3 Semester Pyq
3 Semester Pyq
3. Applying the Gibbs theorem for a multicomponent ideal gas mixture, derive
the relation S'8 =ykS- REyLIny, . Similarly applying the relation for
Gibbs energy GieykG, +RTEy.lny; derive the relation forthe chemical
potential of component i, in an ideal gas mixture. Derive Raoult's law
using the equality of chemical potentials for VLE. (6)
..-G00D LUCK!----.
MALAVIYA NATIONAL INSTrrUTE, OV TECHNOLDGYJAIPUR
B. Tech (Chemical Engineering)- I10Semester
Mid Semester
Examination -2023-24
Computer Alded Numerical Methods (22CHT202)
Date IN/09/2023
Tie: 10 0 12:00 Duration: Ihour 30 mins
(30 marka)
All questionsare compulsory. Missing data if any may be assumed suitably. Seek no
clarification.
Q1. (3 x 2 - 6 Marks]; Suggested time- 10 mins
a) Graphically explainthe Regula-falsi method.
b) Write the formula of Trapcoidal and Simpson's I/3 rule.
c) Write the final form of Newton's forward interpolation and Lagrange's interpolation.
Latm L.atm
Given: a 5,46 h 0.0305 L/mol, R 0,082
moj? mol.K
Time, t (min) 20
Filtrate volume, V(ml) 65 72 78
Page 1 of 2
Q5. (8 Marks]; Suggested time = 25 mins
flowing in the inner tube. The
On one side of a double pipe heat exchan ger is saturated steam and water is
diameter of the inner pipe is 2.4
temperature of entering water 20°C and the velocity of water is I m/s. The inner of 2 mfromthe inlet using
cm. Under steady state conditions, determine the temperature of water at the length
Runge-Kutta 4h order method considering astep size (h) of I m.
of water is 1000 kg/m' and
Assume that the temperature does not change along the radius ofthe pipe. The density inner pipe is 200 W/mK
coefficient of the
the specific heat capacity is 4184 J/kg.K. The overall heat transfer
and the temperature of saturated steam is 250 °C.
Steam
inCpT,-T)
Water
Page 2 of 2
Boll \o. 20220CH |o66
Page 1 of 2
Roll No. 20 220CHlo&<
Malaviya National Institute of Technology Jaipur
Department of Chemical Engineering
Mid Term Examination 2023-2024
B. Tech IIISemester, Mechanical Operations [22CHT-20S]
Time: 90 Min.
Marks: 30
Surta
6
Specitic
Pale
Galena and
of calcite
Ratio
2000
3000
4000
6000
20.000
10,00O
Page 2 of 2
MALAVIYA NATIONAL INSTIUTE OF TCUNOL0GY JA"'
DEPARTMENT 0F CEMICALENGINEERING
Mid- TermFmination Selember 202,3(0dd semester 20023-24)
(OCRSE COD:22MST241
(oURSE NAME: Fundanental of Materials
Fngineering MAN. MARKS: 30
DURATION: 1,5 Hrs
Noe RCad the questions caretull, nd answer all uuesiouy he answer of cach question shouto
Matks lor cach question are mentnedin parenthesis Usw ol caleulator is permitted
Qstrate (100). (|10, ) nd lles in eubic lattice and direction indices o |0m
(4 marks)
|1001. and |20|
with alatite Dareler of 0.,2866 n. Onlan e
QA 278K, iron (he i loun lo sho bee seute
le is 55.845 P)C
0 ron lrom his nlo)uion, (atouie Weh M molu ESS) Der Lmol of
Unsy
uks)
only Iwo (etragonal Bravais lattiCes.
Q3 Thcre are lour orthorhombi Bravais lattices but
lattice is cyuivalent lo aprimitive (P) leraponal
latticc.
( ) Show that abase-centered(O tetraponal () terapoal latticc
leragonal lattice is cuuivalentto a bodv-cenlered
)
(b) Show that a lace-cenleed
(4 marks)
Miller indices for the following planes
alon! with the directions normal
Q4 Delemine the
(4 marks)
lo cach plane.
a) b)
241
c) d)
)5 Ixplain workng principle and instrumentatio of the X-ray Diflractometer (XKD) technique with neat
diagram. How we can predict crystal structure of materials with the help of XRD (4 marks)
()6Cie thc four components that are nvolved in the design. production. and utilization of materalk, and hriefly
describe the interrelationships bctween thee components (3 marks)
)7(a) Brielly cites the main d1tterences betwecn ionic. covalent. and metallic honding
(b) What typets) of hondinp would be espected for cach of the follow ing matcrials: brass (a copper rinc alloy).
rubber. barium sulfide (BaS). olid senon, brone. nylon. ad alummum plosphide (AIPY (4 Marks)
Q.8 For BCC iron, compute (a) the ínterplanar spacing and (b) the diffraction angle for the (220) set of planes.
The lattice paramcter for Ie is 0.2866 nm, Also. assunc that monochromatic radíation having a wavelength of
0.1790 om is used. and the order of rellectionis I (3 marks)
09 Why FCC metals are ductile while BCCand |ICP metals are not? (2 marks)
DEPARTMENT OF CHEMICAL ENGINEERING MNIT.
22CHT201 Chemical Engineering Thermodynamics-lI End Tem Exam 2023
Max Marks: 100 Time: 2.1/2 hs Date: 20-ll-2023
Attempt all questions
Q1. For the nitrogen(1)/methane (2) binary gas mixture with mole fractions y,=0.4 at 200 °K
and 30 bar, estimate 1, , and B.
Species Ti K Pibar Zi Vi
cm'mol!
11 126.2 33.9 0.29 0.04 89.5
22 190.6 46 0.288 0.008 220-499| (29)
B°= 0.083-0.422/T6 and B!=0.139- 0.172/T42 (20)
Q2. (a) Applying the defining relation dá, =RT dinf at constant temperature, and the Lewis
Randall rule, derive the relations for determining G, HM, vií, and Sid, given the composition,
(10) ()
temperature, R, and the corresponding pure component properties (e.g. G; for G")
(b) Construct the block diagram for flash calculations for non-ideal VLE showing appropriate
(10) (5)
equations and functional correlations.
Q3. LiCL.2H,0(6) (AHP298 -1012.65 k) is dissolved in water(AHf298 =-285.830 kJ) to form
LiCI(10H,0) solution. (AH298 for LiCi (10H20) = 441.579kJ). Determine the heat effect per
mole of solution.
(10) (7o)
(b) For the Margules equations prove the Gibbs Duhem equation and M= x; M; (10) (6)
Q4. (a) The molar enthalpy (J mot) ofa binary liquid mixture at given T and Pis represented
by H=400x, + 600x2 + (40x + 20x)x1X2. Determine the values of H, H, H, HE HE, and H,
for x,-0.5. (10) (6)
(b) Toluene (1) and water (2) are essentially immiscible as liquids. Determine dew-point
temperatures and the compositions of the first drops of liquid formed when vapor mixtures of
these species of mole fractions z = 0.23 and z, = 0.77 are cooled at the constant pressure of
101.33 kPa. In P,st = 14 -3103/(t +219.8),ln P,l = 16.3 -3800/(t + 226.3) in kPa and 'C. (10)( lo)
Q5.The following reaction reaches equilibrium at 400° Cand atmospheric pressure:
CH;CHO (g) + H> (g) = CoHOH (g)
If the system initially contains 2 moles H, and 1mole of CH;CHO, what is the composition of
the system at equilibrium? Assume ideal gases. (20)
Species A B
AGi298
J/mol
AHfi,298 J/mol
(20)
CH;CH0 1.693 17.98 X10 3 -6.16 X10 6 -128,860-166,190
-3 8300
H2 3.25 0.422 X10
C,H,OH 3.52 20X10 3 -6 X10 6 -168,490 -235,100
Kantik Khandelsal
DEPARTMENT OF CHEMICAL ENGINEERING, MNIT Jaipur
B.Tech IIYr IISemester) END TERM EXAM (22/11/2023)
Fluid Mechanics (22CHT204)
6Omm
80 mm
03. A300mm x 150 mm venturimeter is provided in a vertical pipe line carrying oil of specific
gravity 0.9. the flow being upwards. The difference in elevation of the throat section of the
venturimeter is 300 mm. The differential U-tube mercury manometer shows a gauge deflection
of 250 mm. Calculate:
1
(i) The discharge of the oil, and
(ii) The pressure difference between the entrance section and the throat section.
Take the coefficient of the meter as 0.98 and the specific gravity of mercury as 13.6.
Q.4. Water is to be pumped from a ground |level tank, which is open to atmosphere to a cooling
tower. The difference between the level of water in the tank and discharge point is 15 m. The
velocity of water through 40mm internal diameter discharge pipe is 3m/s. In the pipe line there
IS a valve which is equivalent to 200 pipe diameter and a fitting equivalent to 150 pipe
diameters. The length of the entire piping is 30m. Calculate the power requirement of pump.
Data: density of water= 1000ke/m: viscosity of water=0.0008Pa.s ; friction factor f= 0.004
Q5. In a packed tower spherical coal particles of diameter 0.1mm and density 1000 kg/m are
present through which air is moving upward. The air properties are density= 2.4 kg/m and
viscosity= 1.9 x10 pa.s. Take void fraction=0.38.. Find the region of fluidization.
Q6. Assuming the law for the velocity distribution in the boundary layer as:
2
i-15) -0s()
Find the thickness of the boundary layer and the shear stress intensity 0.8 meters from the
leading edge and the drag force on one side of a plate 1.2 meters long and 1.10 meters
wide immersed in water moving at a velocity of 0.20m/s. Take u= 0.001 Ns/m.
NOTE: Do necessary derivations before calculating relevant numerical values.
Q7. "Velocity distribution for laminar incompressible flow in a smooth tube is parabolic". Prove
this statement mathematically and thereby derive Hagen-Poiseuille equation from it.
***BEST OF LUCK*
2
Roll No...20220H lo66
Malaviya National Institute of Technology Jaipur
Department of Chemical Engineering
End Term Examination 2023 (22-1 1-2023)
B.Tech IlI Sem.,Conventional &Alternate Energy Resources (CAER) (22CHT-203|
Time: 150 min. Marks: 50
Note: *Answer all questions in chronological order. Missing
data may be assumed suitably.
1)Write a short notes :
a.))Water Gas b.) Coke Oven Gas
2)Define the following.
a.)Geothermal Energy b.) Tidal Energy c.) Biodiesel
d.) Biogas e.) Pyrolysis and Gasification
3)A single solar cell (12cm x 12 cm) produces a voltage
of 0.7 Vand a current up to 3.2 A. If the solar
insolation is 650 Wm,Calculate the efficiency of the
solar cel1?
4) A Nuclear reactor using U'38 generates 263 MW of
electrical power. The efficiency of the reactor is 32%.
What is the amount ofU? used in the reactor per year?
The thermal energy released per fission of U238 is 230
MeV.
5) What is savonjus rotar? Explain its characteristics.
advantages and disadvantages.
6)Discuss the electrolytic production of hydrogen?
Explain tank type electrolyzer. |5|
7) What is producer gas? How it can be produced and
discuss the reaction zones in gas producer elaborately
with chemical reactions.
1/2
8)A coke is gasified in a producer gas plant to produce
the producer gas of following composition (%by
volume):
CO;=6, CO-26.5, H-l1.5, CH-2.5, N-53.5
The coke as used for gasification contains 3% ash & 11%
moisture containing 93% C on d.a.f basis. Calculate the
a.) Volume (Nm) of producer gas
coke gasified. produced per kg of
b.) Volume (Nm) of air required for
kg of coke (no gasification of one
nitrogen)
c.) Theoretical volume (Nm) of.
air required for
combustion of producer gas produced by the gasification
of one kg of coke.
9) A furnace is fired with a
natural gas that consists
entirely of hydrocarbons (negligible inert gases and
Sulphur compounds). The Orsat analysis of the flue
gas given 7.5% CO:, 3% O, and 2.6% CO.
a.) What is the molar ratio of net hydrogen to carbon
in the fuel?
b.)What percentage of excess air is being used?
10) Calculate the angle made by beam radiation with the
normal to a flat collector on December 6,at 9.00A.M.,
solar time for alocation at 27° 33"N.The collector is
tilted at an angle of latitude plus 12°, with the
horizontal and is pointing due south.
...Allthe Best....
2/2
MALAVTYA NATIONAL INSTITUTE OF TECHNOLOGY JAIPUR
B. Tech (Chemical Engineering) IIISemnester
End Sem ester Examination - 2023-24
Computer Aided Numerical Methods (22CHT202)
Duration: 2 hour 30 mins
Date: 23/1 1/2023 (50 marks)
Time: 08:00 - 10:30
time = 20 mins
Q2. (6 Marks]; Suggested algebraic equations by LU factorization method.
linear
Solve the following set of
X1 + X2 t X3 = 1
4x, + 3x, - X3 =6
3x, + 5x, + 3x = 4
/C03, Level - K2/
of
Suggested time = 20 mins formula for the following experimental data
Q3. (6 Marks]; interpolation
sec using Lagrange
of 5
Find the velocity at the end
with time.
change in velocity 4 6
1 3
Time (t in sec) 10
21 15 12
Velocity (v in m/s)
/CO1, Level - K3/
Page 1 of 2
Q5. [10 Marks];
Suggested time = 25 mins (C04, Level - K3/
hcomponentC is transported bymeans of convection and diffusion through a
figure. one-dimensional space shown in
U
X=0
X=1
Discretize the following
dC
=0
convection-diffusion equation
dx
The boundary conditions are:at x = 0, C= 0 and at x = 1, C =1.
Discretize the equation using -
a) Central difference approximation for both
convection and
difference approximation for diffusion and forwarddiffusion
b) Central terms.
difference approximation for convection term
(1 order derivative).
Represent the discretized equations in tridiagonal matrix form (Ax =
boundary. No need to solve the discretized equations. b) by taking 8 equal segments of the
[Given: =50]
D
Discretize the PDE by applying backward difference formula for time dependent derivative.
r=0.4 cm
Sphere
Page 2 of 2
Roll No.
20220CH(o 66
Malaviya National Institute of Technology Jaipur
Department of ChemicalEngineering
End Term Examination 2023-2024
B. Tech IIISemester, Mechanical Operations (22CHT-205] Marks: 50
Time: 2:30 Min.
Allquestions are compulsory.
Attempt all questions in chronological order.
Assume suitable data, if necessary
Q1 The tentative time to complete the Ql (15 min,) mm, which crushing
4
specifically for particles less than 0.005
I. a. In the particle size reduction,
law is applicable and define the law. context of particle sIze
How does the process of crushing differ from that of grinding in the
b.
reduction?
surface area of the uniformn
particulate sample 3
particles and the total
II. What are the total number of
mm and density 2650 kg/m if the
sample mass is 25kg'?
consisting of spherical particles of size 2 min.) 3
Q2 The tentative time to complete the Q2 (20
1. Define the following. sedimentation c. Sphericity
a. Terminal settling velocity b.Cut diameter in 4
screen.
II. a. Differentiate the ideal screen and actual and elaborate them?
of the industrial screening (specific gravity 2.66). The 3
the performance measures
What are limestone
b. uses a roll crusher to crash of 50 cm the clearance between the
III. The slaked lime manufacturer 170cm as diameter by a
width
crushing rolls have rolls of
110 rpm. The angle of nip is 30 degrees. Find out the
is 1cm. The rolls run at of crushing rolls.
rolls
the crusher b. Theoretical
capacity
a. Maximum field size to the 03 (35 min.) volume flow rate.
Q3 The tentative time to complete
carried at a constant pressure drop, not a constant
filtration.
Industrially, filtration is for constant pressure of 0.05m²/h. the 5
1.
your answer. Derive the mathematical expression
conducted under the constant rate
Justify
belongs to the filtration test
II. The following data solid concentration in the slurry is 25 Kg.m'.
filtration area is 0.05m, and the coefficient, and K,
filter medium resistance, Compressibility 92 103.6
Calculate the 69.5 80.5
30 34.1 43.6 52.1 |59.3 70 80 90
AP(kpa) 40 50 60
10 20 30
t (S) min.)
to complete the 04 (35 industry, and you need to 7
04 The tentative time chemical reactor in the petrochemical the one
Suppose you're in charge of a
liquid settle down effectively. Derive the equation for
ensure that solid particles in a
through fluid with assumptions. 3
dimensional motion of solid particle particles (Density= 2800 kg/m'; Diameter of the particle
the galena throughput
In centrifugal sedimentation,the water suspension. The water was fed at a volumetricapplicable.
5 um) were separated from Assume Stokes law is
l000kg/m'; viscosity = 10° Pa.s).
rate of 0.27 m'/s. (density=
value? rate of
a. Calculate the sigma size cut for a suspension of coal particles in oil fed at a
b. What will be corresponding
0.05m'/s?
Oil density 850 kg/m'; Oilviscosity 0.01 Ns/m?
Data: Coal density 1300 kg/m';the Q5 (35 min.)
The tentative time to complete depending on 2
Q5 chemical reactor in a petroleum refinery;
Imagine you're operating a fluidized bed might happen: particulate fluidization and bubbling
scenarios
various factors, two distinct type of fluidization apart from
visible observation? What
fluidization. How can you predict the
same situation?
information do you require to predict the minimum fluidization 5
velocity? Derive the equation for the
What is the minimum fluidization
velocity for the low Reynold number. m² cross-sectional area is packed with spherical particles 4
reactor of 0.05
III. Afluidized bed chemical porosity of the bed is 0.35. It is desired to fluidize the particles with
upto a height of 0.25m. The Pa.s). Determine the minimum fluidization
velocity
water (density= 1000kg/m'; viscosity = 10 particles- 0.01m; Density of the particle 2600
the
by the Ergun equation. Data: Diameter of
kg m
Page 1 of 1
MALAVIYA NATIONAL INSTITUTE OF TECHNOLOGY .JAIPUR
MATERIALS RESEARCHCENTRE
End-Term Examination Dec 2023 (Odd semester 2023-24)
COURSE CODE:22MST241
oRSE NAME: Fundamentals of Engincering Materials MAX. MARKS: 50
pURATION: 2.5 Hrs
one place.
answer all qucstions. Ihe answer of cach question should be in
and
Note: Rcad the questions carefully pernitted.
mentioned in parenthesis. Use of' calculator is
Marks for each question are
structure. eplaining the structure. (2)
0.1Give two examples of Zinc Blende
open structure. Why ? (2)
O2 Silicates in general have an
information docs i provide'? (2)
).3 Define Bond strength. What
marhed planes and directions (3)
).4 Write the indices of the
LIuu
18 3 97 8
100
Q.8 Why are metals shiny and how the color of ceramics is determined? (2 marks)
Q.9 Describe the phenomenon for development of lamellar microstructure andwhy itoccurs. (3marks)
Q.10 (a)For a ternary system, three components are present: temperature is also a variable. What the maximum
number of phases that may be present for aternary system, assuming that presure is held constant?(2 marks)
(b) Explain the development of microstructure during the nonequilibrium solidification of a 35 wt% Ni-65 wt%
Cu alloywith diagram, (3 marks)
Q.11What are the types of crystal imperfections and Why are they important? (3 marks)
).12 Discuss the factors that influence diffusion with example? (3 marks)
)13 Define the following terms: (3 marks)
(a) Dilatation (b) Poisson's Ratio (c) Proportionality limit (d) Yielding Point (e) Fracture Energy ()
Resilience
Q.14 Discuss the steady state and non steady state diffusion process with example and schematic diagram (4
Marks)
QJ5 (a) Conpute the velocity of light in calciun luoride (Cal 2). which hav a dielectric constant of 2.056 (at
Irequencies within the visible range) and amagnetic susceptibility of L43* 101.5 marhs)
(b) In your own words. brietly describe the phenomenon of luminescence. (1.5 marks)