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EXERCISE

The document provides exercises related to the naming and structure of organic compounds, specifically focusing on halogenated benzenes, alkanes, alkenes, and functional groups. It includes tasks such as writing structures, IUPAC names, and bondline formulas for various compounds and their isomers. The exercises aim to enhance understanding of organic nomenclature and structural representation.

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2 views

EXERCISE

The document provides exercises related to the naming and structure of organic compounds, specifically focusing on halogenated benzenes, alkanes, alkenes, and functional groups. It includes tasks such as writing structures, IUPAC names, and bondline formulas for various compounds and their isomers. The exercises aim to enhance understanding of organic nomenclature and structural representation.

Uploaded by

SO S
Copyright
© © All Rights Reserved
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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EXERCISE

11

Halogenated benzenes are named as halobenzenes, for example,


chloro-, bromo-, fluoro-, and iodobenzene. Monosubstituted benzenes
can give rise to three regiomeric disubstituted benzenes. These
regiomers are named as ortho- (1,2-disubstituted), meta- (1,3-
disubstituted), and para- (1,4-disubstituted) and are abbreviated as o-,
m-, and p-, for example,

Cl Cl
Cl Cl

Cl

Cl

o-Dichlorobenzene m-Dichlorobenzene p-
Dichlorobenzene

EXERCISE
1.Write structures and IUPAC names of the following compounds.
(i) Isobutane (ii) neopentane (iii) Isopentane (iv)
n-Octane
2.Write the bondline formulae of the following alkanes.
(i) Icosane (ii) Undecane (iii) Tetraethyl methane (iv)
Tetramethyl methane
3. Write the IUPAC names of the following unbranched alkanes
having number of C-atoms.
(i) 9 (iii) (v) (vii) (ix)
20 22 40 100
(ii) 10 (iv) (vi) (viii)
21 30 50
4. Write the bondline formulae of all the isomers of C6H14 and name
them by IUPAC system.

Write the structures of the following alkyl groups.


5.

(i) Neopentyl (ii) Isohexyl (iii) Secondary butyl (iv)


Tertiary butyl
6. Write the IUPAC names of the following compounds.

7. Write the bondline structures of the following alkenyl groups.


(i) Vinyl (ii) Allyl (iii) Cyclohexenyl (iv)
Propenyl

12 STRUCTURES OF ORGANIC COMPOUNDS

8. Write the IUPAC names of the following alkenes and cyclo alkenes.
9. Write the IUPAC names of the following compounds.
a) Dimethyl acetylene
b) Vinyl acetylene
c) Diacetylene
d) Phenyl acetylene
10. Write the IUPAC names of the following compounds.

11. Write the bondline formulae of all the position isomers of the alkynes
having molecular formula C6H6 and write their IUPAC names.

12.Write the bondline formulae and IUPAC names of the following


compounds.
(i) Allene (iii) 3, 4-Nonadiene (v) 5-Allyl-1, 3-
cyclopentadiene
(ii) Isoprene (iv) 1, 2-Divinyl cyclopropane
13. Give the IUPAC names of the following dienes.
13 EXERCISE

14. Write the bondline formulae of the following functional groups.


4. Conjugated diene (x) Alkanol
5. Conjugated diyne (xi) Alkyl alkanoate
6. Conjugated enyne (xii) Alkane nitrile
7. Alkanone (xiii) gem Diol
8. Alkanal (xiv) vic-Diol
9. Alkanoic acid (xv) Alkanoic anhydride
10. Alkoxide (xvi) Enamine
11. Alkanamide (xvii) Enol
12. Alkanamine (xviii) Alkane dioic acid
15. Write the IUPAC names of the following functional groups
and arrange them with decreasing priority while writing the IUPAC
names of the compounds.

16. Write the IUPAC names of the following compounds.

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