00-Atomic Structure AND Nuclear Physics (Theory)
00-Atomic Structure AND Nuclear Physics (Theory)
Chapter
26
Atomic and Nuclear Physics
Thomson's Atomic Model
J.J. Thomson gave the first idea regarding structure of (1) Most of the -particles pass through the foil straight
atom. According to this model. away undeflected.
(1) An atom is a solid sphere in which entire and positive (2) Some of them are deflected through small angles.
charge and it's mass is uniformly distributed and in which (3) A few -particles (1 in 1000) are deflected through
negative charge (i.e. electron) are embedded like seeds in the angle more than 90o.
Fig. 26.1
N(180°
(2) This model explained successfully the phenomenon )
Fig. 26.3
of thermionic emission, photoelectric emission and ionization.
(3) The model fail to explain the scattering of - particles (6) If t is the thickness of the foil and N is the number of -
and it cannot explain the origin of spectral lines observed in particles scattered in a particular direction (i.e. = constant),
'Geiger and Marsden (students of Rutherford) studied minimum distance from the nucleus up to which the -
particle approach, is called the distance of closest approach
the scattering of -particles by gold foil on the advice of
(r0). At this distance the entire initial kinetic energy has been
Rutherford and made the following observations.
converted into potential energy so
r0
Nucleus
-particle
(energy E )
2 Atomic and Nuclear Physics
Failure of Rutherford's Model
(8) Impact parameter (b) : The perpendicular distance (1) Stability of atom : It could not explain stability of
of the velocity vector ( ) of the -particle from the centre of atom because according to classical electrodynamics theory
the nucleus when it is far away from the nucleus is known as an accelerated charged particle should continuously radiate
impact parameter. It is given as energy. Thus an electron moving in an circular path around
the nucleus should also radiate energy and thus move into
smaller and smaller orbits of gradually decreasing radius and
b e–
+ it should ultimately fall into nucleus.
+
Nucleus
Fig. 26.4
Instability of atom
Fig. 26.6
Rutherford's Atomic Model (2) According to this model the spectrum of atom must
After -particles scattering experiment, following be continuous where as practically it is a line spectrum.
conclusions were made by Rutherford as regard as atomic (3) It did not explain the distribution of electrons outside
structure : the nucleus.
Atom
Bohr's Atomic Model
Nucleus
+ Bohr proposed a model for hydrogen atom which is also
(1) It is valid only for one electron atoms, e.g. : H, He+, Quantity Formula Dependenc
(3) Intensity of spectral lines could not be explained. (3) Time period
(4) Nucleus was taken as stationary but it also rotates on (4) Angular momentum
its own axis.
(5) Corresponding
From equation (i) and (ii) radius of nth orbit Kinetic energy
defined as the energy needed to separate it's constituents (2) Frequency of emitted radiation
(2) According to the Bohr's theory the wavelength of the 4. Bracket n2 = 5, 6, 7 … Infrared
series n1 = 4 region
radiations emitted from hydrogen atom is given by
5. Pfund n2 = 6, 7, 8 … Infrared
series n1 = 5 region
Thermal Neutrons
Fast neutrons can be converted into slow neutrons by
(2) The stability or instability of a particular nucleus is
certain materials called moderator's (Paraffin wax, heavy
determined by the competition between the attractive
water, graphite) when fast moving neutrons pass through a
nuclear force among the protons and neutrons and the
moderator, they collide with the molecules of the moderator,
repulsive electrical interactions among the protons. Unstable
as a result of this, the energy of moving neutron decreases
nuclei decay, transforming themselves spontaneously into
while that of the molecules of the moderator increases. After
other structure by a variety of decay processes.
sometime they both attains same energy. The neutrons are
(3) We could not survive without the 3.90 1026 watt
then in thermal equilibrium with the molecules of the
output of one near by fusion reactor, our sun.
moderator and are called thermal neutrons.
(4) Nuclei are made up of proton and neutron. The
number of protons in a nucleus (called the atomic number or Energy of thermal neutron is about 0.025 eV and speed is
proton number) is represented by the symbol Z. The number about 2.2 km/s.
of neutrons (neutron number) is represented by N. The total
Types of Nuclei
number of neutrons and protons in a nucleus is called it's
The nuclei have been classified on the basis of the
mass number A so A = Z + N.
number of protons (atomic number) or the total number of
(5) Neutrons and proton, when described collectively are
nucleons (mass number) as follows
called nucleons. A single nuclear species having specific
values of both Z and N is called a nuclide. (1) Isotopes : The atoms of element having same atomic
(6) Nuclides are represented as where X denotes number but different mass number are called isotopes. All
the chemical symbol of the element. isotopes have the same chemical properties. The isotopes of
Neutron some elements are the following
of (A – Z) is same. Some examples are (3) These are attractive force and causes stability of the
nucleus.
forces.
where m = Average of mass of a nucleon (= mass of
proton + mass of neutron = 1.66 10–27 kg) and mA = Mass
of nucleus Atomic Mass Unit (amu)
(1) In nuclear physics, a convenient unit of mass is the
Forces that keep the nucleons bound in the nucleus are (2) The amu is defined as mass of a at on.
called nuclear forces. (3) 1 amu (or 1 u) = 1.6605402 10–27 kg .
of hydrogen atom (me + mp) = 1.6729 10–27 kg = 1.0078 amu The rest-mass energy of each of positron and electron is
(5) The energy associated with a nuclear process is E0 = m0c2 = (9.1 10–31 kg) (3.0 108
amu is equivalent to 931 MeV or 1 amu (or 1 u) = 931 MeV electric effect or Compton effect on striking the matter.
Tritium 3.016049
Helium 3.016029
Nuclear Stability
Helium 4.002603
Among about 1500 known nuclides, less than 260 are
Lithium 7.016004
stable. The others are unstable that decay to form other
Beryllium 9.012182
nuclides by emitting , -particles and - EM waves. (This
Carbon 12.000000
process is called radioactivity). The stability of nucleus is
Nitrogen 14.003074
determined by many factors. Few such factors are given
Oxygen 15.994915
below :
+1 0 equal (N Z) i.e.
h +Ze (ii) Heavy nuclei are stable only when they have more
-photon Nucleus neutrons than protons. Thus heavy nuclei are neutron rich
–1 0
Fig. 26.14
PRADIP SIR’S PHYSICS
Atomic and Nuclear Physics 9
compared to lighter nuclei (for heavy nuclei, more is the (ii) An even-odd nucleus (even Z and odd N) or odd-even
number of protons in the nucleus, greater is the electrical nuclide (odd Z and even N) is found to be lesser sable while
repulsive force between them. Therefore more neutrons are the odd-odd nucleus is found to be less stable.
added to provide the strong attractive forces necessary to
(iii) Only five stable odd-odd nuclides are known :
keep the nucleus stable.)
72
64
56 Mass Defect and Binding Energy
48
(1) Mass defect (m) : It is found that the mass of a
40
32 nucleus is always less than the sum of masses of it's
24 constituent nucleons in free state. This difference in masses
16
is called mass defect. Hence mass defect
8
Fig. 26.15
40
30
20
10
0 Mass
A > 240
– 10 number (A)
– 20
10 Atomic and Nuclear Physics
energy is needed to pull them infinitely apart (or the same binding energy per nucleon than their neighbour nuclei. For
energy is released during the formation of the nucleus). This example . These nuclei are
energy is called the binding energy of the nucleus. more stable than their neighbours.
Binding energy per nucleon Stability of nucleus (1) Q value or energy of nuclear reaction : The energy
Binding Energy Curve absorbed or released during nuclear reaction is known as Q-
It is the graph between binding energy per nucleon and value of nuclear reaction.
6.0
Li
4.0
2.0
H2
0
50 56 100 150 200
Mass number A
Fig. 26.17
PRADIP SIR’S PHYSICS
Atomic and Nuclear Physics 11
If Q < 0, The nuclear reaction is known as endothermic. (1) The process of splitting of a heavy nucleus into two
(The energy is absorbed in the reaction) lighter nuclei of comparable masses (after bombardment with
Fission
fragmen
Mass number (A) Before the reaction After the
t
reaction
4 +14 = 18 17 + 1 = 18
235
U
Neutron
Fission
Charge number (Z) 2 + 7 = 9 8+1=9 Neutron s
fragmen
s
Fig. 26.18 t
(ii) Conservation of momentum : Linear
momentum/angular momentum of particles before the
reaction is equal to the linear/angular momentum of the
particles after the reaction. That is p = 0 (3) Fission reaction of U235
Nuclear Fission
12 Atomic and Nuclear Physics
(8) The mass of the compound nucleus must be greater
weight atoms.
Condenser
Moderator Water
Heat
Coolant in
exchanger
PRADIP SIR’S PHYSICS
Atomic and Nuclear Physics 13
(iii) In manufacturing of which is used in atom present rate, it would take about to exhaust its
(iv) They are used to produce neutron beam of high (5) For the same mass of the fuel, the energy released in
intensity which is used in the treatment of cancer and fusion is much larger than in fission.
nuclear research. (6) Plasma : The temperature of the order of 108 K
Nuclear Fusion required for thermonuclear reactions leads to the complete
ionisation of the atom of light elements. The combination of
(1) In nuclear fusion two or more than two lighter nuclei
base nuclei and electron cloud is called plasma. The
combine to form a single heavy nucleus. The mass of single
enormous gravitational field of the sun confines the plasma
nucleus so formed is less than the sum of the masses of
in the interior of the sun.
parent nuclei. This difference in mass results in the release
The main problem to carryout nuclear fusion in the
of tremendous amount of energy
laboratory is to contain the plasma at a temperature of 108K.
No solid container can tolerate this much temperature. If this
problem of containing plasma is solved, then the large
P P
n P quantity of deuterium present in sea water would be able to
2
P 3
He 4
He
P H
P P nP P P serve as in-exhaustible source of energy.
n n n n n
P P
P P
Table 26.7 : Nuclear bomb (Based on uncontrolled
e+
P nuclear reactions)
Fig. 26.22
Atom bomb Hydrogen bomb
(2) For fusion high pressure ( 106 atm) and high
Based on fission process it Based on fusion process.
temperature (of the order of 107 K to 108 K) is required and
involves the fission of U235 Mixture of deutron and tritium
so the reaction is called thermonuclear reaction. is used in it
(3) Here are three examples of energy-liberating fusion In this critical size is There is no limit to critical size
important
reactions, written in terms of the neutral atoms. Together the
Explosion is possible at High temperature and
reactions make up the process called the proton-proton
normal temperature and pressure are required
chain. pressure