“DR.

MADHURESH CHEMISTRY
CLASSES”
Topic :- STRUCTURE OF ATOM

CLASS : XIth SUBJECT : CHEMISTRY

DATE : DPP No. : 1

1. is isoelectrionic with
2+¿¿
Mg
a) 2+¿¿ b) 2 +¿¿ c) +¿ ¿ d) 2+¿ ¿
Cu Zn Na Ca

2. The first orbital of H is represented by :

, where a 0 is Bohr ' s radius. The probability of finding the electron at a

( )
3/ 2
1 1 −r/ a
ψ= e 0

√ π a0
distance r , from the nucleus in the region dV is:
a) b) c) d)
ψ dr
2
∫ ψ 2 4 π r2 d v 2
ψ 4 π r dr
2
∫ψ d v

3. The correct statement about proton is

a) It is a nucleus of deuterium b) It is an ionized hydrogen atom

c) It is an ionized hydrogen molecules

It is an α - particle
d)

4. The energy ∆ E corresponding to intense yellow line of sodium of λ , 589 nm is:

a) b) c) d)
2.10 eV 43.37 eV 47.12 eV 2.11kcal

5. One electron volt is:

a) −19 b) −12 c) −8 d) 8
1.6 ×10 erg 1.6 ×10 erg 1.6 ×10 erg 1.6 ×10 erg

6. The quantum number that is in no way related to other quantum number is:

a) b) c) d)
l s n m

7. The de-Broglie wavelength relates to applied voltage ror α -particles as

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°
a) 12.3 A b) 0.286 ° c) 0.101 ° d) 0.856 °
λ= λ= A λ= A λ= A
√V √V √V √V

8. Calculate the wavelength (in nanometer) associated with a proton moving at 1.0 ×10 m s
3 −1

(Mass of proton ¿ 1.67 ×10

−27
kg∧h=6.63 ×10
−34
Js)
a) 0.032 nm b) 0.40 nm c) 2.5 nm d) 14.0 nm

9. The number of waves in an orbit are

a) 2 b) c) d)
n n n –1 n–2
10. Which of the following electron transition in hydrogen atom will require largest amount of
energy?
From n=1 to n=2 From n=2 to n=3
a) b)

From n=∞ to n=1 From n=3 to n=5

c) d)

11. The principal quantum number n can have integral values ranging from:
a) b) c) d)
0 ¿ 10 1¿∞ 1 ¿(n=l) 1 ¿ 50

12. Electrons will first enter into the set of quantum numbers n=5 ,l=0∨n=3 , l=2
a) b) Both possible c) d) Data insufficient
n=5 ,l=0 n=3 ,l=2

13. The relationship between the energy E1 of the radiation with a wavelength 8000Å and the
energy E2 of the radiation with a wavelength 16000Å is
a) b) c) d)
E1=6 E2 E1=2 E 2 E1=4 E 2 E1=1 /2 E2

14. Which combinations of quantum numbers n , l ,m∧s for the electron in an atom does not provide
a permissible solution of the wave equation?
a) 1 b) 1 c) 1 d) 1
3 , 2 ,1 , 3 , 1 ,1 ,− 3 , 3 ,1 ,− 3 , 2 ,−2 ,
2 2 2 2

15. What is the lowest energy of the spectral line emitted by the hydrogen atom in the Lyman series?
(h =Planck’s constant, c =velocity of light, R =Rydberg’s constant).

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a) 5 hcR b) 4 hcR c) 3 hcR d) 7 hcR
36 3 4 144

16. Which is not electromagnetic radiation?

a) Infrared rays c) Cathode rays

b)
X -rays d)
γ -rays

17. Which one of the following sets of quantum numbers represents the highest energy level in an
atom?
a) +1 b) +1
n=4 ,l=0 , m=0 , s= n=3 ,l=1 ,m=1 , s=
2 2
c) +1 d) +1
n=3 ,l=2 ,m=−2 , s= n=3 ,l=0 , m=0 , s=
2 2

18. Which consists of particle of matter?

a) Alpha rays b) Beta rays c) Cathode rays d) All of these

19. If λ 1 and λ 2 are the wavelength of characteristic X -rays and gamma rays respectively, then the
relation between them is:
a) b) c) d)
λ 1=1/ λ2 λ 1=λ2 λ 1 > λ2 λ 1 < λ2

20. Which best describe the emission spectra of atomic hydrogen?

a) A series of only four lines

b) A discrete series of lines of equal intensity and equally spaced with respect to wavelength

c) Several discrete series of lines with both intensity and spacings between lines decreasing as
the wave number increase within each series
d) A continuous emission of radiation of all frequencies

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2 - LIC, Near Kendriya Vidyalaya Sangathan, Jaleshwar Mandir
Road, Kankarbagh, Patna - 20