Unit 4 Revised Notes (CS) 2023
Unit 4 Revised Notes (CS) 2023
❖ Electronic memories fall into two categories: Volatile and Non-volatile memory
▪ Volatile memory
- This type of memory requires continuous power to enable it to retain
information
- If the power is removed, the 'state of the memory' will be lost
- RAM (Random Access Memory) is in the volatile category
▪ Non-volatile memory
- This type of memory is not dependent upon continuous power to enable
it to retain information
- ROM (Read Only Memory) is non-volatile memory; other examples
include punched card, magnetic tape, magnetic disc, magnetic drum and
magnetic core
▪ Secondary memory
- It is either magnetic, optical or flash memory
- It is not accessible by processor or computer
- It allows user to store data that can be accessed, transmitted and used
by apps
- Examples: CD, USB
I. TRANSISTOR-TYPE
- A transistor is a miniature semiconductor
- It regulates current/voltage, amplifying the electrical signals and acting as a
switch/gate for them
- Transistor consists of three layers of p-type and n-type semiconductor
- A memory chip consists of billions of transistors, which store data based on two
conductivity states
- The low conductivity state and high conductivity state are assigned the “0” and
“1” or “ON” and “OFF” respectively. Thus, each transistor works as a switch
- Transistor made from silicon or metal oxides store data based on charge; it
consists of a minute and complicated electronic circuit
- Whereas, organic transistor memory device stores based on two conductivity
states; the device structure can be simplified and fabricated in simple steps
II. CAPACITOR-TYPE
- Capacitor stores data in the form of electrical energy (electric charges)
- It consists of two conducting plates in close proximity, placed in parallel to one
another
- Positive charges are deposited on one of the conductors and an equal amount
of negative charges is deposited on the another conductor forming bistable state
- Organic and polymeric ferroelectric materials (spontaneous electric polarization)
are used in capacitor type electronic memory device
- The permanent electric polarization can be repeatedly switched between two
stable states (bistable) by an external electric field
III. RESISTOR-TYPE
- A resistor is a passive electrical component that implements electrical resistance
- The main purpose of resistor is to reduce the current flow and to lower the
voltage in circuit
- These memory devices have a simple structure, having a metal-insulator-metal
structure, generally referred to as MIM structure
- The structure comprises of an insulating layer (I) sandwiched between the two
metal (M) electrodes and supported on a substrate (glass, silicon wafer, plastic
or metal foil).
- Initially, the device is under high resistance state or “OFF” (“0” state), when
resistance changed i.e under external applied field, changes to low resistance state
or “ON” logical value “1”.
1. Organic molecules
- There is a category of organic molecules which exhibit bistable or multistable
states when external field is applies
- When a threshold voltage is applied, they undergo a transition from ON to OFF
state or from OFF to ON state
Examples:
(i) Acene derivatives:
- Acenes are polycyclic aromatic compounds consisting of linearly fused benzene
rings;
- They possess high charge carrier mobility
Examples: Pentacene, perfluoropentacene, naphthalene, anthracene.
Pentacene Perfluoropentacene
2. Polymeric molecules
- The characteristic of polymer memory molecules is low-cost and high-
performance
- They have the potential for 3D stacking and mechanical adaptability
Examples:
(i) Polyimides - Most commonly used polymeric materials for organic electrical
memory applications
- They exhibit high thermal stability and mechanical strength
- They exhibit two stable charged states under applied electric field due to Donor-
Acceptor structure
Example: Phthalimide acts as the electron acceptor & triphenylamine acts as an
electron donor
(ii) Conjugated polymers - They are rich in pi electrons and can be made to show
charge states by incorporating electron acceptor groups in their back bone.
Example: poly (ethylene-2,6-naphthalate) in flash devices
(iii) A polymer known as (PEDOT) is vital plastic used to store the digital data in
gigabyte and be adequately modest to rival CDs and DVDs.
Effect of Light:
- When plane polarized light is made to pass through two crossed polarizers, no light
emerges out.
- This is because, the light emerging from the first polarizer is completely absorbed by
the second polarizer and hence appears dark.
- We can make the plane polarized to pass through two crossed polarizers by placing a
twisted nematic liquid crystal in between two polarizers.
- For example, a display is obtained by placing liquid crystal in between two polarizers
which are placed inclined to each other at an angle of rotation by liquid crystals. The
source of light radiation is kept below first polarizer; light passes through it and then
rotated by liquid crystal, it passes through the second polarizer. Hence, it gives bright
appearance to display.
- Now, if an electric field is applied between two polarizers, then liquid crystal
molecules will arrange themselves to applied field
- Hence the rotation of plane of the polarized light is also affected.
- Thus, light passing through first polarizer cannot pass through second polarizer and
it gives appearance to display.
Classifications of LCs
Liquid crystals are classifed into two main catagories;
1. Lyotropic liquid crystals
2. Thermotropic liquid crystals
Jablonski diagram
When a molecule absorbs energy in the form of electromagnetic radiations, and undergoes excitation, there
are a number of routes by which it can return to ground state.
A Jablonski diagram is basically an energy diagram, with energy on a vertical axis and ground state on x axis.
Horizontal lines are representations of the limits of electronic energy states and within each electronic energy
state are multiple vibronic energy states.
Jablonski diagram shows transitions between energy states that occur from the exposure of a molecule to a
particular wavelength of light.
A straight arrow pointing up indicates transition due to absorbance of a photon of a particular energy by the
molecule. Only certain wavelengths of light are possible for absorbance, that is, wavelengths that have
energies that correspond to the energy difference between two different energy states of the particular
molecule.
The excited molecule dissipates energy in two ways
1. Radiative –
(i) Fluorescence – Electron jumps from one electronic state to the other retaining the spin state and
emitting radiation. Fluorescence is a slow process on the order of 10-9 to 10-7 seconds. This is
termed as “allowed transition”.
(ii) Phosphorescence – A delayed fluorescence with a change in the spin state is called
Phosphorescence. Since a change in spin state occurs, it is a slow process and is termed as
“forbidden transition”.
2. Non Radiative - This process is very fast, between 10-14 and 10-11
(i) Vibrational relaxation - Transitions from one vibrational energy level to the other within the same
electronic level and without change in the spin state.
(ii) Internal conversion - Vibrational energy level overlaps with electronic level and hence causes a
transition from one electronic state to the other.
(iii) Intersystem crossing - Transitions involving a change in spin state across pure vibrational energy
levels or overlapped vibrational energy level with electronic level.
Electroactive Materials:
- An electroactive material exhibits a change in size or shape when stimulated by an
electric field.
- The most common applications of this type of material are in actuators, sensors and
artificial muscles.
- A typical characteristic property of an electroactive material is that they will undergo
a large amount of deformation while sustaining large forces.
Examples: Carbon Nanotube, Copolymer, Polypyrrole etc.
Organic compounds with extensive conjugation and n-electrons systems are capable of
exhibiting above mentioned set of properties. These organic materials can be broadly
classified in to three categories;
• Small molecule
• Oligomers with well-defined structure
• Polymers Small organic molecules are crystalline in nature.
Small molecule:
Examples: The metal and metal free phthalocyanines, porphyrins, poly-condensed
aromatic hydrocarbons like anthracenes, and fullerenes.
Construction and working of QLEDs (write the small introduction about QDs before construction &
working)
- A
QLED
is
Applications of QLEDs:
• Televisions and displays: QLED displays are commonly used in televisions, monitors,
smartphones, and other electronic devices. They offer superior image quality and colour
accuracy compared to traditional LCD displays.
• Lighting: QLEDs can also be used as a source of lighting in various applications,
including automotive lighting, street lighting, and architectural lighting. They offer energy-
efficient and highly customizable lighting options.
• Medical imaging: QLEDs can be used in medical imaging applications, such as in MRI
machines, to produce high-resolution and accurate images. Also used in phototherapy
• Virtual and augmented reality: QLED displays are suitable for use in virtual and
augmented reality applications due to their ability to produce vibrant and accurate colours,
which can enhance the immersive experience.
• Advertising displays: QLED displays can be used in advertising displays, such as digital
billboards and signage, to produce high-quality and eye-catching visuals
• Microscopy: QLED is also used for near-field scanning optical microscopy and lighting in
digital cameras
Advantages/Properties Disadvantages
colour accuracy limited viewing angles
higher colour saturation High price
higher contrast ratio require stable polymer shell for support
higher peak brightness uneven degradation of pixels
faster response time poor outdoor visibility
- OLED devices consist of two electrodes, an anode and a cathode and the organic
layers (multiple organic layers) are placed between them
- At least one of the electrodes must be transparent, in order to facilitate emission of
light from the device
- To create white light, most devices use red, green, and blue emitters that can be
arranged in several configurations
- When voltage is applied, charge carriers are injected from the electrodes to the organic
layers
- Anode injects holes (positive charges) and cathode injects electrons (negative charges)
to the system
- The holes and electrons are transported to an emission site in organic layer where they
recombine and cause excitation of the organic material
- When the excited organic material returns to its ground state, light emission occurs
- The intensity of the light emitted is controlled by the amount of electric current
applied, and the colour of light is determined by the type of emissive material used
Applications of OLEDs:
• OLEDS are widely used in display systems such as TV, Computer screens, smart
phones, tablet displays, etc.
• Used to make super-thin pages for electronic books and magazines
• Lighting: used as a source of lighting in various applications, including automotive
lighting, street lighting, and architectural lighting
• Wearable devices: The thin and flexible nature of OLEDs makes them suitable for
use in wearable devices, such as smartwatches and fitness trackers
• Automotive: used in automotive applications, such as dashboard displays, interior
lighting, and taillights
• Medical: used in medical applications, such as in surgical lighting and medical
imaging. They offer bright and highly accurate lighting options that can help improve
medical procedures and diagnosis
Properties of QLEDs
OLEDs exhibit several unique features;
1. OLED devices have solid and planar structure. Therefore, OLED display panels are
very thin, flat and lightweight
2. OLED devices have self-emission property; hence exhibits high contrast ratios (high
resolution) and wide viewing angles
3. The response time is very fast (in micro or nanosecond order). Therefore, OLED
displays can produce sharp moving images (Extremely attractive compared to LCD)
4. In OLEDs, the emission is from organic materials. Using variety of different organic
materials various colour can be generated. Therefore full- colour images can be
obtained
5. The power consumption in OLED displays is very low
QLED OLED
Quantum dot light emitting diode Organic layer light emitting diode
Quantum dots are used in emissive layer Organic compounds are used in emissive
layer