Final 22ches12 Module 2 Notes
Final 22ches12 Module 2 Notes
Organic Semiconductors:-
Organic semiconductors are π-conjugated polycyclic and heterocyclic systems which
have a certain degree of electrical conductivity. There are two major classes of
organic semiconductors:-low molecular weight materials and polymers.
Organic semiconductors can be divided according to the character of charge carriers into
p-type (a positive charge or hole as the major carrier), n-type (a negative charge or
electron as the major carrier) or Ambipolar organic semiconductors (both electrons and
holes are involved as charge carriers)
The HOMO-LUMO gaps of perfluorinated pentacene are smaller than those of the
corresponding Pentacene.
To show that Perfluropentacene is a n-Type semiconductor:-
Consider OTFT (optical Thin Film Transistor) as
shown in the diagram.
Source and drain was made of gold and
semiconductor was perfluropentacene.
The HOMO-LUMO gaps are 2.07ev for
pentacene and 1.95ev for perfluropentacene.
When a positive voltage is applied to gate the
negative charges are induced at the source
electrode (Gold).
The source and drain electrodes inject electrons in its LUMO level.
This charge forms a conducting channel at the insulator and semiconductorinterface and
allows the charge carriers electron from source to drain. Therefore, Perfluoropentacene is
considered as P-type semiconductor.
1. The donors and acceptors of PIs contribute to the electronic transition based on an induced charge
transfer (CT) effect under an applied electric field.
2. When an electric field more than threshold energy is applied, the electrons of the HOMO (TPA
unit) is excited to LUMO.
3. The energy of LUMO of donor and acceptor are similar and therefore, after excitation the electron
transferred to LUMO (acceptor), generating a CT state.
4. This permits the generation of holes in the
HOMO, which produces the open channel
for the charge carriers to migrate through
5. Therefore, Field-induced charge transfer
from Triphenylamine to Phthalimide exhibit
the switching behavior (bistable states
ON/OFF).
6. Memory characteristic of these memory depends on film thickness donor accepter strength and
attached groups.
Photoactive and electro active organic materials:
Organic semiconductors used in electronic and optoelectronic devices are called as electro active and
photoactive materials. They are also called as organic semiconductors. The organic molecules exhibit
optoelectronic properties composed of π- electron systems.
Photoactive materials are respond to light and are capable of change in their optical, electronic, or
magnetic properties whereas electroactive materials that exhibit a strong response to an electric field.
When these materials are used in devices, they exhibit opto-electronic phenomena.
Optoelectronic devices are special types of semiconductor devices that are able to convert light
energy to electrical energy or electrical energy to light energy.
If the photon has an energy larger than the energy a gap, the photon will be absorbed by the
semiconductor, exciting an electron from the valence band into the conduction band, where it is free to
move. A free hole is left behind in the valence band.
When the excited electron is returning to valence band, extra photon energy is emitted in the form a
light.This principle is used in Optoelectronic devices.
P3HT-ITO forms a p-n junction permit the charge carriers to move in opposite
direction and hence, used in Photovoltaic devices.
It can be used as a positive electrode in Lithium batteries.
Used in the construction of Organic Solar Cells.
Manufacture of smart windows.
Used in the fabrication new types of memory devices.
Module-2/CSE stream/ VTU study material/ Dr S. N Karanth /SMVITM Bantakal Page 7
Light emitting material - Poly[9-vinylcarbazole] (PVK)]:-
(ii) Lyotropic liquid crystals: The compounds which transforms into liquid crystal phase when
mixed with solvent. They have both polar lyophilic and nonpolar lyophobic end. These are amphiphilic
compounds which form ordered structures in both polar and nonpolar solvents. They are obtained from
mixing a compound in a solvent and increasing the concentration of compound till liquid crystal phase
is obtained. Such compounds are known as lyotropic liquid crystals. E.g., Soap- water mixture,
Liquid crystals show some orientational order. At any point of time, one molecular axis tends to point
along a preferred direction as the molecules undergo diffusion. This preferred direction is called the
director.
Properties of liquid crystals:-
• They exhibit optical anisotropy which is defined as the difference between refractive index
parallel to the director and refractive index perpendicular to the director. These two properties are
important for the electro-optic effects in liquid crystals.
• The intermolecular forces are rather weak and can be perturbed by an applied electric field.
Module-2/CSE stream/ VTU study material/ Dr S. N Karanth /SMVITM Bantakal Page 10
• Because the molecules are polar, they interact with an electric field, which causes them to change
their orientation slightly.
• Liquid Crystal can flow like a liquid, due to loss of positional order.
• Liquid crystal is optically birefringent, due to its orientation order.
• Liquid crystals, like all other kinds of matter, exhibits thermal expansion (Thermal Imaging).
Applications of liquid crystals:-
• Liquid crystals have a wide range of applications in various fields, including electronics, optics,
displays, sensors, and medicine. Some of the major applications of liquid crystals are:
• Liquid Crystal Displays (LCDs): The liquid crystal layer in LCDs allows for the display of images
and text through the use of electrical currents that control the orientation of the crystals.
• Sensors: Liquid crystal sensors are used in various applications such as temperature
sensing, humidity sensing, and chemical sensing.
• Optical Devices: Liquid crystals are used in various optical devices such as variable optical
attenuators, phase shifters, and tunable filters. These devices are used in optical communication
systems, spectroscopy, and imaging.
• Medicine: Liquid crystals have been used in drug delivery systems, where the drug is encapsulated
in the liquid crystal matrix and delivered to specific target cells.
Applications
Organic Light Emitting Diodes (OLEDs) have a wide range of applications due to their unique
properties, including high contrast, energy efficiency, thinness, and flexibility. Here are some of the
applications of OLED:
Televisions and displays: OLED displays are used in televisions, monitors, smartphones, and
other electronic devices.
Lighting: OLEDs can also be used as a source of lighting in various applications, including
automotive lighting, street lighting, and architectural lighting.
Wearable devices: The thin and flexible nature of OLEDs makes them suitable for use in
wearable devices, such as smart watches and fitness trackers.
Automotive: OLEDs can be used in automotive applications, such as dashboard displays, interior
lighting, and taillights.
Medical: OLEDs can be used in medical applications, such as in surgical lighting and medical
imaging. They offer bright and highly accurate lighting options that can help improve medical
procedures and diagnosis.
Applications of QLED
Televisions and displays: QLED displays are commonly used in televisions, monitors, smart
phones, and other electronic devices. They offer superior image quality and color accuracy
compared to traditional LCD displays.
Lighting: QLEDs can also be used as a source of lighting in various applications, including
automotive lighting, street lighting, and architectural lighting. They offer energy-efficient and
highly customizable lighting options.
Medical imaging: QLEDs can be used in medical imaging applications, such as in MRI machines,
to produce high-resolution and accurate images.
Virtual and augmented reality: QLED displays are suitable for use in virtual and augmented
reality applications due to their ability to produce vibrant and accurate colors, which can enhance
the immersive experience.
Advertising displays: QLED displays can be used in advertising displays, such as digital billboards
and signage, to produce high-quality and eye-catching visuals.