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Adda247 Capsule 466

The document is a chemistry quiz for 12th-grade students consisting of two sections: Section B with 7 short answer questions and Section C with 5 short answer questions. The questions cover various topics including reaction rates, properties of glucose, isomer structures, electrolysis, and coordination complexes. Each question carries a specific mark allocation, and some questions offer internal choices.

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2 views2 pages

Adda247 Capsule 466

The document is a chemistry quiz for 12th-grade students consisting of two sections: Section B with 7 short answer questions and Section C with 5 short answer questions. The questions cover various topics including reaction rates, properties of glucose, isomer structures, electrolysis, and coordination complexes. Each question carries a specific mark allocation, and some questions offer internal choices.

Uploaded by

abhishekmandal82069
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Chemistry (Class – 12th)

Chemistry
Quiz 2
Section B
This section contains 7 questions with internal choice in two questions. The following questions are very short
answer type and carry 2 marks each.
Q1. A first-order reaction takes 69.3 min for 50% completion. What is the time needed for 80% of the reaction
to get completed? (Given; log 5 = 0.6990, log 8 = 0.9030, log 2 = 0.3010)
Q2. Account for the following:
(a) There are 5-OH groups in glucose.
(b) Glucose is a reducing sugar.
OR
What happens when D-glucose is treated with the following reagents?
(a) Bromine water
(b) HNO3.
Q3. Explain how and why will the rate of reaction for a given reaction be affected when
(a) A catalyst is added
(b) The temperature at which the reaction was taking place is decreased
Q4. Write the reaction and IUPAC name of the product formed when 2-Methylpropanal (isobutyraldehyde) is
treated with ethyl magnesium bromide followed by hydrolysis.
Q5. Give reason for the following
(a) During the electrophilic substitution reaction of haloarenes, para substituted derivatives is the major
product.
(b) The product formed during SN1 reaction is a racemic mixture.
OR
(a) Name the suitable alcohol and reagent, from which 2-chloro-2-methyl propane can be prepared.
(b) Out of the Chloromethane and Fluoromethane, which one has higher dipole moment and why?
Q6. The formula Co(NH3)5CO3Cl could represent a carbonate or a chloride. Write the structures and names of
possible isomers.
Q7. Corrosion is an electrochemical phenomenon. The oxygen in moist air reacts as follows:
O2(g) + 2H2O(l) + 4e- → 4OH- (aq)
Write down the possible reactions for corrosion of zinc occurring at anode, cathode, and overall reaction to
form a white layer of zinc hydroxide.

Section C
This section contains 5 questions with internal choice in two questions. The following questions are short
answer type and carry 3 marks each.
Q8. (a) What type of aldehydes undergoes Cannizzaro reaction?
(b) Arrange the following compounds in increasing order of their property as indicated:
(i) CH3COCH3, C6H5COCH3, CH3CHO (Reactivity towards nucleophilic addition reaction)
(ii) Cl-CH2-COOH, F-CH2-COOH, CH3-COOH (acidic character)

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Chemistry (Class – 12th)
OR
(A), (B) and (C) are three non-cyclic functional isomers of a carbonyl compound with molecular formula C4H8O.
isomers (A) and (C) give positive Tollen’s test whereas isomer (B) does not give Tollen’s test but gives positive
Iodoform test. Isomers (A) and (B) on reduction with Zn (Hg)/conc. HCl give the same product (D).
(a) Write the structures of (A), (B), (C) and (D)
(b) Out of (A), (B) and (C) isomers, which one is least reactive towards addition of HCN?
Q9. (a) Solutions of two electrolytes ‘A’ and ‘B” are diluted. The limiting molar conductivity of ‘B’ increases 1.5
times while that of ‘A” increases 25 time. Which of the two is a strong electrolyte? Justify your answer.
(b) The products of electrolysis of aqueous NaCl at the respective electrodes are:
Cathode: H2
Anode: Cl2 and not O2. Explain.
Q10. Give reasons:
(a) E0 value for Mn3+/Mn2+ couple is much more positive than that for Fe3+/Fe2+.
(b) Iron has higher enthalpy of atomization than that of copper.
(c) Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.
Q11. (a) Explain why [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital
complex. (At. No. Co = 27, Ni = 28)
(b) Why CO is stronger complexing reagent than NH3?
(c) Write the coordination number and oxidation state of platinum in the complex [Pt(en)2Cl2].
Q12. Write the equation for the following reaction:
(a) Salicylic acid is treated with acetic anhydride in the presence of conc. H2SO4.
(b) Tert-butyl chloride is treated with sodium ethoxide.
(c) Phenol is treated with chloroform in presence of NaOH.
OR
(i) Haloalkanes undergo nucleophilic substitution whereas haloarenes undergo electrophilic substitution.
Explain.

(ii) Give the IUPAC name of the following compound:

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