Assignment

Submitted By:
Dawood Bajwa
Submitted To:
Ma’am Rabya Aslam
Course:
Computer Applications in Chemical Engineerig
Roll No:
RP21-PG04
Semester:
4th

Institute of Chemical Engineering & Technology

University of the Punjab, Lahore
Question No. 1:
Consider an equimolar stream of water and ammonia at 293K and 1 atm with the molar flow
rate of 100 kmole/hr. Calculate all properties of this stream.
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Case Name: NoName_2.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: SI
4 USA
Date/Time: Sun Dec 10 14:51:30 2023
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Fluid Package: Basis-1
7 Material Stream: 1 Property Package: NRTL - Ideal
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PROPERTIES
11 Overall Vapour Phase Aqueous Phase
12 Molecular Weight 17.52 17.05 17.90
13 Molar Density (kgmole/m3) 9.350e-002 4.159e-002 53.09
14 Mass Density (kg/m3) 1.638 0.7092 950.4
15 Act. Volume Flow (m3/h) 1070 1068 1.046
16 Mass Enthalpy (kJ/kg) -9505 -2923 -1.452e+004
17 Mass Entropy (kJ/kg-C) 6.026 12.21 1.316
18 Heat Capacity (kJ/kgmole-C) 58.45 35.55 76.77
19 Mass Heat Capacity (kJ/kg-C) 3.336 2.085 4.289
20 LHV Molar Basis (Std) (kJ/kgmole) 1.584e+005 3.104e+005 3.682e+004
21 HHV Molar Basis (Std) (kJ/kgmole) 2.097e+005 3.715e+005 8.022e+004
22 HHV Mass Basis (Std) (kJ/kg) 1.197e+004 2.179e+004 4481
23 CO2 Loading --- --- ---
24 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
25 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
26 LHV Mass Basis (Std) (kJ/kg) 9041 1.821e+004 2057
27 Phase Fraction [Vol. Basis] 0.5339 0.5339 0.4661
28 Phase Fraction [Mass Basis] 0.4324 0.4324 0.5676
29 Phase Fraction [Act. Vol. Basis] 0.9990 0.9990 9.785e-004
30 Mass Exergy (kJ/kg) -0.4430 --- ---
31 Partial Pressure of CO2 (kPa) 0.0000 --- ---
32 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
33 Act. Gas Flow (ACT_m3/h) 1068 1068 ---
34 Avg. Liq. Density (kgmole/m3) 43.77 36.43 52.18
35 Specific Heat (kJ/kgmole-C) 58.45 35.55 76.77
36 Std. Gas Flow (STD_m3/h) 2364 1051 1314
37 Std. Ideal Liq. Mass Density (kg/m3) 766.9 621.1 934.0
38 Act. Liq. Flow (m3/s) 2.907e-004 --- 2.907e-004
39 Z Factor --- 1.000 7.834e-004
40 Watson K 12.24 12.24 12.24
41 User Property --- --- ---
42 Partial Pressure of H2S (kPa) 0.0000 --- ---
43 Cp/(Cp - R) 1.166 1.305 1.121
44 Cp/Cv 1.068 1.305 1.174
45 Ideal Gas Cp/Cv 1.317 1.305 1.326
46 Ideal Gas Cp (kJ/kgmole-C) 34.56 35.54 33.78
47 Mass Ideal Gas Cp (kJ/kg-C) 1.972 2.084 1.887
48 Heat of Vap. (kJ/kgmole) 3.771e+004 --- ---
49 Kinematic Viscosity (cSt) --- 11.51 0.8236
50 Liq. Mass Density (Std. Cond) (kg/m3) 786.3 618.8 954.2
51 Liq. Vol. Flow (Std. Cond) (m3/h) 2.228 1.225 1.042
52 Liquid Fraction 0.5556 0.0000 1.000
53 Molar Volume (m3/kgmole) 10.70 24.04 1.884e-002
54 Mass Heat of Vap. (kJ/kg) 2152 --- ---
55 Phase Fraction [Molar Basis] 0.4444 0.4444 0.5556
56 Surface Tension (dyne/cm) 67.67 --- 67.67
57 Thermal Conductivity (W/m-K) --- 2.578e-002 0.5900
58 Bubble Point Pressure (kPa) 428.2 --- ---
59 Viscosity (cP) --- 8.163e-003 0.7828
60 Cv (Semi-Ideal) (kJ/kgmole-C) 50.14 27.24 68.45
61 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.861 1.598 3.824
62 Cv (kJ/kgmole-C) 54.75 27.24 65.39
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Case Name: NoName_2.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: SI
4 USA
Date/Time: Sun Dec 10 14:51:30 2023
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Fluid Package: Basis-1
7 Material Stream: 1 (continued) Property Package: NRTL - Ideal
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PROPERTIES
11 Overall Vapour Phase Aqueous Phase
12 Mass Cv (kJ/kg-C) 3.125 1.598 3.653
13 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
14 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
15 Cp/Cv (Ent. Method) --- --- ---
16 Reid VP at 37.8 C (kPa) 1461 1461 1461
17 True VP at 37.8 C (kPa) 734.0 1432 175.6
18 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 2.267 1.225 1.042
19 Viscosity Index -10.55 --- ---
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Question No. 2:
Consider an equimolar stream of methane, ethane, propane, n-butane and i-butane at 50°C and
25 psia. Calculate temperature in which vapor fraction is 50%.
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Case Name: NoName_2.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: SI
4 USA
Date/Time: Sun Dec 10 15:01:23 2023
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Fluid Package: Basis-2
7 Material Stream: 1 Property Package: Peng-Robinson
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CONDITIONS
11 Overall Vapour Phase Liquid Phase
12 Vapour / Phase Fraction 0.5000 * 0.5000 0.5000
13 Temperature: (C) -37.52 -37.52 -37.52
14 Pressure: (kPa) 172.4 * 172.4 172.4
15 Molar Flow (kgmole/h) 10.00 * 5.000 5.000
16 Mass Flow (kg/h) 412.9 150.1 262.8
17 Std Ideal Liq Vol Flow (m3/h) 0.8565 0.3736 0.4829
18 Molar Enthalpy (kJ/kgmole) -1.197e+005 -9.259e+004 -1.469e+005
19 Molar Entropy (kJ/kgmole-C) 116.9 174.2 59.59
20 Heat Flow (kJ/h) -1.197e+006 -4.630e+005 -7.343e+005
21 Liq Vol Flow @Std Cond (m3/h) 0.8733 * 117.2 0.4764
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Question No. 3:
A 100 mole/hr stream of 50 % methane, 10 % ethane, 20 % propane and 20 % n-butane (mole
percent) at 95 °F and 300 psia is fed to a separator. The operating pressure and temperature
are 250 psia and 80 °F, respectively. Calculate the composition of product streams.
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Case Name: NoName_3.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: SI
4 USA
Date/Time: Sun Dec 10 15:15:09 2023
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7 Workbook: Case (Main)
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Compositions Fluid Pkg: All

11 Name 1 Vapour Liquid

12 Comp Mole Frac (Methane) 0.5000 * 0.5803 0.0629
13 Comp Mole Frac (Ethane) 0.1000 * 0.1084 0.0542
14 Comp Mole Frac (Propane) 0.2000 * 0.1844 0.2851
15 Comp Mole Frac (n-Butane) 0.2000 * 0.1270 0.5978
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Question No. 4:
Find the vapor pressure for the binary mixture of 40 mol% n-hexane and 60% n-heptane at
120°C. Assume flow rate of 1kmol/hr.
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Case Name: NoName_4.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: SI
4 USA
Date/Time: Sun Dec 10 15:19:38 2023
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Fluid Package: Basis-1
7 Material Stream: 1 Property Package: Peng-Robinson
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CONDITIONS
11 Overall Vapour Phase Liquid Phase
12 Vapour / Phase Fraction 1.0000 * 1.0000 0.0000
13 Temperature: (C) 120.0 * 120.0 120.0
14 Pressure: (kPa) 234.2 234.2 234.2
15 Molar Flow (kgmole/h) 1.000 * 1.000 0.0000
16 Mass Flow (kg/h) 94.59 94.59 0.0000
17 Std Ideal Liq Vol Flow (m3/h) 0.1396 0.1396 0.0000
18 Molar Enthalpy (kJ/kgmole) -1.636e+005 -1.636e+005 -1.956e+005
19 Molar Entropy (kJ/kgmole-C) 230.1 230.1 161.2
20 Heat Flow (kJ/h) -1.636e+005 -1.636e+005 0.0000
21 Liq Vol Flow @Std Cond (m3/h) 0.1392 * 0.1392 0.0000
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Question No. 5:
Pure water is fed at a rate of 100 lb/h into a pump at 250°F, 44.7 psia. The exit pressure is 1200
psig, how much energy is required to pump this liquid at required exit pressure?
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Case Name: NoName_7.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: SI
4 USA
Date/Time: Sun Dec 10 15:43:12 2023
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7 Pump: P-100
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CONDITIONS
11 Name 1 2 Qin
12 Vapour 0.0000 0.0000 ---
13 Temperature (C) 121.1111 * 122.5171 ---
14 Pressure (kPa) 308.1957 * 8375.0359 * ---
15 Molar Flow (kgmole/h) 2.5178 2.5178 ---
16 Mass Flow (kg/h) 45.3592 * 45.3592 ---
17 Std Ideal Liq Vol Flow (m3/h) 0.0455 0.0455 ---
18 Molar Enthalpy (kJ/kgmole) -2.776e+005 -2.774e+005 ---
19 Molar Entropy (kJ/kgmole-C) 27.74 27.88 ---
20 Heat Flow (kJ/h) -6.9898e+05 -6.9846e+05 5.2468e+02
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