Che201 1
Che201 1
TUTORIAL 1
INTRODUCTION
This tutorial is designed for students wishing to extend their knowledge of thermodynamics
to a more advanced level with practical applications.
• Before you start this tutorial you should be familiar with the following.
• Fluid property tables and charts mainly a set of standard thermodynamic tables
and a h - s chart for steam which you must have in your possession.
You may be very familiar with all these studies in which case you should proceed directly
to section 2. For those who wish to revise the basics, section 1 should be completed. This
covers
• entropy.
• isentropic processes.
• property diagrams.
• isentropic efficiency.
©D.J.Dunn 1
1. REVISION OF ENTROPY
1.1 DEFINITION
Entropy is a property which measures the usefulness of energy. It is defined most simply as
dS= dQ/dT where S is entropy
T is temperature
Q is heat transfer
The units of entropy is hence J/k. The units of specific entropy are J/kg K.
ISENTROPIC means constant entropy. Usually (but not always) this means a process with
no heat transfer. This follows since if dQ is zero so must be dS.
h-s diagrams are commonly used for steam work. The diagram will hence show the
saturation curve. You should familiarise yourself with the h-s diagram for steam and
ensure that you can use it to find values of h and s for any pressure, temperature or dryness
fraction.
T-s diagrams are commonly used for gas.
Real expansion and compression processes have a degree of friction and this will
©D.J.Dunn 2
An adiabatic process with friction has no external heat transfer (ΦWatts or Q Joules) but
the internal heat generated causes an increase in entropy. Consider the expansion and
compression processes on fig.1 and 2.
fig.1 fig.2
∆h (ideal) h − h1
η is = = 2' for a compression.
∆h (actual) h 2 − h1
T2 − T1
η is = for an expansion
T2 ' − T1
T2' − T1
η is = for a compression
T2 − T1
Note that for an expansion this produces a negative number on the top and bottom lines that
cancels out.
©D.J.Dunn 3
WORKED EXAMPLE No.1
A steam turbine takes steam at 70 bar and 500oC and expands it to 0.1 bar with an
isentropic efficiency 0.9. The process is adiabatic.
The power output of the turbine is 35 MW. Determine the enthalpy at exit and calculate
the flow rate of steam in kg/s.
Note you need the tables and h-s chart for steam.
SOLUTION
h1= 3410 kJ/kg (tables) s1= 6.796 kJ/kg K for an ideal expansion s1=s2'
Assuming that the steam becomes wet during the expansion, then
s2'= sf +x'sfg. at 0.1 bar
Note if x' is larger than 1 then the steam is still superheated and the solution does not
involve x.
(Note the sign convention used here is negative for energy leaving the system)
©D.J.Dunn 4
WORKED EXAMPLE No.2
A gas turbine expands gas from 1 MPa pressure and 600oC to 100 kPa pressure. The
isentropic efficiency 0.92. The mass flow rate is 12 kg/s. Calculate the exit temperature and
the power output.
SOLUTION
Now we use the isentropic efficiency to find the actual final temperature.
T2 = 485.6 K
Φ + P = m cp(T2 - T1)
©D.J.Dunn 5
SELF ASSESSMENT EXERCISE No.1
1. Steam is expanded adiabatically in a turbine from 100 bar and 600oC to 0.09 bar with an
isentropic efficiency of 0.88. The mass flow rate is 40 kg/s.
2. A gas compressor compresses gas adiabatically from 1 bar and 15oC to 10 bar with an
isentropic efficiency of 0.89. The gas flow rate is 5 kg/s.
©D.J.Dunn 6
2. BACK-PRESSURE AND PASS-OUT TURBINES
It is assumed that the student is already familiar with steam cycles as this is necessary for
this tutorial.
If an industry needs sufficient quantities of process steam (e.g. for sugar refining), then it
becomes economical to use the steam generated to produce power as well. This is done
with a steam turbine and generator and the process steam is obtained in two ways as
follows.
• By exhausting the steam at the required pressure (typically 2 bar) to the process
instead of to the condenser.
The diagram shows the basic circuit. The cycle could use reheat as well but this is not
normal.
Figure 3
©D.J.Dunn 7
WORKED EXAMPLE No.3
For a steam circuit as shown previously, the boiler produces superheated steam at 50 bar
and 400oC. This is expanded to 3 bar with an isentropic efficiency of 0.9. The exhaust
steam is used for a process.
The returning feed water is at 1 bar and 40oC. This is pumped to the boiler. The water
leaving the pump is at 40oC and 50 bar. The net power output of the cycle is 60 MW.
Calculate the mass flow rate of steam.
SOLUTION
Referring to the cycle sketch previous for location points in the cycle we can find:
The power output of the turbine is found from the steady flow energy equation so :
P = m(-550.9) kW
P = -550.9 m kW (output)
The power input to the pump is found from the steady flow energy equation so :
P = -m(3) kW
P = -3 m kW(input)
Net Power output of the cycle = 60 MW hence
60 000 = 550.9 m - 3 m
m = 109.51 kg/s
©D.J.Dunn 8
SELF ASSESSMENT EXERCISE No.2
A back pressure steam cycle works as follows. The boiler produces 8 kg/s of steam at 40
bar and 500oC. This is expanded to 2 bar with an isentropic efficiency of 0.88. The pump is
supplied with feed water at 0.5 bar and 30oC and delivers it to the boiler at 31oC and 40
bar.
Calculate the net power output of the cycle. (Answer 5.24 MW)
©D.J.Dunn 9
2.2. PASS-OUT TURBINES
The circuit of a simple pass-out turbine plant is shown below. Steam is extracted between
stages of the turbine for process use. The steam removed must be replaced by make up
water at point 6.
Figure 4
In order to solve problems you need to study the energy balance at the feed pumps more
closely so that the enthalpy at inlet to the boiler can be determined. Consider the pumps on
their own, as below.
Figure 5
From this the value of hC or the mass mC may be determined. This is best shown with a
worked example.
©D.J.Dunn 10
WORKED EXAMPLE No.4
The circuit below shows the information normally available for a feed pump circuit.
Determine the enthalpy at entry to the boiler.
Figure 6
SOLUTION
448.9 = 45 hC - 40 hA - 5hB
hC = 190 kJ/kg
©D.J.Dunn 11
WORKED EXAMPLE No.5
The following worked example will show you to solve these problems.
A passout turbine plant works as shown in fig. 4. The boiler produces steam at 60 bar and
500oC which is expanded through two stages of turbines. The first stage expands to 3 bar
where 4 kg/s of steam is removed. The second stage expands to 0.09 bar. The isentropic
efficiency is 0.9 for the overall expansion. Assume that the expansion is a straight line on
the h - s chart.
The condenser produces saturated water. The make up water is supplied at 1bar and 20oC.
The isentropic efficiency of the pumps is 0.8. The net power output of the cycle is 40 MW.
Calculate:
SOLUTION
Sketching the process on the h - s chart as a straight line enables h4 to be picked off at 3
bar. h4 = 2770 kJ/kg.
Figure 7
©D.J.Dunn 12
POWER INPUT
Figure 8
NET POWER
40 000 kW = Pout - P1 - P2
40 000 = 651 m + 479 m - 1916 - 29.5 - 7.49 m + 29.96
40000 = 1122.5 m - 1916 hence m = 37.34 kg/s
P1 = 29.5 kW
P2= 249.4 kW (using the value of m just found)
m h2 = (m-4) h1 + P1 + P2
37.3 h2 = 33.34 x 183 + 29.5 + 249.7
hence h2 = 171 kJ/kg
HEAT INPUT
Heat input = m(h3 - h2) = 121355 kW
EFFICIENCY
Efficiency = η = 40/121.3 = 33 %
©D.J.Dunn 13
SELF ASSESSMENT EXERCISE No.3
1. A steam turbine plant is used to supply process steam and power. The plant comprises
an economiser, boiler, superheater, turbine, condenser and feed pump. The process
steam is extracted between intermediate stages in the turbine at 2 bar pressure. The
steam temperature and pressure at outlet from the superheater are 500oC and 70 bar, and
at outlet from the turbine the pressure is 0.1 bar. The overall isentropic efficiency of the
turbine is 0.87 and that of the feed pump is 0.8.
Assume that the expansion is represented by a straight line on the h-s chart. The make-
up water is at 15oC and 1 bar and it is pumped into the feed line with an isentropic
efficiency 0.8 to replace the lost process steam.
If due allowance is made for the feed pump-work, the net mechanical power delivered
by the plant is 30 MW when the process steam load is 5 kg/s. Calculate the rate of steam
flow leaving the superheater and the rate of heat transfer to the boiler including the
economiser and superheater. Sketch clear T- s and h-s and flow diagrams for the plant.
(29.46 kg/s 95.1 MW)
2. The demand for energy from an industrial plant is a steady load of 60 MW of process
heat at 117oC and a variable demand of up to 30 MW of power to drive electrical
generators. The steam is raised in boilers at 70 bar pressure and superheated to 500oC.
The steam is expanded in a turbine and then condensed at 0.05 bar. The process heat is
provided by the steam bled from the turbine at an appropriate pressure, and the steam
condensed in the process heat exchanger is returned to the feed water line.
Calculate the amount of steam that has to be raised in the boiler. Assume an overall
isentropic efficiency of 0.88 in the turbine. The expansion is represented by a straight
line on the h-s diagram. Neglect the feed pump work.
(Answer 36 kg/s).
©D.J.Dunn 14
3. ADVANCED STEAM CYCLES
In this section you will extend your knowledge of steam cycles in order to show that the
overall efficiency of the cycle may be optimised by the use of regenerative feed heating and
steam re-heating.
Regenerative feed heating is a way of raising the temperature of the feed water before it
reaches the boiler. It does this by using internal heat transfer within the power cycle. Steam
is bled from the turbines at several points and used to heat the feed water in special heaters.
In this way the temperature of the feed water is raised along with the pressure in stages so
that the feed water is nearly always saturated. The heat transfers in the heaters and in the
boiler are conducted approximately isothermally.
Studies of the Carnot cycle should have taught you that an isothermal heat transfer is
reversible and achieves maximum efficiency.
The ultimate way of conducting feed heating is to pass the feed water through a heat
exchanger inside the turbine casing. In this way the temperature of the steam on one side of
heat exchanger tubes is equal to the temperature of the water on the other side of the tubes.
Although the temperature is changing as water and steam flow through heat exchanger, at
any one point, the heat transfer is isothermal. If no superheating nor undercooling is used
then the heat transfers in the boiler and condenser are also isothermal and efficiencies equal
to those of the Carnot cycle are theoretically possible.
Figure 9
There are several reasons why this arrangement is impractical. Most of them are the same
reasons why a Carnot cycle is impractical.
©D.J.Dunn 15
Steam reheating is another way of improving the thermodynamic efficiency by attempting
to keep the steam temperature more constant during the heat transfer process inside the
boiler.
Figure 10
Superheated steam is first passed through a high pressure turbine. The exhaust steam is
then returned to the boiler to be reheated almost back to its original temperature. The steam
is then expanded in a low pressure turbine. In theory, many stages of turbines and reheating
could be done thus making the heat transfer in the boiler more isothermal and hence more
reversible and efficient.
If a steam cycle used many stages of regenerative feed heating and many stages of
reheating, the result would be an efficiency similar to that of the Carnot cycle. Although
practicalities prevent this happening, it is quite normal for an industrial steam power plant
to use several stages of regenerative feed heating and one or two stages of reheating. This
produces a significant improvement in the cycle efficiency.
There are other features in advanced steam cycles which further improve the efficiency and
are necessary for practical operation. For example air extraction at the condenser, steam
recovery from turbine glands, de-superheaters, de-aerators and so on. These can be found in
details in textbooks devoted to practical steam power plant.
©D.J.Dunn 16
4. FEED HEATING
Practical feed heaters may be heat exchangers with indirect contact. The steam is
condensed through giving up its energy and the hot water resulting may be inserted into the
feed system at the appropriate pressure. The type which you should learn is the open or
direct contact mixing type. The bled steam is mixed directly with the feed water at the
appropriate pressure and condenses and mixes with the feed water. Compare a basic
Rankine cycle with a similar cycle using one such feed heater.
Figure 11
Figure 12
©D.J.Dunn 17
4. 2. ENERGY BALANCE FOR MIXING FEED HEATER
Consider a simple mixing type feed heater. The bled steam at (3) is mixed directly with
incoming feed water (6) resulting in hotter feed water (7).
y h3 + (1-y)h6 = h7
Figure 13
A feed heater is supplied with condensate at 0.1 bar. The bled steam is taken from the
turbine at 30 bar and 0.95 dry. Calculate the flow rate of bled steam needed to just
produce saturated water at outlet.
SOLUTION
Figure 14
Assumptions
Note that it is usual to calculate these problems initially on the basis of 1 kg coming
from the boiler and returning to it.
©D.J.Dunn 18
4. 3. CYCLE WITH ONE FEED HEATER
Figure 15
If only one feed heater is used, the steam is bled from the turbine at the point in the
expansion where it just becomes dry saturated and the saturation temperature is estimated
as follows.
The pressure corresponding to this is 3.5 bar so this is the bleed pressure.
©D.J.Dunn 19
WORKED EXAMPLE No.7
A Rankine cycle works between 40 bar, 400oC at the boiler exit and 0.035 bar at the
condenser. Calculate the efficiency with no feed heating. Assume isentropic expansion.
Ignore the energy term at the feed pump.
SOLUTION
Figure 16
x = 0.785
η= P/ Φ= 38.3 %
©D.J.Dunn 20
WORKED EXAMPLE No.8
Repeat the last example but this time there is one feed heater.
SOLUTION
Figure 17
The bleed pressure was calculated in an earlier example and was 3.5 bar.
Rather than work out the power from the turbine data, we may do it by calculating the
heat transfer rate from the condenser as follows.
©D.J.Dunn 21
SELF ASSESSMENT EXERCISE No.4
A simple steam plant uses a Rankine cycle with one regenerative feed heater. The boiler
produces steam at 70 bar and 500oC. This is expanded to 0.1 bar isentropically. Making
suitable assumptions, calculate the cycle efficiency. (41.8%)
When two (or more) feed heaters are used, the efficiency is further increased. the principles
are the same as those already explained. The mass of bled steam for each heater must be
determined in turn starting with the high pressure heater. It is usual to assume isentropic
expansion that enables you to pick off the enthalpy of the bled steam from the h-s chart at
the pressures stated.
©D.J.Dunn 22
WORKED EXAMPLE No.9
A steam power plant works as follows. The boiler produces steam at 100 bar and 600oC.
This is expanded isentropically to 0.04 bar and condensed. Steam is bled at 40 bar for
the h.p. heater and 4 bar for the l.p. heater. Solve the thermodynamic efficiency.
SOLUTION
Figure 18
Figure 19
Ignoring the energy input from the pump we find:
H.P. HEATER
©D.J.Dunn 23
L.P. HEATER
(1-x)h8 = yh4 + (1-x-y)h7
0.822(605) = 2740y + (0.822-y)(121)
y = 0.152 kg
BOILER
CONDENSER
POWER OUTPUT
η= P/ Φin= 48.3 %
©D.J.Dunn 24
SELF ASSESSMENT EXERCISE No. 5
1. Explain how it is theoretically possible to arrange a regenerative steam cycle which has a
cycle efficiency equal to that of a Carnot cycle.
In a regenerative steam cycle steam is supplied from the boiler plant at a pressure of 60 bar
and a temperature of 500oC. Steam is extracted for feed heating purposes at pressures of 30
bar and 3.0 bar and the steam turbine exhausts into a condenser operating at 0.035 bar.
Calculate the appropriate quantities of steam to be bled if the feed heaters are of the open
type, and find the cycle efficiency; base all calculations on unit mass leaving the boiler.
Assume isentropic expansion in the turbine and neglect the feed pump work.
2. The sketch shows an idealised regenerative steam cycle in which heat transfer to the feed
water in the turbine from the steam is reversible and the feed pump is adiabatic and
reversible. The feed water enters the pump as a saturated liquid at 0.03 bar, and enters the
boiler as a saturated liquid at 100 bar, and leaves as saturated steam.
Draw a T-s diagram for the cycle and determine, not necessarily in this order, the dryness
fraction in state 2, the cycle efficiency and the work per unit mass.
(Answers 0.269 kg/s, 50% and 658.5 kJ/kg).
Outline the practical difficulties that are involved in realising this cycle and explain how
regenerative cycles are arranged in practice.
Figure 20
Note point (6) is the point in the steam expansion where the feed water enters and
presumably the temperatures are equal. There is further expansion from (6) to (2).
©D.J.Dunn 25
5. REHEAT CYCLES
We shall only examine cycles with one stage of reheating and two turbine stages, high
pressure and low pressure. You should refer to text books on practical steam turbine
layouts to see how low, medium and high pressure turbines are configured and laid out in
order to produced axial force balance on the rotors. The diagram below shows a basic
circuit with one stage of reheating.
Figure 21
Figure 22
The calculations for this cycle are not difficult. You need only take into account the extra
heat transfer in the reheater.
©D.J.Dunn 26
WORKED EXAMPLE No.10
A reheat cycle works as follows. The boiler produces 30 kg/s at 100 bar and 400oC. This
is expanded isentropically to 50 bar in the h.p. turbine and returned for reheating in the
boiler. The steam is reheated to 400oC. This is then expanded in the l.p. turbine to the
condenser which operates at 0.2 bar. The condensate is returned to the boiler as feed.
SOLUTION
η= P(net)/Φ in = 37.7 %
©D.J.Dunn 27
SELF ASSESSMENT EXERCISE No. 6
1. Repeat worked example No.10 but this time do not ignore the feed pump term and
assume an isentropic efficiency of 90% for each turbine and 80% for the pump.
( Answers 32.1 MW ,35%)
Calculate the cycle efficiency and draw up an energy balance for the plant. Neglect the
feed pump work. (Answer 30.3%)
3. Steam is raised in a power cycle at the supercritical pressure of 350 bar and at a
temperature of 600oC. It is then expanded in a turbine to 15 bar with an overall
isentropic efficiency of 0.90. At that pressure some steam is bled to an open regenerative
feed heater, and the remainder of the steam is, after reheating to 600oC, expanded in a
second turbine to the condenser pressure of 0.04 bar, again with an isentropic efficiency
of 0.90. The feed pumps each have an overall isentropic efficiency of 0.90.
Calculate the amount of steam to be bled into the feed heater, making the usual
idealising assumptions. Also calculate the cycle efficiency. Use the h-s chart wherever
possible and do not neglect feed pump work.
©D.J.Dunn 28