Series SQR1P/1 SET-1 General Instructions :

Read the following instructions carefully and follow them :

àíZ-nÌ H$moS>
Q.P. Code 56/1/1 (i)
(ii)
This question paper contains 33 questions. All questions are compulsory.
This question paper is divided into five sections Section A, B, C, D and E.
amob Z§. (iii) Section A questions number 1 to 16 are multiple choice type questions. Each
narjmWu àíZ-nÌ H$moS> >H$mo CÎma-nwpñVH$m Ho$ question carries 1 mark
Roll No. _wI-n¥ð >na Adí` {bIo§ & (iv) Section B questions number 17 to 21 are very short answer type questions.
Candidates must write the Q.P. Code Each question carries 2 marks
on the title page of the answer-book.
(v) Section C questions number 22 to 28 are short answer type questions. Each
question carries 3 marks
ZmoQ> NOTE (vi) Section D questions number 29 and 30 are case-based questions. Each
(I) H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _o§ _w{ÐV (I) Please check that this question paper question carries 4 marks
n¥ð> 27 h¢ & contains 27 printed pages. (vii) Section E questions number 31 to 33 are long answer type questions. Each
question carries 5 marks
(II) H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _| (II) Please check that this question paper (viii) There is no overall choice given in the question paper. However, an internal
>33 àíZ h¢ & contains 33 questions. choice has been provided in few questions in all the sections except Section A.
(ix) Kindly note that there is a separate question paper for Visually Impaired
(III) àíZ-nÌ _| Xm{hZo hmW H$s Amoa {XE JE (III) Q.P. Code given on the right hand candidates.
àíZ-nÌ H$moS H$mo narjmWu CÎma-nwpñVH$m Ho$ side of the question paper should be
(x) Use of calculators is not allowed.
_wI-n¥ð> na {bI| & written on the title page of the
answer-book by the candidate. SECTION A
(IV) H¥$n`m àíZ H$m CÎma {bIZm ewê$ H$aZo go (IV) Please write down the serial
Questions no. 1 to 16 are Multiple Choice type Questions, carrying 1 mark
nhbo, CÎma-nwpñVH$m _| àíZ H$m H«$_m§H$ number of the question in the
each. 16 1=16
Adí` {bI| & answer-book before attempting it.
(V) (V) 15 minute time has been allotted to 1. Which one of the following first row transition elements is expected to
Bg àíZ-nÌ 15 {_ZQ >H$m
have the highest third ionization enthalpy ?
g_` {X`m J`m h¡ & àíZ-nÌ H$m {dVaU read this question paper. The
question paper will be distributed (A) Iron (Z = 26)
10.15 ~Oo {H$`m OmEJm &
10.15 ~Oo go 10.30 ~Oo VH$ N>mÌ Ho$db at 10.15 a.m. From 10.15 a.m. to (B) Manganese (Z = 25)
10.30 a.m., the students will (C) Chromium (Z = 24)
àíZ- read the question paper only and
do CÎma-nwpñVH$m na H$moB© CÎma Zht {bI|Jo & (D) Vanadium (Z = 23)
will not write any answer on the
answer-book during this period. 2. Which of the following compounds will give a ketone on oxidation with
chromic anhydride (CrO3) ?
agm`Z {dkmZ (g¡ÕmpÝVH$) (A) (CH3)2CH CH2OH

CHEMISTRY (Theory) (B) CH3CH2CH2OH

(C) (CH3)3C OH
:3 : 70 (D) CH3 CH2 CH CH3
Time allowed : 3 hours Maximum Marks : 70 |
OH
56/1/1-11 1 P.T.O. 56/1/1-11 3 P.T.O.
3. Two among the three components of DNA are -D-2-deoxyribose and a 6. The compound which undergoes SN1 reaction most rapidly is :

heterocyclic base. The third component is :

(A) Adenine

(B) Phosphoric acid

(C) Sulphuric acid

(D) Uracil 7. Acetic acid reacts with PCl5 to give :

(A) Cl CH2 COCl

4. For an electrolyte undergoing association in a solvent, the v
(B) Cl CH2 COOH
factor :
(C) CH3 COCl
(A) is always greater than one
(D) CCl3 COOH
(B) has negative value
8. The formation of cyanohydrin from an aldehyde is an example of :
(C) has zero value (A) nucleophilic addition

(D) is always less than one (B) electrophilic addition

(C) nucleophilic substitution
5. For the reaction X + 2Y P, the differential form equation of the rate
(D) electrophilic substitution
law is :
9. In the Arrhenius equation, when log k is plotted against 1/T, a straight
2d P d Y line is obtained whose :
(A) =
dt dt
A
(A) slope is and intercept is Ea.
d P d X R
(B) =
dt dt Ea
(B) slope is A and intercept is .
R
+d X d P
(C) = Ea
dt dt (C) slope is and intercept is log A.
RT
2d Y +d P Ea
(D) = (D) slope is and intercept is log A.
dt dt 2·303 R

56/1/1-11 5 P.T.O. 56/1/1-11 7 P.T.O.

10. The reaction of an alkyl halide with sodium alkoxide forming ether is 13. Assertion (A) : When NaCl is added to water a depression in freezing
known as : point is observed.
(A) Wurtz reaction Reason (R) : NaCl undergoes dissociation in water.
(B) Reimer-Tiemann reaction
(C) Williamson synthesis 14. Assertion (A) : Separation of Zr and Hf is difficult.
(D) Kolbe reaction
Reason (R) : Zr and Hf have similar radii due to lanthanoid contraction.
11. The correct order of the ease of dehydration of the following alcohols by
the action of conc. H2SO4 is : 15. Assertion (A) : The pKa of ethanoic acid is lower than that of

(A) (CH3)3C OH > (CH3)2CH OH > CH3CH2 OH Cl CH2 COOH.

(B) (CH3)2CH OH > CH3CH2 OH > (CH3)3C OH Reason (R) : Chlorine shows electron withdrawing ( I) effect which

(C) CH3CH2 OH > (CH3)2CH OH > (CH3)3C OH increases the acidic character of Cl CH2 COOH.

(D) (CH3)2CH OH > (CH3)3C OH > CH3CH2 OH

16. Assertion (A) : Aniline is a stronger base than ammonia.
12. Which functional groups of glucose interact to form cyclic hemiacetal Reason (R) : The unshared electron pair on nitrogen atom in aniline
leading to pyranose structure ?
becomes less available for protonation due to resonance.
(A) Aldehyde group and hydroxyl group at C 4
(B) Aldehyde group and hydroxyl group at C 5
SECTION B
(C) Ketone group and hydroxyl group at C 4
(D) Ketone group and hydroxyl group at C 5
17. Calculate the potential of Iron electrode in which the concentration of
2+
For Questions number 13 to 16, two statements are given one labelled Fe ion is 0·01 M.
as Assertion (A) and the other labelled as Reason (R). Select the correct o
(E Fe2+/Fe = 0·45 V at 298 K)
answer to these questions from the codes (A), (B), (C) and (D) as given
[Given : log 10 = 1] 2
below.
(A) Both Assertion (A) and Reason (R) are true and Reason (R) is the
18. Define molecularity of the reaction. State any one condition in which a
correct explanation of the Assertion (A).
(B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not bimolecular reaction may be kinetically of first order. 2
the correct explanation of the Assertion (A).
(C) Assertion (A) is true, but Reason (R) is false. 19. What happens when D-glucose is treated with the following reagents ? 1+1=2

(D) Assertion (A) is false, but Reason (R) is true. (a) HI (b) Conc. HNO3
56/1/1-11 9 P.T.O. 56/1/1-11 11 P.T.O.
20. (a) Draw the structures of major monohalo products in each of the 23. The following initial rate data were obtained for the reaction :
2NO (g) + Br2 (g) 2NOBr (g)
following reactions : 1+1=2
1 1 Initial Rate
Expt. No. [NO]/mol L [Br2]/mol L 1 1
(mol L s )
3
1 0·05 0·05 1·0 10
3
2 0·05 0·15 3·0 10
(ii)
3 0·15 0·05 9·0 10 3

OR (a) What is the order with respect to NO and Br2 in the reaction ?

(b) Give reasons for the following : 1+1=2 (b) Calculate the rate constant (k).

(c) Determine the rate of reaction when concentration of NO and Br2

(i) Grignard reagent should be prepared under anhydrous
are 0·4 M and 0·2 M, respectively. 1+1+1=3
conditions.

24. (a) Write the formula for the following coordination compound :
(ii) Alkyl halides give alcohol with aqueous KOH whereas in the

presence of alcoholic KOH, alkenes are formed. Potassium tetrahydroxidozincate (II)

(b) Arrange the following complexes in the increasing order of

21. Write the chemical equation when : 1+1=2 conductivity of their solution :

(a) Butan-2-one is treated with Zn(Hg) and conc. HCl. [Cr(NH3)5Cl]Cl2, [Cr(NH3)3Cl3], [Cr(NH3)6]Cl3

(b) Two molecules of benzaldehyde are treated with conc. NaOH. (c) Identify the type of isomerism exhibited by the following complexes :

(i) [Co(NH3)5NO2]2+
SECTION C 1 1
(ii) [Co(en)3]Cl3 1+1+( + ) = 3
2 2

22. When a certain conductivity cell was filled with 0·05 M KCl solution, it
25. (a) Which of the following is an allylic halide ?
has a resistance of 100 ohm at 25ºC. When the same cell was filled with
(i) CH3 CH = CH Br
0·02 M AgNO3 solution, the resistance was 90 ohm. Calculate the
(ii) CH2 = CH CH CH3
conductivity and molar conductivity of AgNO3 solution. 3 |
(Given : Conductivity of 0·05 M KCl solution = 1·35 10
2 1 1
ohm cm ) Br

56/1/1-11 13 P.T.O. 56/1/1-11 15 P.T.O.

 (b) Out of chlorobenzene and 2,4,6-trinitrochlorobenzene, which is SECTION D
more reactive towards nucleophilic substitution and why ?
The following questions are case-based questions. Read the case carefully and
(c) Which isomer of C4H9Cl has the lowest boiling point ? 3 1=3
answer the questions that follow.

26. (a) Write the mechanism of the following reaction :

29. Batteries and fuel cells are very useful forms of galvanic cell. Any battery
H or cell that we use as a source of electrical energy is basically a galvanic
CH3CH2OH CH2 = CH2
443 K
cell. However, for a battery to be of practical use it should be reasonably
(b) Write the main product in each of the following reactions : light, compact and its voltage should not vary appreciably during its use.
a) B2 H6 There are mainly two types of batteries primary batteries and
(i) CH3 CH2 CH = CH2
b) 3H 2O2 / OH
secondary batteries.

In the primary batteries, the reaction occurs only once and after use over

(ii) a period of time the battery becomes dead and cannot be reused again,
1 2=3 whereas the secondary batteries are rechargeable.

Production of electricity by thermal plants is not a very efficient method

27. Answer the following : (any three) 3 1=3
and is a major source of pollution. To solve this problem, galvanic cells
(a) What is peptide linkage ?
are designed in such a way that energy of combustion of fuels is directly
(b) What type of bonds hold a DNA double helix together ?
converted into electrical energy, and these are known as fuel cells. One
(c) Which one of the following is a polysaccharide ? such fuel cell was used in the Apollo space programme.
Sucrose, Glucose, Starch, Fructose
Answer the following questions :
(d) Give one example each for water-soluble vitamins and fat-soluble
(a) How do primary batteries differ from secondary batteries ? 1
vitamins.
(b) The cell potential of Mercury cell is 1·35 V, and remains constant
28. Compound (A) (C6H12O2) on reduction with LiAlH4 gives two compounds
during its life. Give reason. 1
(B) and (C). The compound (B) on oxidation with PCC gives compound (D)
which upon treatment with dilute NaOH and subsequent heating gives (c) Write the reactions involved in the recharging of the lead storage

compound (E). Compound (E) on catalytic hydrogenation gives compound battery. 2

(C). The compound (D) is oxidized further to give compound (F) which is
OR
found to be a monobasic acid (Molecular weight = 60). Identify the
1 (c) Write two advantages of fuel cells over other galvanic cells. 2
compounds (A), (B), (C), (D), (E) and (F). 6 =3
2
56/1/1-11 17 P.T.O. 56/1/1-11 19 P.T.O.
 SECTION E
30. The Valence Bond Theory (VBT) explains the formation, magnetic
31. (a) (i) At the same temperature, CO2 gas is more soluble in water
behaviour and geometrical shapes of coordination compounds whereas
than O2 gas. Which one of them will have higher value of
for coordination compounds is based on the KH and why ?
effect of different crystal fields (provided by ligands taken as point (ii) How does the size of blood cells change when placed in an
charges), on the degeneracy of d-orbital energies of the central metal aqueous solution containing more than 0·9% (mass/volume)

atom/ion. The splitting of the d-orbitals provides different electronic sodium chloride ?

arrangements in strong and weak crystal fields. The crystal field theory (iii) 1 molal aqueous solution of an electrolyte A2B3 is 60%

attributes the colour of the coordination compounds to d-d transition of ionized. Calculate the boiling point of the solution. 1+1+3=5

the electron. Coordination compounds find extensive applications in (Given : Kb for H2O = 0·52 K kg mol 1)

metallurgical processes, analytical and medicinal chemistry. OR

Answer the following questions : (b) (i) The vapour pressures of A and B at 25ºC are 75 mm Hg and
25 mm Hg, respectively. If A and B are mixed such that the
(a) What is crystal field splitting energy ? 1
mole fraction of A in the mixture is 0·4, then calculate the
3+ mole fraction of B in vapour phase.
(b) Give reason for the violet colour of the complex [Ti(H2O)6] on the

basis of crystal field theory. 1 (ii) Define colligative property. Which colligative property is
preferred for the molar mass determination of
3+ 2
(c) [Cr(NH3)6] is paramagnetic while [Ni(CN)4] is diamagnetic.
macromolecules ?
Explain why. [Atomic No. : Cr = 24, Ni = 28] 2
(iii) Why are equimolar solutions of sodium chloride and glucose
not isotonic ? 2+2+1=5
OR

3
(c) Explain why [Fe(CN)6] is an inner orbital complex, whereas 32. Answer any five questions of the following : 5 1=5
3+
[Fe(H2O)6] is an outer orbital complex. 2 (a) N,N-diethyl-benzenesulphonamide is insoluble in alkali. Give reason.

[Atomic No. : Fe = 26] (b) Aniline does not undergo Friedel-Crafts reaction. Why ?

56/1/1-11 21 P.T.O. 56/1/1-11 23 P.T.O.

 (c) Write a simple chemical test to distinguish between methylamine (b) (i) Out of Cu2Cl2 and CuCl2, which is more stable in aqueous
and aniline. solution and why ?

(d) Write the chemical reaction involved in Gabriel phthalimide (ii) Write the general electronic configuration of f-block
synthesis. elements.

(e) How will you convert aniline to p-bromoaniline ? (iii) Predict which of the following will be coloured in aqueous

(f) Complete the following reaction : solution and why ?

3+ 3+ 2+
Sc , Fe , Zn
[Atomic number : Sc = 21, Fe = 26, Zn = 30]

(iv) How can you obtain potassium dichromate from sodium

(g) Write the structures of A and B in the following reaction :
chromate ?

(v) Why do transition metals and their compounds show

NH3 Br2 + NaOH
A B catalytic activities ? 5 1=5

33. (a) (i) Account for the following :

(1) The melting and boiling points of Zn, Cd and Hg are low.
4 2+
(2) Of the d species, Cr is strongly reducing while
3+
Mn is strongly oxidizing.
o 2+
(3) E value of Cu /Cu is + 0·34 V.

(ii) Complete and balance the following chemical equations :

heat
(1) KMnO4
+
(2) Cr2O72 + 6 I + 14 H 3+2=5

OR
56/1/1-11 25 P.T.O. 56/1/1-11 27 P.T.O.