Wat 9
Wat 9
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 14 – 18) Questions with Integer Answer Type 3 0 5 15
Total 18 62
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 23) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 24 – 31) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 32 – 36) Questions with Integer Answer Type 3 0 5 15
Total 18 62
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 41) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 42 – 49) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 50 – 54) Questions with Integer Answer Type 3 0 5 15
Total 18 62
Jr.IIT_*CO SC Page 2
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PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. By applying a force F (3 xy 5 z ) ˆj 4 zk a particle is moved along the path y x 2 from
point (0,0,0) to the point (2,4,0). The work done by the F on the particle is (all units
are in SI system)
2. The components of a force acting on a particle are varying according to the graphs
shown. When the particles moves from (0, 5, 12) to (4, 20, 0).Then the work done by
this force is:
Fx in N Fy in N FZ in N
370
20
10
12
15 z in m
y in m
X in m
16
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4. The block A and B shown in fig. have masses MA = 5 kg and MB = 4 kg. The system
is released from rest. The speed of B after A has travelled a distance 1 m along the
incline is (Acceleration due to gravity =g) (All surfaces are smooth and speeds are in
SI system)
3 3 g g
A) g B) g C) D)
2 4 2 3 2
A) B)
C) D)
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SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
6. A point moves with deceleration along the circle of radius R so that at any moment of
time its tangential and normal accelerations are equal in magnitude. At the initial
moment t = 0, the velocity of the point is V0. The velocity of point will be : (S is the
distance travelled)
V0
A) V at t second B) V V0 e S / R after S metre
V0t
1
R
V0
C) V V0 e R / S after S metre D) V at t second
V0t
1
2R
7. A very long uniform helix is made of thin metal wire. The axis of helix is vertical. A
small bead begins to slide down the fixed helix starting from rest. Considering friction
between bead and wire of helix to be nonzero, which of the following statements is/
are true as long as bead moves on helix. ( g is acceleration due to gravity )
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8. A smooth track in the form of a quarter circle of radius 6m lies in the vertical plane.
A particle moves from P1 to P2 under the action of forces F1 , F2 and F3 . Force F1 is
always toward P2 and always 20N in magnitude. Force F2 is always acts horizontally
and is always 30N in magnitude. Force F3 always acts tangentially to the track and is
of magnitude 15N. Select the correct alternative(s) :
6m p2
o
F3
F1
6m
F2
p1
A) Work done by F1 is 120J B) Work done by F2 is 180J
C) Work done by F3 is 45 J D F1 is conservative in nature
9. One of the forces acting on a particle is conservative, then
A) the work done by it is zero when the particle moves exactly in one round in any
closed path
B) the work done by it is equal to change in kinetic energy of particle
C) it obeys newton’s second law
D) its work depends as the end points of the path followed but not as the path
followed
10. A particle of mass m is initially at rest at the origin .It is subjected to a force and starts
moving along the x-axis. Its kinetic energy with time varies as dK / dt t , where is a
positive constant of appropriate dimension and t is time. Which of the following
statements is (are ) true?
A) The force applied on the particle is constant
C) The distance of the particle from the origin increases linearly with time
Jr.IIT_*CO SC Page 6
Narayana IIT Academy 26-07-20_Incoming.Jr.IIT_*CO-SC _JEE-ADV_WAT-9_Q’P
11.
Consider a force F yi x 2 j N (where x and y are in metre) acting on a particle. The
particle displaces from the origin ‘O’ to a point P 10 m,10 m along three different paths
– OLP, OMP and OP.
Y
M P 10 m ,10 m
O X
L
1
12. Two blocks A and B each of mass kg is connected by a massless inextensible string
2
and kept on horizontal surface. Coefficient of friction between block and surface is
shown in figure. A force F = kt(where k = 1 N/s and t is time in seconds) applied on A.
Then (g= 10 m/s2)
Jr.IIT_*CO SC Page 7
Narayana IIT Academy 26-07-20_Incoming.Jr.IIT_*CO-SC _JEE-ADV_WAT-9_Q’P
13. On a train moving along east with a constant speed v, a boy revolves a bob with string
of length l on smooth surface of a train, with equal constant speed v relative to train.
Mark the correct option(s). ( m is the mass of bob )
mv 2
C) Tension in string is at all the moments
l
D) Minimum speed of bob is zero in ground frame
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
14. A boy runs on a circular path of radius R 28m with a constant speed u 4m / s .
Another boy starts from the centre of the path to catch the first boy. The second boy
always remains on the radius connecting the centre of the circle and the first boy and
maintains magnitude of his velocity a constant V 4m / s .If the time of chase is (10+x)
15. The velocity and acceleration vectors of a particle undergoing circular motion are
2
v 2iˆ m/s and a 2iˆ 4 ˆj m/s respectively at an instant of time. Find the radius of
the circle in metres.
16. In figure, shown all the surfaces are frictionless, and mass of the block is m = 100g.
The block and the wedge are held initially at rest. Now the wedge is given a horizontal
acceleration of 10 ms 2 by applying a force on the wedge, so that the block does not
slip on the wedge. Then find the work done in joules by the normal force in ground
frame on the block in 1s.
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17. A chain AB of length equal to the quarter of a circle of radius r is placed on a smooth
fixed hemisphere as shown in figure. When it is released, it starts falling. The velocity
n
of the chain when end B falls off from the hemisphere is gr . The value of
2
18. As shown in the figure ,a person is pulling a mass 2kg from ground on fixed rough
surface upto the top of surface with the help of a light inextensible string. The work
done in joule by tension in the string is 10x, if height of the surface is 1m from
ground, length of base of the surface is 2.5m and friction coefficient is 0.4. Find the
value of x. Assume that the block is pulled with negligible velocity . (assume g=10 SI
units)
Jr.IIT_*CO SC Page 9
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CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19. S will be positive for the reaction
A) 2H2 (g) O2 (g) 2H2O(g) B) 2NO2 (g) 2N2O4 (g)
20. 3 moles of a diatomic gas are heated from 127 °C to 727 °C at a constant pressure of 1
atm. Entropy change is (log 2.5 = 0.4)
C D S(A
C) 50 eu
S(C
D) 30 eu
A B S(B
D) 20 eu
22. In which of the following cases, entropy of case I is larger than that of corresponding
case II?
case I case II
A) NO2 g N2O4 g
D) N2 g at 1 bar, TK N2 g at 5 bar, TK
Jr.IIT_*CO SC Page 10
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23. The enthalpy of neutralization of a weak mono protic acid, HA in its 1 M solution
with a strong mono acidic base is -55.95 kJ/mol. If the unionized acid requires 1.4
kJ/mol heat for its complete ionization and enthalpy of neutralization of the strong
monobasic acid with a strong mono acidic base is -57.3 kJ/mol. Then % ionization of
the weak acid in a molar solution is
A) 1.2 % B) 3.57 % C) 6.07 % D) 12.01 %
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
24. Benzene and naphthalene form an ideal solution at room temperature. For this process,
the true statement(s) is (are)
A) G is positive B) S(System) is positive
25. Consider the following reversible processes being performed on 5 moles of argon
26. For the reaction, A = B, H = 4 kcal mol–1 and S = 10 cal mol–1 K–1. Reaction will
27. For spontaneous adsorption of gas on a solid surface, which of the following is/are
correct?
A) H 0 B) S 0 C) H 0 D) S 0
Jr.IIT_*CO SC Page 11
Narayana IIT Academy 26-07-20_Incoming.Jr.IIT_*CO-SC _JEE-ADV_WAT-9_Q’P
28. Which of te following statements are correct
A) Expansion work for a gas into vacuum is equal to zero
B) 1 mole of a gas occupying 3 lit on expanding to 15 lit at constant pressure of 1 atm
does expansion work 1.215 kJ
C) The S for solid liquid is small in comparison with S for liquid gas for a
particular substance
V1
D) G 2.303 nR log (at constant temperature for an ideal gas when there is no non-
V2
expansion work)
29. Which of the following is/are correct
G G G G
A) V B) S C) S D) V
P T T P T P T T
A) When the entropy change of the system and the entropy change of the surroundings
are added, the sum is always positive.
B) The entropy in isolated system, with P – V work only, is always maximized at
equilibrium.
C) During a spontaneous process, gibbs free energy change will always decrease
irrespective of the changes in temperature and pressure.
D) Phase change of a substance at a constant temperature is an isoentropic process.
31. Identify the true statement(s).
A) No process is possible in which the sole result is the absorption of heat from a
reservoir and its complete conversion into work.
Jr.IIT_*CO SC Page 12
Narayana IIT Academy 26-07-20_Incoming.Jr.IIT_*CO-SC _JEE-ADV_WAT-9_Q’P
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
32. The melting point of a solid is 300 K & its latent heat of fusion is 600 cal mol 1 . The
entropy change for the fusion of 2 mole of the solid in cal K 1 at the same
temperature would be
33. The value of equilibrium constant for the reaction, 2 Mg ( s ) O2( g ) 2 MgO( s ) at 250C is,
34. Suppose that for a certain phase transition of a solid trsV = +1.0 cm3 mol-1 and is
independent of pressure. Then, for an increase in pressure to 3.0 Mbar from 1.0 bar,
the Gibbs energy of the transition changes by a value of (p 10q ) J / mol, what is the
value of (p + q)
35. If the entropy change in the surroundings when 1.00 mol H2O(l) is formed from its
elements under standard conditions at 298 K is ‘Y’ KJ/mol K, what is the nearest
integer to value of ‘Y’ given the enthalpy of combustion of hydrogen gas is -286
kJ/mol.
36. The molar constant-pressure heat capacity of a certain solid at 4.2 K is 0.3 J/ mol K. If
the molar entropy at that temperature is ‘Z’ J/mol K. what is the value of ‘10 Z’ ?
(Hint- when the temperature is so low, we can assume that the heat capacity varies
Jr.IIT_*CO SC Page 13
Narayana IIT Academy 26-07-20_Incoming.Jr.IIT_*CO-SC _JEE-ADV_WAT-9_Q’P
MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
37. Let O 0,0 ,P 3,4 ,Q(6,0) be the vertices of triangle OPQ .The point R inside the
triangle OPQ is such that the triangles OPR, PQR, OQR are of equal area. The point S
is such that OS = PS = QS. Then RS =
13 11 13 11
A) B) C) D)
6 12 24 24
38. In a ABC , the coordinates of B are (0,0) AB=2, ABC and the mid point of
3
BC is (2,0). The centroid of triangle is
1 3 5 1 4 3 1 4 3 1
A) , B) , C) , D) ,
2 2 3 3 3 3 3 3
x1 x 2 ........... x n y y 2 ........y n
and 1 is
n n
A) a x p b y q B) p x a q y b
C) p x p a y q D) b x p a y q
40. Given the points A(0, 4) and B(0, −4), then the equation of the locus of the point
P(x, y) such that, AP BP 6, is
x 2 y2 x 2 y2
A) 1 B) 1
7 9 9 7
x 2 y2 y2 x 2
C) 1 D) 1
7 9 7 9
41. The locus of a point P, so that the join of (-5,-1) and (3,2) subtend, a right angle at P is
A) x 2 y 2 2x 3y 13 0 B) x 2 y 2 2x 3y 17 0
C) x 2 y 2 2x y 17 0 D) x 2 y 2 4x 2y 1 0
Jr.IIT_*CO SC Page 14
Narayana IIT Academy 26-07-20_Incoming.Jr.IIT_*CO-SC _JEE-ADV_WAT-9_Q’P
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
42. Under rotation of axes through , x cos y sin P changes to X cos Y sin P
then
43. The point A divides the join of P = (-5, 1) and Q = (3, 5) in the ratio k : 1. The values
of k for which the area of ABC . Where B = (1, 5), C = (7, -2) is equal to 2 sq. Units
are
30 31
A) 7 B) 4 C) D)
4 9
44. If x, y, z , w R satisfy the following system of equations
x y z w 1 ; x 2 y 4 z 8 w 16 ; x 3 y 9 z 27 w 81 and
A) w , z B) z , y C) y , x D) z , x
1 0 a b
45. If A and A 2012 , then which of the following is/are correct?
2 1 c d
A) a = d B) a + b + c + d = 4026
C) a2 + b2 + d2 = 2 D) b = 2012
(1 x) a (1 2 x) b 1
46. If f(x) = 1 (1 x) a (1 2 x) b , where a, b being positive integers, then
(1 2 x) b
1 (1 x) a
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Narayana IIT Academy 26-07-20_Incoming.Jr.IIT_*CO-SC _JEE-ADV_WAT-9_Q’P
cos( ) sin( ) cos 2
47. The value of the determinant sin cos sin is
cos sin cos
1 a a2
48. The determinant cos(n 1)x cos nx cos(n 1)x 0 , if
sin(n 1)x sin nx sin(n 1)x
A) a = 0 B) cosx 0
1 a2
C) sin x 0 D) cos x
2a
49. P and Q are two variable points on the axes of x and y respectively such that
OP OQ a, then the locus of foot of perpendicular from origin on PQ is
A) x y x 2 y 2 axy B) x y x 2 y 2 axy
C) x y x 2 y 2 a x y D) x y x 2 y 2 axy
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
50. In a ABC If the feet of the perpendiculars from vertices to the opposite sides are
given by (0,0), (3,4), (4,3) and if the orthocentre of ABC is , such that
35
49
p q where p, q N then p-q equals
51. Let A 0, , B 2,0 ,C 1,1 be the vertices of ABC then number of integral values of
such that BAC is obtuse is
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52. Let A sin , cos sin , B cos sin , cos , C cos sin , cos sin and the locus of
49
centroid of ABC , where is a parameter is given by x 2y 2 px qy 2 then the
9
value of product pq equals
53. ABCD is a square in first quadrant in anticlockwise sense such that A lies on positive
x-axis and D lies on positive y-axis. If C = (4,10) and if centre of nine point circle of
ABC is , then equals is GIF
3
54. If Z and P , 1 is an interior point of ABC where A(0,3), B(-2,0), C(6,1) and if
the mean position of all possible points P and origin is (l,m) then the value of 6lm
equals
Jr.IIT_*CO SC Page 17
Sec: INCOMING JR.IIT_*CO SC WAT-9 Date: 26-07-20
Time: 3HRS 2016_P1 Max.Marks: 186
KEY SHEET
PHYSICS
1 D 2 D 3 C 4 C 5 B
11 AC 12 ABC 13 ACD 14 1 15 1
16 5 17 4 18 4
CHEMISTRY
19 C 20 D 21 D 22 D 23 B
29 AC 30 CD 31 ABCD 32 4 33 1
34 8 35 1 36 1
MATHEMATICS
37 D 38 C 39 D 40 D 41 C
42 AC 43 AD 44 C 45 ABC 46 AB
47 AC 48 CD 49 B 50 8 51 2
52 6 53 4 54 2
Narayana IIT Academy 26-07-20_INCOMIG JR.IIT_*COSC_JEE-ADV_WTA-9_Key&Sol’s
SOLUTIONS
PHYSICS
1. The z-component of the force and the x-component of displacement are ineffective here
2 2 5 2
Solving, we get
1 g
v
2 3
7. The component of weight in direction of velocity of bead remains constant. Since speed
increases, the the horizontal component of normal reaction keeps on increasing. Hence
friction force increases till the bead acquires terminal velocity.
8. Work done by F1 is
P2
W1 F1 cos ds
P1
1 2 t2
mv or v t
2 2 m
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Narayana IIT Academy 26-07-20_INCOMIG JR.IIT_*COSC_JEE-ADV_WTA-9_Key&Sol’s
dv
dt m
F m
(i) force is constant
(ii) speed is proportional to t
(iii) Force is constant ,so it is conservative
11.
W F.ds yi x2 j . dxi dy j
y dx x dy 2
10
WOLP WOL WLP 0 100 dy 1000 J
0
10
WOMP WOM WMP y dx 0 10 dy 100 J
0
When x 3 and y 4
W 4i 3 j . dxi dyj
4dx 3dy
WOLP WOL WLp 40 30 70 J
WOMP WOM WMP 30 40 70 J
WOP 4i 3 j . 10i 10 j 70 J
WOLP WOMP WOP
Hence, the force is conservative
12.
f L1 2, f L 2 1, F 3 kt
13. vb / t vT / g vb / g
For vb / g maximum
vbT and vT / g most be parallel
vb / g v v 2v
vb / g 2v
bob performing circular motion in frame of train
mv 2
T
l
For vb / g is minimum
vb /T and vT / g must be anti-parallel
vg / g 0
JR.IIT_*CO SC Page 3
Narayana IIT Academy 26-07-20_INCOMIG JR.IIT_*COSC_JEE-ADV_WTA-9_Key&Sol’s
14. The chasers should always maintain same ' ' as the first boy. So he has two components of velocity.
ux
Vt and Vr V
R
dx dx u 2 x2 dx
Given, Vt 2 Vl 2 u 2 and Vr , u2 2 , u dt
dt dt R x2
1 2
R
x R
Integrating R sin 1 R
0 uT , T
R u 2
15. It can be observed that component of acceleration perpendicular to velocity is
a = 4 m/s2
c
v2 ( 2) 2
radius = ac = 4 = 1 metre.
18.
Work Energy theorem
CHEMISTRY
1
20. 3(7R/2) ln (1000/400) = 80.42 JK
23. enthalpy of ionization of weak acid = 57.3 – 55.95 = 1.35
% ionization = [1-(1.35/1.4)] 100 = 3.57
25. X TO Y = 5Rln(10) = 95.7 JK 1 , X TO Z = adiabatic reversible process = 0
26. equilibrium T = 4000/10 = 400
32. = 600 / 300 = 2
33. G 0 = -2.303RTlogK = -T( S sys
0
+ S surr ) = -T (677.6-217) = T (460)
K = 10100
34. = trsV( P) = 3 105 J/ mol
35. = 286/298 = 0.96 KJ/mol K
36. = ∫ (aT3/T)dT = Cp/3 = 0.1
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Narayana IIT Academy 26-07-20_INCOMIG JR.IIT_*COSC_JEE-ADV_WTA-9_Key&Sol’s
MATHS
R is centroid .S is circumcentre . R 3, , S 3,
4 7
37.
3 8
11
RS=
24
h
38. Let A( h, k ) then cos 600 h 1
2
k
sin 60 0 k 3
2
A(1, 3)
5 3
centroid = ,
3 3
39.
40. Locus, of P is x + y − 8y + 16 − x + y + 8y + 16 = 6
On squaring, we get
x + y − 2 = x + y + 8y + 16 x + y − 8y + 16
⇒ (x + y − 2) = (x + y + 16) − (8y)
On simplification, we get − =1
41.
Transformed equation
3k 5 5k 1
A , , B = (1, 5), C = (7, -2)
k 1 k 1
9k 2 94k 217 0
( k 7)(9k 31) 0
31
k 7,
9
JR.IIT_*CO SC Page 5
Narayana IIT Academy 26-07-20_INCOMIG JR.IIT_*COSC_JEE-ADV_WTA-9_Key&Sol’s
44. Observe that are roots of
sin cos
(cos 2 cos 2 ) (1 ) cos 2
cos sin
Therefore, the given determinant is independent of for all real values of . Also,
= 1, then it is independent of and .
48. sinx(1 – 2a cosx + a2) = 0
1 a2
sin x 0 cos x
2a
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Narayana IIT Academy 26-07-20_INCOMIG JR.IIT_*COSC_JEE-ADV_WTA-9_Key&Sol’s
49. Let P , 0 Q 0,
x 2 y2
x
x 2 y2
III
ly
y
a
35 35
50. Required point = In centre = ,
10 2 10 2
70
10 2 49
35
10 2 p q 10 2 8
51.
52. Let G x1 , y1
6x 9y1
cos 1
3x1 2 cos 3sin 49
locus is x 2y 2x 3y
7
2 2
JR.IIT_*CO SC Page 7