All India Test Series (JEE–2024)

AJAA2/03 Test- 03 Arjuna JEE

DURATION ::180
DURATION Minutes
90 Minutes DATE : 17/12/2023 M. MARKS : 180

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (C) 35. (C)
18. (A)
2. (B) 36. (A)
19. (D)
3. (A) 37. (D)
20. (C)
4. (A) 38. (A)
21. (C)
5. (A, C) 39. (A, B, C, D)
22. (B, C, D)
6. (A, B, D) 40. (A, C)
23. (B, C)
7. (B, C) 41. (A, D)
24. (A, B, C)
8. (49) 42. (6)
25. (8)
9. (1) 43. (3)
26. (03)
10. (7) 44. (20)
27. (74)
11. (1) 45. (21)
28. (530)
12. (5) 46. (10)
29. (3)
13. (2) 47. (13)
30. (20)
14. (2.00) 48. (10.03)
31. (00.50)
15. (8.00) 49. (10.03)
32. (30.00)
16. (45.00) 50. (0.40)
33. (8.75)
17. (25.00) 51. (110.11)
34. (4.00)

[1]
 PART-I (PHYSICS)
1. (C) 1
tan 
a a a 2u y 2 = tan(1 + 2 )
+ + 2 = …(1) 1
ux eux e ux g 1−
2
Horizontal range:
θ1 + θ2 = α
2.uxu y
R= …(2) Also, b2  4ac
g (–sin α)2  4 × 2 cos α × cos α
Solving we get
2. (B)
1
dv v2 dv v2   cos−1  
− = & −v =  3
dt R ds R
7. (B, C)
3. (A) With respect to the reference frame attached to the
box pseudo force mg sin  will act on the bob up
the inclined plane. From work energy theorem (In
the reference frame attached to the box)
1
mg cos 60°. (1 – cos 60°) = mv2
2

If pulley is ideal,
a +a gl
aP = 1 2 v =
2 2
mv2 mg m gl
4. (A) T – mg cos 60° = T = + = mg
l 2 l 2
From conservation of mechanical energy
mgh = Mg ( a 2 + h2 – a ) 8. (49)
42 L
g=
5. (A, C) T2
To find F draw the F.B.D of the mass. then apply t t
Here, T = and T = .
work energy theorem to get maximum speed. n n
T t
Therefore, =
6. (A, B, D) T t
Timer for OA is t = 2u sin( − ) = u cos( − ) …(1) The errors in both L and t are the least count
g cos  g sin 
errors. Therefore,
Solving this equation we get
 g   L   T 
2 tan2 θ cos α – sin α. Tan θ + cos α = 0  =  + 2 
This quadratic equation has two roots  g   l   T 
sin  1 0.1 1
tan 1 + tan 2 = = tan  …(2) = + 2   = 0.027
2cos  2 20.0  90 
Thus, the percentage error in g is
 g   L   T 
100   = 100   + 2 100  T 
 g   L   

cos  1 9. (1)
tan 1  tan 2 = = …(3)
2cos  2 At the instant of collision, the situation is shown
By (2) & (3) in figure.
tan 1 + tan 2
= tan(1 + 2 )
1 − tan 1.tan 2
[2]
 2 x2 
2
 dx 
 dt  = u  1 − 2
   R 
R t
dx
 x2
= u  dt
0
1− 0
R2
R
The velocity of the discs along two perpendicular  x
axes before collision are R sin −1  = ut
 R 0
vx = 10 cos 45° = 5 2 m/s and
22
vy = 10 sin 45° = 5 2 m/s 28 
7 ut
Along x-axis, by conservation of momentum we 2
have
t = 11 sec.
5 × 5 2 + 0 = 0 + 10vx2 …(i) 10 + x = 11
or vx2 = 5 2m / s
12. (5)
Here vx2 is the velocity of the plate after collision
in the x direction. p = (0.1 50cos37 − 0.1100)2 + (0.1 50sin 37) 2
v 1 = 62 + 32 = 3 5 kgm/s
Also e = x2 =
vx 2 kf = ki
1 1 1 45
10. (7)   0.11002 =  0.1 502 + 
2 2 2 m
VmM = 4iˆ + 3 ˆj
45
Vm = uiˆ + 3 ˆj = 1000 = 250 +
m
VM = −Viˆ 45
m= kg
Here, along horizontal direction mVm + MVM = 0 750
um 4 mv2
V= = u and u + V = 4  u = T= + mg
M 1+  l
To move one meter w.r.t. ground = 150.6
4
2 3
1+  24 14
1= 1+  = or  = = 1.40 13. (2)
g g 10 V⊥
=
|r |

11. (1)

1
r |=
5
1
| v⊥ |= 2cos  = 2 
5
At any time t
ωA = ωB = ω/R (14-15)
vt = ωBx
u
vt = x
R
vb = u
dx
Vx2 + Vr2 = u Vr =
dt
2 2R
 u  2  dx   R sin  = 2R cos  … (i)
 2  x +  dt  = u
2
g cos 
R   
mg sin  = m2R …. (ii)
[3]
  tan  = 1 or sin  =
1 and cosθ = sinθ = 1
2 2
R R 2
=
g
and h =
R h = R cosθ = =
2 2
2R 2
14. (2.00)
16. (45.00)
15. (8.00) 17. (25.00)
Solution For (14 – 15)
If line AO makes angle 90 – θ with horizontal Solution For (16-17)
2
1  2R  Relative acceleration is O when both are in motion and g
then g cos .   = 2R when only one is in motion. From graph it can be
2  g sin  
observed that first stone is released at t = 0,
sin 2  Second stone is released at t = 1
 2 R = g
cos  First stone lands at t = 3 and second stone at t = 4.
Now ω2R = g cosθ …. (Centripetal force equation) 1 1
Height of tower = gt 2 = (10)(9) = 45m
1 − 4 R 2  2 2
 g2  When first stone hits the ground, the second stone is in
 ω2R = g   motion for 2 seconds.
  R
2

 g   v = gt = (10) (2) = 20 m/s
1 1
s = gt 2 = (10)(4) = 20m
g g 8 2 2
 = =
2R 4R  h = 45 – 20 = 25 m

PART-II (CHEMISTRY)
18. (A) 21. (C)
50 0.6 XO
%A= 100 = 75 % XO + X2O3 + K2Cr2O7 → + Cr+3
50 0.6 25 0.4 4
a
b mole
19. (D) mole
Pressure of H2O = 20 torr +2 +3 +6 +7
xf = 4 × 2 = xf = 3 × 2 =
pressure due to CO, Cl2, and COCl2 in final state xf = 5
8 6
= 80 torr
eXO eX2O3 eK2Cr2O7 e
XO4
COCl2 → CO + Cl2
a×5+b×8=3×6 …(1)
100 – x x X
POAC on X = nXO + n X2O3 2 n
XO4
2
Total pressure = (100 + x) × = 80
3
x = 20 torr.
2 60 a=2
PCOCl2 (final) 80 torr
3 3 2b = 4 – 2 = 2
20 2 40 b=1
PCO (final) PCl2 (final) torr
3 3 Mass eqn : a × Molecular Weight(XO) + b ×
PH2O(g) 20 torr Molecular Weight (X2O3 ) = 280

3 4 2 2 × (M × 16) + (2M × 48) = 280

x CO 4M + 32 + 48 = 280
100 30 15
4M = 280 – 80 = 200
M = 50
20. (C)
V 1 1 22. (B, C, D)
, Applying V = 2.188 × 106 × , we AB2(g) + A(s) 2AB(g)
C 413 n
0.7 – x 2x
get n = 3.
Total pressure = 0.7 – x + 2x = 0.95
[4]
 x = 0.25 P2
dP Hvap T2 1
(0.5)2
0.25 5 Vβ – Vα = Vgas – Vliquid
kp = P1 P R T T2
1
(0.45) 0.45 9
nRT
Let at new equilibrium Vβ =
AB2(g) + A(s) 2AB(g)
V
x y P2 vap H 1 1
ln
then x + y = 0.4 P1 R T1 T2
y2 5
kp =
x 9 (B) H2O(l) H2O(g)
y2 5 NBPt of water  P = 1 atm, T = 373 K
0.4 y 9 P2 Hvap 1 1
ln
y = 0.27 P1 R T1 T2
0.27 ln 10 = 2.3
% AB = 100 67.5%
0.4 10 8.3 4.6 10 3
1 1
%AB2 = 32.5 % ln
1 8.3 373 T2
23. (B, C) Hvap = 8.3 × 4.6 kJ/mole
th 3
1 8.3 4.6 10 1 1
When base is neutralised 2.3 =
5 8.3 373 T2
RNH2 + HCl → RNH3Cl 1 1 1 1 1 1

a x 2000 373 T2 T2 373 2000
a – a 373 2000
4 T2 = = 458.51 K
5 5 1627
a/5
pOH = pKb + log
4a / 5 25. (8)
1
5 = pKb + log
4
pKb = 5.6
pH = [pKw – pKb – log C]
 4.5 × 2 = (14 – 5.6 – log C)
log C = –0.6
C = 0.25
Let V ml of HCl is used
0.5 V
= 0.25
V 100
V =100 ml
M. Moles of acid = M. Moles of base
= 0.5 × 100 = 50
50 10 3 45
Wt. % of base in sample = ×100 =
2.5 26. (03)
90 PNH3 .VNH3 0.5 2 1
n NH3 mol
24. (A, B, C)
RT 300 R 300 R
dP Hvap n Hvap n PO2 .VO2 1.5 1 1.5
(A) n O2 mol
dT T V T(V V ) RT 300 R 300 R
A(liq) A(gas) 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(l)
H vap n 1 1.5
= Va << Vb Given: mol
nRT 300 R 300 R
T
P
Here NH3 is limiting reagent

[5]
 1 1.5
1200 R 1500 R
1
n NO(g) formed mol
300 R
(b)
1 R 300 1
PNO(g) atm atm
300 R 3 3
1 (c)
9 3
3

27. (74)
m. moles of KI = 50 × 0.04 = 2
m. equivalent of thiosulphate solution reacted
with 10 ml solution = 20 × 2.5 × 10–3 = 50 × 10–3 z = (a + b) – c
m. equivalent of I– left unreacted in 100 ml z = (3 + 2) – 2 = 2
100
solution  50 × 10–3 ×  0.5
10 30. (20)
m. moles of I– reacted with CuCO3 = 2 – 0.5 = First letter (R) : n–l–1=5
1.5 l=1
 n=7
2Cu2+ + 5I– → 2 CuI + I 3
KZe2
2
2+ Second letter (O) : PE = ,
m.moles of Cu = × 1.5 = 0.6 r
5
weight of CuCO3 = 0.6 × 10–3 × 123.5 KZe2
TE =
weight % of CuCO3 2r
3 PE
0.6 10 123.5 100  2
= 74.10 TE
0.10
1240
Third letter (C) : 0.04 (KE)max
12400
28. (530)
 (KE)max = 0.06 eV
dG = V.dP – S.dT;
150
at const. volume = = 50 Å = 5 nm
0.06
G = V.P – (10 10 2 T).dT
Fourth letter (K) :
P1 P2
 P2 = 1 × 400/300 Number of radiations = (n2 – n1)
T1 T2 = (5 – 2) = (3) = 3 + 2 + 1 = 6
G = 24.6 × 4 1 ×100 –
3 31. (00.50)
3O2(g) 2O3(g)
2 T22 T12
10 100 10 Initial volume 1 litre 0
2 2 After reaction 1 – 3x 2x
1 Total volume of gaseous mixture
G = 24.6 × ×100 –
3 = 1 – 3x + 2x = 0.8
x = 0.2
[1000 +10–2 × 160000 90000 ]
2 2 Volume of O3 0.4
Mole fraction of O3 = = 0.5
1 Total volume 0.8
= 24.6 × × 100 – 1000 – 350 = –530 J
3
32. (30.00)
29. (3) Turpentine Oil
(O3 O2 ) O2
100 mL 40mL

Therefore volume of O3 is 60 mL.

(a)
2O3 3O2
2 mL 3 mL
60 mL 90 mL
[6]
 Total volume now = 40 + 90 = 130 mL ( Sm,0K = 1 Cal/mole)
Change (increase) in volume = 130 – 100 = 30
mL Sm,400K x(g)

Sm,400K Sm,0K
33. (8.75)
200k nC 400k nC
300 p,m(s) dT Hfusion p,m(l) dT Hvap
H300 H200 (nCp,m )dT
0k T 200 200k T 400
200
300
3 3
H300 10 0.05TdT 10 10 100 80 10
200 = 20 + + 0.05 × 200 +
200 400
2 300 = 280 cal/mole
T 3
= –0.05 10 = 280 + 1 = 281 Cal/mole
2
200
Sm,400K x(l)
3 3002 2002
= –0.05 10
2 Sm,400K Sm,0K
200k nC 400k nC
9 4 p,m(s) dT Hfusion p,m(l) dT
= –0.5 = – 0.5 × 2.5 = – 1.25
2 0k T 200 200k T
= 20 + 50 + 10
34. (4.00) Sm,400K x(l) = 81 cal/mole
Sm,200K x(s)
Sm,200K x(l)
200k nC
p,m(s) dT
Sm,200K – Sm,0K = 200k nC
p,m x (s) dT Hfusion
0k T Sm,200K Sm,0K
0k T 200
200k
0.1TdT
= = 0.1 × 200 = 20 Cal/mole = 20 + 50
0k T
Sm,400K x(l) = 71 cal/mole
Sm,200K = 20 + 1 = 21 Cal/mole

PART-III (MATHEMATICS)
35. (C) x 2 + y −1 x 2 − y +1
Given P(5, 3) and equation of RQ is x – 2y = 2 C: = 2
3 3
 R  (2, 0) on x-axis
( x 2)2 − ( y − 1)2
C: = 2
3 3
 C : 2x − ( y −1)2 = 32
2

Let R  ( x1, y1 ) and S( x2 , y2 )

C cuts y − 1 = 2 x at R and S.
and Q lies parallel to x-axis through P which is y =
3 So, 2x2 − 4x2 = 32
y = 3 and x – 2y = 2 3
x=8 x= ||
2
 Q  (8, 3)
 x1 − x2 = 6 |  |
Centroid
 5+8+ 2 3+3+ 0  and y1 − y2 = 2 x1 − x2 = 2 6 |  |
G  ,   (5,2)
 3 3  RS2 = 270 (given)
(5, 2) lies on 2x – 5y = 0
 ( x1 − x2 ) + ( y1 − y2 ) = 270
2 2

36. (A)  ( 6)2 + (2 6 |  |)2 = 270

According to the question,
 30 2 = 270   2 = 9

[7]
37. (D)  p2 = a(b + 1)
 1 + b, p, a are in G.P

x  (–, )  (2, 2) 41. (A, D)

for  = 5  x  (–, 5)  (10, 25) Let x1, x2, x3, x4 be the roots of give equation.
Prime numbers are 2, 3, 11, 13, 17, 19, 23  x1 + x2 + x3 + x4 = 4 and x1x2x3x4 = 1
x + x + x3 + x4 4
Now A.M. of roots = 1 2 = =1
38. (A) 4 4
f(x) = Ax2 + Bx + C = 0 1
And G. M. of roots = ( x1x2 x3 x4 ) 4 = 1
(i) D  0  a  (–, –2]  [6, ) …(i)
−B  A.M. = G. M
(ii)  −2  a > – 4 …(ii)
2A Which is possible only if
7 x1 = x2 = x3 = x4 = 1
(iii) Af(–2) > 0  a > – … (iii)
3  given equation will be of the form
From above equations (x – 1)4 = 0
 7   x4 – 4x3 + 4C2x2 – 4C3x + 1 = 0
a   − , − 2  [6, )
 3   x4 – 4x3 + 6x2 – 4x + 1 = 0
Comparing, we get p = 6, q = –4
39. (A, B, C, D)
42. (6)
 2 4  4 4 
tan + 2tan + 4tan + 4  cot – tan  1 – cos 2 x 1 – cos 4 x
9 9 9  9 9  + =1
2 2
 2 4
= tan + 2 tan + 4cot 2cos3x . cosx = 0
9 9 9
  7 5 3 11
 2  2 2  x= , , , , ,
= tan + 2tan + 2  cot – tan  6 2 6 6 2 6
9 9  9 9 
 2 43. (3)
= tan + 2cot
9 9 By observing graph

= cot
9
1    1 
(A)  cot – tan  =  2cot 
2  18 18  2  9
2 
1 + cos 2cos 2
(B) 9 = 9 = cot 
2   9
sin 2sin .cos
9 9 9
 2   44. (20)
1 + cos + cos cos + 2cos2
(C) 9 9 = 9 9 = cot  a b
 2    1− i 2  i −1 3
1+ i  =1 = 1+ i 
sin + sin 9
sin 1 + 2cos 
9 9 9 9    
2    a b
sin + cos cos 1 + 2sin   (1 − i )2  2  ( i − 1)2  3
(D) 9 9 = 9 9  = cot 
 2     =1=  
1 + sin – cos sin + 2sin 2 9  2   −2 
9 9 9 9    
a b
40. (A, C) ( −i ) 2 = 1 = (i ) 3
x2 – (a + b) x + ab = 0 aminimum = 8
 x = a or b bminimum = 12
If x = a is root of other equation then
a3 – ap2 + ab = 0 45. (21)
 p2 = a2 + b Given quadratic expression
2
If x = b is root of the other equation then (1 + 2λ)x – 2(1 + 3λ)x + 4(1 + λ), is positive for
ab2 – p2b + ab = 0 all x  R, then

[8]
 1+2λ>0 ...(i) 48. (10.03)
D<0 1 1
+ + .....
2
 4(1 + 3 λ) – 4(1 + 2 λ)4(1 + λ) < 0 2cos 2 cos  2cos3 cos 2
2 2
 1 + 9λ + 6λ – 4[1 + 2λ + 3λ] < 0 1
......
2 2cos ( n + 1)  cos n
 λ – 6λ – 3 < 0
1  sin ( 2 − ) sin ( 3 − 2 ) 
(
λ  3 – 2 3, 3 + 2 3 ) =  + ....
2sin   cos 2 cos  cos3 cos 2 
1
λ> − 1
2 tn = [tan(n + 1) – tan n]
2sin 
So, λ  (3 – 2 3 , 3 + 2 3 ) On adding the required sum is
So integral values of λ = {0, 1, 2, 3, 4, 5, 6} 1
Sum of natural values of λ is 21 = [tan1001 – tan ]
2sin 

46. (10) 49. (10.03)

Curve is 1
4x2 + y2 – x + 4y = 0 ….(1) sin 3  = [3sin  – sin 3]
4
Let the equation of chords y = mx + c ….(2) 1000
1
 joint equation of OA and OB is  3n–1 sin3 (3n–1)
n=1
 y − mx   y − mx 
4 x2 + y 2 − x   + 4y   = 0 ….(3) 1 1000  1 1 
 c   c    
4 n=1  3n –2
sin(3n –1 ) – n –1 sin3n 
3 
OA ⊥ OB
 coeff. of x2 + coeff. y2 = 0 On addition required sum
 m  4 1 1 
= 3sin  – 999 sin31000 
  4 + c  + 1 + c  = 0 4 3 
   
 5c + m + 4 = 0
put m = –4 – 5c is (2), we get 50. (0.40)
y = (–4 – 5c) x + c log4 (log5(x2 – 3x – 5)) > 0
y + 4x + c (5x – 1) = 0 log5 (x2 – 3x – 5) > 40
clearly the line will pass through x2 – 3x – 5 > 51
x2 – 3x – 10 > 0
 1 −4 
 5 , 5  = ( m, n) (x – 5) (x + 2) > 0
 
x  (–, –2)  (5, )
1 4
− = 5 + 5 = 10 l 2
m n = = 0.40
m 5

47. (13)
51. (110.11)
(a, b, c) can be selected 6C3 ways
|log10x|2 – 3 |log10x| + 2 = 0
but triplets (2, 3, 7), (2, 3, 6), (2, 3, 5), (2, 4, 6),
|log10x| = 1, 2
(2, 4, 7), (2, 5, 7) (3, 4, 7)
log10x = 1, 2
Must be rejected because it can not form triangle
1 1
so number of ways = (6C3 – 7) = 13 x = 10, ,100,
10 100
sum = 10 + 0.1 + 100 + 0.01 = 110.11

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