Class 12th JEE

PST - 4
DATE: 14/11/2024

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (A) 26. (C) 51. (C)
2. (A) 27. (D) 52. (C)
3. (A) 28. (D) 53. (A)
4. (C) 29. (C) 54. (A)
5. (D) 30. (A) 55. (B)
6. (B) 31. (C) 56. (B)
7. (C) 32. (D) 57. (B)
8. (D) 33. (A) 58. (D)
9. (B) 34. (C) 59. (D)
10. (B) 35. (B) 60. (B)
11. (C) 36. (A) 61. (B)
12. (C) 37. (C) 62. (A)
13. (B) 38. (D) 63. (D)
14. (C) 39. (C) 64. (A)
15. (D) 40. (D) 65. (D)
16. (A) 41. (D) 66. (A)
17. (A) 42. (A) 67. (A)
18. (A) 43. (C) 68. (A)
19. (D) 44. (D) 69. (C)
20. (B) 45. (C) 70. (A)
21. (75) 46. (104) 71. (6)
22. (60) 47. (309) 72. (38)
23. (100) 48. (3) 73. (2)
24. (100) 49. (3) 74. (36)
25. (800) 50. (10) 75. (12)
 HINTS AND SOLUTION
SECTION-I (PHYSICS)

1. (A) V
= a n 2 + b (V2 − V1 )
In steady state V1
3
i= A
10 6. (B)
3 PV (5.66) P1
P.d across capacitor = × 6 = 1.8V =
10 T T /2
Charge stored in capacitor = 4µF × 1.8V = 7.2 µC P
P1 =
11.32
2. (A)  P 
PV − 5.66V  
1 1 1  11.32  = PV
= + W=
24µF 40µF K × 40µF γ −1 2( γ − 1)
K = 1.5 T
TV γ−1 = (5.66V ) γ−1
2
3. (A) 2 = (5.66)γ - 1
n2 = (γ - 1) n (5.66)
γ - 1 = 0.4
γ = 1.4
PV
=W = 1.25 PV
2 × 0.4
ε0 adx
dC = 7.
(C)
d + x tan α
PVγ = constant
Ceq = ∫ dC
log P + γ log V = log C
x =a log P = – γ log V + log C
dx
= aε 0 ∫ x tan α + d 2.38 − 2.1
x =0 = γ = 1.4
1.3 − 1.1
a
aε 0 dx
= ∫ x
d 1 + tan α 8. (D)
0
d
a 9. (B)
aε 0  x 
d ∫ d
= 1 − tan α dx (By Binomial expansion) 3 5 nRT
2 × nRT − nRT =
Q=

0 2 2 2
ε 0 a 2  αa 
= 1 −  10. (B)
d  2d 
PV
P= 0
V0
4. (C)
TA = 300 K, TB = 500 K P
PV −1 = 0
Q = – 1200 J, n = 2 V0
WC → A = 0 R R
C
= −
WA → B = nR∆T = 2 × 8.3 × 200 = 3320 J γ −1 n −1
WC → A + WA – B + WB → C = – 1200 J
WB → C = – 4520 J 11. (C)
PV = nR (T0 + αV)
5. (D)
T 
V2 P = R 0 + α
a  V 
W ∫  + b dV
=
 V 
V 1

[2]
 V2 Q = i2Rt
V
W
= ∫ = RT0 n 2 + Rα(V2 − V1 )
PdV = 12 × 100 × 300
V1
V1 = 30 kJ
∆U = n CV∆T = CVα(V2 – V1) ∆U = 30 kJ
Q = W + ∆U
19. (D)
12. (C)
QP = nCP ∆T
CP = 20.7 J mol–1 K–1
CV = 12.4 J mol–1 K–1
QV = nCV ∆T
ε0 x K ( − x)ε0
C
= +
13. (B) d d
ε 
14. (C) C= 0 (vt − Kvt + K )
d
iaf
Q = 50 cal 20. (B)
W = 20 cal Potential after n times
Uf – Ui = 30 cal n
ibf  C0 
V =  V0
Q = 36 cal, ∆U = Uf – Ui = 30 cal  C + C0 
W = 6 cal 1
 V0  n
C + C0 =
 V  C0
15. (D)  
5  1 
γ=
3  V0  n 
=C C0   − 1
V
 
5 5
−1 −1 
T1 ( AL1 ) 3 = T2 ( AL2 ) 3
T1L12/3 = T2 L22/3
21. (75)
2/3
T1  L2  In steady state
= 
T2  L1 

16. (A)
Q=5J
WA → B = 10 J
WB → C = 0
In cyclic process ABCA
Wnet = Qnet I1 = 1A
10 + WC – A = 5 J
I2 = 2A
WC → A = – 5 J
VA – VB = 5 V
17. (A) Potential Energy stored in capacitor
1
V = × 6 × 25 µJ
2
= 75 µJ

22.
(60)
Capacitances of the capacitors,
∈0∈r1 A ∈0∈r2 A
P3 > P1 =C1 = , C2
W<0 t1 t2

18. (A)
[3]
 Let V be the voltage of conducting foil. As the
capacitors are connected in series, so charge on the
capacitors should be same
Q1 = Q2
24. (100)
⇒ C1 (100 –V) = C2V ( Q = CV)
∈0∈r1 A ∈0∈r AV
⇒ (100 − V ) = 2
t1 t2
3 × (100 − V ) 4 ×V
⇒ =
−3
0.5 × 10 1 × 10−3
⇒ 600 – 6 V = 4 V
⇒ V = 60 V
π
23. (100) W= 4
(20 × 103) (20 × 10–3)
qi = q f = 100 πJ
⇒ 5 × 30 = (5 + 10)V′
⇒ V′ = 10 Volt 25. (800)
So, QC = C2V ′
2

= 10 × 10 µC = 100 µC

SECTION-II (CHEMISTRY)

26. (C) 31. (C) 37. (C) 43. (C) 49. (3)
32. (D) 38. (D) 44. (D) 50. (10)
27. (D)
33. (A) 39. (C) 45. (C)
28. (D) 34. (C) 40. (D) 46. (104)
29. (C) 35. (B) 41. (D) 47. (309)
30. (A) 36. (A) 42. (A) 48. (3)

SECTION-II (MATHEMATICS)

51. (C) 52. (C)

Here equation of bisectors y
3x − 4 y + 7 12 x + 5 y − 2 B(0,1)
=±
5 13
Which give, 11x – 3y + 9 = 0 and
x
21x + 77y – 101 = 0 O A
(0,0) (0,1)
Now angle between the line 3x – 4y + 7 = 0 and
one bisector 11x – 3y + 9 = 0 is xy = 0 … (1)
x+y=0 … (2)
− 9 + 44 35
|tan θ| = = <1
33 + 12 45  ∆OAB is a right angled triangle, so, right angle
Hence the bisector is the required. vertex will be the orthocentre, i.e.,(0, 0)
11x – 3y + 9 = 0

[4]
53. (A)
P(2, –1) goes 2 units along x + y = 1 upto A and 5 −1 −1 1 1 1 1
units along ⇒ = ⇒ 2
+ 2 = 2+ 2
1 1 1 1 a b p q
+ 2 + 2
x – 2y = 4 upto B. Slope of PA = –1 = tan135° a 2
b p 2
q
1
Slope of PB = = tan θ
2 58. (D)
1 2 x x
⇒ sin
= θ , cos
= θ Let tan −1 = θ ⇒ tan θ =
5 5 2 2
The coordinates of B i.e.  x 2
⇒ cos  tan −1 =
 cos=
θ
( x1 + r cosθ , y1 + r sin θ ) are ( 2 )
5 + 2, 5 − 1  2 4 + x2
The coordinates of A i.e.  −1 2  2
⇒ f ( x) tan sin=
= 
 4 + x 2  | x |
( x + r cos135 , y + r sin135 ) are ( 2 −
1

1

2, 2 − 1)  −1 2  2
If x > 0=
then f ( x) tan
=  tan 
54. (A)  x x
As the third vertex lies on the line  −1  2   −2
If x<0 = then f ( x) tan
=  tan   
y = x + 3, its co-ordinates are of the form (x, x +   x  x
3). The area of triangle is 2
∴ f ( x) =
x x+3 1 | x|
1 1
2 1 1= 4x − 4 = 2x − 2 Note: Domain of f ( x) = R o . Also, f is an even
2 2
3 −2 1
function
According to given condition 59. (D)
3 7 For y to the real −1 ≤ tan −1 x ≤ 1
⇒ 2 x − 2 =±5 ⇒ x =− ,
2 2
⇒ − tan1 ≤ x ≤ tan1
Hence the coordinates of third vertex can be
 −3 3   7 13  y = t + 1 + 1 − t ⇒ y2 = 2 + 2 1 − t 2
 , ,  ,  .
 2 2 2 2  ⇒ y 2 ∈ [ 2, 4] ⇒ y ∈  2, 2 
55. (B)
The lines x – 2y = 0 and x – 2y + k = 0 are
(
⇒ a 2 + b2 =
6 )
parallel. The distance between these two lines = 60. (B)
2
As, 1 + cot
= θ cosec 2 θ
k
=3 ⇒k =±3 5
1 + ( −2 )
2 (
so, cosec 2 cot −1 x = )
1 + cot 2 cot −1 x =
1 + x2 ( ) ( )
and
56. (B)
Since a, b, c are in A.P. ⇒ 2b =a + c ( ) ( ) ( x − 1).
cot 2 cosec −1 x = cosec 2 cosec −1 x − 1= 2

⇒ a – 2b + c = 0 ⇒ family of lines concurrent at so, cosec ( cot x ) − cot ( cosec x ) =

2 −1
(1 + x )
2 −1 2

the point (1, –2).

57. (B) so, cosec 2 ( cot x ) − cot ( cosec x ) =(1 + x ) − ( x − 1)
−1 2 −1 2 2

x y =1+1=2
The equation of the line L is + =1.
a b 61. (B)
After the rotation of the axes, the line L has  1 
intercepts p and q on the new axes. In this system an = tan −1  
equation of the line is x/p + y/q = 1.  1 + ( n + 3)( n + 2 ) 
Since the origin and the line, both are fixed, the  ( n + 3) − ( n + 2 ) 
= tan −1  
distance between them remains the same  1 + ( n + 3)( n + 2 ) 
= tan–1 (n + 3) – tan–1 (n+2)
∴ Sn = tan–1 (n + 3) – tan–1(3)

[5]
 π 1 66. (A)
⇒ S∞ = − tan −1 3 =cot −1 3 =sin −1
2 10 Lines L1 and L2 trisect the line 4x + 5y = 20.
62. (A) 5 × 1 + 5 × 2 10
x1 = =
−1
sin (sin14)= (14 − 4π) 1+ 2 3
4 ×1 + 0 × 2 4
So, x 2 + 3 | x | −4 = 4π + (14 − 4π) y2 = =
1+ 2 3
⇒ x 2 + 3 | x | −18 =
0 5 8
(x1, y1) ≡  , 
⇒ (| x | + 6)(| x | − 3) =
0  3 3
∴ | x |=
3
So, sin −1 (sin 2 | x |) = sin −1 (sin 6) = (6 − 2π) Ans.
63. (D)
Range of f ( x) is [0,1]
1
∴ b−a=
64. (A)
As, x ∈ (0,1) so the given equation becomes
π Similarly,
(
3 2 tan −1 x ) ( ) (
+2 2 tan −1 x − 4 2 tan −1 x =
4
) 0 × 1 + 5 × 2 10
x2 = =
−1 π π 1+ 2 3
⇒ tan x = ⇒ x = tan = ( 2 − 1) Ans.
8 8 4 ×1 + 0 × 2 4
y2 = =
65. (D) 1+ 2 3
Side of square = 2  10 4 
(x2, y2) ≡  , 
 3 3
B ( 3 - 1, 3 + 1) 8 3 8
Slope of line L1 : m1 = × =
3 5 5
C (- 1, 3) 4 3 2
Slope of line L2 : m2 = × =
3 10 5
2 2 Tangent angle between the lines L1 and L2 :
8 2
−
m1 − m2 5 5 30
tan θ
= = =
1 + m1m2 1 + 8 × 2 41
A( 3,1) 5 5
67. (A)
Solving, 3x + 4y = 9 and y = mx + 1,
x y 5
= = 2 we get
cos30° sin 30° 3 + 4m
So, x can be integer only if m = –1, –2.
2 3
⇒ =x = 3 and y = 1 Hence, the number of integral value of m is 2.
2
68. (A)
x y
= = 2 ⇒ x = –1, y = 3 69. (C)
cos120° sin120°
x y
= = 2 2
cos 75° sin 75°
⇒ x= 3 − 1 and 3 +1
Required sum
=0+ 3 + 3 –1 +(–1) = 2 3 –2
x = sin–1 (sin 10) = 3π – 10

[6]
  3cosy − 4siny 
=β cos −1   ; y ∈ [ 0, 2π]
 10 
Now, 3cosy − 4siny ∈ [ −5,5]

y = cos–1 (cos 10) = 4π – 10  π 2π 

∴ Range of β is  , 
3 3 
Now, y – x = 4π – 10 – 3π + 10 = π
70. (A) = (
Also γ 2tan −1 z 2 − 4 z + 5 , z ∈ R )
Given line, 3x – 4y + 24 = 0
equation of the required line is 3x – 4y + c = 0
= (
γ 2tan −1 ( z − 2) 2 + 1 )
π 
∴ Range of γ is  , π 
c − 24 2 
=4
5 π π
If β + γ is minimum, then β = and γ =
⇒ | c – 24 | = 20 3 2
Also, α, β, γ are angles of a triangle.
c – 24 = 20 or – 20
c = 44 or 4 π π π
Now, α= , β= and γ =
3x – 4y + 44 = 0 6 3 2
or 3x – 4y + 4 = 0 π π
α = 2tan −1 x = ⇒ x = tan = 2 − 3
6 12
3 3x
y = x + 11 or y = +1 π 3cosy − 4siny 1
4 4 β= ⇒ cosβ= =
3 10 2
71. (6) 3cosy 4siny
∴ − = 1
5 5
4
⇒ cos ( y + θ ) =1 where tanθ =
3
4
y + θ = 2π ⇒ y = 2π − θ = 2π − tan −1
Equation of line 3
π π
π
y – 2 = tan (x – 3 )
γ=
2 2
(
⇒ = 2tan −1 z 2 − 4 z + 5 )
6
∴ z − 4 z + 5 =1 ⇒ ( z − 2) 2 = 0 ⇒ z =
2
2
1
y–2= (x − 3)
 −4 
3 (
Now, x + tany + z = 2 − 3 +   + 2
 3 
)
x– 3y+ 3=0
4 8 − 3 3 8 − 27 a − b
Let 3 x – 4y + 8 intersect at Q point =4 − − 3= = ≡
3 3 3 c

Q  3 +
3r r
, 2 + 
∴ a = 8, b = 27, c = 3 ⇒ a + b + c =38
2 2
  73. (2)
Q point satisfy equation Given that,
 3r  r π
3  3 +
 2 

 − 4  2 +  + 8 =
 2 
0 (
tan −1 x 2 − x + cosec −1 1 − x 2 − x =
2
)
3 For domain, we must have x 2 − x = 0 ⇒ x = 0,1
3+ r – 8 – 2r + 8 = 0
2 Also, both x = 0 and x = 1 satisfies the equation
r=6 sin −1 x = 2tan −1 x
72. (38)
 2x  74. (36)
Given α sin −1 
= 2 
; x ∈ [ −1,1]
1+ x 
∴ α 2tan −1 x∀x ∈ [ −1,1]
=

 π π
Hence, range of α is  − , 
 2 2

[7]
 c 4√3 1 − 2 x2
∘
= [By sine rule] ⇒ =k
sin 30 sin 120∘ 1 − x2
2c = 8 ⇒ c = 4
AB = |b + 1| = 4 ⇒ 1 − 2 x2 = k 2 1 − x2 ( )
b = 3, mAB = 0
−1
⇒ (k 2
− 2 x2 =)
k 2 −1
mBC =
√3 k 2 −1
x2 =
−1 k2 − 2
BC: −y = (x − 3)
√3 k 2 −1 2 k 2 −1
=α =⇒ α
√3y + x = 3 k2 − 2 k2 − 2
Point of intersection: 𝑦𝑦 = 𝑥𝑥 + 3, √3𝑦𝑦 + 𝑥𝑥 = 3
k 2 −1 2 k 2 −1
(√3 + 1)𝑦𝑦 = 6 =β = ⇒ β
k2 − 2 k2 − 2
6
𝑦𝑦 = 1 1  k2 − 2  α
√3 + 1 + 2
=  2 & =−1
6 α 2 β2  k −1  β
𝑥𝑥 = −3
√3 + 1 1 1 α
Sum of roots = 2
+ 2+ =b
6 − 3√3 − 3 α β β
=
√3 + 1
⇒
(
2 k2 − 2 ) − 1 =b .... (1)
(1 − √3) 2
=3 k −1
(1 + √3)
 1 1 α
−6 Product of roots =  2 + 2  = –5
= α β β
(1 + √3)2
𝛽𝛽 4
= 36 ⇒
(
2 k2 − 2 ) ( −1) =−5
𝛼𝛼 2 k −12

⇒ 2k 2 − 4= 5k 2 − 5
75. (12)
1
( ) ( )
cos sin −1 x =cos cos −1 1 − x 2 = 1 − x 2 ⇒ 3k 2 =⇒
1 k 2 = ... Put in (1)
3

=
⇒ b
(
2 k2 − 2 ) −1 = 5 – 1 = 4
( )
 1  1 k −12
tan −1 1 − x 2
cot= −1
cotcot=  
 1 − x2  1− x 2
b 4
  = = 12
k2 1
  x  1 − 2 x2
⇒ cos  sin −1    = 3
  2
  1− x  1 − x2

**********************

[8]