QPT-5 Solution

1. Ans: (b) 2RT

Solution: F = Tension in the thread

2F sin θ = T (AB)

2F θ = 2T (2Rθ)

2. Ans: (a) 2rads−1

Solution: In SHM,
Maximum velocity vmax = ωA
Maximum acceleration amax = Aω2
2
Aω amax
⇒ ω = =
Aω vmax

−1
vmax = 0.5 m s
s

−1
amax = 1.0 m s

1 10 −1
ω = = = 2rads
0.5 5

3. Ans: (b) Wire Y is more ductile than wire X .

Solution: A metal is more ductile (and thus less brittle) when point of ultimate strength (i.e., C ) and breaking point (i.e.,
D) are far apart.

So, option (b) is correct. Clearly, Young's modulus (= stress

strain
) of wire Y is more than wire X

4. Ans: (a) water levels in both sections A and B go up

′
Solution: Due to rotation about the axis OO , a force is acting on the liquid column AB outwards, pushing up the liquid
column on the right. This centrifugal force acting on the small element dx of area of cross-section dx, distant x from the
axis is
2 2
dmω x = Adxρω x

The total force due to column of length L(= AB) is

2
L 2 2 L
∫ Aρω ⋅ xdx = Aρω
0 2

Typesetting math: 56%

 Pressure at B = atmospheric pressure +
2 2
Aρω L
h 1 ρg +
A 2

Pressure at B due to liquid column on the right hand side = atmospheric pressure +h2 ρg
Net pressure due to the left hand side = pressure at B due to liquid column
2
L
2
atm. pressure + h 1 ρg + ρω = atm. pressure + h 2 ρg
2

2 2
ω L
∴ h 2 − h 1 = H0 = .
2g
Here one has

Typesetting math: 56%

 2 2 2 2
ω L2 ω L1
H2 = , H1 =
2g 2g

As ω is the same, and L2 > L 1 , H2 > H1 . But both will go up.

5. Ans: (d) 40 cms−1

Solution:

Terminal velocity is proportional to square of radius of the sphere.

2
v ∝ r
2
v1 r
1
=
v2 2
r
2

and using volume conservation,

s s
4 3 4 3
ta

8 × πr = πr
3 1 3 2
ha

⇒ r2 = 2r1
pt

therefore, v2 =4v 1 =40 cms−1

ra
w

6. Ans: (c) 5
u/

Solution: Given, the position and velocity of the particle executing SHM.
y = 3 cm

−1
v = 8 cm s
−1
Angular frequency, ω = 2rad s
The velocity,
−−−−−−
2 2
v = ω√ a − y

−−−−−−−
2 2
8 = 2√ a − (3)

−−−−−−−
2 2
4 = √a − (3)

2
16 = a − 9

2
a = 25

a = 5 cm

7. Ans: (d) Assertion is false but, reason is true.

Solution:

Given,

Breaking stress is equal for both the wires.

s

Breaking load
as

Breaking stress =
Cross−sectional area
.
t
ha

Thus, the breaking load depends on the cross-sectional area of the wire if the breaking stress is same.
pt

Therefore, breaking load of two wires can be different and the lower wire may have much lesser breaking
ra

load as compared with upper wire.

w

8. Ans: (d) All cases

u/

Solution: This happens in accordance with equation of continuity and this equation was derived on the principle of
conservation of mass and it is true in every case, either tube remain horizontal or vertical.

9. Ans: (c) 2s

Typesetting math: 56%

 GmM
Solution: Frest = (
3
)r
R
−−−
3

⇒ From equation (i) ; T = 2π√

R

GM
−−−
3
−
R
⇒ T = 2π√ 3
10R

⇒ T = 2 sec

10. Ans: (c) 8P1 +

24 T

Solution: Using Pi Vi = Pf Vf (for the air bubble)

we have
3
4 T 4 3 4 T 4 r
(P 1 + )( πr ) = (P 2 + )[ π( ) ]
r 3 r/2 3 2

Solving this, we get

24 T
P 2 = 8P 1 +
r

11. Ans: (a) 3.92 × 10

−7
m

Solution:

Given, side of a cube (1) = 10 cm = 0.1 m

2
Area its each face (A) = 12 = (0.1) = 0.01 m2
Load (m) = 100 kg
Tangential force acting on one face of the cube,
F = mg = 100 × 9.8 = 980 N
F
Shear stress acting on this face = A

980 2
= N/m
0.01
4 2
= 9.8 × 10 N/m

Shear modulus of aluminium (η)) = 25GPa

9 2
= 25 × 10 N/m
Shearing stress
Shear modulus (η) =
Shearing strain

Δy Shearing stress
or shearing strain ( ) =
L Shear modulus

Shearing stress
or Δy =
Shear modulus
× L

4
9.8 × 10
= × 0.1
9
25 × 10
.
−5
= 0.392 × 10 m
−7
= 3.92 × 10 m
Typesetting math: 56%
 12. Ans: (b)
a

Solution: Let the displacement at that instant be y

1
2 2 2
K = mω (a − y )
ss 2

3 1
2 2 2
E = mω (a − y )
ta

4 2
ha

3 1 1
( mω a ) =
2 2
mω (a
2 2
− y )
2
,
pt

4 2 2
ra

2
3 a
2 2 2
w

y = a − a =
4 4
a
⇒ y =
2

13. Ans: (a) 2 : 1

Solution:

W l
Y = ×
A Δl

So, Δl =
Wl

AY

Δe1 = Δe2

w1 l w2 l
=
AY1 AY2

w1 Y1
⇒ = = 2
w2 Y2

14. Ans: (d) 1 s

Solution:

Given, density of bob, ρ =

4
× 10
3
kg m
−3

Density of water, σ = 10
3
kg m
−3

If g ′ be gravitational acceleration in water then,

3
σ 10 g
′
g = g (1 − ) = g (1 − 4
) =
ρ 3 4
×10
3

−
−
As, Tair = 2π√
I

g
,

−−
g
Similarly, Twater = 2π√
g
I
′
[Twater = 2 s] (g
′
=
4
)

−
−− −
−
I I
2 = 2π √ = 2π √ ⋅ 2
Typesetting math: 56%
g/4 g
 2 = 2. Tair

⇒ Tair = 1 s

15. Ans: (a) 50 m2 s

−2

Solution: Suppose A be the area of cross section of tank, a be the area of hole, ve be the velocity of efflux, h be the

height of liquid above the hole,

Let v be the speed with which the level decreases in the container. Using equation of continuity, we get ave = Av or
1 1
2 2
P0 + hρg + ρv = P0 + ρve
2 2
2
1 ave 1
2
hρg + ρ( ) = ρve
ave 2 A 2
v =
A
Using Bernoulli's theorem, we have !
2hg 2 × (3 − 0.525) × 10
2
or ve = =
2
2
1 − (a /A )
2 1 − (0.1)

2 −2
= 50 m s

16. Ans: (a) First increase and then decrease to the original value
s
as
at
h
pt

Solution:

and T1 > T2
The given system is like a simple pendulum whose effective length is between the point of suspension and the center of
gravity of the hanging body.
When water slowly flows out, the sphere, the centre of gravity. of system is changing as shown in the figures.
Hence, time period first increases and then decreases to the original value. ^
p
17. Ans: (d) 3B

Solution: V = Volume of sphere =

4

3
3
πr

∆V ∆r
⇒ = 3
V r

∣ ∣
−p
also, bulk modulus, B = ∣
∆V
∣
∣ ( ) ∣
V

∣ ∆V ∣ p
Typesetting
− math:
=56%
∣ V ∣ B
 Δr p
3 =
r B

p
Δr

r
=
3B
/

18. Ans: (c) If assertion is true but reason is false

Solution: The excess pressure inside the small drop is large as compared to the large drop because of which smaller drop
of liquid resists deforming force better than the large drop. Excess pressure = 2T r
where T = surface tension r = radius
of liquid drop. Therefore excess pressure is inversely proportional to its radius and hence the surface area. !
−−−−−−−
2

19. Ans: (a) the motion of the particle is SHM with an amplitude of √A
2 B
+
4

Solution: The displacement of the particle is given by:

2
x = A sin(−2ωt) + Bsin ωt

B
= −A sin 2ωt + (1 − cos 2ωt)
2

B B
= −(A sin 2ωt + cos 2ωt) +
2 2
−−−−−−−
2
2
This motion represents SHM with an amplitude: √A +
B

4
, and mean position B

2
;

ρ 2 −ρ
20. Ans: (b) ρ−ρ
1

Solution: V = Volume of solid sphere. Let V1 = Volume of the part of the sphere immersed in a liquid of density ρ1
and V2 = Volume of the part of the sphere immersed in liquid of density ρ2 . According to law of floatation,

V1 ρg + V2 ρg = V1 ρ 1 g + V2 ρ 2 g

or V1 (ρ − ρ 1 )g = V2 (ρ 2 − ρ)g
Hence from eqns (i) and (ii), *
s
as

V1 ρ − ρ
2
or =
V2 ρ − ρ1
h at

21. Ans: 50
pt
s
as

ra

Solution: Let v be velocity of efflux and v′ be the velocity of fall of liquid level in tank. Using equation of continuity for
t

tube of flow formed between level of tank and orifice is

ha

u/

′
AV = av

p p
Applying Bernoulli's theorem, we have ρ
+
1

2
2
v + gh =
ρ
+
1

2
v
2
+ 0

2gh 2×10×(3−0.525)
2
v + =
2 2
a 1−(0.1)
1−( )
A

2
= 50(
Typesetting m/s)
math: 56%
2 2
= 50 m /s
 22. Ans: 2
at
Solution: Δl= Fl

AY
∆l l
=
F/A Y
3
4000×10 9 2
Y = −3
= 2 × 10 N/m
2×10

23. Ans: 5
−−−−− −−−
m 10
Solution: T = 2π√
k1 +k2
= 2π√
360
=
π

3
s

The maximum velocity is always at equilibrium position since at any other point there will be a restoring force.
impulse
Attempting to slow the mass. ∴ vmax =
mass
=
50

10
= 5 m/s
2π
⇒ ω = = 6rad/s
T
vmax
⇒ A = amplitude = ω
=
5

6
= 0.83 m

24. Ans: 16

Solution: In this question, the system is accelerating horizontally, i.e. no component of acceleration in vertical direction.
Hence, the pressure in the vertical direciton will remain unaffected.
i.e. p = p0 + ρgh
Again, we have to use the concept that the pressure in the same level will be same
a ss
at
th

For air trapped in tube, p1 V1 = p2 V2 p1 = patm = ρg76

∵ v1 = A ⋅ 8(A = area of cross-section )

⇒ p2 = patm − ρg(54 − x) = ρg(22 + x)

∵ V2 = A ⋅ x

or ρg76 × 8A = ρg(22 + x)Ax

2
x + 22x − 76 × 8 = 0 ⇒ x = 16 cm

25. Ans: 9

Solution:

Typesetting math: 56%

 Fl
Y =
A ∆l

V
∵ V = Al so l =
A

2
YA ∆l YA ∆l
F = =
l V

2 2
F1 A1 F A 1
= ( ) ⇒ = ( ) =
F2 A2 F2 3A 9

F2 = 9F1 = 9F

26. Ans: 4

Solution: Let the velocity of efflux at point 2 is v ss

Given, a = 1 cm2 , A = 0.5 m2 = 0.5 × 104 2
cm

Applying continuity equation,

ta

AV = av
ha

a
V = v
pt

A
ra

Since, a ≪ A, V ≪ v, V
2
is negligible.
Pressure at (1)
w

mg
u/

p1 = p0 +
A

30 × 10
s

= p0 +
as

0.5
at

= p0 + 600
th

Pressure at (2),
ap

p2 = p0

where, p0 is atmosple

where, p0 is atmospheric pressure.

Applying Bernoulli's equation between (1) and (2)
1 2 1 2
p1 + ρgh + ρV = ρ2 + ρv
2 2
2
V is negligible, then

p0 + 600 + 1200 × 10 × 0.75

1 2
= p0 + × 1200v
2
2
600v = 9600

2
⇒ v = 16

−1
⇒ v = 4 m s

27. Ans: 4

Solution: For the wire-block system in equilibrium,

Typesetting math: 56% mg/A mg
Young modulus, Y =
stress

strain
= =
A
L

Δl/L Δl
 weight mg
YA
∴ = Δl = kΔl
L

where YA

L
= k = force constant The force equation for the block is, F = −kx
−−
⇒ a = −
k

m
x ⇒ angular frequency, ω = √
k

m
−−−−−−−−−−−−−−−−−−
−−− 9 −2 −7 2
(n)(10 N m )(4.9×10 m )
or ω = √
YA

Lm
= √ = (70rads
−1
)√n
(1 m)(0.1 kg)

But ω = 140rads
−1

⇒ n = 4

28. Ans: 2
4 3 2 3
Solution: Stoke's law : 6πRηv =
3
πR (ρ − σ)g ∴ v ∝ R . As M is given, ρ = 4
M
3
But as R increases,
πR
3

M also increases and ρ is a constant. σ also is a constant. ∴ v , the terminal velocity ∝ R

2
.

29. Ans: 25

Solution:

Force constant K of rubber is given by

8 −6
YA 5×10 ×10 3 −1
K = = = 5 × 10 N m
l 0.1

Now, from conservation of energy,

elastic potential energy of cord = kinetic energy of particle

2
i.e. 1

2
K( ∆l) =
1

2
mv
2

−−
⇒ v = √
K

m
⋅ ∆l

−−−−−
3
5×10
= √ (0. 125 − 0. 1)
−3
5×10

3 −1
= 10 × 0. 025 = 25 m s

30. Ans: 2

Solution: The amplitude of oscillations will be the maximum when compression in the spring is maximum. At the time of
maximum compression, velocities of both the blocks are equal say v, then using law of conservation of momentum,
m1 v0 = (m1 + m2 )v
−1
⇒ 1 × 12 = (1 + 2)v ⇒ v = 4cms

Using law of conservation of energy, we have

1 2 1 2 1 2
m1 v = kx + (m1 + m2 )v
2 0 2 2

Putting the value of v = 4cms

−1
and solving, we get x = 2 cm.

31. Ans: (c) Rate = k[B2 ]

Solution: For the reaction 2 A + B2 ⇌ 2AB,

x y
Rate ∝ [A] [B2 ] . On substituting the given data, we get
From experimental
x y
∝ [0.50] [0.50] …..(i)
−4
1, 1.6 × 10
x y
From experimental 2, 3.2 × 10−4 ∝ [0.50] [1.00] … (ii)
x y
From experimental 3, 3.2 × 10−4 ∝ [1.00] [1.00] … (iii)
x
1.00
1 = [ ]
0.50

or 1 = 2 or 2 = 2 or x = 0
x 0 x

Now, divide equation (ii) by equation (i) we get,

y
1.00
2 = [ ]
0.50
Typesetting math:
y 56%
2 = 2
 y = 1
0 1
Thus rate equation is: Rate = k[A] [ B2 ] = k[B2 ] .

32. Ans: (a) Statement-1 is True, Statement - 2 is True; Statement - 2 is a correct explanation for Statement-1.

Solution:

In the process of reverse osmosis, solvent particles pass through semipermeable membrane towards dilute solution.

In the case of saline water, saline water is more concentrated than that of pure water. Hence water flows from saline
solution to pure water.

33. Ans: (c) (ii), (iv)

2+ − ∘
Fe + 2e ⟶ Fe; E = −0.44

Solution: Cu
2+
+ 2e
−
⟶ Cu; E
∘
= +0.34

− ∘
Ag + 1e ⟶ Ag; E = +0.80

If a metal have negative electrode potential than metal easily displace, other metal, i.e. Fe can displace Cu and Ag.

34. Ans: (c) 2.3 × 102 s

kt

Solution: cis −z ⇌ trans −Z

kb

Initial a 0
ss

At time t a − x x
ta

At equilibrium a − xθ xθ
ha

Kf
Kaq =
Kb
pt

−5
3×10 −3
∴ Kb = = 3 × 10
ra

−2
10
2.303 xθ
According to relation, (Kf + Kb ) = log
w

t x 0 −x
u/

2.303
(Kf + Kb ) = log 2[∵ x = x e /2]
t

−5 −3 0.693
(3 × 10 + 3 × 10 ) =
t

0.693
t = −3
3×10 (1+0.01)

0.693
=
−3
3×10 ×101
2
= 2.3 × 10 s

35. Ans: (b)

Solution:

By Raoult's law, the vapour pressure of a solvent above a solution is equal to the vapour pressure of the pure
solvent at the same temperature scaled by the mole fraction of the solvent present.
0
P solution = Xsolvent P
solvent

Plot of total vapour pressure as a function of mole fraction of the components of an ideal solution formed by
mixing liquids.
Typesetting math: 56%
36. Ans: (a) activation energy for the reaction is very high at room temperature

Solution: The activation energy for the reaction is very high at room temperature hence reaction will not take place.

37. Ans: (a) 0.184 g

Solution: Mass of Au deposited = Number of Faraday passed × Eq. mass

0.30×15×60 197
= × = 0.184 g
96485 3

38. Ans: (d) no blue colour formation

Solution: There will be no blue colour formation because in the process of osmosis, solvent molecules migrate across the
membrane and not solute molecules.

39. Ans: (b) M + + X

−
→ M + X is the spontaneous reaction
+ − + ∘
Solution: M + X → M + X is spontaneous because for the cell represented by M ∣∣M ∥X ∣
∣X, the value of E
is positive i.e. (0.44 − 0.33)V = 0.11 V.

40. Ans: (c) 5.88 V

Solution: Now, the cell reaction is

1 + −
Li(s) + F2 ( g) → Li + F
2

We know that,
o RT Product
E cell = E = ln
cell nF Reactant
o 2.303RT + −
= E − log[Li ][F ]
cell nF
2.303×8.314×298
= 5.92 − log(2 × 2)
1×96500
0.059
= 5.92 − × 2 log 2
1

= 5.92 − 0.035 = 5.887 V

41. Ans: (b) 2 and 3

Solution:

In presence of acid, hydrolysis of ethyl acetate is a pseudo-unimolecular reaction

Pseudo first order rate constant

+
k' = k[H ]

+
rate (r) = k[H ][ester]

If the acid concentration[H+ ] is doubled at constant ester concentration, then

1.The second order rate constant, k is remains same

2.The pseudo first order rate constant, K′ is double.

3. The rate of the reaction is doubled

42. Ans: (a)

−1
Typesetting math:
58 56%
g mol
 Solution: Tb∘ ,
= 353.23 K, WB = 1.8 g WA = 90 g′ Tb = 354.11 K Kb = 2.53 kgmol , −1

∘ WB ×K b ×1000 1.8×2.53×1000
ΔTb = Tb − Tb = 354.11 − 353.23 = 0.88 K M B = =
ΔTb ×WA 0.88×90

−1
= 57.5 ≈ 58 g mol

43. Ans: (a) I only

Solution:

In any mechanism of a reaction, the slowest step of reaction is rate determining step.

As per mechanism (I), rate = k [NO2 ] [O3 ] -----(1)

As per mechanism (II), rate = k [NO2 ] [O] ----------(2)

The intermediate [O] in the above reaction can be eliminated using the following equilibrium reaction

O3 (g) ⇌ O2 (g) + O

Equilibrium constant
[O ][O]
2
Keq =
[O3 ]

[O3 ]
or [O] = Keq
[O ]
2

Put in equation in (2)

−1
rate = k Keq [NO2 ] [O3 ] [O2 ]

44. Ans: (c) SnCl4

A
×i×t
Eit
Solution: ∴ w =
F
=
n

A×i×t 118.7×2×(5×3600)
⇒ n = = = 3.989
w×F 11.1×96500
−1
A = atomic weight of Sn = 118.7 g mol
ss

200 W
i = current = = 2 A
100 V
ta

t = time = 5hrs(5 × 3600 s)

equavalent weight of Sn
n+
ha

A
E = =
n

n = valency of Sn in the salt

pt

w = mass of Sn deposited = 11.1 g

ra

Here, SnO and SnO2 are non-electrolytes (aqueous).

w

4+ −
So, valency of Sn will be 4 in SnCl4 (Sn + 4Cl ).
u/

45. Ans: (c) 2.0

∘
(c) : Given : T1 = 27 C = 27 + 273 = 300 K

∘
T2 = 37 C = 37 + 273 = 310 K

−1
and Ea = 53.6 kJ mol

k2 Ea T2 − T1
log( ) = ( )
k1 2.303R T1 T2
Solution:
3
k 310 K 53.6 × 10 310 − 300
log( ) = ( )
k 300 K 2.303 × 8.314 300 × 310

= 0.3010

k 310 K
∴ = 2
k 300 K

46. Ans: (c) 12

Typesetting math: 56%
Solution:
 K
Λm = 1000 ×
M
−5
2×10 2 −1
= 1000 × = 20 S cm mol
0.001

Λm 20 2
⇒ α = ∞
= = ( )
Λm 190 19

−6
= 12. 3 × 10

47. Ans: (b) If both assertion and reason are true but reason is not the correct explanation of assertion.

Solution: Non-ideal solutions with positive deviation i.e., having more vapour pressure than expected, boil at lower
temperature while those with negative deviation boil at higher temperature than those of the components.

48. Ans: (b) A, B, C

Solution: The more the reduction potential, the more is the deposition of metals at the cathode.
Cation having E∘ value less than -0.83 V (reduction potential of H2 O ) will not deposit from aqueous solution.
= 1.50 V will deposit at the cathode
∘
E 3+
A /A

= 0.3 V will deposit at the cathode

∘
E 2+
B /B

E = −0.74 V will deposit at the cathode

3+
C /C
∘
E
D
2+
/D
= −2.37 V will not deposit at the cathode.

49. Ans: (c) Higher the value of KH at a given pressure, higher is the solubility of the gas in the liquids

Solution: p = KH × x
Where KH = Henry law constant
Henry's constant increases with increase in temperature while it decreases with increase in solubility. Hence, value of KH
increases as solubility of gas increases is a wrong statement.

50. Ans: (b) Its examples are- Rusting of iron, tarnishing of silver

Solution:

Corrosion is the slow process of the destruction of materials by a chemical reaction to the environment. The
examples of corrosion are rusting of iron, tarnishing of silver.

51. Ans: 3

Solution: 2 N2 O5 → 4NO2 + O2
From the unit of rate constant it is clear that the reaction follow first order kinetics.
Hence by rate law equation, r = k[ N2 O5 ]
where r = 1.02 × 10−4 , k = 3.4 × 10−5
−4 −5
1.02 × 10 = 3.4 × 10 [ N 2 O5 ]

[N2 O5 ] = 3M

52. Ans: 1
ss

Solution:
ta
ha

ΔTf = iKf m
0.0557 = i × 1.86 × 0.01
pt

i = 3 , means complex will give 3-ions

ra

Hence, formula should be [Co(NH3 )5 Br]Br2

w
u/

53. Ans: 1

Solution: Writing the equation for pentane-oxygen fuel cell at respective electrodes and overall reaction, we get
At Anode:
+ −
C5 H12 + 10H2 O → 5CO2 + 32H + 32e
(pentane)

At Cathode:
+ −
8O2 +32H +32e →16H2 O
Typesetting math: 56%
Overall :C5 H12 +8O2 →5CO 2 +6H2 O
 Calculation of ΔG∘ for the above reaction
∘
ΔG = [5 × (−394.4) + 6 × (−237.2)]

−[−8.2]

= −1972.0 − 1423.2 + 8.2 = −3387.0 kJ

= −3387000 Joules.

From the equation we find n = 32

Using the relation, ΔG∘ = −nF Ecell
∘
and substituting various values, we get
∘
−3387000 = −32 × 96500 × E (F = 96500C)
cell
3387000
or Ecell ∘
=
32×96500
3387000 3387
=
3088000
or 3088
V = 1.0968 V

54. Ans: 108

Solution:

Given A
s

= t1/2 = 54 min
as

B = t1/2 = 18 min
h at

' ' ' '

pt

t = 0 x M t = 0 x M
ra

⇒ To calculate : [At ] = 16 × [Bt ] time =?

w
u/

A0
⇒ For I order kinetic : [At ] = n
( 2)

n → no. of Half lives

⇒ Now from the relation (1)

x x n2 n1 4
⇒ n
= n
× 16 ⇒ (2) = (2) × (2)
1 2
( 2) ( 2)

t t
⇒ n2 = n1 + 4 ⇒ = + 4
(t ) (t )
1/2 1/2
2 1

1 1 4×18×54
⇒ t( − ) = 4 ⇒ t =
18 54 36

⇒ t = 108 min

55. Ans: 6

Solution:
o
ΔG° = −nF E cell

3 o
17 .37 ×10 = −3 × 96500 × E cell

E cell = −0 .06 V

56. Ans: 3
−5
−1
Solution: [CH3 ] =
10

10
mol L
−6 −1
= 10 mol L
100 −1
[C2 H6 ] = = 10 mol L = 10M
10
2
Kf [CH3 ]
Keq = =
Kb [C2 H6 ]
2
−6
[10 ] 2 −1
3.14×10 s
=
10 Kb

15 −1 −1
Kb = 3.14 × 10 L mol s
Typesetting math: 56%
57. Ans: 106
 Kf ×w×1000
Solution: Molar mass of solute = ΔTf ×W

Given : Kf = 1.86, w = 1.25 g, W = 20 g ,

ΔTf = 273 − 271.9 = 1.1 K
Therefore, molar mass of solute
1.86×1.25×1000
= = 105.7
1.1×20

58. Ans: 3

Solution: Emetal = ( Wt of metal ×96500)/ No of coulombs

(22.2×96500)
= ≈ 59.5
(2×5×60×60)

177
Oxidation no. of metal = 59.5
= +3

59. Ans: 16

Solution:

Suppose R1 initial rate and T 1 initial temperature

ss

= =
ta

When temperature is increased from T 1 to T1 + 10°C the rate doubles; rate = 2R1
ha

When temperature is increased from T1 + 10°Cto T1 + 20°Cthe rate doubles; rate = 2(2R1) = 4R1

When temperature is increased from T1 + 20°C to T1 + 30°Cthe rate doubles;

rate = 2(4 R1) = 8 R1

When temperature is increased from T1 + 30°C to T1 + 40°C the rate doubles;

rate= 2(8 R1) = 16 R 1

When the temperature is raised by 40°C the speed of the reaction increases to about 16 times.

60. Ans: 125

Solution:

Let initial moles of HA is a

2HA → H2 A 2

0. 5a 0. 25a

+ −
HA ⇌ H + A

0. 5a 0. 5a 0. 5a

0.25a+0.5a+0.5a
Now, i =
final moles

initial moles
=
0.5a+0.5a

−2
= 1. 25 = 125 × 10

61. Ans: (d) None of these

Solution:
′
Given, S(K, 0) and S (−K, 0),

Now, S S ′ = ∣
∣2K ∣
∣ and P S + P S ′ = 4 (given)

Now for the ellipse we know that,

′ ′
PS + PS > SS

⇒ 4 > |2K|

Typesetting math:
⇒ K 56%
∈ (−2, 2).
 If P , S & S
′
are collinear, then
′ ′
PS + PS = SS

⇒ K = ±2.

If P S + P S ′ < SS ,
′
then no locus exists.

⇒ K ∈ (−∞, − 2) ∪ (2, ∞).

62. Ans: (c) (4a, 0)

Solution:

The given parabola is y 2 = 4ax.

Let A = (at , 2at 1 )

2
1
and
ss

2
are two points on it.
ta

B = (at , 2at 2 )
2
ha

2at 1 −0
Now, slope of OA = mOA = =
2
pt

2 t1
at −0
1
ra

2at 2 − 0
and slope of OB = mOB = =
2
w

2
at − 0 t2
2

∵ OA ⊥ OB

∴ mOA × mOB = −1,

Thus, t1 t2 = −4

y −y
Using y − y1 = (
2

x 2 −x 1
1
)(x − x 1 ),

to get the equation of line AB as

2a(t 2 −t 1 )
2
y − 2at 1 = (x − at )
1
2 2
a(t −t )
2 1

2(t 2 −t 1 )
2
⇒ y − 2at 1 = (x − at )
1
(t −t )(t +t )
2 1 2 1

2 2
⇒ y − 2at 1 = (x − at )
1
(t 2 +t 1 )

2 2
⇒ y(t 2 + t 1 ) − 2at 1 t 2 − 2at = 2x − 2at
1 1

Putting the value of t1 t2 = − 4,

s

we get
as
at

y(t 2 + t 1 ) + 8a = 2x
h

which is a family of lines L1

pt

⇒ y(t 1 + t 2 ) = 2(x − 4a), + λL 2 = 0,

ra

where λ = t1 + t2 .
w
u/

Hence, the two lines are

L 1 ≡ x − 4a = 0, L 2 ≡ y = 0

The point of intersection of these two lines is (4a, 0). Hence, AB

always passes through a fixed point (4a, 0).

Typesetting math: 56%
63. Ans: (b) straight line

Solution: x + a(2y + 1) = 0

x + b(3y + 1) = 0

x + a(4y + 1) = 0

∣1 2a a∣
∣ ∣
1 3b b = 0
∣ ∣
∣1 4a a∣
R2 → R2 − R1
R3 → R3 − R1

or
Hence, locus of is or

64. Ans: (c)

Solution:

Given circles and

Thus, centers of two circles are and radii are respectively.

Since, center of circles are on the opposite side of line .

Since, circles should not intersect given line.

Hence,

or

and or

Thus,

65. Ans: (a) at most one

Solution: Let two points and lie on the circumference of a circle with centre where
Point equidistant from & will lie on the perpendicular bisector of this line segment.

where
Now it must pass through

There is no such line possible, hence atmost one point lies on the circle.

66. Ans: (d)

Solution:

Let be inclined to transverse axis at an angle such that lies on the hyperbola. Therefore,

Replacing we get,

(where, )

67. Ans: (b)

Solution:

Typesetting math: 56%

s

Slope of line=

Let slope of second line=m

For angle between two lines ,

But line intersects Xaxis, therefore

Slope of req. line

Eq. is
i.e.

68. Ans: (a) units

Solution:

Since the chord subtends a right angle at the origin,

s
as

Now, the point lies on the parabola,

t
ha
pt

i.e.
ra

So,
w

Hence, the length of the chord units

u/

69. Ans: (b) Minimum value of

Solution:

Given , and

So, the coordinates of foci and are and respectively.

Let, be a variable point on the ellipse.

Then,
Since the value of lies between and
So, the maximum value of area of is sq. units
Also,
Typesetting math: 56%
70. Ans: (b)
 Solution: Let, the lines are and
which intersects at the point
&

(given, )
(Hyperbola)
Eccentricity

71. Ans: (b)

ss
Solution: ta
ha
If is the midpoint of the segment between the axes, them point and .
pt

The equation of the line is,

ra

or,
w
u/

The line perpendicular to it is of form,

Since it passes through ,

Line is,

Solving and we get .

72. Ans: (a) \frac{325}{36}

Solution: \begin{array}{l} 4 x^{2}+9 y^{2}-8 x-36 y+15=0 \\ 4\left(x^{2}-2 x\right)+9\left(y^{2}-4 y\right)=-15 \\

4\left(x^{2}-2 x+1\right)+9\left(y^{2}-4 y+4=-15+4+36\right. \\ 4(x-1)^{2}+9(y-2)^{2}=25 \\ \frac{(x-1)^{2}}
{\left(\frac{5}{2}\right)^{2}}+\frac{(y-2)^{2}}{\left(\frac{5}{3}\right)^{2}}=1 \ldots \ldots \ldots \ldots \ldots \ldots
\ldots . .(1) \\ x^{2}-2 x+y^{2}-4 y+5 \\ (x-1)^{2}+(y-2)^{2} \end{array} \min of \left((x-1)^{2}+(y-
2)^{2}\right)=\frac{25}{9} \max of \left((x-1)^{2}+(y-2)^{2}\right)=\frac{25}{4} =\frac{25}{9}+\frac{25}
{4}=\frac{325}{36}

73. Ans: (a) \frac{\sqrt{5}}{12}

Solution:

Length of \mathrm{LR}=2(\mathrm{SM})
=2 \frac{|2(2)+2-0|}{\sqrt{2^{2}+1}}=\frac{12}{\sqrt{5}}
\Rightarrow \frac{1}{\mathrm{~K}}=\frac{12}{\sqrt{5}} \Rightarrow \mathrm{K}=\frac{\sqrt{5}}{12}

74. Ans: (a) 1

Solution:

Let and are the vertice of the and D, E and F are the midpoints,As we know that

Typesetting math: 56%

75. Ans: (c) \mathrm{x}^{2}+\mathrm{y}^{2}=4 \mathrm{a}^{2}

Solution: We know that centroid divides the median in the ratio 2: 1.

Radius of the circle =\frac{2}{3} \times length of median =\frac{2}{3} \times 3 a=2 a
Centre of the (given) circle is \mathrm{C}(0,0).
Therefore the equation of the circle (x-0)^{2}+(y-0)^{2}=(2 a)^{2} \Rightarrow x^{2}+y^{2}=4 a^{2}

76. Ans: (b) \tan ^{-1} \frac{2}{19}

s
as

Solution:
t
ha

Curve, S:(y-k)^{2}=4(x-h) LLR =4 ; Clearly \mathrm{k}=1 ; \Rightarrow \mathrm{A}(\mathrm{h}, 1) \& '

\mathrm{M}^{\prime} is focus (\mathrm{h}+1,1) So D (\mathrm{h}+1,3) \mathrm{S}_{(0,0)}=0 \Rightarrow
pt

\mathrm{k}^{2}=-4 \mathrm{~h} \Rightarrow \mathrm{h}=\frac{-1}{4} \quad \Rightarrow \mathrm{D}\left(\frac{3}

ra

{4}, 3\right) Now ; \tan \alpha=\left|\frac{m_{1}-m_{2}}{1+m_{1} m_{2}}\right|=\left|\frac{\frac{8}{3}-2}{1+\frac{8}

w

{3} \times 2}\right|=\frac{2}{19} where, m_{1}=\frac{3-1}{\frac{3}{4}-0}=\frac{2}{\frac{3}{4}}=\frac{8}{3}

\mathrm{m}_{2}=\frac{3-1}{1}=2
u/

77. Ans: (b)

Solution:

We have rectangular hyperbola

Given is an equilateral triangle.

Side

But side of triangle is .

Hence,

78. Ans: (c)

Typesetting math: 56%
 Solution:

We have,

Hence, slope is . Therefore,

The coordinate of

Let be the image of w.r.t. to the line , then

Image of w.r.t. the line is .

79. Ans: (a) .

Solution:

Since, length does not vary with change of axes or shifting of origin.
So, for simplicity,

consider
Now, focus is So, focal chord at a distance of units from the vertex is latus rectum which has length .
So the length of required focal chord will be .

80. Ans: (c)

Solution: Let and

Right angle at

81. Ans: 6

Solution: Any point on the hyperbola is

Now, the image of by the line mirror is

and
Now eliminating from above two equations we get,
s
as

82. Ans: 1
at

Solution: is
h
pt

is
is the only common point
ra
w

83. Ans: 7
u/

Solution:

Also
Typesetting math: 56%
 Length of the latus rectum, units

84. Ans: 6

Solution:

Reflection of about the line is which lies on side

Equation of is {since, line is passing through and }
is the point of intersection of and

s
coordinates of is

s
coordinates of is { mid point of and is }
ta
ha
85. Ans: 72
pt

Solution: Let is then is

ra

mid point of is
w
u/

{ where }
ss
ta

86. Ans: 3
ha

Solution: We know, area of a triangle

pt

\Delta=\frac{1}{2} \times base \times altitude

\because \frac{\left(\frac{1}{p_{1}}\right)^{2}+\left(\frac{1}{p_{3}}\right)^{2}}{\left(\frac{1}
ra

{p_{2}}\right)^{2}}=\frac{\left(\frac{2 \Delta}{p_{1}}\right)^{2}+\left(\frac{2 \Delta}{p_{3}}\right)^{2}}{\left(\frac{2

w

\Delta}{p_{2}}\right)^{2}}=\frac{(B C)^{2}+(AB)^{2}}{(A C)^{2}} {where \Delta represents the area of triangle A B

u/

C\}
=\frac{(5-3)^{2}+(2-(-1))^{2}+(-1-5)^{2}+(1-2)^{2}}{(-1-3)^{2}+(1-(-1))^{2}}
=\frac{4+9+36+1}{16+4}=\frac{50}{20}=2.5

87. Ans: 9

Solution:

The equation of the common chord is

which passes through
i.e.

88. Ans: 6

Solution:

89. Ans: 4

Solution:

Let and be two rods of length and sliding along axis and axis respectively.

Let the equation of circle through and

intercept and circle

i.e.

intercept and circle

i.e.

From math:
Typesetting and 56%
 Locus of centre is

90. Ans: 4851

Solution: \# of points on x-axis: 0

\# of points on the line y=1 : Still 0.
Because both the points (0,1) and (1,1) are ON the triangle and NOT INSIDE the triangle
\# of points on the line y=2 is 1 : The point being (1,2)
\# of points on the line y=3 is 2 : The points being (1,3),(2,3)
\# of points on the line y=4 is 3 : The points being (1,4),(2,4),(3,4)
\# of points on the line y=99 is 98. The points being (1,99),(2,99),(3,99) \ldots(98,99)
Hence, total answer: 0+0+1+2+3+\ldots+98
=98 * 99 / 2

Typesetting math: 56%