Te ANON Scheie CLASSIFICATION OF ANIONS Reaction with dil. H,SO4 Evolve a gas CO Group | Anion: 1, Carbonate (CO.*) 2, Sulphite ($0;*) so, 3 Sulphide ($*) 1,8 4 Nitrite — (NO;) NO+0}---» NO} (Brown) S: Acetate (cH,coo”) Chacoon Vintget melt Group ii Antors | Reaction with dil, Hy SO, Reaction with cone, Hy SO, 1. | Chloride C1 el {Clp(Cotourless, Pangentyras) —“ 2. [Bromide Br- Bry (Redldisn Brown vapours) Todide I~ 1. (Violet vapours) : | Nitrate NO.” NO; (Brown. gas) 5:lOxalake COE Co, Co (buivk ffererenered Group Ii Anions: aly T] Sulphate ( SO.) No reaction No reaction 2| Phosphate (P07) No reaction No reaction Group 1 ANIONS ((C03°> S0," 6? Kips. cn. co0 4-CARBONATE S. | Experiment Observation Inference No,|- vi 1. | To the Pinelf ofa given salt, add | Colourless, odourless gas is evolved | CO; indicaicd dil. H2SO, + with brisk effervescence. (carbonate) @t03ml).. i 2 2. Vloxe 2ath:be U-tube Grd add| It turns milky due to the formation of #4*Wowpass the gas through © | CaCO;.which again may become Ist Prepared lime water, | colourless if excess of gas is passed. | COs conlivned. 1 due to the formation of soluble Ca(HCO,) | 3. | Take aboutipalf gram of the | given 4aJE add about 4toS ml of distilled water, warm and White PPT then filter, divide the filtrate (Mg.COs ) CO;* confirmed into two parts@To the first-part AW ada few drops of magnesium sulphate solution, [4 @iro the other pant add few drops | The lilacs pink COR" confirmed, | of phenolphihalein reagent, | ‘ Scanned By Camera ScannerScanned By Camera ScannerOf sali solution 5. _ACETATE (C44 C00") ot NOT Experiment Obse | the sult add Tew drops | Evolution of Ac OF dil. Hy SO, vapour recognized by its vinepar like odour Brick red color. Add (ew drops of freshly | Divide into two paris-(i). | ClsCOO7: Prepared FeCl; solution. | Brown PPT on adding | confirmed water& boiling (ii) add | .__| dil, HCl-colorless. 2 Baot 3. [Make paste of the given | Smell like that of vinegar mixture wittroxalic acid CH;COO"is in a watch glass by confirmed. adding water-Rub it and smell. 3 Sannin 4 [Take small quantity of "| salt in a test tube Add ClisCOOTis “| conc.H;S04{2ml) and —_| Pleasant fruity’smell of confitmed. heat. Add ethyl alcohol : | ester. (im)),shake pour the contents of the tube ina beaker full of water. | To the sélrmixture | addcone.l, SO, and | teat the test tube. Te the Aol Adtudion Odd. Lived Cimint °f At) otetic arid Grd both eff Cor: Now Bld Cobeium oN oiele Al ution « Sd To the whue PPT Odd dit He, Gnd Wwar-- White PPT '4 ©,04 jeep toed dit dves « : Scanned By Camera Scanneri orme (Ww Gn arereneS S -FExperiment Observation piaterence NO. | 1 [To the salt add cone. | Evolution of colourless pungent | May: be Chloride CL 14380, conc. +. | gas (HCl) 9 Z t 2. [-To Iml solution inthe test” | White PPT insolubleumniiic 7 - | tube add dil. HINO; and then . | acid:and soluble in excess Silver Nitrate (Ag NOs) ammoniurin hydroxide €Leonfirmed solution: (NH,OH) is obtained. 3. ‘Add solid potassium R dichromate to the salt mixturerand heat it with Cone, H,SOxin a test tube, Pass the evolved gas through |miaow solution ult ules NaOH i solution. Acidify this Yellow PPT (4 obtclined ~ Cbg Ly solution with acetic acid and uo - then add lead acetate soiuti ‘ | 3+ BROMIDE (Rat) S.NO. [Experiment «| Observation [Inference ] 1 To the 4aueadd cone. HySO,, Bvolution oftéddish Brown Vapouits (Brz) addition of MnO; intensifies Brown color. May be Bromide "s (Br) es Zi To Inf of salt sofutign in the_| Yellow PPT patilally soluble Ta test tube add diL HNO; and | ammonium hydroxide is obtatned, then Silver Nitrate (Ag NO) @r “confirmed solution, CChTest: Tolml of salt ae in solution add Iml of Orange colour in CClylayer (lower | By~ confirmed Carbontetra Chloride{CCl,), To this add Chlorine water or drop wise conc. HNO3 with Constant shaking of the solution, layer) is formed, Scanned By Camera Scannerperiment Observation Inference 1 | To salt add cone #280. | Evolution of Violet vapours of j 1, Addition of MnO, intensifies | May be lodide I” ely violet color. To Yellow curdy PPT of silver Saltsolutfon inthe testaube | Jodide insoluble in nitric acid | ITis eofirmed tad dil HNO) and then Silver | and ammonium hydroxide Niteite4Ag NOs) solution, (NELOH) is‘obtained. 3. CC. Test: To Iml of salt Xu x solution add Im! of : Carbontetra Chtoride Voilet color in CCl, layer lis cofirmed. (CCl). To this add Chlorine (lower layer ) is ‘formed. water or drop wise cone:, : HINO) with constant shaking ‘of the's Hution.. i. NITI (Ne Experiment Observation Inference aes | t [To the salt Evolution of Brown gas May be Nitrate NOS add conc.H; SO, and | which increase on adding heat the testtube. Copper chips or paper pellets. 2 To Imi of the salt A brown ring is formed solution add freshly above the heavier sulphuric prepared ferrous acid at the junction of the wo} ) sulphate FeSOzsolution | liquids, ‘The brown ring is in atest tube. Pourthe | [FeSO,NO]. Nitroso “NOS is confirmed cone. H2-SO, gently | Ferrous Sulphates. along the sides of the 3 test tube. aa To Iml ofthe salt A blue ring is formed at the solution in a tesctube contact of wo Liquids or, deep add Diphenylamine blue colouration is obtained. | NOs” is confirmed. ent carelislly down the side of the test tube, me hemmed. Scanned By Camera ScannerGap) U Anions e S04 paw Da Experiment Observation Inference Tothe pinch of sali, add dil, HASOy, No gas evolved COs”, SOX, S NOJ absent.” To the'ffesh pinch of sall,indd coric. H,S0, (ImL) and a warm a litte, No gas evolved Cl, Br5 1, NOG absent To the salt solution, -{ add 1-2 mL of BaCly solution. A white ppt. is formed S077 m be present To the above ppt, add cone. HCI oF cone, HNO;. ‘The ppl. is insoluble. soe confitnied Tothe'salt solution add lead acetate solution, A white ppu is formed. To the above ppt, add ammonium acetate. lulion in exce ce 2: PHOSPHATE if Tike ppt: ie dottolvedt Poy") SO,? rmty be present aaa Observation Inference” ‘the pinch of salt, add dil. 1,804, No readtioit aneino gas is cvalyed C03", NO>, SOS absent. ‘To the pinch of salt, add cone, H)SOy No sis evolved. [Cry Br, NOR: Yo the salt solution, add BaCl solution, No white pi S077 absent, To the aqueous solution add 3 mL of cone, HNO; end boil the solution, then add ammonium Molybdate solution. Canary yellow ppt, PO,**confirmed, fy salt solution add magnesia mixture and Keep the test tube White PPT appears, aside for few minutes, | * Phosplrate PO.” present and confirmed, | =|