PRACTICE ASSIGNMENT – CHEMISTRY – STOICHIOMETRY

Illustrative Problems :- 6. 12 g of impure cyanogen undergo hydrolysis by two

different pathways :
1. 30 ml of a solution containing 9.15 gm/litre of an
oxalate KxHy (C2H4)z.nH2O are required for titrating 27 (i) (CN)2 + 4H2O  (NH4)2C2O4
ml of 0.12 N NaOH and 36 ml of 0.12 N KMnO4
(ii) (CN)2 + 2H2O  NH2CONH2
separately. Calculate x, y, z and n. Assume all H atoms
(except H2O) are replaceable and x, y, z are in the The exact amount of urea was obtained when 11.52 g
simple ratio of gm atoms. of pure ammonium carbonate was heated. If 20 ml of
1.6 M acidic KMnO4 solution was required to
2. The calcium contained in a solution of 1.048 gm of the
completely oxidize (NH4)2C2O4, calculate
substance being analysed was precipitated with 25 ml
2-
of H2C2O4. The excess of C2O4 in one fourth of the (a) % purity of cyanogen.
filtrate was back titrated with 5 ml of 0.1025 N KMnO4
solution. To determine the concentration of the H2C2O4 (b) % progress of reaction in two different pathways.
solution taken, it was diluted four fold, the titration of
25 ml of the dilute solution used up 24.1 ml of KMnO4 (c) In which reaction carbon is oxidized and in which it is
solution. What is percentage of CaO in the substance reduced ?
being analysed.
7. A fused mixture of rubidium fluoride and uranium (IV)
3. If 1 g of H2(g) reacts with 1 g of Cl2(g) in a closed fluoride can be oxidized with fluorine to produced a
container, then how many grams of HCl will be uranium compound in which the uranium is mainly but
produced during the reaction ? not entirely is the +5 oxidation states. The product is
found to contact 54.93% uranium. A 1.0357 gm sample
4. A mixture of CO and CO2 when treated with I2O5, gives of the product immersed in 100 ml of 10.07 centimolar
I2 vapour according to following equation : acidified potassium iodide solution, reaction according
as following equation.
5CO + I2O5  5CO2 + I2
2I- + 2UF6-  2UF4 + I2 + 4F-
I2 vapour was separated and treated with HClO4 and
resultant HIO4 required 0.001 moles of glycerol The iodine produced was titrated with 14.80 ml of
(CH2OHCHOHCH2OH) for complete oxidation. 14.94 centimolar sodium thiosulphate solution. What %
of the original mixture oxidized to +5 oxidation state ?
After treatment with I2O5 and removal of I2, the mixture
was treated with excess of 0.1 N NaOH solution. Finally, 8. 1.249 g of sample of pure BaCO3 and impure CaCO3
this solution required 20 ml of 1 N HCl to reach the end containing some CaO was treated with dil. HCl and it
point using phenolphthalein as indicator followed by evolved 168 ml of CO2 at N.T.P. From this solution,
st
using methyl orange as indicator after 1 end point and BaCrO4 was precipitated filtered and washed. The
10 ml of further HCl was consumed. Calculate the precipitate was dissolved in dil. H2SO4 and diluted to
volume of NaOH used and % mole of CO2 in original 100 ml. 10 ml of this solution when treated with KI
mixture. solution liberated iodine which required exactly 20 ml
2-
of 0.05N Na2S2O3. Calculate the percentage of CaO in
5. Calculate the amount of SeO3 in solution on the basis the sample.
of following data. 20 ml of M/60 solution of KBrO3 was
2-
definite volume of SeO3 solution. The bromine evolved 9. Chile salt peter a source of NaNO3 also contains NaIO3
was removed by boiling and excess of KBrO3 was back can be used as source of iodine produced in the
titrated with 5.1 ml of M/25 solution of NaAsO2. The following reactions :
reactions are given below :
- - - + 2-
Step 1 : IO3 + 3HSO3  I + 3H + 3SO4
2-
(a) SeO3 + BrO3- + -2
+ H  SeO4 + Br2 + H2O
- - +
Step 2 : 5I + IO3 + 6H  3I2 + 3H2O
(b) BrO3- + AsO2- + H2O  Br- + AsO4-3 + H+
 One litre of chile salt peter solution containing 5.80 gm (a) 4.1 ml (b) 8.2 ml
NaIO3, is treated with stoichiometric quantity of
NaHSO3. Now additional amount of same solution is (c) 10.2 ml (d) 4.5 ml
added to the reaction mixture to bring about the
5. Which of the following is/are redox reactions(s) ?
second reaction. How many grams of NaHSO3 are
required in step 1 and what additional volume of chile (a) BaO2 + H2SO4  BaSO4 + H2O2
salt peter must be added in step 2 to bring in complete
-
conversion of I to I2 ? (b) 2BaO + O2  2BaO2

10. Calculate the amount of calcium oxide required when it (c) 2KClO3  2KCl + 3O2
reacts with 852 g of P4O10.
(d) SO2 + 2H2S  2H2O + 3S
3
11. The formula weight of an acid is 82.0. 100 cm of a
solution of this acid containing 39.0 g of the acid per 6. In the reaction,
3
litre were completely neutralized by 95.0 cm of 2- - - -
3Br2 + 6CO3 + 3H2O  5Br + BrO3 + 6HCO3
aqueous NaOH containing 40.0 g of NaOH per litre.
What is the basicity of the acid ? (a) bromine is oxidized and carbonate is reduced

Solved Problems :- (b) bromine is oxidized

1. 10 gm of a sample of SO2Cl2 containing insoluble (c) bromine is reduced

impurities was dissolved in 200 ml of water (d = 1
gm/cc). The resulting solution was titrated against (d) it is disproportionation reaction or autoredox
Barium chloride solution and the end point of white change.
precipitate was formed. Precipitate was filtered off and
7. During the titration of a mixture of Na2CO3 and NaHCO3
filtrate was diluted to 5 times. 50 cc of diluted solution
against HCl,
was required 0.04 N, 100 cc NaOH for half
neutralization. What is the percentage purity of the (a) phenolphathelein is used to detect the first end
original solution. What is the mass of this white ppt ? point

Objective Questions :- (b) phenolphthalein is used to detect the second end

2- 2- 2- point
1. In basic medium, CrO4 oxidizes S2O3 to form SO4 and
itself changes to Cr(OH)4-. How many ml of 0.154 M (c) methyl orange is used to detect the second end
2-
CrO4 are required to react with 400 ml of 0.246 M point
2-
S2O3 ?
(d) methyl red is used detect the first end point.
(a) 200 ml (b) 156.4 ml
COMPREHENSION TYPE QUESTIONS :-
(c) 170.4 ml (d) 190.4 ml
Read the paragraph carefully and answer the following
2. 20 ml of 0.2 M Al2(SO4)3 is mixed with 20 ml of 0.6 M questions :
3+
BaCl2. Calculate of Al ion in the solution will be
The process of addition of the known solution from the
(a) 0.2 M (b) 10.3 M berette to the measured volume of solution of the
substance to be estimated until the reaction between
(c) 0.1 M (d) 0.25 M
the two is just complete is termed as titration.
3. The number of moles of KMnO4 that will be required to
Titration is classified in following two categories :
react with one mol of ferrous oxalate is
(a) Acid-base titration
(a) 3/5 (b) 2/5
(b) Redox titration
(c) 4/5 (d) 1
The acid-base titration is further classified in following
4. What volume of 0.1 M KMnO4 is needed to oxidize 100
three categories :
mg of FeC2O4 in acid solution ?
(a) Simple titration
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 (b) Back titration In double titration mainly two indicators, i.e.,
phenolphthalein (HPh) and methyl orange (MeOH) are
(c) Double titration used. Suppose, for complete neutralization of Na2CO3,
NaHCO3 and NaOH, the amount of standard HCl
In simple titration, we can find the concentration of
required is a, b and c ml. The titration of the mixture
substance with the help of another substance with
may be carried by two different methods as
known concentration, which can react with it.
summarizes below :
Back titration is used to calculate % purity of a sample.

1. 150 ml of N/10 HCl is required to react completely with Matrix-Match Type Questions :-
1.0 g of a sample of limestone. Calculate the percentage
purity of CaCO3. 1. Match the following

(a) 65% (b) 25% Column-I-Acid Column-II-Basicity, Equivalent wt.

(a) H3PO3 (p) Dibasic oxidizing agent
(c) 75% (d) 85% (b) H2SO4 (q) Dibasic reducing agent
(c) H 2S (r) Eq. wt. mol. Mass/2
(d) (s) Eq. wt. = mol. mass

2. An aqueous solution of 6.3 g of oxalic acid dehydrate is

made upto 250 ml. The volume of 0.1 N NaOH required
to completely neutralized 10 ml of this solution is Answer 2, 3 and 4 by appropriately matching the information
given in the three columns of the following table.
(a) 40 ml (b) 20 ml
Column I Column-II Column-III
(c) 10 ml (d) 4 ml (I) P2H2PH3+P4H2 (i) Disproportionation (P) E=3M/4
- -
(II) I2I +IO3 (ii) Intramolecular (Q) E=3M/5
redox
- 2+
(III) MnO4 +Mn +H2O (iii) Intermolecular (R) E=15M/2
3. A solution contained Na2CO3 and NaHCO3. 15 ml of the  Mn3O4+H
+
redox 6
solution required 5 ml of N/10 HCl for neutralization (IV) H3PO2PH3+H3PO3 (iv) Non-redox (S) E=5M/6
using phenolphthalein as an indicator. Addition of reaction
methyl orange required a further 15 ml of the acid for
neutralization. The amount of Na2CO3 present in the 2. The only correct combination is
solution is
(a) (I)(i)(S) (b) (I)(iv)(S)
(a) 21.2 g (b) 2.12 g
(c) (I)(i)(Q) (d) (III)(ii)(P)
(c) 0.212 g (d) 4.24 g
3. The only incorrect combination is

(a) (I)(i)(S) (b) (II)(i)(Q)

(c) (IV)(i)(P) (d) (III)(ii)(R)

4. The only correct combination in which element in their ANSWER KEY
respective elementary state is taken.
Subjective Questions :-
(a) (III)(iii)(R) (b) (IV)(i)(P)
1. 54%
(c) (II)(i)(Q) (d) (I)(i)(S)
Objective Questions :-
Single Integer Answer Type Questions :-
1. (C) 2. (A)
1. What mass of H2SO4 could be produced (in kg) in the
process given below if 5.52 kg of FeS2 is used 3. (A) 4. (A)

FeS2(s) + O2(g)  Fe2O3(s) + SO2(g) 5. (BCD) 6. (BCD)

SO2(g) + O2(g)  SO3(g) 7. (AC)

SO3(g) + H2SO4(l)  H2S2O7(l) Comprehension Type Questions :-

H2S2O7(l) + H2O(l)  H2SO4 (aq) 1. (C) 2. (A)

(At. wt. of Fe = 56, S = 32) 3. (B)

2. 0.45 g of the acid of molecular mass 90 was neutralized Matrix Matching Type Questions :-
by 20 mL of 0.5 N caustic potash. What is basicity of the
1. A-qrs, B-prs, C-qrs, D-qrs 2. (A)
acid ?
2-
3. (D) 4. (C)
3. 2 mole of Fe2C2O4 is oxidized by x mole of Cr2O7 in
acidic medium, x is Single Integer Answer Type Questions :-

4. The volume (in litre) of Cl2 at STP react with 10 g Fe to 1. (9) 2. (2)
produce FeCl3 will be
3. (1) 4. (6)
5. Find the weight of NaOH in its 50 milli equivalents.
5. (2) 6. (8)
6. How many milliliter of 0.5 M H2SO4 are needed to
dissolved 0.5 g of copper II carbonate ? Numerical Value Answer Type Questions :-

Numerical Value Answer Type Questions :- 1. 0.972 2. 89.25%

1. 50 litres of water containing Ca(HCO3)2 when converted 3. 8.09

into soft water required 22.2 g Ca(OH)2. Calculate the
amount of Ca(HCO3)2 present per litre of hard water.

2. 1.2 g of a commercial sample of oxalic acid was

dissolved in 200 ml of water. 10 ml of this sample
required 8.5 ml of N/10 KMnO4. Calculate % purity of
sample.

3. How many milliliters of 0.5 M H2SO4 are needed to

dissolve 0.5 g of copper(II) carbonate ?

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