrogen (N2), oxygen (O2),
chlorine (Cl2), bromine (Br2), and iodine (I2),
all have 2 atoms each in their molecules. So,
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 Na –1 electron
    Na– (cations) and negatively charged ions (anions)
Sodium atom Sodium ion are held together by the strong electrostatic
Protons = 11 (+ charge) Protons = 11 (+charge) forces of attraction. The forces which hold the
Electrons = 11 (– charge) Electrons = 10 (–charge) ions together in an ionic compound are
Overall charge = 0 Overall charge = 1+ known as ionic bonds or electrovalent bonds.
Since an ionic compound consists of an equal
number of positive ions and negative ions, so
 Anion the overall charge on an ionic compound is
zero.
A negatively charged ion is known as anion.
An anion is formed by the gain of one or Ex. Sodium chloride (NaCl) is an ionic compound
more electrons by an atom. which is made up of equal number of
positively charged sodium ions (Na+) and
Ex. A chlorine atom gains 1 electron to form a
negatively charged chloride ions (Cl–).
chloride ion, Cl–, which is an anion.
Some ionic compound
Cl 
1 electron
  Cl –
Chlorine atom Chlorine ion
( An Anion ) S.No. Name Formula Ions present

An anion contains more electrons than a Sodium + –

1 NaCl Na and Cl
normal atom. A normal atom (or a neutral chloride
atom) contains an equal number of protons Potassium + –
and electrons. Now, since an anion is formed 2 KCl K and Cl
chloride
by the addition of one or more electrons to an
atom, therefore, an anion contains more Ammonium + –
3 NH4Cl NH4 and Cl
electrons than protons. The ions of all the non chloride
metal elements are anions Magnesium 2+ –
4 MgCl2 Mg and Cl
1 electron – chloride
Cl    Cl
Chlorine atom Chlorine ion Calcium 2+ –
5 CaCl2 Ca and Cl
Protons = 17 (+ charge) Protons = 17 (+charge) chloride
Electrons = 17 (– charge) Electrons = 18 (–charge) Magnesium 2+ 2–
Overall charge = 0 Overall charge = 1– 6 MgO Mg and O
oxide
Calcium 2+ 2–
 Simple ions 7 CaO Ca and O
oxide
Those ions which are formed from single Aluminium 3+ 2–
atoms are called simple ions. 8 Al2 O3 Al and O
oxide
Ex. Sodium ion, Na+, is a simple ion because it is 9
Sodium
NaOH + –
Na and OH
formed from a single sodium atom, Na. hydroxide
Copper 2+ 2–
 Compound ions 10 CuSO4 Cu and SO4
sulphate
Those ions which are formed from groups of Calcium Ca(NO3) 2+ –
joined atoms are called compound ions 11 Ca and NO3
nitrate 2

Ex. Ammonium ion NH4+, is a compound ion

which is made up of two types of atoms
 Valency
joined together, nitrogen and hydrogen.

 Ionic compounds The combining capacity of an element is

known as its valency.
The compounds which are made up of ions
are known as ionic compounds. In an ionic
compound, the positively charged ions
 Formulae and valencies of common ions

Electropositive Ions Electropositive Ions

Monovalent Bivalent Monovalent Bivalent

Name Formula Name Formula Name Formula Name Formula

– 2–
Potassium K
+
Barium Ba
2+ Hydroxide OH Carbonate CO3
– 2–
+ 2+ Hydride H Chromate CrO4
Sodium Na Calcium Ca
– 2–
+ 2+ Fluoride F Dichromate Cr2 O7
Copper [I] Cu Magnesium Mg
– 2–
Chloride Cl Manganate MnO4
2+
Manganese [II] Mn
– 2–
Bromide Br Tetrathionate S4O6
2+
Zinc Zn – 2–
Iodide I Sulphide S
+ 2+
Silver Ag Iron [II] Fe – 2–
Bicarbonate HCO3 Sulphite SO3
Ammonium NH4 + Bisulphite –
Sulphate 2–
HSO3 SO4
+ 2+
Hydrogen H Nickel Ni Bisulphate HSO4
–
Oxide O
2–

2+ – 2–
Cobalt Co Chlorate ClO3 Zincate ZnO2
2+ – 2–
Tin [II] Sn Hypochlorite ClO Thiosulphate S2O3
–
Cadmium 2+ Nitrite NO2
Cd
–
2+ Nitrate NO3
Lead [II] Pb
–
2+
Permanganate MnO4
Copper [II] Cu

Trivalent Tetravalent
Trivalent Tetravalent
Name Formula Name Formula
Name Formula Name Formula
3+ 4+
Aluminium Al Manganese [II] Mn 3– 4–
Nitride N Ferrocyanide Fe(CN) 6
3+ 4+
Chromium Cr Tin [IV] Sn 3–
Phosphate PO4
3+ 4+
Iron [III] Fe Lead [IV] Pb Ferricyanide Fe(CN) 6
3–

3+ 4+ 3– 4+
Gold Au Platinum Pt Phosphide P Pt

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 in one molecule. One molecule of hydrogen
 Variable valency
element contains two atoms of hydrogen,
There are certain elements that exhibit more therefore, the formula of hydrogen is H2.
than one valencies in their ions (or Ex. The formula H2 indicates that one molecule
compounds). of hydrogen element contains 2 atoms of
Ex. Iron can exist as Fe2+ or Fe3+ in its hydrogen. 2 H represents 2 separate atoms of
hydrogen; H 2 represents 1 molecule of
compounds. In such cases the name of the ion
with lower valency ends with a suffix ‘ous’ hydrogen and 2H2 represents 2 molecules of
while that with higher valency ends with a hydrogen.
suffix ‘ic’.  Formulae of compounds
The chemical formula of a compound is a
Some basic ions exhibiting variable valency statement of its composition in which the
Name of Formula chemical symbols tell us which elements are
ions + present and the subscripts tell us how many
Cuprous Cu
2+ atoms of each element are present in one
Cupric Cu
2+ molecule of the compound.
Mercurous Hg2
2+ Ex. Water is a compound whose molecule
Mercuric Hg contains 2 atoms of hydrogen and 1 atom of
2+
Ferrous Fe oxygen. So, the formula of water is H2O.
3+
Ferric Fe
2+
 Rules for writing a chemical formula
Plumbous Pb
4+
 We first write the symbols of the elements
plumbic Pb which form the compound
2+
Stannous Sn  Below the symbol of each element, we write
4+
Stannic Sn down its valency.
+
Aurous Au  Finally, we cross-over the valencies of the
Auric Au
3+ combining atoms. That is, with first atom we
write the valency of second atom (as a
 Chemical formulae subscript); and with the second atom we write
the valency of first atom (as subscript).
A compound is represented in the abbreviated
Ex.
form by chemical formula.
Element C C
The chemical formula of a compound l
represents the composition of a molecule of Formula C1Cl4 or CCl4
the compound in terms of the symbols of the Valency 4 1
elements present in it.
Ex.
Ex. Water is a compound made up of 2 atoms of
hydrogen element and 1 atom of oxygen Element H C
element, so the formula of water is written as l
Valency 1 1
H2O. In the formula H2O, the subscript 2
indicates 2 atoms of hydrogen. In the formula Formula HCl
of water, oxygen O is written without a Ex.
subscript and it indicates 1 atoms of oxygen. Element H O
Formulae of elements
The chemical formula of an element is a Valency 1 2
statement of the composition of its molecule Formula H2O
in which symbol tells us the element and the
subscript tells us how many atoms are present
Ex. Thus, the formula of barium nitrate is
Element H Ba(NO3)2
S

Valency 1 2
 Significance of the formula of a substance
Formula H2S
 Formula represents the name of the substance
Ex.
 Formula represents one molecule of the
Element N H substance
 Formula also represents one mole of
Valency 3 1 molecules of the substance. That is, formula
Formula NH3 also represents 6.022 × 1023 molecules of the
substance.
 Writing the formula of a compound  Formula gives the name of all the elements
Step-1 : present in the molecule.
 Formula gives the number of atoms of each
Write the symbols of formulae of the ions of element present in one molecule.
the compound side by side with positive ion
on the left hand side and negative ion on right  Formula represents a definite mass of the
hand side. substance

Step-2 :  Molecular mass/Formula mass

Enclose the polyatomic ion in a bracket. Molecular mass expresses as to how many
times a molecule of a substance is heavier
Step-3 : 1
than th of the mass of an atom of carbon
Write the valency of each ion below its 12
symbol (carbon-12). Thus, Molecular mass =
Step-4 : Mass of a molecule
1
th mass of a carbon atom (carbon  12)
Reduce the valency numerals to a simple ratio 12
by dividing with a common factor, if any.
Molecular mass = 2 × vapour density
Step-5 : Ex. A molecule of water is 18 times heavier than
Cross the valencies. Do not write the charges 1
th of the mass of carbon atom. Therefore,
positive or negative of the ions. 12
the molecular mass of water is 18 u.
Ex. Formula of barium nitrate.
 Calculation of molecular mass from atomic
Step-1 : Writing the formula of the ions : masses
Ba2+ NO3– The molecules are made up of two or more
atoms of different elements. Therefore, the
Step-2 : Ba2+ (NO3)– molecular mass may be calculated as the sum
Step-3 : Ba2+ (NO3)– of the atomic masses of all the atoms in a
molecule of that substance.
2 1 Ex. Ammonia has the formula, NH3. it consists of
Step-4 : Not applicable, because ratio is one atom of N and three atoms of H. The
already simple atomic mass of N and H are 14.0 and 1
respectively. Therefore, the molecular mass
Step-5 : of NH3 is
Ba2+ (NO3)– Molecular mass of NH3 = At. mass of N + 3 ×
At. mass of H
= 14 + 3 × 1 = 17 u
2 1
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Ex. Sulphuric acid has the formula H2SO4. It Similarly,
consists of two H, one S and four O atoms. 1 Mole of molecules = 6.022 × 1023 molecules
The atomic masses of H, S and O are 1,32 = Gram molecular mass of Molar mass
and 16 respectively. Therefore, the molecular Mass of substance
mass of H2SO4 is Number of moles =
Molar mass
Molecular mass of H2SO4 =
m
(2 × at. m. of H) + (1 × at. m. of S) n=
M
+ (4 × at. m. of O)
Number of moles
= (2 × 1) + (1 × 32) + (4 × 16) = 98 u Given number of molecules
 Gram molecular mass =
Avogadro number
The molecular mass of a substance expressed N
in gram is called its gram molecular mass. n=
N0
Ex. Molecular mass of oxygen, O2 = 32 u
or m = n × M and N = n × N0
So, gram molecular mass of oxygen, O2 = 32
grams. Relationship between mole, number of
particles and mass and interconversion of
 Mole concept one into the other.
Molarity (1 m) × Vol. (1lit.)
Atoms and molecules are so small in size that
NA molecules In terms of 1 gm atom
they cannot be counted individually. The concentration of elements
chemists use the unit mole for counting In form of In form of 1 gm formula
atoms, molecules or ions. It is represented by particle mass
1 mole mass of
n. A mole represents 6.022 × 1023 particles. substance
Ex. 1 mole of atoms = 6.022 × 1023 atoms. NA atoms
In form of
volume at STP 1 gm
molecules
1 mole of molecules = 6.022 × 1023 molecules of
22.4 lit.
The number of particles present in 1 mole of
any substance is fixed i.e. 6.022 × 1023. Molarity (M) : - Moles of solute is one litre of
This number is called Avogadro constant or solution is known as molarity .
Avogadro number. Number of moles of solute
M=
it is represented by No. Volume of solution in litre
1 mole of atoms = 6.022 × 1023 atoms = Gram Ex. An ornament of silver contains 20 g of silver.
atomic mass or Molar mass of element Calculate the moles of silver present (atomic
Mass of element mass of silver = 180 u)
Number of moles =
Molar mass Sol. Moles of silver,
m
m n=
n= M
M
Mass of silver, m = 20 g,
Given number of atoms
Number of moles = Molar mass of silver,
Avogadro number
M = 108 g
N 20
n=  n= = 0.185 mol.
N0 108
No. of moles = n Ex. How many moles of CO2 are present in 51.2
Given mass = m g of it ?
Molar mass = M Sol. Molecular mass of CO2 = 12 + 2 + 16 = 44 u
Molar mass of CO2 (M) = 44 g
Given number of particles = N
Mass of CO2 (m) = 51.2 g
Avogadro number of particles = N0
Moles of CO2,
These relations can be interchanged as
m 51.2
Mass of element, m = n × M n=  = 1.16 mol.
N 44
or No. of particles of element, N = n × N0
Ex. Calculate the mass of Empirical formula
(i) 0.5 moles of N2 gas The empirical formula of a compound may be
defined as the formula which gives the
(ii) 0.5 moles of N atoms simplest whole number ratio of atoms of the
Sol. (i) 0.5 moles of N2 gas various elements present in the molecule of
Mass = Molar mass × Number of moles the compound.
Ex. The empirical formula of the compound
m=M×n
glucose (C6H12O6), is CH2O which shows that
M = 28 g, n = 0.5 C, H, and O are present in the simplest ratio of
 m = 28 × 0.5 = 14 g 1 : 2 : 1.

(ii) Mass = Molar mass × Number of moles Rules for writing the empirical formula
m=M×n The empirical formula is determined by the
following steps :
n = 0.5 mole, M = 14 g
 Divide the percentage of each elements by its
m = 14 × 0.5 = 7 g atomic mass. This gives the relative number
Mass percentage of an element from of moles of various elements present in the
molecular formula : compound.
The molecular formula of a compound may  Divide the quotients obtained in the above
be defined as the formula which specifies the step by the smallest of them so as to get a
number of atoms of various elements in the simple ratio of moles of various elements.
molecule of the compound.  Multiply the figures, so obtained by a suitable
Ex. The molecular formula of glucose is C6H12O6. integer, if necessary, in order to obtain whole
This indicates that a molecule of glucose number ratio.
contains six atoms of carbon, twelve atoms of  Finally write down the symbols of the various
hydrogen and six atoms of oxygen. elements side by side and put the above
The mass percentage of each element is then numbers as the subscripts to the lower right
calculated by the following formula : Mass hand corner of each symbol. This will
percentage of element X represent the empirical formula of the
compound.
Mass of X in one mole
= × 100. Ex. A substance, on analysis, gave the following
Gram molecular mass
composition : Na = 43.4%, C = 11.3%, O =
Ex. Calculate the percentage composition (by 45.3%. Calculate its empirical formula
mass) of formaldehyde (CH2O). [Atomic masses = Na = 23, C = 12, O = 16]
Sol. Molecular mass of formaldehyde,
Sol.
CH2O = 12 × 1 + 1 × 2 + 16 × 1 = 30 Relative Simple Simplest
Atomic
Element Symbol % number of ratio of whole no.
Mass of one mole of formaldehyde = 30 g mass
moles moles ratio
43 .4 1.88
1 Mole of CH2O contains 1 mole (12 g) of Sodium Na 43.4 23  1.88 2 2
23 0.94
carbon. 2 moles of hydrogen (2 g) and 1 mole 11 .3 0.94
of oxygen (16 g) Carbon C 11.3 12  0.94 1 1
12 0.94
45 .3 2.83
12g Oxygen O 45.3 16  2.83 3 3
Percentage of carbon = × 100 = 40.0% 16 0.94
30g
Therefore, the empirical formula is Na2CO3
2g  Determination molecular formula :
Percentage of hydrogen = × 100 = 6.7%
30g
Molecular formula = Empirical formula × n
16g Molecular formula
Percentage of oxygen = × 100 = 53.3% n=
30g Empirical formula

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Ex. What is the simplest formula of the Ex. If all iron present in 1.6 gm Fe2O3 is converted
compound which has the following in form of FeSO4. (NH4)2SO4.6H2O after series
percentage composition : Carbon 80%, of reaction. Calculate mass of product obtained.
Hydrogen 20%, If the molecular mass is 30,
calculate its molecular formula. Sol. If all iron will be converted then no. of mole
Sol. Calculation of empirical formula : atoms of Fe in reactant & product will be
same.
Relative Simple ratio Simplest
Atomic
Element % number of of moles whole no. 1.6 1
mass
moles ratio
 Mole of Fe2O3 = =
160 100
80 6.66
C 80 12  6.66
2.3 1 1 1 1
12 6.66 mole atoms of Fe = 2 × =
20 20
100 50
H 20 1  20
12 3 3
1 6.66 mole of FeSO4. (NH4)2SO4.6H2O will be
 same as mole atoms of Fe because one atom
  Empirical formula is CH3. of Fe is present in one molecule.
Calculation of molecular formula : 1
 Mole of FeSO4.(NH4)2.SO4.6H2O =
Empirical formula mass = 12 × 1 + 1 × 3 = 15 50
Molecular mass 30 1
n= = =2 Mass = × Molecule wt.
Empirical formula mass 15 50
Molecular formula 1
= × 342 = 7.84 gm. 
= Empirical formula × 2 = CH3 × 2 = C2H6. 50

Ex. On heating a sample of CaCO3, volume of Ex. Calculate mass of hydrazine N2H4 obtained
CO2 evolved at NTP is 112 cc. Calculate when 1.12 litre of N2 taken at NTP reacts
(i) Weight of CO2 produced with H2 according to N2 + 2H2  N2H4.
1.12 1
(ii) Weight of CaCO3 taken Sol. Moles of N2 taken = =
22.4 20
(iii) Weight of CaO remaining
N2 + 2H2  N2H4
112 1
Sol. (i) Mole of CO2 produced = mole (1/20 mole) (1/20 mole)
22400 200
1 1
mass of CO2 = × 44 = 0.22 gm mass of N2H4 = × 32 = 1.6 gm
200 20

(ii) CaCO3  CaO + CO2 Ex. Calculate mass of Na2SO4 obtained when
(1/200 mole) 100 ml of 0.2 M H2SO4 is completely
1 neutralised by NaOH.
mole of CaCO3 = mole
200 Sol. Mole of H2SO4 taken =
1 100
mass of CaCO3 = × 100 = 0.5 gm Molarity × Vol. (lit) = 0.2 × = 0.02
200 1000
1
(iii) mole of CaO produced = mole
200 H2SO4 + 2NaOH  Na2SO4 + 2H2O
1 0.02 mole 0.02 mole
mass of CaO = × 56 = 0.28 gm
200 Mole of Na2SO4 obtained = 0.02
* Interesting by we can apply
mass of Na2SO4 = 0.02 × 142 = 2.84 gm
Conversation of mass or wt. of CaO
= wt. of CaCO3 taken – wt. of CO2 produced
= 0.5 – 0.22 = 0.28 gm
 EXERCISE- 1
A. Very Short Answer Type Questions Q.19 “If 100 grams of calcium carbonate are
Q.1 Name of the building block of all matter. decomposed completely, then 56 grams of
calcium oxide and 44 grams of carbon
Q.2 What are the symbols of copper and cobalt? dioxide are obtained” Which law of chemical
combination is illustrated by this statement?
Q.3 Name two elements whose symbols are
derived from Latin names. Give their Q.20 Name the scientist who gave law of
symbols. conservation of mass

Q.4 What is the mass of 1 mole of water ?

B. Short Answer Type Questions
Q.5 Give symbols of lead and aluminium.
(MORE 31-46 words)
Q.6 What is meant by 1 mole of carbon atoms ? Q.21 Define mole.
Q.7 What is the molecular mass of H2SO4? Q.22 Calculate the number of moles in
12.044 × 1025 atoms of phosphorus.
Q.8 Sodium carbonate (Na2CO3.10H2O) is an
important industrial compound. Calculate its Q.23 Write down the formulae for the following
formula mass. compounds :
(a) Calcium oxide (b) Magnesium hydroxide
Q.9 Which of the following is tetraatomic
Q.24 An element Y has a valency of 4. Write the
molecule
formula its :
CH3OH, CH4, H2O2?
(a) Chloride (b) Oxide
Q.10 Helium gas consists of single atoms. What (c) Sulphate (d) Carbonate
mass of helium contains 6.022 × 1023 atoms ? (e) Nitrate
Q.11 What is the atomic mass unit? Q.25 An element B shows valencies of 4 and 6.
Write the formulae of its two oxides.
Q.12 What is the ratio by mass of nitrogen and Q.26 An element X of valency 3 combines with
hydrogen in ammonia? another element Y of valency 2. What will be
the formula of the compound formed ?
Q.13 Give two examples of trivalent metal ions.
Q.27 What is an ion ? How is an ion formed?
Q.14 What is the chemical formula of calcium
oxide? Q.28 What is the difference between a cation and
an anion? Explain with examples.
Q.15 Which of the following has larger mass
(i) A mole of ammonia (NH3) Q.29 Define ‘formula unit’ of an ionic compound.
(ii) A mole of methane (CH4) What is the formula unit of (a) sodium
chloride and (b) magnesium chloride?
Q.16 How many moles of helium are present in
104 g of He Q.30 Define ‘formula mass’ of a compound.

Q.17 What is the molar mass of sulphur molecule Q.31 Explain the difference between 2N and N2.
(S8)? Q.32 What do the symbols, H2, S and O4 mean in
Q.18 “If 100 grams of pure water taken from the formula H2SO4?
different sources is decomposed by passing
electricity, 11 grams of hydrogen and 89
grams of oxygen are always obtained”.
Which chemical law is illustrated by this
statement?

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 EXERCISE- 2
Q.11 What weight of oxygen gas will contain the
A. Long Answer Type Questions same number of molecules as 56 g of nitrogen
(More than 47–60 words) gas? (O = 16 u ; N = 14 u)

Q.1 Explain the following terms

(i) Atomic mass (ii) Molecular mass B. Fill in the Blanks
(iii) Mole (iv) Avogadro constant Q.12 In water, the proportion of hydrogen and
(v) Polyatomic ions oxygen is ........by mass.

Q.2 What is Dalton’s atomic theory? Give its Q.13 ................ is a pure substance which is made
main postulates. Which postulate of Dalton’s up of only one kind of atoms.
atomic theory explain the law of conservation
of mass. Q.14 The atomicity of ozone is ..............

Q.3 Calculate the following : Q.15 1 mole of oxygen atoms = ............... oxygen
atoms.
(i) Number of S atoms in 3.2 g of S8.
(ii) Number of molecules of CH4 in 80.0 g of it Q.16 The ratio by mass of S and O in SO2
(iii) The mass of 1 molecule of NH3. is..............
(iv) The mass of 0.25 moles of calcium
(v) Number of bromide ion in 0.2 mole of C. True /False Type Questions
MgBr2.
Q.17 Two elements sometimes form more than one
Q.4 What is the significance of the symbol of an compounds.
element? Explain with the help of an
example. Q.18 The smallest particle of a compound is
element.
Q.5 What is meant by saying that ‘the atomic
mass of oxygen is 16” ? Q.19 Mass of 6.022 atoms of an element is called
atomic mass.
Q.6 Calculate the molecular masses of the
following compounds : Q.20 One mole of every substance has same mass.
(i) Methanol, CH3OH (ii) Ethanol, C2H5OH
Q.21 One mole of CO2 and SO2 contains same
Q.7 What is the significance of the formula of a number of oxygen atoms.
substance?
Q.22 Mass of 1 mole of CO2 is 44 g.
Q.8 The mass of one atom of an element X is
2.0 × 10–23 g. Q.23 The mass of a hydrogen atom is th the mass
of a carbon atom.
(i) Calculate the atomic mass of element X.
(ii) What could element X be?
Q.9 The mass of one molecule of a substance is
4.65 × 10–23 g. What is its molecular mass?
What could this substance be?

Q.10 If 1 gram of sulphur dioxide contains x

molecules, how many molecules will be
present in 1 gram of oxygen? (S = 32 u ;
O = 16 u)
 ANSWER KEY
EXERCISE-1
A. Very Short Type Answer
1. Atoms 2. Cu and Co 3. (i) Fe for iron from ferrum (ii) Na for sodium from natrium
4. 18 g 5. Pb, Al 6. 12 g 7. 98 u 8. 286 u
9.H2O2 10. 4 g 11. 1/12th the mass of atom of carbon – 12 isotope 12. 14 : 3
+3 +3
13. Al , Fe 14. CaO 15. NH3 16. 26
17. 256 g 18. Law of constant proportions 19. Law of conservation of mass
20. Lavoisier

EXERCISE-2
12. 1 : 8 13. Element 14. 3 15. 6.022 × 1023 16. 1 : 1
17. True 18. False 19. False 20. False 21. True
22. True 23. False