vio Structure of Atom nh & oe Atomic Models The number of protons, neutrons and electrons in 1Lu, respectively, are (a) 71, 104 and 71 (b) 104,71 and 71 (c) 71,71 and 104 (d) 175, 104 and 71 (NEET 2020) 2. Be?* is isoelectronic with which of the following ions? (a) H* (b) Lit (c) Nat (d) Mg?* (2014) 3. Isoelectronic species are (a) CO, CN’, NO*, C? (b) CO”, CN, NO, Cy (c) CO*, CN*, NO’, C, (d) CO, CN, NO, C, (2000) 4. The ion that is isoelectronic with CO is (a) CN- (b) Ny (c) OF (d) Nz (1997) 5. Which one of the following is not isoelectronic with or? (a) TI* (b) Nat* (c) N* (d) F (1994)ED Developments Leading to the Bohr's Model of Atom 6. Which of the following series of transitions in the spectrum of hydrogen atom falls in visible region? (a) Brackett series (b) Lyman series (c) Balmer series (d) Paschen series (NEET 2019) 7. Calculate the energy in joule corresponding to light of wavelength 45 nm. (Planck’s constant, h = 6.63 x 10-*4J s, speed of light, c=3x108ms"') (a) 6.67 x 10'5 (b) 6.67 x 10!" (c) 4.42 x 1075 (d) 4.42 x 1078 — (2014) 8. The value of Planck’s constant is 6.63 x 10-*4 Js. The speed of light is 3 x 10!7 nm s!. Which value is closest to the wavelength in nanometer of a quantum of light with frequency of 6 x 10's}? (a) 50 (b) 75 (c) 10 (d) 25 (NEET 2013) 9. According to law of photochemical equivalence the energy absorbed (in ergs/mole) is given as (h = 6.62 x 10° ergs, c=3 x 10! cms"), N, = 6.02 x 10? mol") 8 2.859 x 10° (a) 1:196%10 () : 16 16 (c) 2.85910 (a) 1:196x10 a a (Karnataka N] HINT )10. 11. 12. 13. The energies E, and E, of two radiations are 25 eV and 50 eV respectively. The relation between their wavelengths i.e., A, and A, will be (a) Ay =A, (b) Ay = 2A, (0) y= 4Ay (d) 4, =F), (2011) The value of Planck’s constant is 6.63 x 1074 J s. The velocity of light is 3.0 x 108 m s“!. Which value is closest to the wavelength in nanometers of a quantum of light with frequency of 8 x 10° s1? (a) 2x 10° (b) 5x 1078 (c) 4x 10! (d) 3 x 107 (2003) For given energy, E = 3.03 x 10°” joules corresponding wavelength is (h = 6.626 x 10-4 J sec, c = 3 x 10° m/sec) (a) 65.6nm (b) 6.56 nm (c) 3.4nm (d) 656 nm (2000) What will be the longest wavelength line in Balmer series of spectrum? (a) 546 nm (b) 656 nm (c) 566 nm (d) 556 nm (1996)EZ Bohr's Model for Hydrogen Atom 14. 15. 16. 2 Based on equation E = - 2.178 x 107% {2} n certain conclusions are written. Which of them is not correct? (a) Equation can be used to calculate the change in energy when the electron changes orbit. (b) For n = 1, the electron has a more negative energy than it does for n = 6 which means that the electron is more loosely bound in the smallest allowed orbit. (c) The negative sign in equation simply means that the energy of electron bound to the nucleus is lower than it would be if the electrons were at the infinite distance from the nucleus. (d) Larger the value of n, the larger is the orbit radius. (NEET 2013) According to the Bohr theory, which of the following transitions in the hydrogen atom will give rise to the least energetic photon? (a) n=6ton=1 (b) n=5ton=4 (c) n=6ton=5 (d) n=5ton=3 (Mains 2011) The energy of second Bohr orbit of the hydrogen atom is -328 kJ mol’; hence the energy of fourth Bohr orbit would be (a) - 41k] mol"! (b) -82 kJ mol"! (c) -164 kJ mol" (d) -1312 kJ mol"! 95)17. 18. 19. 20. 21. ‘The frequency of radiation emitted when the electron falls from n = 4 to n = 1 in a hydrogen atom will be (Given ionization energy of H = 2.18 x 10-!8J atom! and h = 6.626 x 1034J s) (a) 1.54x 10!% 5"! (b) 1.03 x 10!5 s"! (c) 3.08 x 10% s"! (d) 2.00 x 10's! (2004) In hydrogen atom, energy of first excited state is -3.4 eV. Then find out K.E. of same orbit of hydrogen atom. (a) +3.4eV (b) +6.8 eV (c) -13.6eV (d) +13.6eV (2002) Who modified Bohr’s theory by introducing elliptical orbits for electron path? (a) Rutherford (b) Thomson (c) Hund (d) Sommerfeld (1999) The Bohr orbit radius for the hydrogen atom (n = 1) is approximately 0.530 A. The radius for the first excited state (n = 2) orbit is (in A) (a) 4.77 (b) 1.06 (c) 0.13 (d) 2.12 (1998) In a Bohr’s model of an atom, when an electron jumps from n = 1 to n = 3, how much energy will be emitted or absorbed? (a) 2.389 x 10" ergs (b) 0.239 x 107" ergs (c) 2.15 x 107! ergs (d) 0.1936 x 10-!° ergs (1996)22. 23. 24. 25. The radius of hydrogen atom in the ground state is 0.53 A. The radius of Li?* ion (atomic number = 3) ina similar state is (a) 0.53 A (b) 1.06A (c) 0.17A (d) 0.2654 (1995) The energy of an electron in the n‘* Bohr orbit of hydrogen atom is 13.6 a) BF ey (b) Sev n n (« BSev @) B&ey (1992) wr n The spectrum of He is expected to be similar to that (a) H (b) Lit (c) Na (d) Het (1988) If r is the radius of the first orbit, the radius of n‘ orbit of H-atom is given by (a) rn? (b) rn (c) r/n (d) rn? (1988) ED Towards Quantum Mechanical Model of 26. the Atom In hydrogen atom, the de Broglie wavelength of an electron in the second Bohr orbit is [Given that Bohr radius, ay = 52.9 pm] (a) 211.6 pm (b) 211.6 tpm (c) 52.97 pm (d) 105.8 pm (Odisha NEET 2019)27. A 0.66 kg ball is moving with a speed of 100 m/s. 28. 29. 30. The associated wavelength will be (h = 6.6 x 10**J s) (a) 6.6 x 10° m (b) 6.6 x 1034 m (c) 1.0x 105m (d) 1.0 x 102m (Mains 2010) If uncertainty in position and momentum are equal, then uncertainty in velocity is (a) 1 fh (b) ft (0) 2 ft (a) fe mV T 2mn\T 20 (2008) The measurement of the electron position is associated with an uncertainty in momentum, which is equal to 1 x 10-!* g cm s“!. The uncertainty in electron velocity is (mass of an electron is 9x 10°78 g) (a) 1x 10°cms? (b) 1x 10% cms"! (c) 1x 10°cms?! (d) 1x 10°cms" (2008) Given : The mass of electron is 9.11 x 10! kg, Planck constant is 6.626 x 10-*4 J s, the uncertainty involved in the measurement of velocity within a distance of 0.1 A is (a) 5.79 x 10°ms"! (b) 5.79 x 10°ms! (c) 5.79 x 10’ms! (d) 5.79 x 10®ms?! (2006)