06-10-2024

6001CJA10102124SRG09 JA

PART-1 : PHYSICS

SECTION-I (i)

1) There are nine 2 F capacitors, two 1 F capacitors and one 4 F capacitor in the circuit shown

in the Figure. Find charge on 'R’ capacitor

(A)
(B)
(C)
(D)

2) A body of mass 2 gm has specific heat capacity 0.25 cal/gm-°C and surface area 30 cm2. It is kept
in an enclosure which is maintained at temperature 127°C. Body is being supplied heat at rate 2
watt. If temperature of body is 27°C and its absorptive power is 0.5. Determine the rate at which its
temperature is changing (in K/s) at the given instant. (Stefan’s constant is

(A) 0.81
(B) 1.64
(C) 8.1
(D) 16.5

3) In the circuit shown in the Figure is under steady state calculate the quantity of charge that flows

through the switch after it is closed.

(A)
(B)
(C)
(D)

4) AOB is a right angled isosceles triangle with sides in xy plane. It is carrying

current i as shown. The magnetic induction at the point P(0, 0, a)

(A)
Due to current in BA is

(B)
Due to current in BA is

(C)
Due to current in BA is

(D)
Due to current in BA is

SECTION-I (ii)

1) L is a smooth conducting loop (zero resistance) of radius = 1.0 m & fixed in a horizontal plane. A
conducting rod (zero resistance) of mass m = 1.0 kg and length slightly greater than hinged at the
centre of the loop can rotate in the horizontal plane such that the free end slides on the rim of the
loop. There is a uniform magnetic field of strength B =1.0 T directed vertically downward. The rod is
rotated with angular velocity = 1.0 rad/s and left. The fixed end of the rod and the rim of the loop
are connected through a battery of e.m.f. E, a resistor of resistance R = 1.0 , and initially
uncharged capacitor of capacitance C = 1.0 F in series. (neglect internal resistance of the battery)

The time dependence of e.m.f. E such that the current I0 = 1.0 A in the circuit is constant, is
(A)
 The time dependence of e.m.f E is such that the current I0 = 1.0 A in the circuit is constant,
(B)
then power delivered by the battery increases linearly with time.
The time dependence of e.m.f. E is such that the current I0 = 1.0 A in the circuit is constant,
(C)
then the energy supplied by the battery by the time rod stops is .
The time dependence of e.m.f. E is such that the current I0 = 1.0 A in the circuit is constant,
(D)
then energy supplied by the battery by the time rod stops is .

2) Two plane mirrors, a source S of light, emitting wavelengths of

and a screen are arranged as shown in figure. The angle shown is 0.05 radian and distance a and
b are 1 cm and 38 cm respectively. Consider interference of reflected light only.

(A) The fringe width of interference pattern formed on screen by the wavelength light is
112 micrometer.

(B) The fringe width of interference pattern formed on screen by the wavelength Light is 82
micrometer.
The distance between two black lines which are nearest to the central bright fringe is 560
(C)
micrometer.
The distance between two black lines which are nearest to the central bright fringe is 280
(D)
micrometer

3) In each of the following diagrams, the magnetic field in the circular region is into the plane of the
paper and is increasing with time. Four different shaped metallic conductors 'PQR' are placed as
shown. The end P will be more positively charged compared to R in: (Q is the centre of the circular

region in fig (i) and (ii)).

(i) (ii) (iii) (iv)

(A) (i)
(B) (ii)
(C) (iii)
(D) (iv)

SECTION-I (iii)
1) Use figure i for options P and Q in column I
Figure i

Use figure ii for options R and S in column I

Figure ii

Column -
Column - I
II

The wave is propagating in positive X direction. The

magnetic field through the small rectangle at position x
is shown at an instant. Here magnetic field is directed
P in negative Z-direction as shown in figure (i). Rate of 1
change of magnitude of magnetic field with respective
time is positive . Then at this instant at x
position will be

The wave is propagating in positive X direction. The

magnetic field through the small rectangle at position x
is shown at an instant. Here magnetic field is directed
Q in negative Z-direction as shown in figure (i). Rate of 2
change of magnitude of magnetic field with respective
time is positive . Then at this instant at x
position will be

R 3
In figure (ii) at given instant is

S 4 <0
In figure (ii) at given instant is

5 =0
(A) P → 2;Q → 2;R → 4;S → 4
(B) P → 2;Q → 4;R → 4;S → 4
(C) P → 2;Q → 2;R → 1;S → 1
(D) P → 4;Q → 4;R → 2;S → 2

2) For the circuit shown in figure, ohm, ohm, micro

farad, and henry. The electromotive force of the battery is E = 10 volt. The
voltmeter connected in circuit is an ideal voltmeter. Initially the switch is closed and the system is
under steady state. Key opened at t = 0.

Column I Column II

Reading of voltmeter at steady state (just before t=0)

P 1 10
is

Reading of voltmeter just after key opened (just after

Q 2 100
t=0) is

Total heat dissipated in resistor R1 after key

R 3 1000
opening.(after t=0) is H1 micro joule. then H1 is

Total heat dissipated in resistor R2 after key

S 4 50
opening.(after t=0) is H2 micro joule. then H2 is

5 20
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 2;Q → 5;R → 1;S → 4
(C) P → 1;Q → 5;R → 2;S → 3
(D) P → 1;Q → 2;R → 5;S → 3

3) A.C. circuits are shown in list-I and graph is shown in list-II match the corresponding
graph

List - I List - II

P 1

Q 2

R 3
 S 4

(A) P → 4;Q → 3;R → 1;S → 2

(B) P → 3;Q → 2;R → 1;S → 4
(C) P → 1;Q → 2;R → 3;S → 4
(D) P → 4;Q → 2;R → 3;S → 1

4) Five identical neutral metal plates each of area A are arranged parallel to each other separation
between adjacent plates are d, are arranged as shown in figure. Battery of emf V is connected to the
system as shown in fig. In List-I total amount of charges on plates are given and in List-II,
corresponding plate number is given. Match the elements of List-I with List-II and select the correct

option.

List I List II

P 1 Plate-1

Q 2 Plate-2

R 3 Plate-3

S 4 Plate-4

5 Plate-5
(A) P → 3;Q → 3;R → 1;S → 2,5
(B) P → 2,5;Q → 1;R → 3;S → 3
(C) P → 1;Q → 3;R → 3;S → 2,5
(D) P → 1;Q → 2;R → 3;S → 5

SECTION-II

1) A conducting disc of mass ‘m’ and volume ‘V’ is suspended with the help of a light spring of force
constant ‘k’ from a fixed support. Thickness of the disc is much smaller than its radius. A uniform
horizontal magnetic field of induction ‘B’ parallel to the plane of the disc is established. The disc is
slightly pulled down from equilibrium position and then released. If the time period of small

oscillations of the disc is . Find the value of .

2) Consider a planet of radius R, and assume that it rotates so that the same side always faces the
Sun. The bright side facing the Sun has a constant uniform temperature T1, while the dark side has a
constant uniform temperature T2. The orbit radius of the planet is R0, the Sun has temperature Ts,
and the radius of the Sun is Rs. Assume that outer space has zero temperature, and treat all objects
as ideal blackbodies. (R0 > > R)
In order to keep both T1 and T2 constant, heat must be continually transferred from the bright side to
the dark side. By viewing the two hemispheres as the two reservoirs of a reversible heat engine work
can be performed from this temperature difference, which appears in the form of wind power. For
simplicity, we assume all of this power is immediately captured and stored by windmills. The wind

power (Pw) is given as . Where . Find .

Note that net change in entropy in a reversible heat engine is zero.

3) A particle of mass m and charge q is projected with a velocity v0 in a viscous medium, where a
uniform and constant magnetic field of induction B exists everywhere in a direction perpendicular to
the direction of projection of the particle. The force of viscous drag on the particle is given by the
law , where b is a positive constant and is velocity of the particle. Distance travelled by the
particle during a time interval from the instant of projection until velocity vector turns by radians

is then n is. (Consider gravity free space)

4) The magnetic moment of a thin wire with a current I = 0.8 A, wound tightly on half a toroid

(figure) is . [The diameter of the cross-section of the tore is equal to d = 5.0 cm, the number
of turns is N = 500] then n is

5) In circuit (i), Inductance and resistance of the inductor are L and R respectively. In
circuit (ii), capacitance and resistance of the capacitor and resistor are C and Rc respectively.

In circuit (iii),Inductance and resistance of the inductor are L and R, capacitance

of the capacitor is C, Rc is resistance of the resistor which is connected in parallel with the capacitor
as shown in figure. R1 and R2 are resistors of resistance of 2:3 ratio. If reading of the voltmeter
connected across the terminals A and B as shown in figure is zero, find ratio of time constants of

circuit (i) and circuit (ii).

6) In a young’s double slit interference experiment, the fringe pattern is observed on a screen placed
at a distance D. The slits are separated by d (<< D) and are illuminated by coherent sources. The
central maxima is formed at the geometrical centre on the screen with respect to the slits. If at a
distance h from the central maximum on the screen the intensity is half of the maximum intensity

then the value of may be then is

PART-2 CHEMISTRY

SECTION-I (i)
1)
Which of the following is CORRECT?

(A) 'X' has 'Z' - configuration (alkene)

(B) 'P' [C2H4O] oxidises by Tollen's reagent
(C) 'Y' don't give yellow precipitate with NaOI solution
(D) All of these

2)
Find major product 'Q' from the following?

(A)

(B)

(C)

(D)

3) Iodide ion is oxidized to hypoiodite ion (IO–) by hypochlorite ion (ClO–) in basic solution as:
I–(aq) + ClO–(aq) IO–(aq) + Cl–(aq)
The following initial - rate experiments were run and, for each, the initial rate of formation of IO– was
determined.
 Initial concentration (mol/L)
Exp. no. Initial rate (mol L–1 s–1)
– – –
I ClO OH

1 0.010 0.020 0.010 12.2 × 10–2

2 0.020 0.010 0.010 12.2 × 10–2

3 0.010 0.010 0.010 6.1 × 10–2

4 0.010 0.010 0.020 3.0 × 10–2

The correct rate law for the reaction is
0
(A) r = K[I–] [ClO–] [OH–]
0
(B) r = K[I–]2 [ClO–]2 [OH–]
(C) r = K[I–] [ClO–] [OH–]
(D) r = K[I–] [ClO–] [OH–]–1

4) Find the 'INCORRECT STATEMENT' about P,

Q & R?

(A) 'P' is aromatic compound

(B) 'R' can be 2-chloro-1,3,5- trinitrobenzene
(C) 'Q' can produce CO2 gas upon reaction with (aq) NaHCO3
(D) 'Q' is less acidic than benzoic - acid

SECTION-I (ii)

1) In the given reaction scheme, P is a phenyl alkyl ether, Q is an aromatic compound; R and S are
the major products

Which of the following statements is/are CORRECT?

(A) Pure compound 'Q' is white crystalline solid

(B) (R) is more acidic than benzoic-acid
(C) Degree of unsaturation in (S) is six
(D) (R) gives 2,4,6-tribromophenol, upon reaction with bromine water

2) Reagent(s) which can be used to bring about the following transformation is(are)
(A) LiAlH4 in (C2H5)2O
(B) BH3 in THF
(C) NaBH4 in C2H5OH
(D) Raney Ni/H2 in THF

3) For a first-order reaction, [According to kinetics of reaction]

(A) The degree of dissociation is equal to (1 – e–kt), k = Rate constant

(B) A plot of reciprocal concentration of the reactant vs time gives a straight line.
(C) The time taken for the completion of 75% reaction is thrice the t1/2 of reaction.
(D) The pre-exponential factor in the Arrhenius equation of the dimension of time T–1

SECTION-I (iii)

1) Match the column

Column I Column II

P 1 Schmidt reaction

Q 2 Hofmann bromamide reaction

R 3 R – CH2 – NH – CH3

S 4 Foul smelling product

5 Isocyanate intermediate
(A) P → 3;Q → 2,5;R → 1,5;S → 4
(B) P → 1,2;Q → 2,3;R → 3,4;S → 4,5
(C) P → 1;Q → 2,4;R → 3;S → 4
(D) P → 4;Q → 3;R → 2,5;S → 1,5

2) Match column I with column II for the reaction A → products, with initial concentration of 'A'
equal to 'a' M, k = Rate constant

Column I Column II
 P 1 Half-life of zero-order reaction

Q 2 Half-life of first-order reaction

R 3 Average life of zero-order reaction

S 4 Average life of Radioactive substance

5 Half-life of second-order reaction

(A) P → 1,5;Q → 2,5;R → 3;S → 4
(B) P → 1,4;Q → 4;R → 3;S → 1
(C) P → 2;Q → 1;R → 4;S → 5
(D) P → 1,2,3;Q → 3,4;R → 1,3;S → 1,4

3) Match the following

List-I List-II

P CH3CH2OH 1 Tollen's test

Q 2 Fehling's solution test

R 3 Iodoform test

S CH3COOH 4 Br2 water test

5 NaHCO3 test
(A) P → 3;Q → 2;R → 5;S → 4
(B) P → 3;Q → 1;R → 4;S → 5
(C) P → 2;Q → 2;R → 3;S → 4
(D) P → 4;Q → 3;R → 4;S → 5

4) Match the following

List-I List-II

P 1 Cross Cannizzaro

Q 2 Mixed Claisen condensation

R 3 Benzoin condensation

S 4 Cyanohydrin formation

5 At first mixed Aldol reaction

(A) P → 3;Q → 4;R → 1;S → 5
(B) P → 4;Q → 4;R → 2;S → 1
(C) P → 4;Q → 4;R → 3;S → 2
(D) P → 3;Q → 4;R → 2;S → 1

SECTION-II

1) Mixture of 1 mole of each propene and ethene undergoes Ozonolysis, separately and the resultant
mixture contains P and Q (if 100% yield in all the reactions given below)

The value of is ____ ?

2) For a chemical reaction, An Arrhenious plot of ln (rate constant) (as 'y') against (as 'x'), if
graph is seen to have gradient of –2400 K. Then activation energy of reaction is ____ × 10 kJ mol–1
(nearest integer)

3) Consider the following reaction scheme:

Number of 'sp2' hybridised carbon atoms present in 'Z' is ____ ?

4) A sample initially contains only U-238 isotopes of uranium. With time, some of the U-238
radioactively decays into Pb-206 while the rest of it remains undisintegrated. When the age of the
sample is P × 108 years, the ratio of mass of Pb-206 to that of U-238 in the sample is found to be 7.
The value of P is _____. (Nearest Integer Value)
[Given: Half life of U-238 is 4.5 × 109 years; log 2 = 0.3010 and log 3 = 0.4771]
5)
How much larger is the molecular mass of C than P?

6) An organic cyclic compound P having molecular formula C6H6O3 gives ferric chloride test and
does not have intramolecular hydrogen bond. The compound P reacts with 3 equivalents of NH2OH
to produce oxime Q. Treatment of P with excess methyl iodide in the presence of KOH produces
compound R as the major product. Reaction of R with excess iso-butylmagnesium bromide followed
by treatment with H3O+ gives compound S as the major product.
The total number of methyl (–CH3) groups(s) in compound S is ____.

PART-3 : MATHS

SECTION-I (i)

1) The value of is

(A) 3
(B) 2
(C) 4
(D) 6

2) Let y = y(x) be the solution of the differential equation (x + 1)y' – y = e3x(x + 1)2, with .

Then, the point for the curve y = y(x) is:

(A) Not a critical point

(B) A point of local minima
(C) A point of local maxima
(D) A point of inflection

3) Let for x > 1 and g(t)dt (x > 1), then :

(A) h is increasing on (1, )

(B) h is decreasing on (1, 2) and increasing on (2, )
(C) h is decreasing on (1, )
(D) h is increasing on (1, 2) and decreasing on (2, )

4) Let y(x) be a solution of the differential equation .

If . Then which statement is false:

y(x) attains a maximum value in

(A)

y(x) is decreasing function in

(B)

(C)

(D)

SECTION-I (ii)

1) Suppose then

(A)
(B)
(C)
(D)

2) If and

let and then which of the following

options are correct (where [.] denotes greatest integer function)

(A) [P] = 18
(B) [Q] = 17
(C) P + Q > 36
(D) P + Q < 36

3) Let and be differentiable function such that

and then

(A)
(B)

(C)

(D)
 SECTION-I (iii)

1) Match the following

List - I List - II

P 1 2
Let , then for x = 4 is ( where [.]
represents greatest integer function)

Q If the area enclosed by the curves and is , where p and q 2 4

are coprime then the value of (p— q) is

R The curve that satisfies the differential equation is hyperbola 3 6

6
passing through (2, 1) with eccentricity e. The value of e is equal to

Let if
S 4 7

, then the value

of a is

5 8
(A) P → 2;Q → 3;R → 5;S → 1
(B) P → 4;Q → 2;R → 5;S → 1
(C) P → 2;Q → 4;R → 1;S → 5
(D) P → 5;Q → 1;R → 4;S → 3

2) Let and , then match the following

List - I List - II

P Area bounded by f(x) and g(x) is 1

Area bounded by y = f(x), x = -1, x

Q 2
= + 1 and x-axis is

Area bounded by y = g(x) and x-

R 3
axis

Area bounded by max {f(x), g(x)},

S 4
x-axis, x= –2 and y-axis

5
(A) P → 3;Q → 1;R → 2;S → 4
(B) P → 3;Q → 1;R → 4;S → 2
(C) P → 5;Q → 2;R → 3;S → 4
(D) P → 3;Q → 2;R → 5;S → 4

3) Let f(x) is strictly increasing and continuous function in [0, 1] and for ,

also . Local minimum value of g(x) is –1 occurs at x = a, where , then

match the following

List - I List - II

P 1 0

Q 2 2

R 3 3

S 4 –1

5 4
(A) P → 2;Q → 1;R → 3;S → 4
(B) P → 2;Q → 3;R → 2;S → 4
(C) P → 5;Q → 2;R → 2;S → 4
(D) P → 5;Q → 3;R → 3;S → 5

4) Matching the following statement

List - I List - II

P 1 5
If Then k equals

Q The area of the region defined by 1 ≤ |x –2| + |y+1| ≤ 2 is 2 –2

R 3 1
then k equal to (where [.]
denotes greatest integer function)

S 4 6
If and then f(0) is

5 9
(A) P → 3;Q → 4;R → 1;S → 2
(B) P → 2;Q → 3;R → 1;S → 4
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 2;Q → 4;R → 1;S → 3

SECTION-II

1) For any real number b, let f(b) denotes the maximum of . If

the minimum value of f(b) is p/q, where p, q are coprime then p + q is

2) Let f(2 – x) = f(2 + x) and f(4 – x) = f(4+ x). Function f(x) satisfies . If .

Find . Where [.] denotes greatest integer function.

3) Let f be a continuous and differentiable function in (x1, x2). If f(x) ≥ and

and . Then minimum value of is ______ (where [.] denotes

the greatest integer function).

4) Let a, b, c be the three distinct positive real numbers and such

that and . Then 6a + 5bc is equal to ___

5) The area bounded by curve y = x + sin x and its inverse function between the ordinates x = 0
and x = 2π is 4α find α?

6) Let the solution curve y = y(x) of the differential equation (4 + x2 )dy – 2x(x2 + 3y + 4) dx = 0
pass through the origin. Then y(2) is equal to ___
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B B B D

SECTION-I (ii)

Q. 5 6 7
A. B,C A,C B,D

SECTION-I (iii)

Q. 8 9 10 11
A. B C A D

SECTION-II

Q. 12 13 14 15 16 17
A. 3 8 1 5 1 3

PART-2 CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. B A D D

SECTION-I (ii)

Q. 22 23 24
A. A,B,C,D C,D A,D

SECTION-I (iii)

Q. 25 26 27 28
A. A C B A

SECTION-II

Q. 29 30 31 32 33 34
A. 2 2 7 143 14 12

PART-3 : MATHS
 SECTION-I (i)

Q. 35 36 37 38
A. C B A B

SECTION-I (ii)

Q. 39 40 41
A. A,B,C A,B,C A,B,C,D

SECTION-I (iii)

Q. 42 43 44 45
A. B A B A

SECTION-II

Q. 46 47 48 49 50 51
A. 7 8 1 8 2 12
 SOLUTIONS

PART-1 : PHYSICS

1)

2)

3)

Sum of charge on plate 2 and 3 before closing the switch was zero. After closing the switch the
charge on these two plates is
(in direction shown)

4)
 5)

Force of Rod B is = 1N

Torque =

Angular acceleration

emf induced in Rod

So not emf

Time at which Rod comes to rest is

6)

Distance of S from each mirror

Since is small

7)

Electric field produced by variable magnetic field is in tangential direction.

8)

9)

At steady state

Just after t = 0

10)

For R - L circuit, impendence

 12)

Let at any instant velocity of disc is v upward then force on free charge carrier say q is Bqv due to
magnetic field. This force is in horizontal direction. As thickness very small there is an electric field
develops which is cause of electric current.
Bqv=Eq
E=Bv
Force on disc
Let charge on one side of disc is q

13)

Intensity of radiation at earth surface (bright side) due to sun radiation power is
Wind power
Q1, is heat transferred from bright side per unit time, out of this Q2, is heat received by dark side per
unit time

Power received by bright side from sun (P)

So energy per unit time equation for bright side
So energy per unit time equation for dark side

Wind power

Entropy is zero as it is reversible process

14)

15)

For

16)
 17)

PART-2 CHEMISTRY

18)

19)
 20) From (2) & (3) : order with respect to I– = 1
From (1) & (3) : order with respect to ClO– = 1
From (3) & (4) : order with respect to OH– =

21)

22)

23)

NaBH4 and Raney Ni/H2 do not react with acid, ester or epoxide entities of an organic compound

27)

CH3CH2OH gives iodoform test

CH3COOH gives off CO2 from NaHCO3 solution
PhCHO gives Tollen's test but not Fehling's test
PhOH give Br2 water test result in yellow ppt.

28)
 29)

y = 1 mole
x=3
z=1

30)

K = A.e–Ea/RT

= (2400 × 8.314) × 10–3

= 20 kJ
= 2 × 10 kJ.mol–1

31)
all 'C' and 'O' atoms are sp2 hybridized

32)

Mass = Number of moles × Molar mass

t = 14.265 × 109 = 142.65 × 108 years

P = 142.65

33)
10 + 16 – 12 = 26 – 12 = 14

34)
 Number of methyl group in product(S) = 12

PART-3 : MATHS

35)

Put

36)

Clearly, is point of local minima

37)

For ne is increasing
as (g(x) > 0)
Let H(x) = 2x2 – In x

where x > 1

is increasing on

38)
y’ sinx + y cosx = x sinx

Now,

Hence y(x) is strictly increasing in

39)

put 2x = t

40)

P > 18 > Q ... (1)

also P + Q > 36 ... (2)

and

41)
when y = 1 then x = 0

h(g(g(x)) = x

h(g(x)) = f(x)

h(0) = f(f(0)) = 7
h(g(2))
f(f(g(2)) = f(2) =8 + 10+ 1=19

= (147 +5) (3 +5) = 152 x 8 =1216

42)

(R) with

Whose solution is x(1—v2) = c. When x = 2, so that

The equation of the curve is

This Is a rectangular hyperbola with eccentricity

(S)

(P)
So, given expression is 4

43)

(P)
(Q)

(R)

(S)

44)

Since g(x) has minimum value –1 at x = a

therefore and
.... (1)
Now since f(x) is increasing function in [0, 1]
for and f(x) > 0 for

(given)

Also
Now

45)

(P)
(Q) Put x -2 = x, y + 1 = y
The required region is defined by 1 ≤|x| +|y| ≤ 2

Required area =

(R)

(S)

46)

sin x = t

increasing

if
min of

47)

f(x) is periodic function with T = 4

48)

49)

Let

and
then ... (1)
and ... (2)

from (1) and (2)

or y = x or y = -x are rejected

and

50)

f(x) = x + sin x , therefore f(x) is ↑

required area
= 2(2) + 2(2) = 8

51)

(4 + x2 )dy – 2x(x2 + 3y + 4) dx

2xdx = dt

passes through origin (0, 0)