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Kinetics

The document contains answer keys for various exercises related to chemical kinetics, including multiple-choice questions and calculations. It covers topics such as reaction rates, stoichiometric coefficients, and order of reactions. The answers are presented in a structured format, with numerical values and equations provided for clarity.

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iknowshivam74
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9 views5 pages

Kinetics

The document contains answer keys for various exercises related to chemical kinetics, including multiple-choice questions and calculations. It covers topics such as reaction rates, stoichiometric coefficients, and order of reactions. The answers are presented in a structured format, with numerical values and equations provided for clarity.

Uploaded by

iknowshivam74
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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(Physical Chemistry) CHEMICAL KINETICS

ANSWER KEY

EXERCISE #O-I
RATE OF REACTION AND STOICHIOMETRIC COEFFICIENT

1. (B) 2. (D) 3. (C) 4. (B) 5. (B) 6. (A) 7. (D)


8. (B) 9. (C) 10. (A) 11. (D) 12. (A) 13. (A) 14. (B)

15. (C) 16. (A) 17. (B) 18. (C) 19. (A) 20. (D) 21. (B)

22. (A) 23. (A) 24. (A) 25. (D) 26. (C) 27. (A) 28. (C)

29. (A) 30. (C) 31. (C) 32. (C) 33. (D) 34. (C) 35. (C)

36. (A) 37. (C) 38. (C) 39. (B) 40. (B) 41. (C) 42. (B)

43. (C) 44. (D) 45. (B) 46. (A) 47. (C) 48. (B) 49. (C)

50. (B) 51. (B) 52. (D) 53. (D) 54. (C) 55. (C) 56. (D)

57. (B) 58. (C) 59. (B) 60. (B) 61. (D) 62. (A) 63. (B)

64. (C) 65. (A) 66. (B) 67. (B) 68. (D) 69. (C) 70. (B)

71. (C) 72. (A) 73. (B) 74. (C) 75. (A)

APNI KAKSHA 58
(Physical Chemistry) CHEMICAL KINETICS

EXERCISE #S-I
1. 8.33 × 10–6 Ms–1, 0.012 atm min–1

1 d  NO 
2. (i) r = = 9 ×10–4 mol litre–1 sec–1, (ii) 36 × 10–4mol litre–1sec–1, (iii) 54×10–4 mol litre–
4 dt
1sec–1

3. (a) 4.5 × 10–3 M sec–1 (b) 3.0 × 10–3 M sec–1s

4. (a) 40.5 gm min–1 (b) 76.5 gm min–1s

dx
5. (i) = k[A][B]2, (ii) rate increases by 8 times
dt
6. rate increase by 27 times

7. (a) 0.019 mol L–1 s–1, (b) 0.037 mol L–1 s–1

8. 1/6

9. (i) 7.2 M, (ii) 10 M

10. K = 0.01 M min–1

11. 6 × 10–9 sec

12. 1.2 hr

10
13. (i) 9.994 M (ii) (iii) 5 × 106 mins
2  (2  10−6 )

14. (i) 36 min., (ii) 108 min.

15. (i) 0.0223 min–1, (ii) 62.17 min

16. t = 10 × t1/2

17. (a) 5 x 10−5 M/s (b) 4.2 x 10−5 M/s

18. 7 × 10–3 Ms–1

19. 40 month

20. 3.3 × 10–4s–1

21. 87.5 %

22. 75

23. (a) Third order, (b) r = k[NO]2[H2], (c) 8.85 ×10–3 M sec–1.

24. n = 2,

APNI KAKSHA 59
(Physical Chemistry) CHEMICAL KINETICS

ln ( (t1/2 ) 2 / (t1/2 )1 )
Order of reaction = 1 +
(
ln a o1 / a o2 )
25. First Order

26. Zero order

27. 2

28. (i) Zero order, (ii) K = 5 Pa/s

29. (i) first order (ii) k = 1.308 × 10–2 min–1 (iii) 73%

1 P3
30. k = /n
t 2(P3 − P2 )

31. r = K[(CH3)2 O], 0.000428 sec–1

32. k1 = 2.605 × 10–3 min–1

33. 0.180 atm, 47.69 sec

34. 8.44 ×10–4 sec–1

35. 3.27 × 10–3 min–1


1 r
36. k = /n
t ( r − rt )
37. 966 min

38. 0.1 min–1

 C  10 11x
39. = (e – 1)
 A  11

40. 86.625 min

41. t1/2 = 36 min.

42. 10 M

43. t = 4 min

44. 4.83 mins

45. 5 kJ mol–1
46. 13.44 kcal/mole
47. t = 20.4 minutes
48. 10.757 k cal mol–1
49. 80.65%

APNI KAKSHA 60
(Physical Chemistry) CHEMICAL KINETICS

50. (A) y + z (B) z (C) x + y + z (D) x (E) x + y (F) – y

51. – 1000

52. (a) 2 B+F → 2E; (b) A; (c) C, D; (d) rate = k [B][C]; (e) rate = k'[A][B] (f) 2.

53. k [N2O5]

54. r = K' [NO]2[Br2]


55. r = K [NO]2 [H2], where K = k2 × K1

EXERCISE # O-II
1. (AD) 2. (ABD) 3. (ABC) 4. (ABD) 5. (AD)

6. (BC) 7. (ABC) 8. (ACD) 9. (BCD) 10. (ABC)

11. (C) 12. (C) 13. (C) 14. (A) 15. (B)

16. (A) 17. (C) 18. (C) 19. (C) 20. (B)

21. (B) 22. (A) 23. A- S ; B- R ; C- P; D – Q

24. A → P,Q,S; B → P, Q,S; C → R; D → P`

25. A → P,Q; B → P; C → R,S; D → S

EXERCISE # S-II
1. 0050.00 2. Pt = 379.55 mm Hg, t7/8 = 399.96 min 3. 20 min

4. 0.537 6. 10–19 minute 7. k = 0.0327 min–1

k1 k2
8. (a) 43.46 kJmol–1, (b) 20.47 hour 9.  Eaoverall = Ea1 + Ea
k1 + k 2 k1 + k 2 2

10. Eoverall = E/3(2n+1)

EXERCISE # JEE MAINS

1. (1) 2. (C) 3. (C) 4. (02.00) 5. (4) 6. (81) 7. (300)


8. (D) 9. (14) 10. (50) 11. (A) 12. (C) 13. (D) 14. (B)
15. (D) 16. (B) 17. (C) 18. (C) 19. (A) 20. (A) 21. (B)
22. (C) 23. (D) 24. (A) 25. (C) 26. (A) 27. (C) 28. (D)
29. (C) 30. (B) 31. (A) 32. (B) 33. (B) 34. (B) 35. (A)
36. (C) 37. (C) 38. (C) 39. (C) 40. (A) 41. (C) 42. (B)
43. (A) 44. (B) 45. (A) 46. (B) 47. (A) 48. (D) 49. (D)
50. (B)

APNI KAKSHA 61
(Physical Chemistry) CHEMICAL KINETICS

EXERCISE # JEE ADVANCED

1. (5) 2. (A) 3. (BCD) 4. (A) 5. (6.75) 6. (2.303)


7. (AD) 8. (AB) 9. (BCD) 10. (B) 11. (8) 12. (B)
13. (D) 14. (9) 15. (ABD) 16. (0) 17. (A) 18. (D)
19. (A) 20. (D) 21. (D)
22. First Order, 𝟔. 𝟗𝟑 × 𝟏𝟎−𝟑 𝐦𝐢𝐧−𝟏 , 𝐭 = 𝟐 × 𝟏𝟎𝟐 𝐦𝐢𝐧, 𝐏 = 𝟗𝟓𝟎⁡𝐧𝐦
23. 𝐊[𝐀]𝟏 [𝐁]𝟎 , 𝐊 = 𝟎. 𝟓⁡𝐬𝐞𝐜.−𝟏
24. (C) 25. (C) 26. (A) 27. (D) 28. (24.096 min)
29. (D) 30. (100 kJ/moL) 31. (ABD) 32. 𝟑. 𝟒𝟒 × 𝟏𝟎−𝟑 𝐦𝐨𝐥⁡𝐋−𝟏 ⁡𝐦𝐢𝐧−𝟏

APNI KAKSHA 62

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