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 HYDROCARBONS
1. Thermal decomposition of

a) b) c) d)

2. Which of the following is not a petroleum product?

a) Petrol b) Paraffin wax c) Bees wax d) Kerosene
3. A knocking sound is produced more in the engine when the fuel contains mainly:
a) 𝑛-alkanes b) CO2 c) CO d) Lubricating oil
4. Reaction of HBr with propene in presence of peroxides gives:
a) Isopropyl bromide b) 3-bromopropane c) Allyl bromide d) 𝑛-propyl bromide
5. The next higher homologue of C6 H14 is:
a) C7 H14 b) C7 H16 c) C7 H10 d) C7 H12
6. The reaction conditions used for converting 1,2-dibromopropane to propylene are
a) KOH, alcohol⁄∆ b) KOH, water⁄∆ c) Zn, alcohol⁄∆ d) Na, alcohol⁄∆
7. A gas formed by the action of alcoholic KOH on ethyl iodide, decolourises alkalineKMnO4 . The gas
is
a) C2 H6 b) CH4 c) C2 H2 d) C2 H4
8. Alkyne, C7 H12 , when reacted with alkaline KMnO4 followed by acidification with HCl gives a mixture of
(CH3 )2 CHCOOH + CH3 CH2 COOH,The alkyne 𝐶7 𝐻12 is
a) 3-hexyne b) 2-methyl-2-hexene c) 2-methyl-3-hexene d) 3-methyl-2-hexyne
9. The relationship between acetylene and benzene is comparable to the relationship between
propyne and
a) Dimethyl benzene b) Neoprene c) Propyl benzene d) Mesitylene
10. Complete oxidation of one mole of an alkane forms 3 moles ofCO2 . The alkane is
a) CH4 b) C2 H6 c) C3 H8 d) C6 H14
11. The ozonolysis of ethylene, acetylene and propylene respectively gives:
a) HCHO, CHO— CHO and CH3 CHO + HCHO
b) CHO— CHO, HCHO and CH3 CHO
c) HCHO + CH3 CHO, CHO— CHO and HCHO
d) CHO— CHO, CH3 CHO + HCHO and HCHO
12. The reaction, CH = CH + CH COCl AlCl 3
→ gives the product:
2 2 3
a) CH3 COCH2 CH2 Cl
b) CH3 . CH2 . CH2 Cl
c) CH3 COCH2 . CH2 COCH3
d) ClCH2 CH2 Cl
13. Alkyl halides react with dialkyl copper reagents to give
a) Alkenyl halides b) Alkanes
c) Alkyl copper halides d) Alkenes
14. The gas which is used for the artificial ripening of fruits is:
a) C2 H6 b) C2 H2 c) C2 H4 d) Marsh gas
15. CH3 — C ≡ CH reacts with HCI to give:
a) 2,2-dichloropropane b) 1,1-dichloropropane c) 1,2-dichloropropane d) 1-chloropropene
16. 675 K
CH3 CH3 + HNO3 → ?
a) CH3 CH2 NO2 b) CH3 CH2 NO2 + CH3 NO2
 c) 2CH3 NO2 d) CH2 = CH2
17. Which of the following is produced when coal is subjected to destructive distillation?
a) Methane b) Ethane c) Acetylene d) Coal gas
18. The product of the following reaction are:

a) CH3 COOH + CH3 COCH3

b) CH3 COOH + CH3 CH2 COOH
c) CH3 CHO + CH3 CH2 CHO
d) CH3 COOH + CO2
19. Methyl bromide heated with zinc in closed tube produces:
a) Methane b) Ethane c) Ethylene d) Methanol
20. Aqueous solution of an organic compound, ′𝐴′ on electrolysis liberates acetylene and CO2 at a
node. ′𝐴′ is
a) Potassium acetate b) Potassium succinate
c) Potassium citrate d) Potassium maleate
21. The reaction of alkanes with halogen is explosive in the case of:
a) F2 b) Cl2 c) I2 d) Br2
22. Which of the following is unsymmetrical alkene?
a) 1-butene b) 2-hexene c) 1-pentene d) All of these
23. Which of the statement is wrong for alkanes?
a) Most of the alkanes are soluble in water
b) Their density is always less than water
c) At room temperature some alkanes are liquid, some solid and other are gases
d) All alkanes burn
24. Propane cannot be prepared from which reaction?
B2 H6 HI
a) CH3 − CH = CH2 → −
b) CH3 CH2 CH2 I →
OH P

c) CH3 CH2 CH2 COONa →

NaOH ⁄CaO,∆ d) None of the above
25. Nitrating mixture is
a) Fuming nitric acid
b) Mixture of conc. H2 SO4 and conc. HNO3
c) Mixture of nitric acid and anhydrous zinc chloride
d) None of the above
26. Cyclohexene on reaction with OsO4 followed by reaction with NaHSO3 gives
a) 𝑐𝑖𝑠 − diol b) 𝑡𝑟𝑎𝑛𝑠 − diol c) Epoxy d) Alcohol
27. Al4 C3 on hydrolysis yields
a) Nitrogen gas b) Methane gas c) Hydrogen gas d) Carbon dioxide
28. The compounds 𝑃, 𝑄 and 𝑆
 where separately subjected to nitration using HNO3 ⁄H2 SO4 mixture. The major product formed
in each case respectively, is

a)

b)

c)

d)

29. Which of the following is not a mixture of hydrocarbons?

a) Candle wax b) Kerosene c) Vegetable oils d) Paraffin oil
30. C H (𝐴) O →
3 /H2 O
acid(𝐵)
8 10
CO2,H3 O+
C3 H5 MgBr(C) → acid 𝐵
Identify 𝐴, 𝐵 and 𝐶

a) b)

CH3 − CH2 − CH2 − CH3 , CH3 CH2 CH2 COOH, CH2

c) d)
= CH − CH2 MgBr
31. Which of the following has the maximum heat of hydrogenation?

a) b) c) d)

32. 400−600℃
CH3 CH2 CH3 → 𝑋 + 𝑌, 𝑋 and 𝑌 are
a) Hydrogen and methane b) Hydrogen and ethylene
c) Ethylene and methane d) Any of these
33. Position of double bond in alkenes is identified by
a) Ozonolysis b) Bromine water
c) Ammonical silver nitrate d) None of these
34. Consider the following reaction

I. H2 /Ni2 B
II. H2 /Pd − CaCO3 in quinoline
III. Na/NH3 or LiAIH4
This reaction takes place by
a) I or II b) I or III c) II or III d) I, II or III
35. Which of the following reagent can distinguish between 1-butyne and 2-butyne?
a) Aqueous NaOH
b) Bromine water
c) Fehling’s solution
d) AmmoniacalAgNO3
36. CH4 is formed when:
a) Sodium acetate is heated with soda lime
b) Iodo methane is reduced
c) Aluminium carbide reacts with water
d) All of the above
37. Reaction of HBr with propene in the presence of peroxide gives
a) 𝑖𝑠𝑜-propyl bromide b) 3-bromo propane c) Allyl bromide d) 𝑛-propyl bromide
38. Predict structure of 𝑋 in following reaction

a) b) c) d)

39. The middle oil fraction of coal-tar distillation contains:

a) Benzene b) Anthracene c) Naphthalene d) Xylene
40. On halogenation, an alkane(C5 H12 ) gives only one monohalogenated product. The alkane is
a) 𝑛-pentane b) 2-methyl butane
c) 2, 2-dimethyl propane d) Cyclopentane
41. Acrylic emulsion in paints is a polymer of:
a) CH2 = CH − COOCH3
b) CH3 − CH = CH − COOCH3
c) CH2 = CH − COOH
d) CH2 = C(CH3 ) − COOCH3
42. A hydrocarbon Xadds on one mole of hydrogen to give another hydrocarbon and decolourised bromine
water. X react with KMnO4 in presence of acid to give two mole of the same carboxylic acid. The structure
of X is:
a) CH3 CH = CHCH2 CH2 CH3
b) CH3 CH2 CH = CHCH2 CH3
c) CH3 CH2 CH2 — CH = CHCH3
d) CH2 = CH— CH2 CH2 CH3
43. An anaestheticnarcylene is commercial name of:
a) C2 H4 b) C2 H2 c) CHCI3 d) ether
44. By which one of the following compounds both CH4 and CH3 − CH3 can be prepared in one step?
a) CH3 I b) CH3 OH c) CH3 CH2 I d) C2 H5 OH
45. What volume of methane (NTP) is formed from 8.2 g of sodium acetate by fusion with sodalime?
a) 10 litre b) 11.2 litre c) 5.6 litre d) 2.24 litre
46. When methyl iodide is treated with sodium in ethereal solution, it gives
a) Methane b) Ethane
c) Methyl sodium iodide d) Sodium methoxide
47. 2-methylpentene 2 on ozonolysis will give:
a) Only propanal
b) Propanal and ethanal
c) Propanone-2 and ethanal
d) Propanone-2 and propanal
48. The reaction,

a) Eglinton’s reaction
b) Glaser reaction
c) Gomberg-Beckmann’s reaction
d) Leuckart reaction
49. 2-Hexyne gives 𝑡𝑟𝑎𝑛𝑠-2-hexene on treatment with:
a) Li/NH3 b) Pd/BaSO4 c) LiAlH4 d) Pt/H2
50. Which of the following will give three mono-bromo derivatives?
a) CH3 CH2 CH2 CH(CH3 )CH3 b) CH3 CH2 C(CH3 )2 CH3
c) CH3 CH3 (CH3 )CH (CH3 )CH3 d) All the above can give
51. The reagent for the following conversion

a) Alc. KOH Alc. KOH followed by Aqueous KOH followed

b) c) d) Zn/CH3 OH
NaNH2 by NaNH2
52. In a reaction if half of the double bond is broken and two new bonds are formed, this is a case of:
a) Elimination b) Addition c) Displacement d) Rearrangement
53. Which represents a cyclic alkane?
a) C3 H6 b) C3 H8 c) C8 H10 d) C8 H12
54. CH − CH − CH − CH AlCl 3
→ Product
3 2 2 3
HBr
Product in the above reaction is
CH3 − CH − CH2 − CH3 CH3 − CH − CH3
a) | b) |
Br CH3
CH3 − CH2 − CH2 d) All of these
c) ||
BrBr
55. According to Huckel’s rule an aromatic compound must possess
a) (4𝑛 + 1)𝜋-electrons b) (4𝑛 + 2)𝜋-electrons
c) 4𝑛 𝜋-electrons d) (4𝑛 + 3)𝜋-electrons
56. Acetylene gives:
a) White ppt. with AgNO3 and red ppt. with Cu2 Cl2
b) White ppt. with Cu2 Cl2 and red ppt. with AgNO3
c) White ppt. with both
d) Red ppt. with both
57. 1,1,2,2-tetrabromoethane on heating with Zn powder in alcohol finally gives:
 a) Methane b) Ethane c) Ethyne d) Ethene
58. The carbide which reacts with water to form ethyne is
a) CaC2 b) SiC c) Mg 2 C3 d) Al4 C3
59. What is the product when 2-butyne is treated with liquid NH3 in presence of lithium?
a) 𝑛-butane b) 𝑐𝑖𝑠-2-butene c) 𝑡𝑟𝑎𝑛𝑠-2-butene d) 1-butene
60. 2+
Hg /H+
Ph— C ≡ C— CH3 → 𝐴. A is:

a) b) c) d)

61. 1-butyne on reaction with hot alkaline KMnO4 gives:

a) CH3 CH2 CH2 COOH
b) CH3 CH2 COOH + CO2
c) CH3 CH2 COOH
d) CH3 CH2 COOH + HCOOH
62. Which statement is not correct in case of ethane?
a) It can be catalytically hydrogenated
b) When burnt produces CO2 and H2 O
c) It is homologue of isobutane
d) It can be chlorinated with chlorine
63. CH3 COCH3 can be converted to CH3 CH2 CH3 by the action of
a) HNO3 b) HIO3 c) H3 PO3 d) HI
64. When ethyl chloride and alcoholic KOH are heated, the compound obtained is
a) C2 H4 b) C2 H2 c) C6 H6 d) C2 H6
65. Which of the following will react with sodium metal?
a) Ethene b) Propyne c) But-2-yne d) Ethane
66. When the boiling point of the first ten normal alkanes are plotted, the graph looks like:

a) b) c) d)

67. Which is generally used as reducing agent in organic chemistry?

a) Zn+HCl b) Zn + CH3 COOH c) Zn/Hg+HCl d) Na + C2 H5 OH
68. Alkynes can be reduced to alkenes by hydrogenation in presence of:
a) Raney Ni b) Anhy. AlCl3 c) Pd d) Lindlar’s catalyst
69. Which reagent distinguishes ethylene from acetylene?
a) Aqueous alkaline permanganate
b) Chlorine dissolved in carbon tetrachloride
c) Ammoniacal cuprous chloride
d) Concentrated sulphuric acid
70. By heating tetraethyl ammonium hydroxide, the product formed are:
a) C2 H4
b) (C2 H5 )3 N
c) H2 O
d) All of these
71. Addition of ICl on propene gives the product:
a) CH3 CHClCH3 b) CH3 CHlCH2 Cl c) CH3 CHClCH2 I d) CH3 CHClCH2 Cl
72. Which of the following alkenes gives on acetaldehyde on ozonolysis?
 a) Ethene b) Propene c) 1-butene d) 2-butene
73. In the following sequence of reactions, the alkene affords the compound ‘B’
O3 H2 O
CH3 CH = CHCH3 → 𝐴 → 𝐵
The compound B is
a) CH3 CH2 CHO b) CH3 COCH3 c) CH3 CH2 COCH3 d) CH3 CHO
74. CH3 CH = CH − CH3 + CH2 N2 → 𝐴; 𝐴 is

a) b)

c) Both (a) and (b) d) None of these

75. Direct fluorination of alkanes is not made because:
a) Reaction does not occur
b) Alkane fluorides are not formed
c) Reaction occurs violently
d) None of the above
76. On monochlorination of 𝑛-pentane, the number of isomers formed is:
a) 4 b) 3 c) 2 d) 1
77. Which of the following is the predominant product in the reaction of HOBr with propene?
a) 2-bromo-1-propanol b) 3-bromo-1-propanol
c) 2 − bromo − 2 − propanol d) 1-bromo-2-propanol
78. Acetylene is prepared industrially by passing electric discharge through graphite electrodes in the
atmosphere of:
a) Air b) N2 c) H2 d) CO2
79. The reaction of an aromatic halogen compound with an alkyl halide in presence of sodium in
ether is called
a) Sandmeyer’s reaction b) Wurtz reaction
c) Kolbe reaction d) Wurtz-Fittig reaction
80. How many isomeric forms of pentane exist?
a) 3 b) 2 c) 5 d) 6
81. Alkanes mainly show reactions involving:
a) Carbonium formation
b) Ionic elimination
c) Ionic formation
d) Heat/photochemical substitution
82. Ozonolysis of an organic compound A produces acetone and propionaldehyde in equimolar
mixture. Identify A from the following compounds.
a) 2-methyl-1-pentene b) 1-pentene
c) 2-pentene d) 2-methyl-2-pentene
83. Using anhydrous AlCl3 as catalyst, which one of the following reactions produce
ethylbenzene(PhEt)?
a) H3 C − CH2 OH + C6 H6 b) CH3 − CH = CH2 + C6 H6
c) H2 C = CH2 + C6 H6 d) H3 C − CH3 + C6 H6
84. On vigorous oxidation by alkaline permanganate solution (CH3 )2 C = CH— CH2 CHO gives:

a)

b)
 c)

d)

85. The compound that is most reactive towards electrophilic nitration is

a) toluene b) benzene c) benzoic acid d) nitrobenzene
86. One mole of a symmetrical alkene on ozonolysis gives two moles of an aldehyde having a
molecular mass of 44 u. The alkene is
a) Propene b) 1-butene c) 2-butene d) Ethene
87. The conversion of propene to propanol is … type of reaction.
a) Hydrogenation b) Hydration c) hydrolysis d) Dehydrogenation
88. When 𝑛-hexane/𝑛-heptane is passed through Cr2 O3 supported over alumina at 600C gives:
a) Hexane b) Hexyne c) Benzene, Toluene d) None of these
89. If 20cm of methane (CH4 ) is burnt using 50cm of oxygen. The volume of the gases left after cooling to
3 3

room temperature will be:

a) 60cm3 b) 70cm3 c) 30cm3 d) 50cm3
90. An alkane of mol. weight 72 gives on monochlorination only one product. Name the alkane:
a) 2-methylbutane b) 𝑛-pentane c) 2,2-dimethylpropane d) None of these
91. The number of disubstituted products of benzene is
a) 2 b) 3 c) 4 d) 5
′
92. The treatment of 𝑅 Mg𝑋 with 𝑅C ≡ CH produces
a) 𝑅H b) 𝑅′ H c) 𝑅 − 𝑅 d) 𝑅 − 𝑅′
93. Electrolysis of an aqueous solution of sodium acetate, yields
a) Ethane b) Ethene c) Ethyne d) Propane
94. Propyne on passing through red hot copper tube forms
a) benzene b) Toluene c) Mesitylene d) None of these
95. Among the following, the compound that be most readily sulphonated is
a) Benzene b) Nitrobenzene c) toluene d) chlorobenzene
96. Propylene on hydrolysis with sulphuric acid forms
a) 𝑛-propyl alcohol b) Isopropyl alcohol c) Ethyl alcohol d) Butyl alcohol
97. What is the product formed when acetylene reacts with hypochlorous acid?
a) CH3 COCl b) ClCH2 CHO c) Cl2 CHCHO d) ClCH2 COOH
98. When CaC2 was hydrolysed a gas was obtained. It had a garlic odour due to phosgene present as impurity.
The gas was passed through ammoniacal solution of Cu2 Cl2 , ared ppt. was obtained. The gas was:
a) Ethylene b) Propyne c) Acetylene d) Ethane
99. Alkenes undergo
a) Addition reactions
b) Substitution reactions
c) Both (a) and (b)
d) None of these
100. Aromatic compound among other things should have a 𝜋-electron cloud containing (4𝑛 + 2)𝜋
electrons where, 𝑛 cannot be
1 b) 3 c) 2 d) 1
a)
2
101. Polymer of propyen is:
a) Polyethylene b) Polythene c) Benzene d) Mesitylene
102. Which of the following has the least octane number?
a) Octane b) Cetane c) 2,2,4-trimethylpentane d) 𝑛-heptane
103. Name the reaction C3 H6 ⟶ C3 H8 :
a) Alkylation b) Cracking c) Hydrogenation d) Dehydrogenation
104. The tar which is used to make roads is a solid known as:
a) Pitch b) Paraffin wax c) Coal d) None of these
105. Thermal decomposition of alkanes in the absence of air is called
a) Cracking b) Oxidation c) Combustion d) Hydrogenation
106. The conditions for aromaticity is
a) Molecule must have clouds of delocalised𝜋-electrons
b) Molecule must contain (4𝑛 + 2)𝜋-electrons
c) Both (a) and (b)
d) None of the above
107. C2 — C3 bond length in but-1,3-diene is:
a) 1.46Å b) 1.20Å c) 1.39Å d) 1.34Å
108. For synthesis of 1-butene, CH3 Mgl should be treated with
a) Propene b) 2-chloropropene c) Allyl chloride d) Ethyl chloride
109. The highest boiling point is expected for
a) 𝑛-butane b) 𝑖𝑠𝑜-octane
c) 𝑛-octane d) 2,2,3,3-tetramethyl butane
110. When butane-1 is mixed with excess of bromine, the expected reaction product is:
a) Hydrogen bromide b) Butylene gas c) 1,2-dibromobutane d) Perbromobutane
111. An alkene having molecular formula C9 H18 on ozonolysis gives 2, 2-dimethyl propanal and 2-
butanone. The alkene is
a) 2,2,2-trimethyl-3-hexene b) 2,2,6-trimethyl-3-hexane
c) 2,3,4-trimethyl-2-hexene d) 2,2,4-trimethyl-3-hexene
112. Propene on reaction with diazomethane in presence of UV radiations gives:
a) Cyclopropane b) Methyl cyclopropane c) Butane d) Butene
113. Both methane and ethane may be obtained by a suitable one-step reaction from
a) CH3 I b) C2 H5 I c) CH3 OH d) C2 H2 OH
114. The product (s) obtained 𝑣𝑖𝑎 oxymercuration (HgSO4 + H2 SO4 ) of but-1-yne would be
a) CH3 CH2 COCH3 b) CH3 CH2 CH2 CHO
c) CH3 CH2 CHO + HCHO d) CH3 CH2 COOH + HCOOH
115. Alkene-1 on hydroboration followed with action of H2 O2 gives:
a) Alkanol-2 b) Alkanol-1 c) Alkanal d) Alkanone
116.

on ozonolysis gives
d) None of these
a) b) c)

117. The compound ‘𝐶’ in the following reaction is

3Cl2 ⁄∆ Br2 ⁄Fe Zn⁄HCl
C7 H7 → 𝐴→ 𝐵→ 𝐶
a) 𝑜-bromotoluene b) 𝑚-bromotoluene
c) 𝑝-bromotoluene d) 3-bromo-2,4,6-trichlorotoluene
118. Iodination of alkane is made in presence of:
a) KMnO4 b) HgO or HIO3 c) K 2 Cr2 O7 d) None of these
119. Pick out the wrong statement.
a) Toluene shows resonance
 b)

is non-aromatic.
c) The hybrid state of carbon in carbonyl group is 𝑠𝑝2 .
d) The hyperconjugative effect is known as no bond resonance.
120. An alkene on vigorous oxidation with KMnO4 gives only acetic acid. The alkene is
a) CH3 CH2 CH = CH2 b) CH3 CH = CHCH3 c) (CH3 )2 C = CH2 d) CH3 CH = CH2
121. A hydrocarbon reacts with hypochlorous acid to give 2-chloroethanol. The hydrocarbon is:
a) Methane b) Ethylene c) Acetylene d) Ethane
122. The angle strain in cyclobutane is
a) 24°44′ b) 29°16′ c) 19°22′ d) 9°44′
123. During chlorination of methane usually a mixture of all the chlorinated products, 𝑖. 𝑒., methyl chloride,
methylene dichloride, chloroform and carbon tetrachloride are obtained. What will happen, if we use
excess of Cl2 in this reaction?
a) Only methyl chloride will be formed
b) Only chloroform will be formed
c) Only CCl4 will be formed
d) Only methylene dichloride will be formed
124. Aromatization of 𝑛-heptane and 𝑛-octane gives respectively:
a) Toluene, ethyl benzene
b) Ethyl benzene, toluene
c) Toluene, benzene
d) Benzene, ethyl benzene
125. Which of the following organic compounds exhibit acidic character?
a) H3 C − C ≡ CH b) H3 C − C ≡ C − CH3 c) H2 C = CH2 d) H3 C − CH3
126. Sodium formate on heating with soda lime gives:
a) CH4 b) CO2 c) H2 d) All of these
127. Which of the following can be used for preparation of propane?
1.B2H6 1.Mg/ether
a) CH3 CH = CH2 → b) CH3 CH2 CH2 Cl →
2.AgNO3/NaOH 2.H2O2
HI/∆ 150℃ NaOH(CuO)
c) CH3 CH2 CH2 I → d) CH3 CH2 CH2 COONa →
∆
128. The marsh gas detector used by miners works on the principle of:
a) Difference in the rates of diffusion of gases
b) Avogadro’s hypothesis
c) Gay-Lussac’s law of gaseous volumes
d) Berzelius hypothesis
129. The compound with highest boiling point.
a) 𝑛-nexane b) 𝑛-pentene
c) 2,2-dimethyl propane d) 2-methyl butane
130. The most stable conformation of chlorocyclohexane at room temperature is:

a) b) c) d)

131. Acetylene is not used in making:

a) Textile yarn b) PVC c) Glucose d) Drugs
132. An aromatic compound ‘𝑋’ with molecular formula C8 H10 produces on nitration one mononitro
 derivative and three dinitro derivatives. Compound ‘𝑋’ would be
a) Ethyl benzene b) 𝑚-xylene c) 𝑜-xylene d) 𝑝-xylene
133. That acetylene is a linear molecule is shown by
a) Its C ≡ C bond distance being 1.21 Å b) Its C − H bond distance being 1.08 Å
c) ItsH − C − C bond angle being 180° d) All of the above
134. Benzene on treatment with a mixture of conc. HNO3 and conc. H2 SO4 at 100℃ gives
a) Nitrobenzene b) 𝑚-dinitrobenzene c) 𝑝-dinitrobenzene d) 𝑜-dintrobenzene
135. Which of the following differs with the other three?
a) Naphthalene b) Ethylene c) Toluene d) Xylene
136. A saturated hydrocarbon is shown by C𝑛 H10 The value of carbon atom ‘𝑛’ in this compound is:
a) 2 b) 4 c) 5 d) 6
137. Which of the following reactions will yield, 2, 2-dibromopropane?
a) CH3 − C ≡ CH + 2HBr → b) CH3 CH = CHBr + HBr →
c) CH ≡ CH + 2HBr → d) CH3 − CH = CH2 + HBr →
138. CH2 = CH2 reacts with HCI to form:
a) CH2 CH2 Cl2 b) CH2 ClCH3 c) CH2 ClCH2 Cl d) CH3 CHCl2
139. Reduction of carbonyl compounds to alkanes with NH2 — NH2 and NaOH is called:
a) Clemmensen reduction
b) Wolff-Kishner reduction
c) Wurtz’s reaction
d) PondrofVerley reduction
140. The compound which cannot decolourise alkaline KMnO4:
a) Acetylene b) Ethanol c) Ethanal d) Ethane
141. Which one of the following can distinguish propyne from propene?
a) Br2 water b) AmmoniacalAgNO3 c) Aq. KMnO4 d) Dil. H2 SO4
142. The reaction of ethene with oxygen in presence of a silver catalyst gives:
a) Ethylene glycol b) Ethylene epoxide c) Glyoxal d) Acetaldehyde
143. 4-nitrotoluene →K2 Cr2O7 product. The product in the reaction is
H2SO4
a) Benzoic acid b) 4-nitrobenzene c) 4-nitrobenzoic acid d) 2-nitrobenzoic acid
144. Which of the following is Wurtz-Fittig reaction?

a) b)

c) d)

145. Ozonolysis can be used to detect:

a) 1-butene and 2-butene
b) Branched alkene from unbranched alkene
c) Location of double bond/triple bond in carbon chain
d) All are correct
146.

Product 𝑋 is obtain by reaction 𝑅. 𝑋 and 𝑅 are

a) b)
 c) d)

147.

a) b) c) d)

148. In which of the following will Kharasch effectoperate?

a) CH3 CH2 CH = CH2 + HCI
b) CH3 CH2 — CH = CH2 + HBr
c) CH3 CH = CH— CH3 + HBr
d) CH3 CH2 CH = CH2 + HI
149. In the following reaction, 𝐴 and 𝐵, respectively are
HBr 𝐵
𝐴→ C2 H5 Br → 𝐴
a) C2 H4 , alc. KOH⁄∆ b) C2 H5 Cl, aq. KOH⁄∆ c) CH3 OH, aq. KOH⁄∆ d) C2 H5 , PBr3
150. Addition of HBr on:
CH ≡ C—CH2—CH = CH2and CH ≡ C—CH = CH2
Separately gives:

a)

b)

c)

d) None of the above

151. Compound C6 H12 is an:
a) Aliphatic saturated compound
b) Alicyclic compound
c) Aromatic compound
d) Heterocyclic compound
152. A lead compound known as….is used as anti-knock in petroleum industry to increase the efficiency of fuel
consumption
a) (C2 H5 )4 Pb b) Pb(CH3 COO)2 c) (C2 H5 )2 Pb d) PbCO3
153. Which of the following form alkynide?

a)

b)
 c)

d)

154. Which of the following reagents when heated with ethyl chloride, forms ethylene?
a) Aqueous KOH b) Zn⁄HCl c) Alcoholic KOH d) HI
155. Reduction of 2-methyl-1-bromopropane with metal and acid gives:
a) Butyl bromide b) 𝑛-butane c) Isobutene d) None of these
156. Dehydration of 2-butanol yield
a) 1-butene b) 2-butene c) 2-butyne d) Both (a) and (b)
157. Which statement is correct?
a) Knocking decreases the efficiency of an internal combustion engine
b) Knocking cannot be eliminated completely by adding anti-knock compounds
c) The higher the octane number, the better is the quality of fuel
d) All of the above
158.
The treatment of with NaIO4 or boiling KMnO4 produces
KMnO4 produces
a) CH3 COCH3 + CH3 COOH b) CH3 COCH3 + CH3 CHO
c) CH3 CHO + CO2 d) CH3 COCH3 only
159. Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne?
a) NaNH2 b) HCl c) O2 d) Br2
160. 2-chloro-3-methylbutane is treated with sodium in etherial solution, then it will give
a) 2,4-dimethylhexane b) 3,5-dimethylhexane
c) 2,3,4,5-tetramethylhexane d) 2,6-dimethyloctane
161. The hydrocarbon which can react with sodium in liquid ammonia is
a) CH3 CH2 CH2 C ≡ CCH2 CH2 CH3 b) CH3 CH2 C ≡ CH
c) CH3 CH = CHCH3 d) CH3 CH2 C ≡ CCH2 CH3
162. Which of the following is incorrect? The members of the homologous series of alkanes?
a) Are all straight chain compounds
b) Have the general formula C𝑛 H2𝑛+2
c) Show a regular gradation in physical properties
d) Have similar chemical properties
163. Ammoniacal cuprous chloride will give red precipitate with which one of the following?
a) CH3 − C ≡ C − CH3 b) CH3 − CH = CH2
c) CH3 − C ≡ CH d) CH3 − CH = CH − CH3
164. Mustard gas is:
a) CH4 b) C2 H4 c) CH2 Cl— CH2 — S— CH2 —d)CHNone
2 Cl of the above
165. During pyrolysis of alkane, C—C bond rather than C—H bond break because:
a) C—C bond is reactive site in alkane
b) C—H bond is reactive site in alkane
c) Bond energy of C—C is lower than C—H bond
d) Energy of activation of C—C bond is very high
166. A mixture of CH4 and steam on passing over nickel suspension on alumina at 800° C gives:
a) CO only b) H2 only c) CO and H2 d) None of these
167. A compound 𝑋(C5 H8 ) reacts with ammoniacalAgNO3 to give a white precipitate, and on oxidation with hot
 alkaline KMnO4 gives the acid,(CH3 )2 CHCOOH. Therefore, 𝑋 is
a) CH2 = CHCH = CHCH3 b) CH3 (CH2 )2 C ≡ CH c) (CH3 )2 CH − C ≡ CH d) (CH3 )2 C = C = CH2
168. What are the products obtained by the ozonolysisof𝑅CH = C𝑅1 𝑅2 ?
a) 𝑅1 CH2 CH2 𝑅2 b) 𝑅2 CO c) 𝑅1 CO𝑅2 d) None of these
169. Following compound is treated with NBS

Compound formed A is

a) b)

c) d)

170. The structural formula of the compound which yields ethylene upon reaction with zinc:
a) CH2 Br— CH2 Br b) CHBr2 — CHBr2 c) CHBr=CHBr d) None of these
171. An alkyne combines with a conjugated diene to give an unconjugatedcycloalkadiene. The most
likely title of this reaction is
a) Schotten-Baumann reaction b) Hofmann-bromamide reaction
c) Pinacol-Pinacolone rearrangement d) Deils-Alder reaction
172. The most important method of preparation of hydrocarbons of lower carbon number is:
a) Pyrolysis of higher carbon number hydrocarbons
b) Electrolysis of salts of fatty acids
c) Sabatier-Senderen’s reaction
d) Direct synthesis
173. The number of carbon atoms in hydrocarbons of kerosene is in the range of:
a) C5 — C7 b) C12 — C16 c) C1 — C4 d) C17 — C20
174. A mixture of 1-chlorobutane and 2-chlorobutane when treated with alcoholic KOH gives
a) 1-butene b) 2-butene
c) 𝑖𝑠𝑜-butylene d) Mixture of 1-butene+2-butene
175. Which of the following react with Cl2 and Br2 at room temperature and in the absence of diffused sunlight
to produce dihalogen derivatives?
a) Cyclobutane b) Cyclopentane c) Cyclohexane d) All of these
176. A compound (X) on ozonolysis followed by reduction gives an aldehydeC2 H4 O and 2-butanone,
compound (X) is
a) 3-methyl pentene-2 b) 3-methyl pentene-3 c) 3-methyl hexene-3 d) 3-ethyl pentene-3
177. An octane number 100 is given to:
a) 𝑛-hexane b) Iso-octane c) Neopentane d) Neo-octane
178. When butene-1 is mixed with HBr, the major reaction product is:
a) 1,2-dibromobutane b) 1-bromobutane c) 2-bromobutane d) None of these
179. Which cycloalkane has the lowest heat of combustion per CH2 group?
a) Cyclopropane b) Cyclobutane c) Cyclopentane d) Cyclohexane
180. The order of appearance of the following with rising temperature during the refining of crude oil is:
a) Kerosene, gasoline, diesel
b) Diesel, gasoline, kerosene
c) Gasoline, diesel, kerosene
d) Gasoline, kerosene, diesel
181. CH — C ≡ C— CH NaNH2
𝑋; what is X ?
3 3→

a) CH3 — CH2 CH2 CH3 b) CH3 CH2 C ≡ CH c) d) CH2 = C = CH— CH3

182.

A(Predominantly) is:

a)

b)

c)

d)

183. The reagent 𝑋 in the reactions

a) H3 O+ b) (CH3 COO)2 Hg c) OH − d) HCOOH

184. Cetane number of diesel fuel increases with the addition of:
a) Decane b) Hexadecane c) Pentane d) Methyl naphthalene
185. Distillation of acetone with concentrated sulphuric acid gives
a) Diacetone alcohol b) Mesityl oxide c) Mesitylene d) Propene-2-ol
186.

a)

b)

c)

d) None of the above

187. Soda lime is used extensively in decarboxylation reaction to obtain alkanes. Soda lime is:
a) NaOH b) NaOH and CaO c) CaO d) Na2 CO3
188. Incomplete combustion of petrol or diesel oil in automobile engines can be best detected by testing fuel
gases for the presence of:
a) Carbon dioxide and water vapour
b) Carbon monoxide
c) Nitrogen oxide
d) Sulphur dioxide
189. A compound with molecular formula C4 H6 may contain:
a) A double bond
b) Two triple bonds
c) All single bonds
d) Two double bonds or a triple bond
190. Mustard gas is a
a) Oil gas b) Poisonous gas c) Fuel gas d) Life gas
191. Which of the following is not true?
a) Acetylene has a linear structure
b) Alkynes undergo electrophilic addition, but not nucleophilic addition reactions
c) Alkenes show geometrical isomerism
d) There is 𝑠𝑝3 -hybridisation in propane
192. Pure CH4 can be obtained by:
b) HCOONa+NaOH Electrolysis of
a) CH3 COONa + BaO c) CH3 COONa + Sodalime d)
HCOONa(𝑎𝑞.)
193. Viscosity coefficients of some liquids are given below,
Liquid  in
millipoise
at 30C
CH3 (CH2 )3 CH3 2.11
CH3 (CH2 )4 CH3 2.89
CH3 (CH2 )5 CH3 3.68
The order of viscosity coefficient of the liquids,
(𝐴)CH3—CH2—CH2—CH2—CH2—CH3

is:
a) The same b) (A)>(B)>(C) c) (A)<(B)<(C) d) (A)>(B)=(C)
194. Action of 𝑅Mg X with vinyl chloride gives:
a) Alkane b) Alkyne c) Alkene d) All of these
195. The following reaction is called

a) Michael addition reaction b) Diels-alder reaction

c) Wolff-Kishner reaction d) None of the above
196. Which branched chain isomer of the hydrocarbon with molecular mass 72u gives only one isomer of mono
substituted alkyl halide?
a) Neopentane
b) Isohexane
c) Neohexane
d) 𝑇𝑒𝑟𝑡𝑖𝑎𝑟𝑦-butyl chloride
197. A 𝑚𝑒𝑡𝑎 directing functional group is
a) −COOH b) −OH c) −CH3 d) −Br
198. Which one of the following compounds is prepared in the laboratory from benzene by a
 substitution reaction?
a) Glyoxal b) Cyclohexane
c) Acetophenone d) Hexabromocyclohexane
199. Only two isomeric monochloro derivatives are possible for:
a) 𝑛-pentane b) 2,4-dimethylpentane c) Benzene d) 2-methylpropane
200. Butene-1 may be converted to butane by reaction with
a) Zn − HCl b) Sn − HCl c) Zn − Hg d) Pd⁄H2
201. Identify ‘B’ in the following reaction,
Anhy.AlCl3
CH2 = CH2 + HCl →
Zn−Cu
𝐴 + 2[H] → 𝐵 + HCl
C2 H5 OH
a) CH4 b) C2 H6 c) C2 H5 Cl d) C2 H5 OH
202. The reaction of toluene with chlorine in presence of ferric chloride gives predominantly
a) benzoyl chloride b) 𝑚-chlorotoluene
c) Benzyl chloride d) 𝑜-and 𝑝-chlorotoluene
203. Hg 2+ ⁄H+
Ph − C ≡ C − CH3 → 𝐴
The product A is

a) b) c) d)

204. During Wurtz reaction, which of the following is sometimes also obtained because of decomposition of
free radicals?
a) Alkynes b) Alkenes c) CO2 d) Alkyl halide
205. Which of the following reagents cannot be used to locate the position of triple bond in CH3 — C ≡ C— CH3 ?
a) Br2 b) O3 c) Cu+ d) KMnO4
206. Decarboxylation of malonic acid gives:
a) CH4 b) C2 H6 c) C3 H8 d) None of these
207.

The product of reaction is:

a) b) c) d)

208. Which compound will react with an aqueous solution of Ag(NH3 )+ −

2 OH ?
a) CH3 — C ≡ C— CH3 b) CH3 CH2 C ≡ CH c) CH3 — CH3 d) CH2 = CH2
209. Reactivity of tertiary H, secondary H and primary H towards elimination is:
a) Tert. > sec. >pri. b) Sec. >tert. >pri c) Sec. >pri. >tert. d) Pri. > sec. >tert.
210. 1-butyne on hydration gives
a) Butyn-1, 2-diol b) Butan-1-ol c) Butan-2-ol d) Butan-2-one
211. The hydration of propyne in the presence of HgSO4 /H2 SO4 produces
a) HCHO b) CH3 CHO c) CH3 CH2 CHO d) CH3 COCH3
212. The most reactive halogen in the halogenation of alkanes is:
a) Cl2 b) Br2 c) I2 d) All are equal
213. A gas decolourised by KMnO4 solution but gives no precipitate with ammoniacal cuprous chloride
is
a) Ethane b) Methane c) Ethene d) Acetylene
214. Indane is:
a) Commercial propane
b) Commercial isobutene and propane mixture
c) Methane, propane mixture
d) Butane, ethane mixture
215. Which reacts with ammoniacalAgNO3 ?
a) Propyne b) 2-butyne c) 1,3-butadiene d) Pentene
216. The conversion

Can be effected using

a) Br2 /CCl4 b) Br2 /H2 O
c) Br2 /Fe d) Br/ benzoyl peroxide
217. Which of the following cycloalkane gives open chain compound, when reacts with bromine?
a) Cyclopropane b) Cyclopentane c) Cyclohexane d) Cyclooctane
218. The addition of HBr to an alkene in the presence of peroxide is the example of
a) Electrophilic addition reaction
b) nucleophilic addition reaction
c) Free radical addition reaction
d) The formation of carbocation as an intermediate
219. On mixing a certain alkane with chlorine and irradiating it with UV light, it form one monochloroalkane.
The alkane could be
a) Neopentane b) Propane c) Pentane d) Isopentane
220. Which of the following statements is true for ethane, ethene and acetylene?
a) Acetylene is the weakest acid and has the longest C − H bond distance
b) Acetylene is the strongest acid and has the shortest C − H bond distance
c) Ethane is the strongest acid and has the longest C − H bond distance
d) Ethene is the strongest acid and has the shortest C − H bond distance
221. On cracking petrol we get:
a) CH4
b) C3 H6
c) Both of the above
d) CH3 + CH4 + C2 H6 + alcohols
222. Methyl bromide is converted into ethane by heating it in ether medium with
a) Al b) Zn c) Na d) Cu
223. The addition of oxygen gas to reaction mixture of chlorine and methane (photochemical chlorination):
a) Accelerates the reaction
b) Retards the reaction for sometime
c) Has no effect on the rate of reaction
d) May accelerate or retard the reaction depending upon the amount of oxygen
224. Order of reactivity of C2 H6 , C2 H4 and C2 H2 is
a) C2 H6 > C2 H4 > C2 H2 b) C2 H2 > C2 H6 > C2 H4
c) C2 H4 > C2 H2 > C2 H6 d) All are equally reactive
225. Bacterial decomposition of cellulose material present in sewage water gives:
a) H2 b) CH4 c) O2 d) N2
226. The reaction, CH3 Br + Na →Product, is called
 a) Perkin reaction b) Levit reaction c) Wurtz reaction d) Aldol condensation
227. 𝑀𝑒𝑠𝑜-dibromobutane on debromination gives
a) 𝑡𝑟𝑎𝑛𝑠-2-butene b) 𝑐𝑖𝑠-2-butene c) 1-butene d) 1-butyne
228. CH ≡ CH + HBr → 𝑋, product X is
a) Ethylene bromide b) Vinyl bromide
c) Bromo ethane d) Ethyledine bromide
229. Kolbe’s synthesis of sodium salt of butanoic acid gives:
a) 𝑛-hexane b) Isobutane c) Butane-1 d) Ethylene
230. The compound formed when silver powder is heated with chloroform:
a) CH4 b) C2 H2 c) C2 H4 d) C2 H6
231. The reaction of toluene with chlorine in the presence of ferric chloride gives predominantly
a) 𝑚-chlorotoluene b) Benzyl chloride
c) Benzoyl chloride d) 𝑜 and 𝑝-chlorotoluene
232. Which of the following will yield 𝑡𝑟𝑎𝑛𝑠 product from butyne?
a) LiAlH4 b) Na⁄Liq. NH3 c) NaBH4 d) Ni catalyst
233. A hydrocarbon of molecular formula C6 H10 reacts with sodamide and the same on ozonolysis
followed by hydrogen peroxide oxidation gives two molecules of carboxylic acids, one being
optically active. Then, the hydrocarbon may be
a) 1-hexyne b) 3-hexyne
c) 3-methyl-1-pentyne d) 3,3-dimethyl-1-butyne
234. Which of the following is not correct about the reaction,
Nal(aq)
CH2 = CH2 + Br2 → ?
a) The products formed are CH2 BrCH2 Br and CH2 BrCH2 I
b) The reaction follows polar mechanism
c) The reaction occurs readily in solution and is catalysed by inorganic halides
d) CH2 ICH2 I is formed only
235. During ozonolysis of CH2 = CH2 if hydrolysis is made in absence of Zn dust the products formed are:
a) HCHO b) HCOOH c) CH3 OH d) CH2 OHCH2 OH
236. The formation of butane on heating C2 H5 I with Na in presence of ether is contaminated with impurities of:
a) C2 H4 b) C3 H6 c) CH4 d) None of these
237. When sodium propionate is heated with soda-lime, the product formed is
a) Methane b) Ethane c) Ethene d) Ethyne
238. Isopropyl bromide on Wurtz reaction gives
a) Hexane b) Propane
c) 2,3-dimethyl butane d) 𝑛𝑒𝑜-hexane
239. Which one of the following has the minimum boiling point?
a) 𝑛-butane b) 1-butyne c) 1-butene d) 𝐼𝑠𝑜-butene
240. The substance that would not at all be formed during the reaction of methane and chlorine in the presence
of sunlight is:
a) CH3 Cl b) CHCl3 c) CH3 CH3 d) CH3 CH2 CH3
241. When isopropyl magnesium iodide is treated with water, the product is:
a) Propane b) 𝑛-butane c) Isobutene d) Isobutyl alcohol
242. The monosodium salt of acetylene on treating with dry CO2 forms:
a) CH ≡ CCOOH b) CH ≡ CCOONa c) CH ≡ CCONa d) None of these
243. Propyne on passing through red hot iron tube gives
 d) None of these

a) b) c)

244. (CH3 )3 CMgCl on reaction with D2 O produces

a) (CH3 )3 COD b) (CD3 )3 CH c) (CH3 )3 CD d) (CD3 )3 CD
245. 𝑛-hexadecane (cetane) has cetane number:
a) 100 b) Zero c) 90 d) 110
246. Acetylene does not react with
a) Na b) ammoniacal AgNO3 c) HCl d) NaOH
247. What volume of CH4 at NTP is formed when 20.5 g of CH3 COONa is treated with sodalime?
a) 4.4 litre b) 2.2 litre c) 3.2 litre d) 5.6 litre
248. The hydrocarbon which decolourizes alkaline KMnO4 solution, but does not give any precipitate with
ammoniacal silver nitrate is:
a) Benzene b) Acetylene c) Propyne d) Butyne-2
249. What is the molecular formula of the product formed when benzene is reacted with ethyl chloride
in presence of anhydrous aluminium chloride?
a) C8 H10 b) C6 H6 c) C8 H8 d) C6 H5 Cl
250. Which will give CH2 = C = CH2?
Zn/CH3 OH
a) CH2 Br— CBr = CH2 →
K CO3 (𝑎𝑞)
b) CH ≡ C— CH2 — COOH →2
2Na
c) 2CH2 = CH— CH2 I →
d) None of the above
251. A dibromo derivative of an alkane reacts with sodium metal to form an alicyclic hydrocarbon. The
derivative is
a) 1,1-dibromopropane b) 2,2-dibromopropane
c) 1,2-dibromoethane d) 1,4-dibromobutane
252. By coaltar distillation which is not obtained?
a) Light oil b) Middle oil c) Heavy oil d) Mobil oil
253. In the following reaction:

The major product is:

a) b) c) d)

254. The treatment of ethane with cold alkaline potassium permanganate produces
a) Ethylene glycol b) Formaldehyde
c) Formic acid d) Carbon dioxide and water
255. As compared to melting points of even carbon chain isomers, the melting points of odd carbon chain
alkanes are:
a) Lower
b) Higher
c) Same
 d) Not depend upon branching
256. Hg2+ /H+
Ph − C ≡ C − CH3 → 𝐴,

a) b) c) d)

257. In the reactions,

Lindlar catalyst ⁄H2 Na/NH3
𝐵← 𝑅C ≡ C𝑅 → 𝐴
H2
𝐴and𝐵 are geometrical isomers. Then,
a) 𝐴 is 𝑐𝑖𝑠 and 𝐵 is 𝑡𝑟𝑎𝑛𝑠 b) 𝐴 is 𝑡𝑟𝑎𝑛𝑠 and 𝐵 is 𝑐𝑖𝑠
c) 𝐴 and 𝐵 are 𝑐𝑖𝑠 d) 𝐴 and 𝐵 are 𝑡𝑟𝑎𝑛𝑠
258. Identify ‘A’ in the reaction:

a) b) c) d) CH3 C ≡ CH = CH2

259. Choose the correct statement

a) Acetylene is more reactive than ethylene to an electrophilic attack
b) Acetylene and ethylene show similar reactivities towards an electrophilic attack with different rates
c) The reactivities of acetylene and ethylene towards an electrophilic attack depend on the electrophilic
reagent
d) Acetylene is less reactive than ethylene to an electrophilic attack
260. CrO2Cl2
C6 H5 CH3 → Z
In the given sequence, Z is
a) Benzaldehyde b) Toluic acid c) Phenyl acetic acid d) Benzoic acid
261. 2-hexyne can be converted to 𝑡𝑟𝑎𝑛𝑠-2-hexene by the action of:
a) H2 − Pd/BaSO4 b) Li/Liq. NH3 c) H2 − Pt O2 d) NaBH4
262. In the following reaction,
𝑅CH2 CH = CH2 + ICI → [𝐴]
Markownikoff’s product [𝐴] is
𝑅CH2 CH − CH2 I 𝑅CH2 CH − CH2 CI
a) | b) |
Cl I
𝑅CH2 − C = CH2
c) | d) 𝑅CH = CH − CH2 I
I
263. Which of the following will not produce ethane?
a) Reduction of CH3 COOH with HI and red P
b) Reduction of CH3 COCH3 with HI and red P
c) Sodalimedecarboxylation of sodium probionate
d) Hydrogenation of ethane in presence of Raney-Ni
264. Which will not react with acetylene?
 a) NaOH b) Na c) HCl d) Amm. AgNO3
265. Ozonolysisof an organic compounds gives formaldehyde as one of the products. This confirms the
presence of
a) Two ethylenic double bonds b) A vinyl group
c) An 𝑖𝑠𝑜-propyl group d) An acetylenic triple bond
266. Among the paraffins it is generally found that with an increase in the molecular weight:
a) The freezing point decreases
b) The boiling point decreases
c) The boiling point increases
d) The vapour density decreases
267. Which of the following reactions can be used to prepare methane?
a) Clemmensen reduction
b) Wurtz reaction
c) Reduction of CH2 = CH2 by LiAlH4
d) Reduction of methyl iodine by using a zinc-copper couple
268. Ethylene reacts with dil. H2 SO4 in presence of HgSO4 to give:
a) Ethanal b) Ethanol c) Ethane d) Ethene
269. Household gas or liquefied petroleum gas (L.P.G.) mainly contains:
a) Methane and ethane
b) Liquefied butane and isobutene
c) Ethylene and CO
d) C2 H2 and H2
270. Which one of the following gives, on ozonolysis, both aldehydes and ketones?
a) Me2 C = CHMe b) Me2 C = CMe2
c) MeCH2 − C(Me) = CMe2 d) MeCH(Me) − CH = CHMe
271. Which among the following give alkanes on reduction?
a) Aldehydes b) Ketones c) Carboxylic acids d) All are correct
272. Lewisite (a war gas) is an…….compound.
a) Organosulphur b) Organoarsenic c) Organoantimony d) Organophosphorus
273. In the following reaction,
H2 O
C2 H2 → X ⇌ CH3 CHO . What is X?
HgSo4 /H2 SO4
a) CH3 CH2 OH b) CH3 − O − CH3 c) CH3 CH2 CHO d) CH2 = CHOH
274. Compound (𝐴) on oxidation with OsO4 /NaIO4 gives Hexanedinal. Structure of compound. (𝐴) will be

a) b) c) d)

275. Major product of the following reaction is:

a) Butene-1 b) Butene-2 c) Butane d) Butyne-1

276. The compound formed as a result of oxidation of ethyl benzene by KMnO4 is
a) Benzophenone b) Acetophenone c) Benzoic acid d) Benzyl alcohol
277. Methane reacts with conc. HNO3 at high temperature to yield:
a) CO2 and H2 O b) HCHO c) HCOOH d) CH3 NO2
278. Butyne-1 and butyne-2 can be distinguished by:
a) Br2 , CCl4
 b) H2 , Lindler catalyst
c) Dilute H2 SO4 , HgSO4
d) Ammoniacal cuprous chloride
279. An isolated alkadiene is:
a) Penta-1,4-diene b) Penta-1,3-diene c) Penta-1,2-diene d) None of these
280. ′
Lindlar s catalyst
CH3 − C ≡ C − CH3 → 𝐴, the compound 𝐴 is
a) 𝑐𝑖𝑠-2-butene b) 𝑡𝑟𝑎𝑛𝑠-2-butene c) 𝑖𝑠𝑜-butene d) 1-butene
281. If a halogen compound contains OH group, will it be possible to carry out the Wurtz reaction?
a) Yes b) No c) - d) -
282. Reduction of 2-butyne with Na in liquid NH3 gives predominantly:
a) 𝑛-butane b) 𝑇𝑟𝑎𝑛𝑠-2-butene c) No reaction d) 𝐶𝑖𝑠-2-butene
283. Phenyl magnesium bromide reacts with methanol to give
a) A mixture of anisol and Mg(OH)Br b) A mixture of benzene and Mg(OMe)Br
c) A mixture of toluene and Mg(OH)Br d) A mixture of phenol and Mg(Me)Br
284. Iso-octane is added to petrol:
a) To precipitate inorganic material
b) To prevent freezing of petrol
c) To increase the boiling point of petrol
d) To increase octane number
285. When cyclohexane is poured on water, it floats, because:
a) Cyclohexane is in ‘boat’ form
b) Cyclohexane is in ‘chair’ form
c) Cyclohexane is in ‘crown’ form
d) Cyclohexane is less dense than water
286. Ethylene reacts with 1% cold alkaline KMnO4 (Baeyer’s reagent) to form:
a) Oxalic acid b) Acetic acid c) Glycerol d) Glycol
287. The reagent that would effect the following transformation is:
C6 H5 − CH = CH − NO2 → C6 H5 CH2 − CH2 − NO2 :
a) NaBH4in alcohol b) [(C6 H5 )3 P]3 RhCl/H2 c) LiAlH4 d) All of these
288. How many primary and tertiary carbon atoms are present in

a) 3𝑝, 1𝑡 b) 2𝑝,2𝑡 c) 1𝑝, 3𝑡 d) None of these

289. Which of these will not react with acetylene?
a) NaOH b) Amm. AgNO3 c) Na d) HCl
290. The catalytic hydrogenation is more easier in case of which alkene?

a) b) c) d)

291. Addition of hydrogen on C=C is called hydrogenation. Addition of halogen on C=C is called:
a) Halogenation
b) Dehalogenation
c) Elimination of halogen
d) None of these
292. The synthetic gas is:
a) CH4 b) C2 H2 c) CO + 3H2 d) NH3
293. Toluene on treatment with CrO3 and (CH3 CO)2 O followed by hydrolysis with dil. HCl gives
a) Benzaldehyde b) Benzoic acid c) Phenol d) Phenylacetaldehyde
294. Identify the product (P) in the reaction:
 Alk.KMnO4
𝑅3 C— H → P
a) No reaction b) 𝑅3 C— CR 3 c) 𝑅3 C— OH d) 𝑅3 C— O— C𝑅3
295. 𝐺𝑒𝑚 dihalides on treatment with alcoholic KOH give
a) Alkyne b) Alkene c) Alkane d) All of these
296. The presence of Ag ion increases the solubility of alkenes due to the formation of
+

a) 𝑑𝜋 − 𝑑𝜎 bonding b) 𝑝𝜎 − 𝑝𝜋 bonding c) 𝑝𝜋 − 𝑑𝜋 bonding d) 𝑝𝜋 − 𝑑𝜎 bonding

297. Acetylene and HCHO react in presence of copper acetylide catalyst to form
a) 1-butyne-1,4-diol b) 2-butyne-1,2-diol c) 2-butyne-1,4-diol d) None of these
298. Decarboxylation of isobutyric acid leads to:
a) Isobutene b) Propane c) Butane d) None of these
299. In the addition of HBr to propene in the absence of peroxides the first step involves the addition of:
a) H + b) Br − c) H d) Br
300. The IUPAC name of— C ≡ C— CH3 group is:
a) Prop-2-ynyl b) Prop-2-enyl c) Prop-1-ynyl d) None of these
301. Pure methane can be produced by
a) Wurtz reaction b) Kolbe’s electrolytic method
c) Soda lime decarboxylation d) reduction with H2
302. What are X and Y respectively, in the following reaction?
𝑌 𝑋
𝑍 − product ← 2 − butyne → 𝐸 − product
a) Na⁄NH3 (liq. ) and Pd⁄BaSO4 + H2 b) Ni⁄140℃ and Pd⁄BaSO4 + H2
c) Ni⁄140℃ and Na⁄NH3 (liq. ) d) Pd⁄BaSO4 + H2 and Na⁄NH3 (liq. )
303. When a mixture of methane and oxygen is passed through heated molybdenum oxide, the main
product formed is
a) Methanoic acid b) Ethanal c) Methanol d) Methanal
304. Propyne and propene can be distinguished by
a) conc. H2 SO4 b) Br2 in CCl4 c) alk. KMnO4 d) AgNO3 in NH3
305. Conformation in molecules is due to:
a) Rotation about a single bond
b) Change in direction of light
c) Structural changes
d) Restricted rotation about a double bond
306. The non-aromatic compound among the following is

a) b) c) d)

307. Kerosene is a mixture of:

a) Alkenes b) Alkanes c) Alkynes d) Arenes
308. Which of the following alkenes is most stable?
a) 𝑅2 C = C𝑅2 b) 𝑅— CH = CH— 𝑅 c) 𝑅CH = CH2 d) CH2 = CH2
309. What is obtained when chlorine is passed in boiling toluene and product is hydrolysed?
a) 𝑜-cresol b) 𝑝-cresol
c) 2,4-dihydroxytoluene d) Benzyl alcohol
310. It is necessary to use…..in the iodination of alkane.
a) Alcohol b) Oxidant c) Benzene d) Reductant
311. Ozonolysis of propyne gives:
a) CH3 CHO b) CH3 COCHO c) HCHO d) CHOCHO-
312. Reactivity of alkenes towards H𝑋 decreases in the order:
a) Butene>propene>ethene
b) Butene>ethene>propene
c) Ethene>propene>butene
d) None of the above
313. Propyne on oxidation with SeO2 gives:
a) CHOCHO b) CH3 CH2 CHO c) CH3 COCHO d) CHOCH2 CHO
314. 2-methylbutane on reacting with bromine in the presence of sunlight gives mainly
a) 1-bromo 3-methylbutane b) 2-bromo 3-methylbutane
c) 2-bromo 2-methylbutane d) 1-bromo 2-methylbutane
315. The product of following reaction is,

a) b) c) d)

316. Which statement is correct?

a) Alkanes are called paraffins because of their little chemical affinity
b) Alkanes have only sigma bonds
c) Most abundant alkane is CH4
d) All are correct
317. An activating group
a) actinates only 𝑜𝑟𝑡ℎ𝑜 and 𝑝𝑎𝑟𝑎 positions b) Deactivates 𝑚𝑒𝑡𝑎 position
c) activates 𝑜𝑟𝑡ℎ𝑜 and 𝑝𝑎𝑟𝑎 more than 𝑚𝑒𝑡𝑎 d) Deactivates 𝑚𝑒𝑡𝑎 more than 𝑜𝑟𝑡ℎ𝑜 and 𝑝𝑎𝑟𝑎
318. An alkyl bromide,𝑅Brof molecular weight 151 is the exclusive product of bromination of which
hydrocarbon?
a) Dodecane b) 2, 2-dimethylpropane
c) 2, 2-dimethylhexane d) 2, 2, 3-trimethylheptane
319. The conversion of liquid hydrocarbon into a mixture of gaseous compounds by heat alone is known as:
a) Hydrolysis b) Reduction c) Oxidation d) Cracking
320. Ethyl benzene cannot be prepared by
a) Wurtz reaction b) Wurtz-Fittig reaction
c) Friedel-Craft’s reaction d) Clemmensen reduction
321. Silver acetylide when heated with HCl gives:
a) C2 H2 b) H2 c) C2 H4 d) C6 H6
322. The addition of HCl to 3, 3, 3-trichloropropene gives
a) Cl3 CCH2 CH2 Cl b) Cl3 CCH2 CHCl2 c) Cl2 CHCH2 CHCl2 d) Cl2 CHCH(Cl)CH2 Cl
323. Sodium ethoxide is specific reagent for:
a) Dehydration
b) Dehydrohalogenation
c) Dehydrogenation
d) Dehalogenation
324. A fuel contains 25% 𝑛-heptane and 75% iso-octane. Its octane number is:
a) 50 b) 75 c) 100 d) 25
325. The greatest strain is involved in cycloalkane, when the bond angle is:
a) 60 b) 90 c) 120 d) 108
326. Which of the following will be obtained by the bromination of ethylbenzene in the presence of light?
 a) b) c) d)

327. On passing electric discharge through graphite in presence of H2 the compound formed is:
a) CH4 b) C2 H6 c) C2 H2 d) All of these
328. Propene reacts with Cl2 at 400-600C to give:
a) 1,2-dichloropropane b) Allyl chloride c) No reaction d) Polyvinyl chloride
329. Methane reacts with oxygen at 100 atm and 300C in presence of Cu to give:
a) Acetaldehyde b) Methyl alcohol c) Acetic acid d) Ethyl alcohol
330. Ethylene is used in making:
a) Anti-freeze b) Solvent c) Fumigant d) All of these
331. The main constituent of light oil fraction is:
a) Benzene b) Toluene c) Phenol d) Naphthalene
332. The major product in the acid catalysed dehydration of 2-pentanol is:
a) 4-pentene b) 3-pentene c) 2-pentene d) 1-pentene
333. Which gas is commonly used in welding?
a) C2 H4 b) C2 H2 c) CH4 d) C2 H6
334. The synthesis of 3-octyne is achieved by adding a bromoalkane into a mixture of sodium amide
and an alkyne. The bromoalkane and alkyne respectively are
a) BrCH2 CH2 CH2 CH2 CH3 and CH3 CH2 C ≡ CH b) BrCH2 CH2 CH3 and CH3 CH2 CH2 C ≡ CH
c) BrCH2 CH2 CH2 CH2 CH3 and CH3 C ≡ CH d) BrCH2 CH2 CH2 CH3 and CH3 CH2 C ≡ CH
335. Which is most acidic of the following?
a) Methane b) Acetylene c) 1-butene d) 𝑁𝑒𝑜-pentane
336. Addition of HI on double bond of propene yields isopropyl iodide and not 𝑛-propyl iodide as the major
product, because addition proceeds through:
a) A more stable carbonium ion
b) A more stable carbanion
c) A more stable free radical
d) None of the above
337. Correct statement about 1,3-dibutene
a) Conjugated double bonds are present b) Reacts with HBr
c) Forms polymer d) All of the above
338. Preparation of ethane by electrolysis of aqueous solution of potassium acetate is called
a) Wurtz reaction b) Kolbe’s synthesis
c) Grignard reaction d) Sabatier-Sendersen’s reaction
339. 𝐴(C H ) →H2 ,Ni O
𝐵(C H ) →
3 /H2 O/Zn
CH CHO
4 6 4 8 3
1 mole
Thus, 𝐴 and 𝐵 are

a) b)

c) CH3 CH2 C ≡ CH, CH3 CH = CHCH3 d) CH2 = CH − CH = CH2 , CH3 CH = CH − CH3

340. The major product P in the following reaction is
HI
CH3 − CH = CH2 → 𝑃
peroxide
CH3 − CH − CH3
a) CH3 CH2 CH2 I b) |
I
c) CH2 − CH = CH2 d) CH2 − CH2
 | | |
I II
341. CH3 CH = CHCHO is oxidized to CH3 CH = CHCOOH using:
a) Alkaline permanganate
b) Ammoniacal silver nitrate
c) Selenium dioxide
d) Osmium tetraoxide
342. O3 ⁄
H2 O
OH+
CaC2 + H2 O → 𝑋 → HCOOH
+HCOOH, 𝑋 is
a) C2 H4 b) C2 H2 c) C2 H6 d) Ca(OH)2
343. Acetylene reacts with hypochlorous acid to form
a) Cl2 CH. CHO b) ClCH2 COOH c) CH3 COCl d) ClCH2 CHO
344. Dehydrohalogenation of 1,2-dibromobutane with alc. KOH gives:
a) 1-butyne b) 2-butene c) 1-butene d) 1-bromo-1-butene
345. Water can be added across a triple bond in the presence of
a) Acidic medium b) Alkaline medium c) Neutral medium d) Acid and HgSO4
346. Both methane and ethane may be obtained in one step reaction from:
a) CH3 COONa b) CH3 I c) Both (a) and (b) d) None of these
347.

The reaction of
with HBr gives predominantly

a) b)

c) d)

348. The product formed when acetylene is passed through red hot tube is:
a) Benzene b) Cyclohexane c) Neoprene d) Ethane
349. The product formed when toluene is heated in light with 𝐶𝑙2 and in absence of halogen carrier is
a) Chlorobenzene b) Gammexane c) Benzotrichloride d) DDT
350. Among the following statement on the nitration of aromatic compounds, the false one is
a) The rate of nitration of benzene is almost the same as that of hexadeuterobenzene
b) The rate of nitration of toluene is greater than that of benzene
c) The rate of nitration of benzene is greater than that of hexadeuterbenzene
d) Nitration is an electrophilic substitution reaction
351. Reaction of one molecule of HBr with one molecule of 1, 3-butadiene at 40℃ gives predominantly
a) 1-bromo-2-butene under kinetically controlled conditions
b) 3-bromobutene under thermodynamically controlled conditions
c) 1-bromo-2-butene under thermodynamically controlled conditions
d) 3-bromobutene under kinetically controlled conditions
352. Which of the following compound is aromatic?
 a) b) c) d)

353. Ethylene reacts with 1% alkaline KMnO4 to form

a) Oxalic acid b) Ethylene glycol c) Ethyl alcohol d) HCHO
354. To prepare a pure sample of 𝑛-hexane using sodium metal as one reactant, the other reactant or reactants
will be:
a) Ethyl chloride and 𝑛-butyl chloride
b) Methyl bromide and 𝑛-pentyl bromide
c) 𝑛-propyl bromide
d) Ethyl bromide and 𝑛-butyl bromide
355. Friedel-Craft acylation can be given by

𝑋 is
𝑅 − C − Cl 𝑅−C−𝑅 𝑅−C−H
a) || b) || c) || d) 𝑅 − O − 𝑅
O O O
356. A mixture ofCS2 and H2 S on passing over heated Cu gives:
a) C2 H6 b) CH4 c) C3 H8 d) None of these
357. Photochemical chlorination of alkane is initiated by a process of:
a) Pyrolysis b) Substitution c) Homolysis d) Peroxidation
358. Under which one of the following conditions, does the reaction,
?
CH ≡ CH + CH3 OH → CH3 O − CH = CH2 take place?
a) NH4 OH⁄80℃ b) Conc. H2 SO4 ⁄160℃
c) Anhydrous ZnCl2 ⁄150℃ d) CH3 OK⁄160 − 200℃
359. Which one is correct for the given change?

a) The product formed is 𝑡𝑟𝑎𝑛𝑠-2-methyl-1-cyclopentanol

b)

c) The addition is syn addition

d) All of the above
360. The electrolysis of aqueous solution of potassium succinate produces
a) Methyl alcohol b) ethyl alcohol c) ethene d) ethane
361. Ozonolysis products of an olefin are
CHOCH2 CHO
 | and |
CHO CH2 CHO
Olefin is

a)

b)

c)

d)

362. (1)NaNH2 H2
CH3 C ≡ CH → 𝐴 → 𝐵
(2) CH3 CH2 Br Lindlar′ s catalyst
What is 𝐵 in the above reaction?

a) b)

c) d)

363. The gas believed to be the cause of explosion in coal-mines or fire damp is:
a) Methane b) Ethane c) C3 H8 d) CO
364. Addition of HBr to propylene in presence of benzoyl peroxide, follows
a) Markownioff’s rule b) Baeyer’s rule
c) Carbanion mechanism d) 𝑎𝑛𝑡𝑖-Markownioff’s rule
365. 2-phenyl propene on acidic hydration gives,
a) 2-phenyl-2-propanol b) 2-phenyl-1-propanol
c) 3-phenyl-1-propanol d) 1-phenyl-2-propanol
366. CH2 = CH2 is also called a:
a) Monomer b) Polymer c) Isomer d) Equimer
367. Halogenation of alkanes is an example of:
a) Electrophilic substitution
b) Nucleophilic substitution
c) Free radical substitution
d) Oxidation
368. The most stable isomer of 1,2-dichloroethane is:
a) Staggered b) Gauche c) Eclipsed d) Partially eclipsed
369. Which does not decolourizeBr2 water?

a) CH2 = CH2 b) c) CH3 C ≡ CH d) CH2 = CHCH3

370. Grignard’s reagent gives alkane with:

a) H2 O b) C2 H5 OH c) C2 H5 NH2 d) All of these
371. The carbon-carbon bond length in benzene is
 a) In between C2 H6 and C2 H4 b) Same as in C2 H4
c) In between C2 H6 and C2 H2 d) In between C2 H4 and C2 H2
372. Electrolysis of a concentrated solution of sodium fumarate gives:
a) Fumaric acid b) Ethylene c) Ethane d) Acetylene
373. In order to overcome angle strain, cyclohexane acquires:
a) Square planar structure
b) Planar structure
c) Puckered ring structure
d) Pyramidal structure
374. 𝑜-toluic acid on reaction with Br2 + Fe gives

a) b)

c) d)

375.

is called:
a) Wurtz’s reaction b) Kolbe’s reaction c) Sabatier and Senderens d) Carbylamines reaction
reaction
376.

Identify the 𝑋 in the above reaction

a) b) c) d)

377. CH3 − CH = CH2 + NOCl → 𝑃

Identify the adduct
CH3 − CH − CH2 CH3 − CH − CH2
a) | | b) | |
ClNO NOCl
CH3 − CH2 − CH CH2 − CH2 − CH2
c) | d) | |
Cl NOCl
378. Ethane can be freed(isolated) from the impurity of ethylene by washing with:
a) HCl b) HNO3 c) H2 SO4 d) water
379. Poisonous gases are:
a) Phosgene b) Lewisite c) Mustard gas d) All of these
380. A chlorohydrocarbon, named chlorodane is used especially as:
a) Insecticide b) Anti-worm c) Fungicide d) Anti-termite
381. The highest boiling point is expected for
a) 𝑖𝑠𝑜-octane b) 𝑛-octane
c) 2, 2, 3, 3-tetramethyl butane d) 𝑛-butane
382. The addition of tetraethyl lead of petrol:
a) Lowers its octane number
b) Raises its octane number
c) May raise or lower the octane number
d) Has no effect on octane number
383. Which of the following reactions will give an alkyne?
Zn/alc. alc.KOH
a) CH3 CBr2 CHBr2 → b) CH3 CH2 CHBr2 →
NaNH
c) CH3 CHBrCH2 Br → 2 d) All of the above
384. Which one among the following is assigned an octane number of zero?
a) Iso-octane b) 𝑛-heptane c) Isoheptane d) 2-methyloctane
385. The process where straight run gasoline is cracked in order to increase octane number is called:
a) Aromatization b) Rearrangement c) Substitution d) Reforming
386. The treatment of aluminum carbide with water or dilute acid produces
a) acetylene b) ethene c) methane d) ethane
387. When acetylene is passed through red hot iron tube, compound 𝑋 is formed. Which one of the
following reactions will yield 𝑋 as the major product?
Distillation
a) C6 H5 OH + Zn → b) C6 H5 SO3 H + NaHCO3 →
Ni ∆
c) C6 H12 + 3H2 → d) C6 H5 Cl + H2 O →
388. In the reaction
Oxidation NaOH Sodalime
C6 H5 CH3 → 𝐴→ 𝐵→ 𝐶
Identify 𝐶 is
a) C6 H5 OH b) C6 H6 c) C6 H5 COONa d) C6 H5 ONa
389. The major product formed when a 3, 3-dimethyl butan-2-ol is heated with concentrated sulphuric
acid, is
a) 2,3-dimethyl-2-butene
b) 2,3-dimethyl-1-butene
c) 3,3-dimethyl-1-butene
d) 𝑐𝑖𝑠 and 𝑡𝑟𝑎𝑛𝑠 isomers of 2,3-dimethyl-1-butene
390. Most of the hydrocarbons from petroleum are obtained by:
a) Fractional distillation
b) Fractional crystallization
c) Vaporisation
d) Polymerization
391. Cyclopentadienyl anion is
a) Aromatic b) Non-aromatic c) Non-planar d) Aliphatic
392. Ozonolysis of buta-1,3-diene gives:
a) HCHO and glyoxal
b) CH3CHO and glyoxal
c) CO2 and glyoxal
d) HCHO+glyoxal+CH3 CHO
393. Which is not true in the case of natural gas?
a) It is a fuel
b) It is used in the manufacture of fertilizer
 c) It is a mixture of CO2 and H2
d) It is a mixture of gaseous hydrocarbons
394. Wurtz reaction using bromoethane yields:
a) 2-bromobutane b) 𝑛-butane c) Isobutene d) Ethane
395. Which of the following compounds is not aromatic?

a) b) c) d)

396. Which products are formed during the addition of Br2 on ethylene in presence of aqueous NaNO3 solution?
a) CH2 Br. CH2 ONO2
b) CH2 Br. CH2 Br
c) CH2 (ONO2 ). CH2 ONO2
d) Both (a) and (b)
397. Alkanes containing…..carbon atoms are converted into an aromatic hydrocarbon, when heated in presence
of Cr2 O3 on Al2 O3
a) 6 to 10 b) 4 to 8 c) 3 to 6 d) 5 to 6
398. Chlorination of toluene in the presence of light and heat followed by treatment with aqueous
NaOH solution gives
a) 𝑜-cresol b) 𝑝-cresol
c) Benzoic acid d) 2,4-dihydroxytoluene
399. Toluene can be converted into benzaldehyde by oxidation with
a) KMnO4 /alkali b) CrO2 Cl2 c) K 2 Cr2 O7 /H2 SO4 d) O2 /V2 O5
400. HgSO 4
CH3 − CH2 − C ≡ CH → 𝐴
H2 SO4
The compound A is
O
a) || b) CH3 − CH2 − CH2 − CHO
CH3 − CH2 − C − CH3
c) CH3 − CH2 − CH2 − COOH d) None of the above
401. When acetylene is passed through dil. H2 SO4 in presence of HgSO4 , the compound formed is
a) Ether b) Acetaldehyde c) Acetic acid d) Ketone
402. The reagent used for dehydration is:
a) Conc. H2 SO4 b) P2 O5 c) Al2 O3 d) All of these
403. A hydrocarbon has the formula C3 H4 . To find out whether it contains two double bonds or triple bonds,
the following test is performed:
a) Passed through ammoniacalAgNO3
b) Treated with Baeyer’s reagent
c) Treated with Fehling’s solution
d) Treated with Br2 water
404. The chemicals and the reaction conditions required for the preparation of ethane are
a) C2 H5 I, Zn − Cu, C2 H5 OH b) CH3 Cl, Na, H2 O
c) KOOC − CH = CH − COOK, electrolysis d) CH3 CO2 Na, NaOH, CaO, ∆
405. Formation of alkane by the action of zinc on alkyl halide is called
a) Wurtz reaction b) Kolbe’s reaction c) Ulmann’s reaction d) Frankland reaction
406.

the following type of hybridisation:

a) 𝑠𝑝3 b) 𝑠𝑝 2 c) 𝑠𝑝 d) 𝑠
407. (i)𝑥
CH3 − C ≡ C − CH3 →
(ii)Zn/H2 O

In the above reaction 𝑥 is.

a) HNO3 b) O2 c) O3 d) KMnO4
408. Temperature of oxyacetylene flame is:
a) 2549C b) 2400C c) 2700C d) 3000 to 3500C
409. Benzene can be obtained by heating either benzoic acid with 𝑋 or phenol with 𝑌. 𝑋 and 𝑌 are
respectively
a) Zinc dust and soda lime b) Soda lime and zinc dust
c) Zinc dust and sodium hydroxide d) Soda lime and copper
410. Hydrocarbon reacts with metal by displacing the H-atom is:
a) CH4 b) C2 H6 c) C2 H4 d) C2 H2
411. Petroleum is a mixture of:
a) Aromatic hydrocarbons with small amounts of aliphatic compounds
b) Aliphatic hydrocarbons with small amounts of aromatic compounds
c) Mixture of equal amount of aliphatic and aromatic hydrocarbons
d) Alcohols and fatty acids
412. The reduction of an alkyne to alkene using Lindlar catalyst result into
a) 𝑐𝑖𝑠 addition of hydrogen atoms
b) 𝑡𝑟𝑎𝑛𝑠 addition of hydrogen atoms
A mixture obtained by 𝑐𝑖𝑠 and 𝑡𝑟𝑎𝑛𝑠 additions of hydrogen atoms which are in equilibrium with each
c)
other
A mixture obtained by 𝑐𝑖𝑠 and 𝑡𝑟𝑎𝑛𝑠 additions of hydrogen atoms which are not in equilibrium with
d)
each other
413. Which molecule will undergo radical formation oxidation reaction most readily?

a) CH3 CH2 CH3 b) CH3 CH2 CH2 CH3 c) (CH3 )3 CH d)

414. Which of the following is expected to be aromatic?

a) b) c) d)

415. Aniline is treated with a mixture of sodium nitrite and hypophosphorus acid, the product formed
is
a) Aniline diazonium hypophosphate b) Benzene
c) Anilinium hypophosphite d) Aniline diazonium hypophosphite
416. Hexachloroethane is also called
a) DDT b) TNT c) Artificial camphor d) BHC
417. In presence of nickel cyanide, acetylene gives
a) Benzene b) Cyclooctatetraene c) Cyclohexatriene d) Cyclobutadiene
418. Conjugated double bonds are present in:
a) Propylene b) Isobutylene c) Butylene d) 1,3-butadiene
419. Normal alkanes can undergo sulphonation if they contain:
a) 4 carbon atoms
b) 5 carbon atoms
c) At least 6 carbon atoms
 d) 3 carbon atoms
420.

In the above reaction, 𝑋 is

a) HNO3 b) O2 c) O3 d) KMnO4
421. The dehydrohalogenation of neopentyl bromide with alcoholic KOH gives mostly:
a) 2-methyl-1-butene b) 2,2-dimethyl-1-butene c) 2-methyl-2-butene d) 2-butene
422. What is obtained, when ammoniacalAgNO3 reacts with acetylene?
a) Propanone b) Silver acetylide c) Ethylene d) None of these
423. Which of the following liberates methane on treatment with water?
a) Silicon carbide b) Calcium carbide c) Beryllium carbide d) Magnesium carbide
424. Which statement is correct?
a) Chloroacetic acid is less acidic than acetic acid because chlorine atom has-I effect
b) The greater the branching in a paraffin the lower is its b.p.
c) Kjeldahl’s method is used for the estimation of chlorine
d) All of the above
425. The most stable conformational isomer of cyclohexane is:
a) Chair form b) Boat form c) Half chair form d) Twisted form
426. In the following reaction sequences,

the termination step is:

a) Reaction 1 b) Reaction 2 c) Reaction 3 d) Reaction 4
427. Which of the following is elimination reaction?
a) CH3 CH2 OH ⟶ CH2 = CH2 + H2 O
b) CH3 CH2 Br ⟶ CH2 = CH2 + HBr
Zn
c) Br— CH2 — CH2 — Br → CH2 = CH2 +ZnBr2
d) All of the above are correct
428. CH ≡ CH O
→
3 /NaOH Zn/CH3 COOH
X→ Y. Y is:
a) CH2 OH— CH2 OH b) CH3 CH2 OH c) CH3 COOH d) CH3 OH
429. Baeyer’s reagent is used in the laboratory for:
a) Detection of double b) Detection of glucose c) Reduction d) Oxidation
bonds
430. Product formed on electrolysis of potassium salt of fumaric and maleic acid is
a) Ethane b) Ethene c) Ethyne d) Methane
431. The product ‘X’ in the following reaction is

Br
a) CH3 Br − CH = CH2 b) |
CH3 − C = CH2
c) CH3 CH = CHBr d) None of the above
432. Observe the following reactions and predict the nature of A and B.
 a) b)

c) d)

433. HBr is added to CH3 — CH = CH2 in presence of peroxides. The resultant compound is:
a) CH3 CHBrCH3 b) C2 H5 CH2 Br c) CH2 = CH2 CH2 Br d) None of these
434. Amount of Br2 required to react with 5 g pentene to form monobromo derivative is:
a) 11.11 g b) 11.43 g c) 5.55 g d) None of these
435. The compound (i) decolourisesKMnO4 (ii) forms ozonide with ozone and (iii) undergoes polymerization.
It will be:
a) C6 H6 b) C3 H8 c) C2 H4 d) C2 H6
436. The strongest 𝑜𝑟𝑡ℎ𝑜/𝑝𝑎𝑟𝑎 directing group is
a) −NH2 b) −CH3 c) −Cl d) −C2 H5
437. Which of the following species will be aromatic?
d) None of these

a) b) c)

438. When chlorine is passed through warm benzene in presence of the sunlight, the product obtained
is
a) Benzotrichloride b) Chlorobenzene c) Gammexane d) DDT
439. The C = C bond distance in an organic compound is1.34 Å. It can be
a) Butene b) Hexatriene c) Cyclohexatriene d) Any of these
440. The lowest possible alkane with ethyl group as substituents possesses mol. mass equal to:
a) 16 b) 72 c) 84 d) 128
441. The reagent(s) for the following conversion,
cis/are
a) Alcoholic KOH b) Alcoholic KOH followed by NaNH2
c) Aqueous KOH followed by NaNH2 d) Zn⁄CH3 OH
442. Aqueous H2 SO4 reacts with 2-methyl-1-butene to give predominantly:
a) Isopentyl hydrogen sulphate
b) 2-methyl-3-butene
c) 2-methyl-1-butene
d) Secondary butyl hydrogen sulphate
443. The number of conformation(s) for ethane is/are:
a) 1 b) 2 c) 3 d) Infinite
444. The test for unsaturation is confirmed by the decolourisation of which of the following?
a) Iodine water b) CuSO4 solution c) Bromine water d) All of these
445. Which does not react with chlorine in dark?
a) CH4 b) C2 H2 c) C2 H4 d) CH3 CHO
446. The ozonolysis of isobutene gives:
a) CH3 CHO b) CH3 COCH3 and HCHO c) CH3 CH2 OH d) CH3 OH
447. Which compound on reductive ozonolysis forms only glyoxal?
a) Ethyne b) Ethene c) Ethane d) 1,3-butadiene
448. The reaction,

is the example of:

a) Sulphonation b) Dehydration c) Alkylation d) Decomposition
449. The catalyst used in the manufacture of polythene by Ziegler method is:
a) Titanium tetrachloride and triphenylaluminium
b) Titanium tetrachloride and trimethylaluminium
c) Titanium dioxide
d) Titanium isopropoxide
450.

On reductive ozonolysis yields

a) 6-oxoheptanal b) 6-oxoheptanoic acid
c) 6-hydroxyheptanal d) 3-hydroxypentanal
451. The treatment of CH3 Mg𝑋 with CH3 C ≡ C − H produces
H H
a) CH3 − CH = CH2 b) CH3 C ≡ C − CH3 c) | | d) CH4
CH3 − C = C − CH3
452. 1,3-butadiene has:
a) Only 𝑠𝑝-hybridised C-atoms
b) Only 𝑠𝑝2 -hybridised C-atoms
c) 𝑠𝑝, 𝑠𝑝2 and 𝑠𝑝3 -hybridised C-atoms
d) 𝑆𝑝 and 𝑠𝑝2 -hybridised C-atoms
453. Chloroform, on warming with Ag powder gives
a) C2 H6 b) C2 H6 c) C2 H4 d) C2 H2
454. By Wurtz reaction, a mixture of methyl iodide and ethyl iodide gives
a) Butane b) Ethane
c) Propane d) A mixture of the above three
455. The following reaction is an example of,
Light
C3 H8 + 2Cl2 → C3 H6 Cl2 + 2HCl
a) An addition reaction
b) A substitution reaction
c) An elimination reaction
d) None of the above
456. Acetylene on passing into excess of HOCI solution forms:
a) Ethylene chlorohydrin
b) Acetaldehyde
c) Dichloroacetaldehyde
d) Methyl chloride
457. Ethylene forms ethylene chlorohydrin by the action of:
a) Dry chlorine gas
 b) Dry hydrogen chloride gas
c) Solution of chlorine gas in water
d) Dilute hydrochloric acid
458. Which one of the following has the smallest heat of hydrogenation per mole?
a) 1-butene b) 𝑇𝑟𝑎𝑛𝑠-but-2-ene c) 𝐶𝑖𝑠-but-2-ene d) Buta-1, 3-diene
459. OS O4
→ 𝐴, 𝐴 is
H2 O2
a) 𝑚𝑒𝑠𝑜 diol b) Racemicdiol c) Both (a) and (b) d) None of these
460. Which of the following characteristic apply both to ethane and ethyne?
a) Explode when mixed with chlorine
b) Decolourise Baeyer’s reagent giving brown precipitate
c) Rapidly absorbed by cold conc. H2 SO4
d) Form white precipitate with AgNO3 solution
461. Conjugated double bond is present in:
a) Propylene b) Isobutylene c) 1,3-butadiene d) Butylene
462. The reactivities of ethane, ethylene and acetylene are of the order
a) Ethane<ethene<ethyne b) Ethane <ethyne<ethene
c) Ethyne = ethene> ethane d) Any of the above
463. Which is not linked with methane?
a) Marsh gas b) Natural gas c) Producer gas d) Coal gas
464. Acetylene can be obtained by the reaction?
Electrolysis
a) HCOOK →
∆
b) CHI3 + Ag →
Conc.H2 SO4
c) CH3 CH2 OH →
443 K
d) Be2 C + H2 O →
465. Wet ether is not used as a solvent in Wurtz reaction, because the water present in it
a) Hydrolyses 𝑅𝑋 to 𝑅OH b) Reduces 𝑅𝑋 to 𝑅H
c) Destroy the Na metal d) Reacts with 𝑅 − 𝑅
466. When excess of C6 H6 reacts with CH2 Cl2 in presence of anhydrous AlCl3 , the following compound is
obtained

a) b) c) d)

467. The product formed during the reaction,

0C
CH ≡ CH + NaOCl → is:
a) 1,2-dichloroethane b) 1,2-dichloroethanal c) 1,2-dichloroethene d) 1,2-dichloroethyne
468. Out of the following fractions of petroleum the one having the lowest boiling point is:
a) Kerosene b) Diesel oil c) Gasoline d) Heavy oil
469.

a) b) c) d)

470. Acetylene on reacting with hypochlorous acid gives:

 a) CH3 COCl b) ClCH2 CHO c) Cl2 CH. CHO d) ClCH2 COOH
471. The reduction of 4-octyne with H2 in the presence of Pd/CaCO3 quinoline gives
a) 𝑡𝑟𝑎𝑛𝑠-4-octene b) 𝑐𝑖𝑠-4-octene
c) A mixture of 𝑐𝑖𝑠-and 𝑡𝑟𝑎𝑛𝑠-4-octene d) A completely reduced product C8 H18
472.

a) Clemmensen reduction
b) Fisher-Spier reduction
c) Birch reduction
d) Arndt-Eistert reduction
473. Which one of the following compounds will react with methyl magnesium iodide?
a) CH3 CH2 CH2 CH2 CH3 b) CH3 CH = CH − CH = CH2
c) CH3 − C ≡ C − CH2 CH3 d) CH3 CH2 CH2 C ≡ CH
474. Degree of unsaturation in the following compound is

a) 1° b) 2° c) 3° d) 4°
475. Suitable reagents A and B for the following reactions are

a) Br, Br2 b) Br2 , NBS c) NBS, NBS d) NBS, Br2

476. During ozonolysis of CH2 = CH2 if reduction is carried out by LiAlH4 the products formed are:
a) HCHO b) HCOOH c) CH3 OH d) CH2 OHCH2 OH
477. Ethyl hydrogen sulphate is obtained by reaction of H2 SO4 on:
a) Ethylene b) Ethane c) Ethyl chloride d) Ethanal
478. When HCI gas is passed through propene in the presence of benzoyl peroxide, it gives:
a) 𝑛-propyl chloride b) 2-chloropropane c) Allyl chloride d) No reaction
479. Hydrocarbon which is liquid at room temperature is
a) Pentane b) Butane c) Propane d) Ethane
480. Which of the following reactions are not expected to give

In yields of more than 50%?

a) b)

d) None of the above

c)

481. Incorrect name of an alkyne is:

 a) Propyne b) But-2-yne c) Pent-3-yne d) But-1-yne
482. The alkyne which gives pyruvic acid (CH3 COCOOH) on oxidation with alk. KMnO4 is:
a) CH ≡ CH b) CH3 C ≡ CH c) CH3 C ≡ C— CH3 d) CH3 — CH2 — C ≡ CH
483. A hydrocarbon of formula C6 H10 absorbs only one molecule of H2 upon catalytic hydrogenation. Upon
ozonolysis the hydrocarbon yields,

The hydrocarbon is :
a) Cyclohexane b) Benzene c) Cyclohexene d) Cyclobutane
484. Alkyl halides react with dialkyl copper reagents to give
a) Alkenyl halides b) Alkanes
c) Alkyl copper halides d) Alkenes
485.

Thus, 𝐴 is
a) (CH3 )2 CHCH = CHCH = CH2 b) (CH3 )2 C = CH − CH = CH2
c) CH3 CH = CH − CH = CH − CH = CH2 d) none of the above
486. In the series,
NaNH2 CH3 I HgSo4
C2 H5 → 𝑋→ 𝑌→ 𝑍
H2 SO4 ,H2 O
The compound Z is
a) CH3 CH2 CH = CH2 b) CH3 COCH3 c) CH3 CHO d) CH3 CH2 CH2 CHO
487. Paraffin dissolves in:
a) Distilled water b) Benzene c) Methanol d) Salt water
488. Which cannot be prepared by Kolbe’s electrolytic reaction using single salt?
a) CH4 b) C2 H6 c) C4 H10 d) H2
489. Which will react withNaBH4 ?
a) Benzoic acid b) Benzamide c) Cyclohexanone d) Acetic acid
490. When methane is made to react with a halogen (𝑋2 ), halides are formed, the order of reactivity is:
a) F2 > 𝐶l2 > 𝐵r2 > I2 b) Cl2 > F2 > 𝐵r2 > I2 c) I2 > 𝐵r2 > 𝐶l2 > F2 d) Cl2 > F2 > I2 > 𝐵r2
491. Which of these does not follow 𝑎𝑛𝑡𝑖 −Markownikoff’s rule?
a) 2-butene b) 1-butene c) 2-pentene d) 2-hexene
492. Acetylene reacts with HCN in the presence of Ba(CN)2 to yield
a) 1,1-dicyanoethane b) 1,2-dicyanoethane c) Vinyl cyanide d) None of these
493. An alkyl bromide (X) reacts with Na to form 4, 5-diethyl octane. Compound (X) is:
a) CH3 (CH2 )3 Br
b) CH3 (CH2 )5 Br
c) CH3 (CH2 )3 CHBr. CH3
d) CH3 (CH2 )2 CHBrCH2 CH3
494. To avoid lead pollution, a new anti-knock compound is used. It is:

a)

b) Cyclopentadienyl manganese carbonyl

c) AK-33-X
d) All of the above
495. Identify B and D in the following sequence of reactions.
 a) Methanol and bromoethane b) Ethyl hydrogen sulphate and alcoholic KOH
c) Ethyl hydrogen sulphate and aqueous KOH d) Ethanol and alcoholic KOH
496. Angle strain in cyclopropane is
a) 24°44′ b) 9°44′ c) 44′ d) −5°16′
497. When propyne react with H2 O in presence of dil. H2 SO4 and HgSO4 product formed is
a) Acetone b) Acetaldehyde c) Acetic acid d) Ethyl alcohol
498. Which of the following compounds cannot be prepared singly by the Wurtz reaction?
a) C2 H6 b) (CH3 )2 CHCH3 c) CH3 CH2 CH2 CH3 d) All can be prepared
499. The olefin which on ozonolysis gives CH3 CH2 CHO and CH3 CHO is:
a) 1-butene b) 2-butene c) 1-pentene d) 2-pentene
500. Which statement is false?
a) Peroxide effect is applicable only for HBr and not for the other halogen halides
b) Meta directing groups are deactivating groups
c) Chlorination of methane follows an ionic mechanism
d) In benzene the C atoms are 𝑠𝑝 2 -hybridized
501. The presence of unsaturation (olefinic or acetylinic bond) in an organic compound can be tested with:
a) Schiff’s reagent b) Tollen’s reagent c) Fehling’s solution d) Baeyer’s reagent
502. An alkene on reductive ozonolysis gives 2-molecules of CH2 (CHO)2 . The alkene is
a) 2,4-hexadiene b) 1,3-cyclohexadiene
c) 1,4-cyclohexadiene d) 1-methyl-1, 3-cyclopentadiene
503. A mixture of ethyl iodide and 𝑛-propyl iodide is subjected to Wurtz reaction. The hydrocarbon that will not
be formed is:
a) 𝑛-butane b) 𝑛-propane c) 𝑛-pentane d) 𝑛-hexane
504. Which of the following reacts with benzene in presence of anhydrous aluminium chloride and
forms acetophenone?
a) CH3 Cl b) CH3 COOH c) CH3 CHO d) CH3 COCl
505. Oxidation of 1-butene with hot KMnO4 solution produces
a) CH3 CH2 COOH + HCOOH b) CH3 CH2 COOH + CO2
c) CH3 COOH + CO2 d) (CH3 )2 C = O + CO2
506. Action of Br2 on cyclopentene gives:
a) 1,2-dibromo cyclopentane
b) Cyclopentyl bromide
c) Cyclopentyl dibromide
d) No reaction
507. Which of the following species is aromatic?

a) b) c) d)

508. Propene, CH3 — CH = CH2 can be converted into 1-propanol by oxidation. Which set of reagents among the
following is ideal to effect the conversion?
 a) Alkaline KMnO4 b) B2 H6 and alk. H2 O2 c) O3 /zinc dust d) OsO4 /CHCl3
509. Compound which gives acetone on ozonolysis
a) CH3 − CH = CH − CH3 b) (CH3 )2 C = C(CH3 )2
c) C6 H5 CH = CH2 d) CH3 CH = CH2
510. Toluene, when treated with Br2 /Fe, gives p-bromotoluene as the major product because the – CH3 group
a) Is 𝑚𝑒𝑡𝑎 directing b) deactivates the ring
c) activates the ring by hyperconjugation d) None of the above
511. Alkynes occur in nature in the:
a) Free state b) Partially free state c) Not in the free state d) None of the above
512. Which of the following will have least hindered rotation about carbon-carbon bond?
a) Ethane b) Ethylene c) Acetylene d) Hexachloroethane
513. Identify Z in the series,
HBr aq.KOH NaCO3
CH2 = CH2 → 𝑋→ 𝑌→ 𝑍
I2 excess
a) C2 H5 I b) C2 H5 OH c) CHI3 d) CH3 CHO
514. Action of NH3 over C2 H2 at high temperature gives:
a) Amine b) Furan c) Thiophene d) Pyrrole
515. Wurtz reaction converts alkyl halide into alkane when it is made to react with
a) Na in alcohol b) Na in dry ether c) Zn in alcohol d) Zn in dry ether
516. Polyethylene is a resin obtained by polymerization of:
a) Butadiene b) Ethylene c) Isoprene d) Styrene
517. Cyclohexane (C6 H12 ) a hydrocarbon, floats on water because:
a) It is immiscible with water
b) Its density is less than that of water
c) It is a non-polar substance
d) It is immiscible and lighter than water
518. Which of the following are produced from coaltar?
a) Synthetic dyes b) Drugs c) Perfumes d) All of these
519. The reduction of an alkyne to alkene using lithium metal in liquid ammonia as solvent results into
a) 𝑐𝑖𝑠 addition of hydrogen atoms
b) 𝑡𝑟𝑎𝑛𝑠 addition of hydrogen atoms
Both 𝑐𝑖𝑠 and 𝑡𝑟𝑎𝑛𝑠 additions of hydrogen atoms. The relative amounts of the two depends on
c)
temperature
d) Both 𝑐𝑖𝑠 and 𝑡𝑟𝑎𝑛𝑠 additions of hydrogen atoms. The relative amounts depend on the nature of alkyne
520. Propene on reaction with hypochlorous acid to give

a) b)

c) d)

521. A mixture of nitrogen and acetylene, on passing electric spark through it gives:
a) Hydrogen and carbon b) Hydrogen cyanide c) Nitromethane d) Nitroethane
522. In the sequence of reactions,
HBr AgCN ( H)
C2 H4 → 𝑋→ 𝑌 → 𝑍,
H2 /Ni
Compound Z is
a) N-methyl ethanamine b) N-propylamine
 c) N, N-dimethylamine d) Ethyl cyanide
523. Which one of these is not true for benzene?
a) It forms only one type of monosubstituted product.
b) There are three carbon-carbon single bonds and three carbon-carbon double bonds
c) The heat of hydrogenation of benzene is less than the theoretical value.
d) The bond angle between the carbon-carbon bonds is 120°.
524. Presence of a nitro group in a benzene ring
a) Activates the ring towards electrophilic substitution
b) Renders the ring basic
c) Deactivates the ring towards nucleophilic substitution
d) Deactivates the ring towards electrophilic substitution
525. The major product in the reaction of 2-butyne with Li/liq. NH3 is

a) b)

c) CH3 CH2 CH2 CH3 d) H2 C = CH − CH2 − CH3

526. Hydrocarbon liquid at STP is:
a) Ethane b) Propane c) Butane d) Pentane
527. Chlorination of benzene is not possible in the following reaction
FeCl3 H+ ZnCl2 AlCl3
a) C6 H6 + Cl2 → b) C H + HOCl → c) C6 H6 + I − Cl → d) C6 H6 + Cl2 →
6 6
528. In the series, ethane, ethene and ethyne, the C-H bond energy is
a) Same in all the three compounds b) Greatest in ethane
c) Greatest in ethene d) Greatest in ethyne
529. The shape of 2-butene is:
a) Linear b) Planar c) Tetrahedral d) Pyramidal
530. The substance used as an anti-knock compound is:
a) Tetraethyl lead b) Lead tetrachloride c) Lead acetate d) Ethyl acetate
531. Petroleum refining is:
a) Obtaining aromatic b) Cracking of petroleum c) Purification of d) Distillation of
compounds from to get gaseous petroleum petroleum to get
aliphatic compounds in hydrocarbons different fractions
petroleum
532. Zinc-copper couple that can be used as a reducing agent is obtained by:
a) Mixing zinc dust and copper gauze
b) Zinc coated with copper
c) Copper coated with zinc
d) Zinc and copper wires welded together
533. Which of the following hydrocarbons has the lowest dipole moment?

a) b) CH3 C ≡ CCH3 c) CH3 CH2 C ≡ CH d) CH2 = CH— C ≡ CH

534.
Alkene

a) b) c) d)
535. A solution of sodium salt of fatty acid was electrolysed during Kolbe’s reaction. The solution left after
electrolysis is:
a) Richer in NaOH b) Richer in H2 SO4 c) Richer in sodium salt d) All of these
536. Sample of 2,3-dibromo-3-methylpentane is heated with zinc dust. The resulting product is isolated and
heated with HI in the presence of phosphorus. Indicate which is the structure that represents the final
organic product in the reaction?

a)

b)

c)

d)

537. Which compound does not give precipitate with ammoniacal silver nitrate solution?
a) C2 H5 − C ≡ CH b) CH3 − C ≡ C − CH3
CH3
c) | d) Ph − CH2 − C ≡ CH
CH3 − CH − C ≡ CH
538. Hydroxylation of propyne in the presence of HgSO4 /H2 SO4 is initiated by the attack of:
a) Carbene b) Free radical c) Electrophile d) Nucleophile
539. Benzene vapour mixed with air when passed over V2 O5 catalyst at 775 K gives
a) Glyoxal b) Oxalic acid c) Maleic anhydride d) Fumaric acid
540. Kolbe’s synthesis on electrolysis of sodium salt of butanoic acid gives:
a) 𝑛-hexane b) Isobutene c) Butane d) Ethene
541. Which among the following is aromatic?

a) b) c) d)

542. The neutral wax called Ozokerite found near petroleum well is a mixture of:
a) Solid halides b) Solid hydrocarbons c) Solid alcohols d) None of these
543.

Identify A:

d) None of these
a) b) c)

544. Which among the following are used as catalyst in cracking?

a) Oxides of Al b) Oxides of Cr, Mo c) Oxides of V d) All of these
545. The general formula of a cycloalkane is
a) C𝑛 H𝑛 b) C𝑛 H2𝑛 c) C𝑛 H2𝑛−2 d) C𝑛 H2𝑛+2
546. Toluene reacts, with excess of Cl2 in presence of sunlight to give a product, which on hydrolysis
followed by reaction with NaOH gives
 d) None of these
a) b) c)

547. Which of the following alkanes can be easily sulphonated?

a) 𝑛-butane b) Isobutene c) 𝑛-pentane d) 𝑛-hexane
548. When propionic acid is treated with aqueous sodium bicarbonate, CO2 is liberated. The ‘C’ of CO2 comes
from:
a) Methyl group b) Carboxylic group c) Methylene group d) Bicarbonate
549. 10mL of a certain hydrocarbon require 25mL of oxygen for complete combustion and the volume of CO2
produced is 20mL. what is the formula of hydrocarbon?
a) C2 H2 b) C2 H4 c) CH4 d) C2 H6
550. Which of the following compounds is the most stable?

a) b) c) d)

551. The octane number of any fuel increases with:

a) Increase in 𝑛-heptane
b) Decrease in 2,2,4-trimethylpentane
c) Increase in 2,2,4-trimethylpentane
d) None of the above
552. 3-methyl-2-pentene on reaction with HOCl gives:

a)

b)

c)

d)

553. The reaction of propene with HOClproceeds 𝑣𝑖𝑎 the addition of

a) Cl+ and OH − in a single step b) Cl+ in the first step
c) H + in the first step d) OH − in the first step
554. Select the reagent for the following reaction,

a) SeO2 b) O3 , Zn⁄H2 O
c) O3 , H2 O2 − CH3 COOH d) PCC
555. The chemical reactivity of ethylene is due to:
 a) Short carbon to carbon bond distance
b) High double bond energy
c) Trigonal planar structure
d) Presence of 𝜋-electrons
556. Which of the following species could be expected to exhibit aromatic character?

Select the correct answer from the following

a) I and IV b) II and IV c) I and III d) II and III
557. Product formedwhen 1-butene is subjected to HBr in the presence of peroxide:
a) 1-bromobutane b) 2-bromobutane c) 1,1-dibromobutane d) 1,2-dibromobutane
558. Nitrobenzene can be prepared from benzene by using a mixture of concentrated HNO3 and
concentratedH2 SO4 . In the nitrating mixture, HNO3 acts as
a) Base b) Acid c) Reducing agent d) Catalyst
559. In the reaction sequence,
(i)O3
CH3 CH = CH2 → Products Products will be
(ii)H2O/Zn
a) CH3 COCH3 b) CH3 COCH2 OH
c) CH3 COOH + HCOOH d) CH3 CHO + HCHO
560. Petrol or gasoline used as an automobile fuel is a mixture of:
a) Hydrocarbons
b) Alcohols
c) Carbohydrates
d) Hydrocarbons and alcohols
561. In which of the following electron delocalisation is possible?
a) CH2 = CH − CH2 − O−

b)

c) CH2 = CH − CH2 − CH = CH2

d) None of the above
562. The major component of L.P.G. is:
a) Methane b) Ethane c) Propane d) Iso-butane
563. Which of the following alkenes will yield 2-butanone on ozonolysis followed by the reaction
withZn⁄H2 O?
a) 2-methyl-2-hexene b) 2-methyl-1-hexene
c) 3,4-dimethyl-3-hexene d) 2,3-dimethyl-3-hexene
564. Acetylene and ethylene reacts with alk. KMnO4 to give:
a) Oxalic acid and formic acid
b) Acetic acid and ethylene glycol
c) Ethyl alcohol and ethylene glycol
d) None of the above
565. According to Markownikoff’s rule, what will be the major product of reaction
HBr
CH2 = CH − CH3 → ?
Br
a) b) Br − CH2 − CH2 − CH3
|
 CH3 − CH − CH3
c) CH2 = CH − CH2 Br d) CH2 = C = CH2
566. Carbon black, used in making printing ink is obtained by the oxidation of:
a) Acetylene b) Benzene c) Methane d) CCl4
567. Ethylbenzene with bromine in presence of FeBr3 , predominantly gives

a) b)

c) d)

568. Which reaction produces acrylonitrile (CH2 = CHCN)?

KCN
c) Ethyne →
KCN HOCI
a) b) Acrylic acid → d) Ethyne →

569. Gasoline is:

a) C3 H8 to C6 H14 b) C7 H16 to C10 H22 c) C7 H24 to C14 H34 d) C17 H36 to C21 H50
570. Which of the following gives methane [CH4 ] on hydrolysis?
a) Fe3 O4 b) Al2 O3 c) CaC2 d) Al4 C3
571. The compound (CH3 )2 CH— CHCl— CH3 reacts with alcoholic KOH to give the following alkene:
a) (CH3 )2 CH— CH = CH2
b) CH3 — CH = C = CH2
c) CH3 — CH2 — CH = CHCH3
d) (CH3 )2 C = CH— CH3
572. A hydrocarbon reacts with HI to give (X) which on reacting with aqueous KOH forms (Y). Oxidation of (Y)
gives 3-methyl-2-butanone. The hydrocarbon is:

a) b) c) d)

573. Pure acetylene has sweet ethereal smell while impure smells like garlic due to presence of:
a) NH3 b) PH3 c) AsH3 d) H2 S
574. An alkyl halide by formation of its Grignard reagent and heating with water yields propane. What
is the original alkyl halide?
a) Methyl iodide b) Ethyl iodide c) Ethyl bromide d) Propyl bromide
575. 1-propyne on treatment with dilute H2 SO4 in presence of HgSO4 gives acetone. The change is due to:
a) Hyperconjugation b) Resonance c) Tautomerism d) None of these
576. O2 required for complete oxidation of 1 litre of ethane at NTP is:
a) 3.5 litre b) 0.156 mole c) 5.00 g d) All of these
577. In the following sequence the product 𝐷 is,
HBr HBr KOH ale. NaNH2
CH ≡ CH → 𝐴 → 𝐵 → 𝐶→ 𝐷:
a) Ethanol b) Ethane c) Ethyne d) Ethanal
578. Which of the following compounds react with HBr obeying Markownikoff’s rule?

a) CH2 = CH2 b)
 c) d)

579. Liquid hydrocarbon can be converted to a mixture of gaseous hydrocarbon by:

a) Oxidation
b) Cracking
c) Hydrolysis
d) Distillation under reduced pressure
580. Two jars 𝐴 and 𝐵 are filled with hydrocarbons. Br2 inCCl4 is added to these jars. 𝐴does not decolourise the
Br2 solution but 𝐵 decolourises. What are 𝐴and 𝐵?
a) Alkane and alkene b) Alkene and alkane c) Alkene and alkyne d) None of these
581. In the following structures which two forms are staggered conformation of ethane?

1. 2.

3. 4.
a) 1 and 4 b) 2 and 3 c) 1 and 2 d) 1 and 3
582. A mixture of ethane, ethene and ethyne is passed through ammoniacalAgNO3 solution. The gases which
remain unreacted are:
a) Ethane and ethene b) Ethane and ethyne c) Ethene and ethyne d) Ethane only
583. In the reaction,
Oxidation NaOH Soda lime
C6 H5 CH3 → 𝐴→ 𝐵→ 𝐶
The product 𝐶 is
a) C6 H5 OH b) C6 H6 c) C6 H5 COONa d) C6 H5 ONa
584. (I) BH3 .THF HgSO4
𝐴← CH3 C ≡ CH → 𝐵
(II)H2 O2 ,OH− H2 SO4

Identify 𝐴 and 𝐵
a) CH3 CHO, CH3 COCH3 b) CH3 CH2 CHO, CH3 COCH3
c) CH3 CH2 CHO, CH3 COCH2 CH3 d) HCHO, CH3 COCH3
585. Cyclobutadiene is said to be
a) aromatic b) aliphatic c) non-aromatic d) None of these
586. Acetylene reacts with hypochlorous acid to form
a) Cl2 CHCHO b) ClCH2 COOH c) Cl3 COCl d) ClCH2 CHO
587. To enable easy detection of gas leakage from cylinders, the substance added to L.P.G. is:
a) Glycols b) Phenols c) Thioalcohols d) Glycerols
588. Octane no. of 2,3,3-trimethylbutane has been assumed to be:
a) 100 b) −45 c) 124 d) Zero
589. 𝐶4 𝐻6 may contain
a) One double bond b) Two double bond c) One triple bond d) Both (b) and (c)
590. Which of the following compounds can form metallic derivatives?
a) Ethane b) Propyne c) 2-butyne d) 2-butene
591. Increasing order of volatility of C2 H6 , C2 H4 , C2 H2 and C6 H6 is:
a) C6 H6 , C2 H6 , C2 H4 , C2 H2 b) C2 H2 , C2 H4 , C2 H6 , C6 H6 c) C6 H6 , C2 H2 , C2 H4 , C2 H6 d) C2 H2 , C2 H6 , C2 H4 , C6 H6
592. Octane no. of a fuel can be increased by:
a) Isomerism b) Alkylation c) Reforming d) All of these
593. 1-propanol on dehydration with H2 SO4 produces:
a) CH3 − CH = CH2
b) CH3 − CH = CH − CH3
c) CH3 CH2 CH2 OCH2 CH2 CH3
d) CH3 CH2 CH2 CH2 CH = CH2
594. Propadiene, C3 H4 molecule contains:
a) Two 𝑠𝑝2 and one 𝑠𝑝-hybrid carbon
b) One 𝑠𝑝2 and two 𝑠𝑝-hybrid carbons
c) One 𝑠𝑝2 and three 𝑠𝑝-hybrid carbons
d) None of the above
595. Catalyst used in dimerization of acetylene to prepare chloroprene is:
a) HgSO4 + H2 SO4 b) Cu2 Cl2 c) Cu2 Cl2 + NH4 Cl d) Cu2 Cl2 + NH4 OH
596. Cyclopentene on treatment with alkaline KMnO4 gives:
a) Cyclopentanol
b) 𝑡𝑟𝑎𝑛𝑠-1,2-cyclopentanediol
c) 𝑐𝑖𝑠-1,2-cyclopentanediol
d) 1 : 1 mixture of 𝑐𝑖𝑠-and 𝑡𝑟𝑎𝑛𝑠-1,2-cyclopentanediol
597. 3Cl2 ,Heat Fe⁄Br2 Zn⁄HCl
C7 H8 → 𝐴→ 𝐵→ 𝐶
Here, the compound 𝐶 is
a) 3-bromo 2,4,5,6-trichlorotoluene b) 𝑜-bromo toluene
c) 𝑝-bromo toluene d) 𝑚-bromo toluene
598. Naphalene is an example of
a) Polynuclear hydrocarbon b) alicyclic compound
c) heterocyclic compound d) aliphatic compound
599. Which of the following will give 𝑡𝑟𝑎𝑛𝑠-diols?

a) b)

c) d)

600. Benzene can react with

a) Bromine water b) HNO3 c) H2 O d) CH3 OH
601. A mixture of methane and steam when passes over nickel supported on alumina catalyst at 725C gives:
a) CH3 OH b) CO2 and H2 c) CO and H2 d) None of these
602. In which reaction addition takes place according to Markownikoff’s rule?
a) CH3 CH = CH2 + Br2 ⟶
b) CH3 CH = CH2 + HBr ⟶
c) CH2 = CH2 + HBr ⟶
d) CH3 CH = CHCH3 + Br2 ⟶
603. Paraffin wax is:
a) Ester b) Alcohol c) Unsaturated d) Saturated hydrocarbon
hydrocarbon
604. Propyne when passed through a hot iron tube at 400℃ produces
a) Benzene b) Methyl benzene
c) Dimethyl benzene d) Trimethyl benzene
605. Which of the following is called Marsh gas?
 a) C2 H4 b) C2 H6 c) C2 H2 d) CH4
606. Which can be easily oxidized?
a) Alkene b) 1-alkyne c) Alkane d) Benzene
607. 𝑛-butane and isobutene, which have same number of hydrogen and carbon atoms in their molecules, boil
at different temperatures because:
a) 𝑛-butane is much hotter
b) Their volumes are different
c) Isobutene is an alkene
d) Their atoms are not having the same carbon chain
608. Common oxidizing agents used in organic chemistry are:
a) Fenton’s reagent b) Osmium tetraoxide c) Acidified KMnO4 d) Alkaline KMnO4
609. Acetylenic hydrocarbons are acidic because:
a) Sigma electron density of C—H bond in acetylene is nearer a carbon which has 50% 𝑠-character
b) Acetylene has only one hydrogen atom at each carbon atom
c) Acetylene contains least number of hydrogen atoms among the possible
d) Acetylene belongs to the class of alkynes with formula C𝑛 H2𝑛−2
610. Butene -1 may be converted to butane by the reaction with:
a) Zn Hg b) Pd H2 c) Zn HCI d) Sn HCI
611. Number of acidic hydrogen atom in butyne-1 is:
a) 2 b) 3 c) 1 d) 4
612. Propene on reaction with methylene iodide in presence of Zn-Cu couple gives:
a) Cyclopropane b) Cyclopropene c) Methyl cyclopropane d) Cyclobutene
613. Addition of O2 on ethylene in presence of Ag at 200C forms:
a) Epoxy ethane b) Oxiranes c) Cyclic ethers d) All of these
614. The carbon-carbon bond distance in benzene is
a) Longer than a C − C single bond b) Longer than a C = C double bond
c) Shorter than a C = C double bond d) Shorter than a C ≡ C triple bond
615. Method of converting high boiling hydrocarbons into low boiling hydrocarbons is called:
a) Polymerisation b) Isomerisation c) Cracking d) Condensation
616. The mechanism of Wurtz reaction involves:
a) Free radical b) Carbocation c) Carbanion d) None of these
617. The most important energy yielding constituent in biogas is:
a) C2 H4 b) C2 H2 c) CH4 d) H2 S
618. PVC is a polymer of:
a) CH2 = CH2 b) ClCH2 — CH2 Cl c) CH2 — CHCl d) Cl— C = C— Cl
619. Cyclohexene on ozonolysis followed by reaction with zinc dust and water gives compound E.
Compound E on further treatment with aqueous KOH yields compound F. Compound F is

a) b) c) d)

620. The flash point in India is fixed at:

a) 44C b) 35C c) 22.8C d) 30C
621. Lindlar’s catalyst is:
a) Pd-CaCO3 deactivated by lead acetate
b) Pd − BaSO4
c) Pd
d) None of the above
622. The energy of π-bond in kcal is about :
a) 36 b) 50 c) 74 d) 140
623. Ozonolysis(O3 , H2 O) of,
 a)

b)

c)

d) None of the above

624. What is the end product of the following sequences of operations?

a) Methyl alcohol b) Acetaldehyde c) C2 H5 OH d) C2 H4

625. The order of relative acidic strengths of water, ethyne and propyne is:
a) Water>propyne>ethyne
b) Propyne>ethyne>water
c) Water>ethyne>propyne
d) Ethyne>water>propyne
626. Reaction of 𝑡𝑟𝑎𝑛𝑠-2-phenyl-1-bromocyclopentane on reaction with alcoholic KOH produces:
a) 4-phenylcyclopentene
b) 2-phenylcyclopentene
c) 1-phenylcyclopentene
d) 3-phenylcyclopentene
627. Ethylene reacts with slphurmonochloride to give:
a) Phosgene b) Mustard gas c) Ethylene chloride d) None of these
628. The dihalogen derivative ‘X’ of a hydrocarbon with three carbon atoms reacts with alcoholic KOH
and produces another hydrocarbon which forms a red precipitate with ammoniacal Cu2 Cl2 . ‘X’
gives an aldehyde on reaction with aqueous KOH. The compound
‘X’ is
a) 1,3-dichloropropane b) 1,2-dichloropropane
c) 2,2-dichloropropane d) 1,1-dichloropropane
629. Ethylene may be prepared by the dehydration of:
a) Ethyl alcohol b) Methyl alcohol c) Acetic acid d) Oxalic acid
630. Petroleum is formed by the chemical changes in:
a) Inorganic matter b) Vegetable matter c) Animal matter d) Both (b) and (c)
631. Common dehydrating agents for alkanes are:
a) H2 SO4 b) Al2 O3 c) ZnCl2 d) All of the above
632. The most stable conformation of butane is:
a) Skew b) Staggered c) Gauche d) Eclipsed
633. A cyclic hydrocarbon molecule has all the carbon and hydrogen in a single plane. All the carbon-
carbon bonds are of same length, less than 1.54Å, but more than 1.34Å. The C-c bond angle will be
a) 109°28′ b) 100° c) 180° d) 120°
634. The product of acid catalysed hydration of 2-phenyl propene is:
a) 3-phenyl-2-propanol b) 1-phenyl-2-propanol c) 2-phenyl-2-propanol d) 2-phenyl-1-propanol
635. When C2 H5 , CH4 and C2 H4 passes through a test tube which have ammoniacalCu2 Cl2 , find out
which gas comes out unaffected from test tube?
 a) C2 H2 and CH4 b) C2 H2 and C2 H4 c) C2 H4 and CH4 d) C2 H2
636. Benzene reacts with chlorine in sunlight to give a final product
a) CCl4 b) C6 H6 Cl6 c) C6 Cl6 d) C6 H5 Cl
637. When 2-butyne is treated with Pd − BaSO4 ; the product formed will be
a) 𝑐𝑖𝑠-2-butene b) 𝑡𝑟𝑎𝑛𝑠-2-butene c) 1-butene d) 2-hydroxy butane
638. The overlapping of orbitals in benzene is of the type
a) 𝑠𝑝 − 𝑠𝑝 b) 𝑝 − 𝑝 c) 𝑠𝑝2 − 𝑠𝑝2 d) 𝑠𝑝3 𝑠𝑝3
639. The product obtained when methyl magnesium bromide reacts with methyl alcohol is:
a) Acetone b) Alcohol c) Methane d) Ethane
640. The treatment of benzene with benzoyl chloride in the presence of AlCl3 gives
a) Benzaldehyde b) Benzophenone c) Diphenyl d) Cyclohexane
641. Which of the following have delocalised electron?
a) Benzene b) Cyclohexane c) CH4 d) C2 H6
642. The IUPAC name of CH2 = CH— CH2 —group is:
a) Allyl b) Propyl c) Prop-2-enyl d) Prop-1-enyl
643. Which statement is correct?
a) Low chemical reactivity of alkanes is due to strong C—C and C—H bonds
b) Alkanes show characteristic substitution reactions because they are saturated
c) Reaction of alkanes with fluorine is explosive even in dark
d) All of the above
644. Ease of sulphonation of alkanes is:
a) 3>2>1 b) 1>2>3 c) 2>3>1 d) 3>1>2
645. Arrange the following in order of decreasing boiling point

a) I > 𝐼𝐼 > 𝐼𝐼𝐼 > 𝐼𝑉 b) IV > 𝐼𝐼𝐼 > 𝐼𝐼 > 𝐼 c) I > 𝐼𝐼𝐼 > 𝐼𝑉 > 𝐼𝐼 d) II > 𝐼𝐼𝐼 > 𝐼 > 𝐼𝑉
646. The product B is:
HI
CH3 . CH2 . C = CH + HCI ⟶ B → C

a) b) c) d)

647. 𝑛-propyl bromide on treating with alcoholic KOH produces

a) Propane b) Propene c) Propyne d) Propanol
648. An unsaturated hydrocarbon upon ozonolysis gives one mole each of formaldehyde, acetaldehyde and
methylglyoxal(CH3 COCHO). The structure of the hydrocarbon is
a) CH2 = CH − CH2 − CH = CH2 b) CH2 = CH − C(CH3 ) = CH − CH3
c) (CH3 )2 C = CH − CH3 d) CH3 − CH = C(CH3 ) − CH3
649. Fischer-Tropsch process is used in the manufacture of:
a) Synthetic petrol b) Ethanol c) Benzene d) Ethanoic acid
650. 2-methylpropene is isomeric with butane-1. They can be distinguished by:
a) Baeyer’s reagent b) AmmoniacalAgNO3 c) Br2 solution d) O3 , Zn/H2 O
651. Acetylene reacts with 42% H2 SO4 containing 1% HgSO4 to give:
 a) C2 H5 HSO4 b) CH3 CHO c) HCHO d) CH2 = CH2
652. The simplest alkyne is:
a) CH b) CH2 c) C2 H2 d) C2 H4
653. A Friedel-Crafts reaction of benzene with chloroform produces
d) All of these

a) C6 H5 CHCl2 b) c)

654. An alkene, obtained by the dehydration of an alcohol (A), on ozonolysis gives two molecules of
acetaldehyde for every molecule of alkene. The alcohol (A) is:

a) CH3 CH2 CH2 OH b) CH3 CH2 OH c) CH3 CH = CHCH2 OH d)

655. Which of the following annulenes is 𝑎𝑛𝑡𝑖-aromatic?

a) Benzene b) Cyclobutadiene c) Cyclodecapentene d) Cyclooctatetraene
656. The number of possible isomers of alkane with formula C6 H14 is:
a) 2 b) 3 c) 4 d) 5
657. Which statement is correct?
a) Alkanes from CH4 to C4 H10 are colourless odourless gases
b) Alkanes from C5 H12 to C17 H36are colourless liquids
c) All alkanes are lighter than water
d) Melting point of alkanes increases with increase in the number of carbon atoms
658. Which compound does not decolourize bromine dissolved in carbon tetrachloride?
a) C2 H2 b) C3 H6 c) C6 H6 d) C2 H4
659. The principal organic product formed in the reaction,
Peroxide
CH2 = CH(CH2 )8 COOH + HBr → …..is:
a) CH3 — CHBr(CH2 )8 COOH
b) CH2 = CH(CH2 )8 COBr
c) CH2 BrCH2 (CH2 )8 COOH
d) CH2 = CH(CH2 )7 CHBrCOOH
660. What would be the product formed when 1-bromo-3-chlorocyclobutane reacts with two
equivalents of metallic sodium in ether?

a) b) c) d)

661. Lindlar′ s Na in
[ 𝐴] ← CH3 − C ≡ C − CH3 → [𝐵]
catalyst liq.NH3
[A] and [B] are respectively
a) 𝑐𝑖𝑠, 𝑡𝑟𝑎𝑛𝑠-2-butene b) Both 𝑡𝑟𝑎𝑛𝑠-2-butene
c) 𝑡𝑟𝑎𝑛𝑠, 𝑐𝑖𝑠-2-butene d) Both 𝑐𝑖𝑠-2-butene
662. Which of the following reacts with KMnO4 but does not react withAgNO3 ?
a) C2 H6 b) CH4 c) C2 H4 d) C2 H2
663. Octane number 116 is given for:
a) 2,2,2-trimethyl pentane
b) 2,3,4-trimethyl pentane
c) 2,2,3-trimethyl butane
d) 2,2,4-trimethyl butane
664. Which of the following statements is incorrect?
a) Acetylene is explosive above 2 atm
 b) It is transported by dissolving in acetone
c) It has unpleasant garlic odour
d) It is used in the manufacture of Lewisite
665. Formation of ethylene from ethyl bromide is a case of:
a) Addition reaction
b) Substitution reaction
c) Elimination reaction
d) Rearrangement reaction
666. The most stable alkene is,
a) 𝑅2 𝐶 = 𝐶𝑅2 b) 𝑅CH = CH𝑅 c) CH2 = CH2 d) 𝑅CH = C𝑅2
667. Ethylene can be prepared by electrolysis of an aqueous solution of:
a) Sodium acetate b) Sodium succinate c) Sodium fumarate d) Sodium propionate
668. HBr reacts with CH2 = CH − OCH3 under anhydrous conditions at room temperature to give
a) CH3 CHO and CH3 Br b) BrCH2 CHO and CH3 OH
c) BrCH2 − CH2 − OCH3 d) H3 C − CHBr − OCH3
669. Identify 𝑍 in the following series?
HBr Hydrolysis Na2 CO3
CH2 = CH2 → 𝑋→ 𝑌→ 𝑍
I2 excess
a) C2 H5 I b) CHI3 c) CH3 CHO d) C2 H5 OH
670. Reactive species in halogenation of benzene in cold and dark
a) Cl• b) Cl+ c) Cl− d) None of these
671. An organic alkadiene on reductive ozonolysis produces
(i)acetaldehyde
(ii)acetone
(iii)2-methylpropane-1, 3-dial
The formula of alkadiene will be
CH3 C = CHCHCH = CHCH3 CH3 CHCH = CCH = CHCH3
a) | | b) | |
CH3 CH3 CH3 CH3
CH3 C = CHCHC = CHCH3 CH3 CH2 CHCH = CHC = CH2
c) | | d) | |
CH3 CH3 CH3 CH3
672. Synthetic petrol and kerosene can be obtained by passing……under heat and pressure over coal.
a) O2 b) H2 c) N2 d) CO2
673. A hydrocarbon containing 2 carbon atoms give Sabatier and Senderen’s reaction but does not give
precipitate with ammoniacal silver nitrate solution. The hydrocarbon in question is:
a) Ethane b) Acetylene c) Ethylene d) None of these
674. Acetylene can be converted to higher alkyne using the following sequence of reactions:
a) Na, 𝑅𝑋 b) 𝑅Mg 𝑋, 𝑅 𝑋 c) Either of these two d) None of these
675. At low temperature, the slow addition of molecular bromine to H2 C = CH— CH2 — C ≡ CH gives:
a) CH2 = CH— CH2 — CBr = CHBr
b) BrCH2 — CHBr— CH2 — C ≡ CH
c) H2 C = CH— CH2 — CH2 — CBr3
d) CH3 — CBr2 — CH2 — C ≡ CH
676. Which of the following statement is correct?
a) Benzene has a tetrahedral geometry like an alkane
b) Benzene is aromatic while naphthalene is not
c) Benzene and Cyclohexane are both aromatic
d) Benzene behaves more like and alkane than an alkene
677. CaC + H O → 𝐴 H →
2 SO4 /HgSO4
𝐵
2 2
Identify 𝐴 and 𝐵 in the given reaction
a) C2 H2 and CH3 CHO b) CH4 and HCOOH
c) C2 H4 and CH3 COOH d) C2 H2 and CH3 COOH
678. The correct boiling point order for corresponding hydrocarbons is:
a) Alkyne>alkane>alkene
b) Alkane>alkene>alkyne
c) Alkyne>alkene>alkane
d) Alkene>alkyne>alkane
679.

Identify A and B

a) b)

c) d)

680. Electrolysis of cold concentrated aqueous solution of potassium methyl succinate yields:
a) Ethane b) Ethyne c) Propene d) Ethane-1,2-diol
681. An alkene gives two moles of HCHO, one mole of CO2 and one mole of CH3 COCHO on ozonolysis.
What is its structure?
CH3
a) CH2 = C = CH − CH2 − CH3 b) |
CH2 = CH − CH − CH = CH2
CH2 = C = C − CH3 CH3
c) | d) |
CH3 CH2 = C = C − CH = CH2
682. Alkyl halides get converted to alkenes through:
a) Electrophilic b) Nucleophilic addition c) Elimination reaction d) Hydrolysis
substitution
683. In the complete combustion of C𝑛 H2𝑛+2 , the number of oxygen moles required is:
𝑛 𝑛+1 3𝑛 + 1 𝑛+2
a) ( ) O2 b) ( ) O2 c) ( ) O2 d) ( ) O2
2 2 2 2
684. When CH3 CH2 CHCI2 is treated with NaNH2 the product formed is:

a) CH3 CH = CH2 b) CH3 — C ≡ CH c) d)

685. Cycloalkanes are isomeric with

a) Alkanes b) Alkenes c) Alkynes d) Arenes
686. Which gives only one monosubstitution product on chlorination?
a) 𝑛-pentane b) Neopentane c) Isopentane d) 𝑛-butane
687. The products obtained via oxymercuration(HgSO4 + H2 SO4 )of 1-butyne would be:
a) CH3 CH2 COCH3
b) CH3 CH2 CH2 CHO
c) CH3 CH2 CHO + HCHO
d) CH3 CH2 COOH + HCOOH
688.

a) Wolff-Kishner reaction b) Clemmensen reduction c) Red P+HI at 200C d) Wurtz reaction

689. The presence of the chlorine atom on benzene ring makes the second substituent enter at a
position
a) 𝑜𝑟𝑡ℎ𝑜 b) 𝑚𝑒𝑡𝑎 c) 𝑝𝑎𝑟𝑎 d) 𝑜𝑟𝑡ℎ𝑜⁄𝑝𝑎𝑟𝑎
690. Two organic compounds (A) and (B) both containing only carbon and hydrogen, on quantitative
analysis gave the same percentage composition by weight
12 1
C = ( ) × 100%, H = ( ) × 100%
12 13
Adecolourises bromine water but B does not. A and B respectively are
a) C2 H2 and C6 H6 b) C6 H6 and C2 H2 c) C2 H4 and C2 H6 d) C2 H2 and C2 H6
691. Which of the following compounds react with, an aqueous solution ofAg(NH2 )2 OH?
a) ethane b) Ethene c) 1-butyne d) 2-butyne
692. Aromatisation of 𝑛-heptane by passing over (Al2 O3 + Cr2 O3 ) catalyst at 773 K gives
a) Benzene b) Toluene c) Mixture of both d) Heptylene
693. In a mixture of 𝑛-hexadecane and 𝛼-methylnaphthalene the percentage of the latter is 10.The value of
cetane number is:
a) 110 b) 90 c) 10 d) Zero
694. Addition of bromine to 1,3-butadiene gives:
a) 1,2-addition product only
b) 1,4-addition product only
c) Both 1,2 and 1,4-addition products
d) No reaction
695. 𝑅— COOH ⟶ 𝑅CH2 OH. This mode of reduction can be effected only by:
a) NaBH4 b) Na + Alcohol c) LiAlH4 d) All of these
696. A Wittig reaction with an aldehyde gives
a) Ketone compound b) A long chain fatty acid
c) Olefin compound d) Epoxide
697. Ethylene di bromide on heating with metallic sodium in ether solution yields
a) Ethene b) Ethyene c) 2-butene d) 1-butene
698. When alcoholic solution of ethylene dibromide is heated with granulated zinc, the compound formed is:
a) Ethane b) Ethylene c) Butane d) Isobutene
699. Octane number is:
a) Number of carbon atoms in octane
b) Number of molecules of octane formed in cracking of 1.0g of gasoline
c) Number of hydrogen atoms in octane
d) Number for representing standard rating of fuel
700. When an aqueous solution containing sodium acetate and sodium propionate is electrolysed we get:
a) Ethane b) Propane c) Butane d) All of these
701. Which one of the following methods is neither meant for the synthesis nor for separation of
amines?
a) Curtius reaction b) Wurtz reaction c) Hofmann method d) Hinsberg method
702. 𝑉𝑖𝑐-dihalide on treatment with zinc dust gives:
a) Alkane b) Alkene c) Alkyne d) All of these
703. Identify the substitute group, that acts as 𝑜𝑟𝑡ℎ𝑜 − 𝑝𝑎𝑟𝑎 director, during electrophilic substitution
in aromatic compounds.
a) −NH2 b) −NO2 c) −SO3 H d) N2
704. Order of acidity of H2 O, NH3 and acetylene is:
a) NH3 > 𝐶𝐻 ≡ 𝐶𝐻 > H2 O
b) H2 O > 𝑁H3 > 𝐶𝐻 ≡ 𝐶𝐻
c) H2 O > 𝐶𝐻 ≡ 𝐶𝐻 > 𝑁H3
d) NH3 > H2 O > 𝐶𝐻 ≡ 𝐶𝐻
705. C H I + C H I + 2Na Ether
→ C H — C H + 2Nal
2 5 5 11 2 5 5 11
The above equation represents:
a) Hofmann’s reaction
b) Dow’s reaction
c) Wurtz synthesis
d) Reimer-Tiemann’s reaction
706. Identify Z in the sequence,
HBr/H2 O2 C2H5 O− −Na+
CH3 − CH2 − CH = CH2 → Y→ Z:

a)

b)

c) CH3 − (CH2 )3 − O − CH2 − CH3

d) CH3 − (CH2 )4 − O − CH3
707. Which will give cyclooctyne when treated with base?
a) 1,2-dibromocyclobutane
b) 1,1-dibromocyclobutane
c) 1,1-dibromocyclooctane
d) 1,2-dibromocyclopropane
708. The final product in following sequence of reaction is
NaNH2 CH3 Br
CH ≡ CH → 𝐴→ 𝐵
a) CH2 = CH − CH = CH2 b) HC ≡ C − CH3
c) CH2 = CH − CH3 d) CH3 − CH2 − CH3
709. What are the products obtained upon the ozonolysis of pent-2-ene?
a) CH3 CH2 CHO b) CH3 CHO c) CH3 COCH3 d) Both (a) and (b)
710. Addition of halogen acid occurs at slowest rate in:
a) CH2 = CHCl b) CH2 = CH2 c) CH3 — CH = CH2 d) (CH3 )2 C = CH2
711. Benzyl chloride (C6 H5 CH2 Cl) can be prepared from toluene by chlorination with
a) SO2 Cl2 b) SOCl2 c) Cl2 d) NaOCl
712. The Markownikoff’s rule is the best applicable to the reaction between
a) C2 H4 + HCl b) C3 H6 + Br2 c) C3 H6 + HBr d) C3 H8 + Cl2
713. Which of the following acid reacts to reverse the Markownioff’s rule?
a) HCl b) HBr c) HF d) HI
714. The addition of HOClon alkenes in presence of strong acids to form halohydrins proceeds via formation of:
a) Chloronium ion b) Carbocation c) Chloro carbocation d) None of these
715. On treatment with chlorine in presence of sunlight, toluene gives the product
a) 𝑜-chloro toluene b) 2,5-dichloro toluene
c) 𝑝-chloro toluene d) Benzyl chloride
716. The most oxidized form of hydrocarbon 𝑅CH3 is:
a) CO2 b) 𝑅CHO c) RCOOH d) RCOCOOH
717. Ethylene is used for:
a) Ripening of food
b) Preparing ethylene oxide
c) For preparing ethylene chloride
d) All are correct
 HYDROCARBONS
1 (a)
The formation of the alkene in an elimination
reaction is called Hofmann elimination
(Thermal decomposition). Elimination of
hydrogen occurs from the β-carbon. So,

10 (c)
C3 H8 + 5O2 → 3CO2 + 4H2 O
11 (a)
2 (c) Follow cleavage of two bonds at multiple bonding
Bees wax is myricyl palmitate, 𝑖. 𝑒., position during ozonolysis.
C15 H31 COOC30 H61 . 12 (a)
3 (a) AlCl
CH2 = CH2 + CH3 COCl → CH3 COCH2 CH2 Cl.
The knocking order is:
13 (b)
Straight > branched >olefins>arenes.
chain alkane chain alkane It is a Corey House synthesis of alkanes.
4 (d) 14 (b)
Follow peroxide effect. C2 H2 is used for artificial ripening of fruits.
5 (b) C2 H4 for natural ripening.
Successive homologous differ by —CH2gp. 15 (a)
6 (c) Follow Markownikoff’s rule for addition.
1, 2-dihalogen (𝑣𝑖𝑐𝑖𝑛𝑎𝑙) derivatives of the 16 (b)
alkanes on reaction with zinc dust and Ethane gives a mixture of nitroethane and
methanol produces alkenes by loss of two nitromethane.
halogen atoms (dehalogenation). CH3 − CH3 + HNO3
Alcohol⁄∆ Ethane
CH3 − CH − CH2 + Zn → CH3 CH = CH2 673 K
→ CH3 − CH2 − NO2 + CH3 NO2
| | propylene −H2 O

Br Br nitro ethane (minor)

1,2-dibromopropane (major)
7 (d) During nitration chain fission of alkanes also
Ethylene is formed by dehydrohalogenation takes place, so CH3 NO2 is also obtained along
of alkyl halide in presence of alcoholic KOH. with CH3 CH2 NO2 .
Ethylene decolourise alkaline KMnO4 due to 17 (d)
get oxidized by it. Coal gives coal gas.
Alc.KOH 19 (b)
CH3 − CH2 I → CH2 = CH2 Zn
ethylene Frankland reaction: 2CH3 Br → C2 H6 .
8 (c) 20 (d)
[O] CHCOOKCH
(CH3 )2 CH − C ≡ C − CH2 CH3 → (CH3 )2 CH2 COOH Electrolysis
+ CH3 CH2 COOH || → ||| + 2CO2 + 2KOH + H2
9 (d) CHCOOKCH cathode
Benzene is obtained by the polymerisation of Potassium maleate acetylene anode
acetylene,. Similarly, mesitylene is obtained 21 (a)
by the polymerisation of propyne. F2 reacts violently even in dark.
22 (d)
𝑒. g.,CH3 CH2 CH = CH2 is unsymmetrical.
CH3 CH = CHCH3is symmetrical. Note the
positions of carbon atoms on two sides of double
 bond. Al4 C3 + 12H2 O → 4Al(OH)3 + 3CH4
23 (a) 29 (c)
Due to non-polar nature, alkanes are Vegetable oils are esters of glycerol or glycerides.
insoluble in water because water is a polar 31 (c)
solvent. As the conjugation increases, heat of
24 (a) hydrogenation decreases. Thus, alkene (c)
B2 H 6 with two isolated double bonds has the
(a)CH3 − CH = CH2 →
highest heat of hydrogenation.
OH− 32 (c)
(CH3 − CH2 − CH2 )3 B → CH3 CH2 CH2 OH
400−600℃
CH3 CH2 CH3 → CH2 = CH2 + CH4
Hydroboration of alkenes followed by (𝑋)(𝑌)
hydrolysis in basic medium yield alcohol. 33 (a)
HI⁄P The position of the double bond in alkene is
(B)CH3 − CH2 − CH2 I → CH3 − CH2 − CH3 identified by ozonolysis. Bromine water is used to
detect the presence of π-bond whereas
propane ammoniacal silver nitrate AgNO3 is used to detect
the presence of terminal alkynes or – CHO group
Reduction of alkyl halides yieldalkane.
34 (a)
(c)CH3 CH2 CH2 COONa + NaOH
CaO
→ CH3 CH2 CH3 + Na2 CO3

Propane

Decarboxylation of sodium salt of fatty acid

yield alkane having one carbon atom less than
While with Na/NH3 or LiAlH4 , 𝑡𝑟𝑎𝑛𝑠 alkene is
parent acid salt.
obtained, 𝑖𝑒, 𝑎𝑛𝑡𝑖-addition product
25 (b) 35 (d)
AgNO3
Nitrating, mixture is conc.HNO3 + H3 C − CH2 C ≡ CH → CH3 CH2 C ≡ CAg
NH4 OH
conc. H2 SO4 .
It produces NO+ (1-butyne) (silver-1 butynide)
2 electrophile which carried AgNO3
out electrophilic substitution reaction. H3 C − C ≡ C − CH3 → No reaction
NH4 OH
26 (a)
2-butyne
OsO4 is a valuable oxidising agent. It oxidises
36 (d)
alkenes to give 𝑐𝑖𝑠 − diols. Soda lime
CH3 COONa → CH4
Al4 C3 + 12H2 O ⟶ 4Al(OH)3 + 3CH4
2H
CH3 I → CH4 + HI.
37 (d)
Reaction of HBr with propene in the presence
of peroxide gives 𝑛-propyl bromide. This
addition reaction is an example of 𝑎𝑛𝑡𝑖-
Markownikoff’s addition reaction.
(𝑖. 𝑒.,it is completed in form of tree radical
addition.)
Peroxide
27 (b) CH3 − CH = CH2 + HBr → CH3 − CH2
Al4 C3 on hydrolysis gives methane gas. − CH2 Br
 𝑛-propyl Vinyl bromide loss HBr only by strong base.
bromide 53 (a)
38 (d) General formula of cycloalkane is C𝑛 H2𝑛 .
Friedel-Craft reaction proceeds 𝑣𝑖𝑎 most stable 54 (b)
carbocation When alkene is passed over AlCl3 , isomerisation
39 (c) takes palce
Follow text.
41 (a)
The polymer is
55 (b)
According to Huckel’s rule, the molecules
which contain (4𝑛 + 2)𝜋-electrons are
42 (b)
aromatic.
Symmetrical alkenes on ozonolysis give same
product during ozonolysis. 56 (a)
43 (b) AgC ≡ CAgis white and CuC ≡ CCu is red.
58 (a)
C2 H2 is commercially named narcylene.
44 (a) CaC2 + 2H2 O → C2 H2 + Ca(OH)2
Zn+HCl ethyne
CH3 I + 2H → CH4 + HI
or Zn−Cu/C2 H5 OH 59 (c)
Li
methane CH3 − C ≡ C − CH + 2(H) →
Dry ether liq.NH3
CH3 I + 2Na + ICH3 → CH3 − CH3
+ 2NaI
ethane
45 (d) 2-butyne
CaO
CH3 COONa + NaOH → CH4 + Na2 CO3 But in presence of Lindlar’s catalyst (Pd −
82 g CH3 COONa gives 22.4 litre CH4. CaCO3 ) 2-butyne reacts with hydrogen giving
46 (b) 𝑐𝑖𝑠-2-butene.
Ether Pd−CaCO3
2CH3 I + 2Na → C2 H6 + 2NaI CH3 − C ≡ C − CH + H2 →
48 (a) (2-butyne)
It is the name of reaction.
49 (c)
Na/Liq. NH3 or LiAlH4 reduce hex-2-yne to trans-
hex-2-ene.
50 (b)
The number of di-and poly-halogenation products 61 (d)
[O]
depends upon (i) and the number of different CH3 CH2 C ≡ CH → CH3 CH2 COOH + HCOOH
types of hydrogens present in an alkane and (ii) 62 (a)
the number of halogens introduced Ethane is already a saturated compound.
63 (d)
HIO3andHNO3 both are oxidizing agent. HI is
reducing agent which can reduce CH3 COCH3 to
propane,
CH3 − COCH3 + 4HI → CH3 CH2 CH3 + H2 O + 2I2
64 (a)
51 (b)
We know that
CH3 CH2 Cl + KOH → CH2 = CH2 + KCl + H2 O
Thus, in this reaction ethene(C2 H4 ) is
produced.
65 (b)
This reaction is utilized for the preparation of
higher alkynes
Liq.NH3
CH3 − C ≡ C − H + Na → CH3 − C ≡ C − Na
Propyne The addition takes place according to
CH3 − C ≡ C − Na + BrCH3 → CH3 − C Markownikoff’s rule.
≡ C − CH3 + NaBr 78 (c)
But-2-yne
Arc
C + H 2 → C2 H 2
66 (a)
79 (d)
B.P. increases with increase in mol. wt.
Wurtz-Fittig reaction
67 (f)
These are common reductants.
68 (d)

Lindlar’s catalyst prevents further reduction of The reaction is used to yield aromatic
ethane to ethane. hydrocarbons.
69 (c) 81 (d)
Am. Cu2 Cl2 gives red ppt.with alkyne. Alkanes are non-polar and have almost non-polar
70 (d) bonds C—H and non-polar bond C—C. They show
∆
(C2 H5 )4 NOH → (C2 H5 )3 N + C2 H4 + H2 O only substitution reactions in presence of light.
72 (d) 82 (d)
Ozonolysis involves the breaking of double
bond and insertion of O atoms in place of
double bond. Therefore, the structure of
alkene is as To identify alkene (from ozonolysis
products)place these products with O-atoms
face to face. Replace O-atoms by = (double
bond).

74 (b)
Alkenes on treatment with diazomethane
(CH2 N2 ) in the presence of UV light give
cyclopropane and its derivatives. This addition
takes place across the double bond

83 (c)
By the reaction of benzene with ethylene in
presence of anhydrous AlCl3 , ethylbenzene is
75 (c)
produced.
Fluorination is highly explosive and occurs
violently.
76 (b)
CH3 CH2 CH2 CH2 CH2 Cl; CH3 CH2 CH2 CHClCH3;
CH3 CH2 CHClCH2 CH3
77 (d) 84 (b)
Double bond is broken to give ketone and acid.
85 (a)
 Toluene has electron releasing group (CH3 ) thus
it most reactive towards electrophilic nitration
86 (c)
𝐶𝑛 𝐻2𝑛 𝑂 = 44
𝐶𝑛 𝐻2𝑛 = 44 − 16 = 28 95 (c)
∴𝑛=2 Reactivity towards electrophilic substitution
So, CH3 − CH = CH − CH3 is increases as the electron density in the benzene
symmertricalalkene. ring increases. Since 𝐶𝐻3 is a strong electron
Thus, donating group thus can be most readily
I.O3 sulphonated
CH3 − CH = CH − CH3 → 2CH3 − CH = O 96 (b)
II.Zn/H O 2

2-butene acetaldehyde OH
87 (b) |
H2 SO4
Conversion of propene to propanol is CH2 = CH − CH3 + H2 O → CH2 − CH
hydration. − CH3
OH Propylene isopropyl
| alcohol
H2 SO4
CH3 − CH = CH2 + H2 O → CH3 − CH Thus, in this reaction isopropyl alcohol is
− CH3 formed.
Propene propanol-2 98 (c)
88 (c) CaC2 + 2H2 O ⟶ Ca(OH)2 + C2 H2
The process is called aromatization. C2 H2 + Cu2 Cl2 ⟶ CuC ≡ CCu
89 (c) (Red ppt.)
CH4 + 2O2 ⟶ CO2 + 2H2 O 100 (a)
20 50 0 0 According to Huckel’s rule, an aromatic
0 10 20 Liquid
90 (c) compound should have (4𝑛 + 2)𝜋-electrons.
Where, 𝑛 is an integer, 𝑖. 𝑒., 0, 1, 3, 4, … and
possesses unusual stability due to the
delocalisation of 𝜋-electrons.
102 (d)
give only one monosubstituted product.
The octane no. for 𝑛-heptane is zero.
Is symmetrical alkane and will give only one
103 (c)
monosubstituted product.
This is hydrogenation of alkane.
Also C𝑛 H2𝑛+2 , 𝑖. 𝑒. , 12𝑛 + 2𝑛 + 2 = 72
104 (a)
𝑛=5
Tar, 𝑖. 𝑒., pitch contains alkanes from C30 to C40
91 (b)
chain.
The number of disubstituted products of benzene
105 (a)
is three
Thermal decomposition of alkanes in the
absence of air is called cracking or
pyrolysis𝑒. 𝑔.,
1000℃
CH4 → C + 2H2
106 (c)
92 (b) The following are the necessary conditions
𝑅′ Mg𝑋 + HC ≡ C𝑅 → 𝑅′ H + 𝑅C ≡ CMg𝑋 for compound to be aromatic.
93 (a)
1. Molecule must be planar and cyclic.
Electrolysis
2CH3 COONa → 2CH3 COO− + 2Na+
At anode 2. Conjugated double bond must be
 present.

3. It must have (4𝑛 + 2)𝜋-electrons.

107 (d)
115 (b)
CH2 = CH— CH = CH2 ; 𝑠𝑝2 − 𝑠𝑝 2 (C — C)bond B2H6
length is 1.34Å 6𝑅— CH = CH2 → 2(𝑅CH2 CH2 )3 B2
6H2 O2
1 2 3 4 2(𝑅CH2 CH2 )3 B2 → 𝑅CH2 CH2 OH + 2H3 BO3
108 (c) This process always gives alkanol-1 from alkane-
CH2 = CH − CH2 Cl + CH3 MgI → 1.
117 (b)
allyl chloride
Side chain hydrogen atoms are substituted in
presence of light or heat. Ring hydrogens are
substituted in presence of Lewis acid.

109 (c)
(i)Among alkanes boiling point increases with
increase in molecular mass.
(ii)Among isomeric alkanes the boiling point
decreases with branching due to decrease in
surface area.
𝑛-octane will have highest boiling point
because it has highest number of carbon
atoms and does not show branching.
118 (b)
110 (c)
Direct iodination of alkane is not possible because
of reversible nature of HI. It is therefore carried
out in presence of HgOor HIO3.
(addition reaction). CH4 + I2 ⟶ CH3 I + HI
111 (d) HgO + 2HI → HgI2 + H2 O
119 (b)

is aromatic.
It contains 3 double bonds (6𝜋 electrons).
According to Huckel rule (4𝑛 + 2)𝜋 = 6𝜋
electrons where, 𝑛 = 1
120 (b)
Since, the alkene of oxidation gives only acetic
acid, therefore, the alkene must be
To symmetrical containing two carbon-atoms on
determine alkene, place these products with either side of the double bond, 𝑖𝑒., 2-butene.
O-atoms face to face and replace O-atoms by KMnO4
=bond. CH3 CH = CHCH3 → 2CH3 COOH
114 (a) 122 (d)
The presence of dilH2 SO4 and mercury salts, When carbon is bonded to four other atoms,
alkynes add a molecule of H2 O to form aldehydes the angle between any pair of bonds =
or ketones 109°, 28′ (tetrahedral angle) but the ring of
 cyclobutane is square with four angles of 90°.
So, deviation of the bond angle (angle strain)
in cyclobutane
= 109°28′ − 90°⁄2
= 19°28′⁄2
= 9°44′
123 (c)
Excess of Cl2 finally converts all products to CCl4 .
124 (a)
𝑛-heptane gives toluene; 𝑛-octane gives ethyl
benzene.
125 (a)
The H-atoms of terminal alkyne (𝑖𝑒. , H3 C −
C ≡ CH) is weakly acidic.
Liq.NH3
CH3 ≡ CH + NaNH3 → H3 C − CH
≡ CNa + NH3
126 (c)
NaOH
HCOONa → H2 + Na2 CO3
134 (b)
127 (c)
At 60° (low temperature) mononitration
Alkyl halides undergo reduction with red
phosphorus and hydrogen iodine occurs and nitrobenzene is obtained but at
Red P/HI 100℃, nitrobenzene further undergoes
CH3 CH2 CH2 I → CH3 CH2 CH3
150℃ electrophilic substitution and gives 𝑚-
128 (a) dinitrobenzene (as – NO2 is a 𝑚𝑒𝑡𝑎 −
CH4 diffuses rapidly because of low mol. wt. directing group).
129 (a)
1
Boiling point ∝ molecualr mass ∝ branching

(∴ surface area decreases)

∴ 𝑛-hexane has the highest boiling point

among the given. 135 (b)
Rest all are aromatic compounds.
130 (d) 136 (b)
In this conformer Cl is at equatorial position and General formula of alkane is C𝑛 H2𝑛+2 ; 2𝑛 + 2 =
is least hindered. 10.
131 (c) 137 (a)
Rest all are industrial uses of C2 H2 . CH3 − C ≡ CH + HBr → CH3 − C = CH2
132 (d) |
In 𝑝-xylene, the four nuclear H-atoms are Br
equivalent and hence, only one on e
mononitro derivative is formed. But it gives
three dinitro derivatives (2,3;2,6 and 2,5) as
shown below
 HBr sealed tube, an addition product (adduct) is
CH3 − CH = CHBr → CH3 − CH2 − CHBr2
2HBr obtain. This reaction is called Diel’s Alder reaction
CH ≡ CH → CH3 CHBr2
HBr
CH3 − CH = CH2 → CH3 − CHBr − CH3
138 (b)
CH2 = CH2 + HCI ⟶ CH3 CH2 Cl (addition 148 (b)
reaction). Unsymmetric alkene and HBr are primary
140 (d) conditions for Kharasch effect.
Primary alcohols are oxidized to aldehydes and 149 (a)
then to acid to decolouriseKMnO4 . Also ethylene HBr
H2 C = CH2 → CH3 CH2 Br
oxidizes to formic acid.
(𝐴)
141 (b) Alc.KOH
Propyne gives white ppt. with ammoniacalAgNO3 . → H2 C = CH2
∆
144 (a) (𝐴)
Homologues of benzene may be prepared by
warming an ethereal solution of an alkyl or aryl Hence, 𝐴 = C2 H4 ; 𝐵 = alc. KOH⁄∆
halide with sodium

145 (d)
These are characteristics of ozonolysis.
146 (a)
When a conjugated diene (diene) is heated with
an unsaturated compound (dienophile) in a
150 (a)
HBr
The first addition will occur on double bond. Thus, CH ≡ CH— CH2 — CH = CH2 → CH ≡
C— CH2 — CHBr— CH3 but in CH ≡ C— CH = CH2 , the addition will occur at CH ≡ C because the product
formed is conjugated alkadiene, which is more stable.

151 (b)
It is alicyclic or aliphatic unsaturated.
152 (a)
(C2 H5 )4 Pb on addition to gasoline increases its
octane no. by about 5 units.
153 (b)
On heating with
156 (d)
sodamide(NaNH2 in liq. NH3 ),alkynide is formed
CH3 CH2 CH − CH3
|
OH
H+ −H2O
→ CH3 − CH2 − CH − CH3 →
154 (c) |
+
Only alcoholic KOH gives H−O −H
dehydrohalogenation reaction. Ethyl chloride (Major)CH3 CH = CHCH3
reacts with alcoholic KOH as (Minor)CH3 CH2 CH = CH2
157 (d)
 It is fact. Follow octane number. precipitate with 1-alkynes (terminal alkynes).
158 (a) CH3 − C ≡ CH + 2[Cu(NH3 )2 ]Cl →
KMnO4
CH3 C = CH3 → CH3 COCH3 + CH3 COOH CH3 − C ≡ C − Cu + 2NH4 Cl + 2NH3
∆
| (red ppt.)
CH3 165 (c)
159 (a) C—C bond involves 2𝑠𝑝3 − 2𝑠𝑝3 (𝜎) whereas, C—
1-Butyne reacts with NaNH2 to give sodium salt H bond involves 2𝑠𝑝3 − 1𝑠(𝜎) in alkanes.
while 2-butyne does not react. Only terminal 166 (c)
Ni/Al2 O3
alkynes are acidic. CH4 + H2 O → CO + 3H2
NaNH2
CH3 — CH2 — C ≡ C— H → No reaction 167 (c)
NH3 + CH3 — CH2 — C ≡ C Na
 Terminal alkyne reacts with ammoniacalAgNO3
160 (c) solution give a whilteppt, therefore 𝑥 must be a
When an alkyl halide reacts with sodium in terminal alkyne. Thus, 𝑥 must be(CH3 )2 CHC ≡ CH
KMnO4
presence of dry ether, an alkane with the (CH3 )2 CHC ≡ CH → (CH3 )2 CHCOOH
double number of carbon atoms than the + [HCOOH]
parent halide, is obtained and this reaction is 168 (c)
Zn
known as Wurtz reaction. 𝑅CH = C𝑅1 𝑅2 + O3 → 𝑅CHO + 𝑅1 CO𝑅2
H2 O
4 3 2 170 (a)
CH3 − CH − CH − Cl Zn
CH2 Br— CH2 Br → CH2 = CH2 + ZnBr2
| |
171 (d)
CH3 CH3
An alkyne combine with a conjugated diene to
2-chloro-3-methyl butane
give an unconjugatedcycloalkadiene. This
3 2
Na
reaction is known as Diels-Alder reaction.
+CH3 − CH − CH − Cl →
Dry ether
−2NaCl
| |
CH3 CH3
6 5 4 3 2 1 172 (a)
CH3 − CH − CH − CH − CH − CH3 Now-a-days used in refineries.
| | | | 173 (b)
CH3 CH3 CH3 CH3 Kerosene contains alkanes from C12 to C16 .
2,3,4,5-tetramethyl hexane 174 (d)
161 (b) On treatment with alcoholic KOH, 1-
Na⁄Liq.NH3 chlorobutane gives 1-butene while 2-
CH3 CH2 C ≡ CH → CH3 CH2 C ≡ CNa+
∆ chlorobutane gives 2-butene (major) +1-
Considering the options given it appears butene (minor). Therefore, a mixture of 1-
correct. Na⁄liq. NH3 is known for metal butene +2-butene is formed.
dissolved reduction. Actually it is truth that 176 (a)
Na⁄liq. NH3 reduces internal triple bond and O
terminal double bond and do not reduce the ∥
terminal alkyne due to such alkylide (i)O3
𝑋 → C2 H4 O + CH3 CH2 − C − CH3
formation. (ii)Zn/AcOH

162 (a) Aldehyde 2-butanone

Homologous may or may not be straight chain The aldehyde should be CH3 CHO because the
compounds. molecular formula is C2 H4 O.
163 (c)
Ammoniacal cuprous chloride will give red
 184 (b)
Cetane number of hexadecane is 100 and of
methyl naphthalene is zero.
177 (b) 185 (c)
Octane no. for iso-octane has been arbitrarily Distillation of acetone with concentrated
assumed to be 100 and for 𝑛-heptane as zero.
conc. H2 SO4 gives mesitylene.
178 (c)
HBr
CH3 CH2 CH = CH2 → CH3 CH2 CHBrCH3
179 (d)
In cyclopropane the angle strain is maximum.
Hence, it is highly strained molecule and
consequently most unstable. The angle strain 186 (b)
in cyclobutane is less than cyclopropane.
Hence, cyclobutane is more stable. This
stability increases up to 6 membered rings See rupture of C=C to convert it to C=O.
then decreases from 7 to 11 membered rings 187 (b)
and from the 12 membered rings onwards Soda lime (NaOH+CaO) is used to slow down the
attains the stability of 6 membered ring. Heat decarboxylation otherwise the reaction will occur
of combustion is a method of measuring violently.
chemical stability. Hence, cyclohexane has the 188 (b)
More is the amount of CO in exhaust fuel, more
lowest heat of combustion.
incomplete is combustion of fuel.
180 (d)
189 (d)
At 70 120C gasoline, at 150 250C kerosene; at
It may be CH3 CH2 C ≡ CH or CH2 = CH— CH =
250 400C diesel oil.
CH2 or
181 (b)
CH3 HC = CH— CH3 .
Triple bond is shifted from centre to corner.
183 (b)
Oxymercuration-demercuration is an example of
hydration of alkene according to Markownikoff’s
rule
190 (b)
Mustard gas is β, β-dichlorodethylsulphide which is prepared by the action of
sulphurmonochloride on ethylene.

191 (b) C2 H2 , C2 H4 and H2 .

CH ≡ CH + CH3 OH →
CH3 ONa
CH2 = CH. OCH3 is 193 (b)
nucleophilic addition. Larger is surface area, more is viscosity. Surface
192 (a) area decreases with increase in branching.
CH4obtained in (c) is contaminated with 196 (a)
C5 H12 has molecular mass=72
 Ag(NH3 )+ −
2 OH to give white ppt.
209 (a)
The reactivity order of 1, 2 and 3 H-atoms has
been explained in terms of hyper conjugation.
will give only one mono substituted product. 210 (d)
197 (a) HgSO4⁄H2SO4
CH3 CH2 C ≡ CH + H2 O →
(i)Electron rich groups are 𝑜, 𝑝directing
1-butyne
. , −OH, −Br, −CH3 etc.
OHOH
(ii)Electron deficient groups having multiple
| |
bonds are 𝑚-directing. H2 O
𝑒𝑔. , −COOH, −NO2 CH3 CH2 C = CH2 → CH3 CH2 − C − CH3
198 (c) |
In the given compounds only acetophenone is OH
prepared by substitution. Other compounds unstable
−H2O
are prepared by addition reactions. → CH3 CH2 − C − CH3
Acetophenone is prepared when benzene ||
reacts with acetyl chloride in presence of O
anhy. AlCl3 as butan-2-one
212 (a)
The reactivity order is, Cl2 > 𝐵r2 > I2 .
213 (c)
Decolourisation of KMnO4 (unsaturation test)

200 (d)
CH2 = CH − CH2 CH3
Butene-1
Pd/H2
→ CH3 − CH2 − CH2 − CH3
∆,pressure
butane
Other reagents are successful with polar
double bonds.
203 (a) 214 (b)
Hg2+ ⁄H+ Indane is commercial name of L.P.G.
Ph − C ≡ C − CH3 → Ph − C = CH − CH3
215 (a)
| Terminal alkynes react with
OH
ammoniacalAgNO3 to give silver salt as they
Ph − C = CH2 CH3
have acidic hydrogen.
||
CH3 − C ≡ CH + AgNO3 + NH4 OH →
O
CH3 − C ≡ C. Ag + NH4 NO3 + H2 O
(𝐴) 217 (a)
204 (b) Cyclo propane is the most unstable cyclic
Follow mechanism of Wurtz reaction.
compound. So, with bromine it gives an open
205 (c)
chain compound 1, 3-dibromopropane.
It is a non-terminal alkyne.
207 (b)
1, 2-bromo cyclopentane on heating with 1− in
acetone gives cyclopentene.
208 (b)
Terminal alkynes react with am. AgNO3 or 218 (c)
 Addition of HBr to an alkene in the presence of
peroxide is the example of free radical addition
reaction

228 (b)
CH ≡ CH + HBr → CH2 = CHBr
219 (a) 229 (a)
Electrolysis
All H-atoms in 𝑛𝑒𝑜-pentane are equivalent thus, it CH3 CH2 COONa → CH3 (CH2 )4 CH3 + NaOH
will yield monochloro product + H2
220 (b) 230 (b)
Acetylenichydrogens are acidic because sigma 2CHCl3 + 6Ag ⟶ C2 H2 + 6AgCl
electron density of C − H bond in acetylene is 231 (d)
nearer to carbon, which has 50% 𝑠-character In the presence of ferric chloride, electrophilic
221 (c) substitution at 𝑜𝑟𝑡ℎ𝑜 and 𝑝𝑎𝑟𝑎 position take place
Follow text. 232 (b)
222 (c) Butyne reacts with Na⁄liq. NH3 to give 𝑡𝑟𝑎𝑛𝑠-
Wurtz reaction Alkyl halide reacts with product.
sodium in presence of dry ether forms alkane
is known as Wurtz reaction.
CH3 Br + 2Na + BrCH3
Ether 233 (c)
→ CH3 − CH3 + 2NaBr
CH3
223 (b)
|
It is an experimental fact. +NaNH2
224 (c) CH3 − CH2 − CH − C ≡ CH →
+O3
(i)Unsaturated hydrocarbons are more 3-methyl-1-pentyne
reactive than saturated hydrocarbons.
(ii)Among alkene and alkyne, alkene are
more reactive because C ≡ C is quite strong
bond.
∴ Correct order of reactivity CH3
Alkene>alkyne>alkane |
or C2 H4 > C2 H2 > C2 H6 CH3 − CH − CH − COOH + HCOOH
etheneethyne ethane Optically active carboxylic acid.
225 (b)
236 (a)
Bacteria
(C6 H10 O5 )𝑛 + 𝑛H2 O → 3𝑛CH4 + 3𝑛CO2 The mechanism of Wurtz reaction is:
226 (c) C2 H5 Br + Na ⟶ Ċ2 H5 + NaBr
It is a common method to prepare alkanes. Ċ2 H5 + Ċ2 H5 ⟶ C4 H10
Methane cannot be prepared by Wurtz The disproportionation of free radical gives
reaction. Ċ 2 H 5 + Ċ2 H 5 ⟶ C2 H 4
CH3 Br + 2Na + BrCH3 → C2 H6 + 2NaBr 237 (b)
ethane When sodium propionate is heated with
227 (b) sodalime, ethane is formed.
CaO
Symmetrical optical isomers are called CH3 CH2 COONa + NaOH → C2 H6 + Na2 CO3
mesomers. ethane
238 (c) reaction with alkyle halide. This is called
Dry ether
2CH3 − CHBr + 2Na → CH3 − CH − CH Friedel-Craft’s alkylation.
− CH3
| | |
CH3 CH3 CH3
Isopropyl 2,3-dimethyl
butane
bromide
239 (d) 250 (a)

Isobutene has minimum force This is dehalogenation.

of attraction (due to steric hindrance). Thus, 251 (d)
minimum boiling point. 𝜔 -dihalides when reacts with sodium metal,
240 (d) gives cyclic hydrocarbons. This is an example
CH4 + 𝑋2 ⟶ CH3 𝑋 + CH2 𝑋2 + CH𝑋3 + C𝑋4 , of intramolecular Wurtz reaction.
Also combination of ĊH3 free radical may give Na
CH2 − CH2 CH2 − CH2 →
C2 H6 . The free radicals formed are −2NaBr
| |
242 (b) BrBr cyclobutane
CH ≡ C. Na + CO2 ⟶ CH ≡ C. COONa 252 (d)
243 (a) Rest all are detained by it.
Propyne on passing through red hot iron tube 255 (a)
Due to more close packing, even carbon atom
gives mesitylene
alkanes have higher value.
258 (b)
Product will be spiropentane.
260 (a)
Toluene is oxidised to benzaldehyde in
presence of chromyl chloride. This reaction is
called Etard’s reaction.
244 (c)
(CH3 )3 C − MgCl + D. OD
Grignard reagent
→ (CH3 )3 C. D + MgCl(OD)
[Grignard reagent when reacts with a protic
solvent, gives alkane]. 262 (a)
245 (a) Markownikoff’s addition the negative part of
These are arbitrarily assigned values.
the unsymmetrical reagents adds to a less
246 (d)
hydrogenated (more substituted) carbon
Acetylene does not react withNaOH.
atom of the double bond. In ICl, Cl is more
247 (d)
82 g CH3 COONa gives 22.4 litre CH4. electronegative. So, it will take negative
248 (d) charge, . 𝑒. , I + Cl− . So, the product is
Non-terminal alkynes do not have acidic H-atom.
249 (a)
In presence of a Lewis acid (like AlCl3 ),
263 (b)
benzene gives electrophilic substitution
Reduction of CH3 COCH3 with HI and red P will
 give propane 275 (b)
264 (a) Follow Saytzeff’s rule for elimination.
Acetylene is acidic and thus reacts withNaNH2. 276 (c)
Na. Amm. AgNO3 reduces itself on reacting with Any aliphatic carbon with hydrogen attached
acetylene with HCl it gives addition reactions. to it, in combination with benzene ring, will
However, being weak it does not react with NaOH. be oxidised to benzoic acid by KMnO4 ⁄H + .
265 (b) 277 (d)
Alkenes give carbonyl compounds on ∆
CH4 + HNO3 → CH3 NO2; nitration reaction.
ozonolysis
278 (d)
O3 ⁄Zn/H2 O Terminal alkynes give red. Ppt. with amm. Cu2 Cl2 .
Alkene → HCHO + other carbonyl 279 (a)
compound An isolated alkadiene has double bonds, one at
each corner.
(𝐴)
281 (b)
Na will react with —OH group
283 (b)
PhMgBr can be protonated by any of the
protic solvent 𝑒. 𝑔. , 𝐶𝐻3 𝑂𝐻.
To determine alkene, place carbonyl
compounds with their O-atom face to face.
Replace O-atom by a double bond 284 (d)
Addition of iso-octane to gasoline increases
octane number of fuel or decreases knocking.
285 (d)
Because of less density cyclo hexane floats over
water.
286 (d)
CH2 = CH2 + H2 O + [O]
Baeyer′ sreagent
→ CH2 OH. CH2 OH
287 (b)
The reduction of >C=C< only to >CH—CH< is
influenced by H2 /catalyst.
266 (c) 289 (a)
An increase in molecular weight results in an Except NaOH rest all reacts with C2 H2 .
increase in van der Waals’ forces of attractions 290 (b)
which results in an increase in b.p. Catalytic hydrogenation is free radical addition.
268 (b) Also more is heat of hydrogenation (∆𝐻 =
H2 O −ve)more is reactivity for alkene for
CH2 = CH2 → CH3 . CH2 OH
269 (b) hydrogenation.
LPG is a mixture of lower alkanes mainly 291 (d)
isobutene and butane. It is simply called addition of halogen.
271 (d) 292 (c)
Reducing agent P+HI gives alkane in every case. CO + 3H2, is called synthetic gas.
293 (a)
272 (b)
Lewisite is

AsCl3 on CH ≡ CH
 molybdenum oxide (MoO), it gives methanal
(formaldehyde).
[MoO]
CH4 + 2[O] → HCHO + H2 O
formaldehyde
304 (d)
Propyne reacts with AgNO3 in NH3 to give
benzaldehyde while ppt. of silver acetylide and propene
294 (c) does not react with it. (Only terminal alkynes
Alkaline KMnO4 converts an H-atom to —OH gp.
react withAgNO3 in NH3 ).
295 (a)
CH3 − C ≡ CH + AgNO3 + NH3
𝐺𝑒𝑚dihalides on treatment with alcoholic KOH
give alkyne.
Propyne
→ CH3 − C ≡ C Ag
silver acetylide
(white ppt.)
296 (c)
CH3 − CH = CH2 + AgNO3 + NH3
Ag + ion increases the solubility of alkenes due
→ no reaction
to the formation of 𝑝𝜋 − 𝑑𝜋 bonding. 305 (a)
297 (c) Rotation of groups or atoms round single bond
CH ≡ CH + 2HCHO → HOH2 C − C produces conformation.
≡ C − CH2 OH 306 (a)
Acetylene 2, butyne-1, 4-diol A compound is said to have aromatic
298 (b) character if ring system is planar (with 𝑝-
NaOH+CaO
(CH3 )2 CHCOONa → (CH3 )2 CH2 + Na2 CO3 orbital) and there is complete delocalisation
299 (a) of 𝜋-electrons (lone pair may be taken for
Alkenes show electrophilic addition. delocalisation as relay electrons). This is true
301 (c) is conjugated cyclic system.
Methane cannot be produced by Wurtz
reaction, Kolbe’s electrolytic method and
reduction with H2 because, it has one carbon
atom. Huckel rule is followed by when electrons
Pure methane can be produced by the used in delocalisation=(4𝜋 + 2)
decarboxylation of sodium acetate. (including lone-pair)
CaO
CH3 COONa + NaOH → CH4 + Na2 CO3 Where, 𝑛=0, 1, 2, 3,….
Soda lime methane
302 (a)

4. ring is planar

5. ring is not conjugated

6. delocalisation of 𝜋-electrons is not

Hence, reagent X and Y are respectively possible after C4 .
Na, NH3 and Pd⁄BaSO4 + H2 .
7. (4𝜋 + 2)𝜋-electrons=4
303 (d)
When methane is oxidised in presence of
 Hence, it is not aromatic. Only primary hydrogen atoms are present here,
thus only one product is formed
307 (b) 319 (d)
Kerosene contains C11 — C16 atoms alkanes. The phenomenon of decomposition of higher
308 (a) alkanes into lower hydrocarbons on heating in
The stability of alkenes increases with increase in absence of air is called cracking.
substitution of H attached on doubly bonded 320 (a)
carbon by alkyl groups. Ethyl benzene cannot be prepared by Wurtz
309 (d)
reaction. This method is suitable for the
When chlorine is passed in boiling toluene, preparation of symmetrical alkanes.
substitution in side-chain takes place and 321 (a)
benzyl chloride is obtained which on HCI
AgC ≡ CAg → CH ≡ CH
hydrolysis give benzyl alcohol.
322 (a)
HCl
Cl3 − C − CH = CH2 → Cl3
anti−Markownikoff rule
− C − CH2 − CH2 Cl
(∵ CCl3 is highly electron attracting group)
323 (b)
310 (b) KOH alc., NaNH2 and C2 H5 ONa are used for
To oxidize HI formed during the reaction; dehydrohalogenation.
otherwise the strong reducing nature of HI will 324 (b)
reverse the iodination. Octane number represents percentageof iso-
312 (c) octane.
Reactivity of alkenes decreases with increase in 325 (a)
no. of carbon atoms in alkene as well as Cyclopropane is most strained alkane; follow
substitution of H-atom attached to double bond. Baeyer’s strain theory.
313 (c) 326 (c)
SeO2 If the side chain is larger than a methyl group, the
CH3 C ≡ CH → CH3 COCHO
halogenation always at the benzylic carbon
314 (c)
3° (C − H) bond has minimum bond energy
hence easily cleaved giving 2 bromo 2-methyl
butane
327 (d)
Arc
C + H 2 → C2 H 2 + C2 H 4 + C2 H 6
Main
328 (b)
Propene undergoes allylic substitution at this
315 (a)
Hg(OOC.CH3 )2 temperature instead of addition reaction.
(CH3 )3 CCH = CH2 → 330 (d)
C2 H4 (OH)2is anti-freeze; C2 H5 Cl is solvent.
C2 H4 Ois fumigant.
331 (a)
316 (d) C6 H6 is main product of light oil fraction.
These are facts about alkanes. 333 (b)
318 (b) C2 H2 is commonly used in oxy-acetylene welding.
334 (d)
3-octyne is obtained by the reaction of 1-
bromobutane and but-1-yne in presence of
 sodamide. Calcium carbide ethyne
(i)O3
CH3 CH2 C ≡ CH + NaNH2 → HCOOH + HCOOH
(ii)H2O/H+
Formic Formic
̅ Na+
→ CH3 CH2 − C ≡ C
acid acid
̅ Na + BrCH2 CH2 CH2 CH3
CH3 CH2 C ≡ C 346 (c)

→ CH3 CH2 C ≡ C − CH2 CH2 CH2 CH3 Electrolysis

CH3 COONa → C2 H 6 ;
3-octyne NaOH
CH3 COONa → CH4
335 (b) 347 (a)
In C2 H5 each C-atom is sp-hybridised which The addition of HBr to an alkene is an
contains 50% 𝑠-character. The greater the 𝑠- example of electrophilic addition reactions. It
character of an orbital, the bonding electron takes place by following mechanism.
pair will be more inclinated towards the
nucleus as a result carbon would acquire a
negative charge and hydrogen a positive
charge. Hence, it is acidic in nature.
H − C ≡ C: H
𝑠𝑝𝑠𝑝
and removal of hydrogen as proton takes
place.
336 (a)
Follow mechanism of addition reactions.
337 (d)
CH2 = CH − CH = CH2 (1,3-dibutene) is a
conjugate diene because it has alternate
carbon-carbon single and double bonds. It
reacts with HBr. It also polymerises to form
Buna-N rubber etc.
It also polymerises to form SBr.
348 (a)
340 (b) ∆
The product of give reaction will be 3C2 H6 → C6 H6 + 3H2 ; the reaction is called
according to Markownikoff’s rule, this is aromatisation.
because peroxide effect is applicable only in 349 (c)
When toluene is heated in light with Cl2 in the
case of HBr and not effective in case of HI.
HI absence of halogen carrier, Benzotrichloride is
CH3 − CH = CH2 → CH3 − CH − CH3 obtained
peroxide
|
I
341 (b)
A characteristic reaction of aldehyde with Tollen’s
reagent. Rest all also attacks C=C.
342 (b)
When calcium carbide reacts with water,
ethyne is formed. 351 (c)
CaC2 + 2H2 O → C2 H2 CH2 = CHCH = CH2 + HBr →
−Ca(OH)2
CH3 CHCH = CH2 + CH3 CH = CHCH2 Br
 | 356 (b)
Cu
Br CS2 + 2H2 S → CH4 + 3S
1,2-addition product 1,4-addition product 358 (d)
Addition is through the formation of CH ≡ CH + CH3 OH
allyliccarbocation. CH3 OK
→ CH3 O − CH = CH2
160−200℃
Ethyl vinyl ether
359 (d)
These are facts about addition reaction.
CH2 = CHCHCH3 ↔ CH3 CH = CHCH2 363 (a)
Under mild conditions (temperature≈ Fire damp is name for CH4.
−80℃) kinetic product is the 1, 2-addition 364 (d)
product and under vigorous conditions (i)Markownikoff’s rule is applicable to
(temp. ≈ 40℃) thermodynamic product is the addition of unsymmetrical alkene to
1,4-addition product. unsymmetrical reagent.
Thus, 1-bromo-2-butene is the major product (ii)𝐴𝑛𝑡𝑖-Markwonikoff’s rule is applied to
under given condition. addition of HBr to unsymmetricalalkene in
352 (b) presence of peroxide. Free radical is the
reaction intermediate during this reaction.
According to this rule negative part of the
reagent adds to carbon atom having more
number of hydrogen atoms.
HBr
is aromatic because the compound is cyclic CH3 − CH = CH2 →
peroxide
and number of 𝜋-electrons is 2, which is in
CH3 − CH2 − CH2 − Br
accordance with the Huckel’s rule, (4𝜋 + 2)𝜋.
365 (a)
When 𝑛=0, according to this rule, number of
Acidic hydration of 2-phenyl propene follows
𝜋-electrons is 4 × 0 + 2 = 2.
electrophilic reaction mechanism forming an
353 (b)
intermediate 3° carbocation (more stable),
Ethylene reacts with 1% alkaline KMnO4
thereby forming 2-phenyl-2-propanol.
gives ethylene glycol.
CH2 CH2 OH
1% alkaline
|| + H2 O + O → |
KMnO4
CH2 CH2 OH
354 (c)
Wurtz reaction.
355 (a)
Friedel-Craft’s acylation in this reaction
benzene reacts with acetyl chloride or acetic 366 (a)
anhydride in presence of anhy. AlCl3 . C2 H4 is a monomer unit of polythene, 𝑖. 𝑒.,

367 (c)
Halogenation of alkanes is free radical
The X is substitution.
O 368 (a)
∥ Staggered form is more stable.
R − C − Cl 369 (b)
 Alkene having all its H attached on double bond increases regularly with increasing number of
does not decolouriseBr2 water due to low carbon atoms
reactivity. 382 (b)
370 (d) (C2 H5 )4 is anti-knock agent and increase octane
R of RMgX reacts with acidic H to give alkane. no. of gasoline.
371 (a) 384 (b)
The carbon-carbon bond length in benzene It is a fact.
(1.39 Å) in between that of C − 385 (d)
It is definition.
C(1.54 Å)and C = C(1.34 Å)𝑖. 𝑒., in between
387 (a)
that of C2 H6 and C2 H4 .
When acetylene is passed through red hot
373 (c)
iron tube, benzene is formed as
Follow strainless ring theory.
Red hot tube
374 (c) 3C2 H2 → C6 H6
(𝑋)
Reaction (a) also gives C6 H6 (or 𝑋) as
Distillation
C6 H5 OH + Zn → C6 H6 + ZnO
389 (a)
CH3
|
(∵ In the product, −Br is𝑝𝑎𝑟𝑎to − CH3 − CH − C − CH3
CH3 and𝑚𝑒𝑡𝑎to − COOH. ) | |
375 (c) OH CH3
Hydrogenation of alkene or alkyne in presence of
3,3-dimethyl butane-2-ol
Ni is called Sabatier and Senderen’s reaction.
CH3 CH3
376 (b)
| |
Conc.H2 SO4
→ H3 C − C = C − CH3
−H2 O
2,3-dimethyl-2-butene
This reaction is an example of Friedel-Craft’s (major product)
reaction. 390 (a)
Mechanism: Fractional distillation of petroleum gives a large
number of products aliphatic and aromatic.
391 (a)
377 (a)

(Cyclopentadienyl anion)
This reaction is an example of electrophilic According to Huckel’s rule
addition reaction and in it addition takes Total number of 𝜋-electrons inside the ring
place according to Markownikoff’s rule. (4𝑛 + 2)𝜋electrons.
378 (c)
= (4 × 1 + 2) = 6𝜋 electrons
H2 SO4 absorbs ethene.
So, it is aromatic.
379 (d)
392 (a)
These all are poisonous gases.
Follow ozonolysis.
380 (d)
393 (c)
It is an anti-termite.
Natural gas is a mixture of 80% CH4 and 10%
381 (b)
C2 H6 +10% higher hydrocarbons.
The boiling points of straight chain or 𝑛-alkanes
394 (b) (i)Wurtz reaction
C2 H5 Br + 2Na + BrC2 H5 → C2 H5 C2 H5or𝑛-butane. Ether
2𝑅𝑋 + 2Na → 𝑅−𝑅
395 (c)
Alkane
According to Huckel’s rule an aromatic
(ii)Kolbe’s reaction
compound has (4𝑛 + 2)𝜋-electrons, where,
Electrolysis
𝑛 =0, 1, 2, 3,…etc. 𝑅COONa + H2 O → 𝑅−𝑅
alkane
(iii)Ulmann’s reaction
2C6 H5 I + 2Cu → C6 H5 − C6 H5
;4𝑛 + 2 = 2; 𝑛 = 0; aromatic
biphenyl
(iv)Frankland reaction
2𝑅𝑋 + Zn → 𝑅 − 𝑅
; 4𝑛 + 2 = 6; 𝑛 = 1; aromatic alkyl halide alkane
406 (c)
Both carbon have two sigma bonds on each.
407 (c)
; 4𝑛 + 2 = 4; 𝑛 = 0.5; non − aromatic

; 4𝑛 + 2 = 6; 𝑛 = 1; aromatic
397 (a)
Zn/H2 O
Alkanes with six to 10 carbons are converted to → CH3 − C − C − CH3
−H2 O2
aromatic hydrocarbons, 𝑒. g.,
|| ||
O O
408 (d)
Note this temperature used in oxy-acetylene
welding.
409 (b)
399 (b) Benzene can be obtained by heating benzoic
With acidic manganese dioxide or chromyl acid with sodalime.
chloride, in CCl4 solution, toluene and all other
homologues of benzene are oxidized to terminal
carbon atom giving aldehydes

402 (d)
All are dehydrating agents.
403 (a) Benzene can also be obtained by heating
Terminal alkynes give white ppt. with am. AgNO3
phenol with zinc dust.
404 (a)
Alkyl halides can be reduced to hydrocarbons
by means of Zn − Cu couple in presence of
alcohol.
Zn−Cu
C2 H5 I → C2 H6 + HI
C2 H5 OH
ethane 410 (d)
405 (d) Due to acidic hydrogen.
411 (b) 425 (a)
Fractional distillation of petroleum gives a large Chair form is more stable.
number of products aliphatic and aromatic. 426 (d)
413 (c) Both free radicals are used in terminating step.
𝑡. radicals are most readily formed. 427 (d)
414 (d) It involves removal of a molecule from substrate.
According to the Huckel rule, a compound will be 428 (a)
aromatic if compound should have (4𝜋 + 2)𝜋 Ozonolysis
CH ≡ CH → CHO. CHO
conjugated or delocalized electrons where 𝑛 is a Reduction
whole number and it may be 𝑛 = → CH2 OH. CH2 OH
0, 1, 2, 3, 4, 5, 6, … 429 (a)
It is a test for unsaturation in molecule.
430 (c)
On electrolysis of potassium salt of fumaric
415 (b) and maleic acid, ethyne gas is obtained.
CHCOOKCH
Electrolysis
|| → ||| + 2CO2 + 2KOH + H2
CHCOOKCH
Potassium maleateethyne
431 (a)
Column I Column II
Benzene (4𝑛 + 2)𝜋-
electrons
Ethylene Mustard gas
In this reaction H3 PO2 serves both as an acid
Acetaldehyde Silver mirror
as well as a reducing agent.
Chloroform Phosgene
416 (c) Benzene has 6𝜋-electrons, 𝑖. 𝑒., it follows
C2 Cl6 is artificial camphor.
Huckel rule (4𝑛 + 2)𝜋-electrons. Ethylene
418 (d)
reacts with S2 Cl2 to give mustard gas (war
1, 3-butadiene is CH2 = CH— CH = CH2; alternate
single and double bonds. gas).
419 (c)
Hexane and onwards alkanes are sulphonated. 433 (b)
Follow peroxide effect.
Isobutene is also sulphonated due to 3H-atom.
434 (b)
422 (b)
CH3 CH2 CH2 CH = CH2 + Br2
Acetylene has some acidic character and its
⟶ CH3 CH2 CH2 CHBrCH2 Br
hydrogen gets replaced by silver to give silver
∵70 g C5 H10 requires 160 g Br2
acetylide. 160×5
5g C5 H10 requires = 11.43g Br2
CH ≡ CH + 2AgNO3 + 2NH4 OH → 70

AgC ≡ CAg ↓ +2NH4 NO3 + 2H2 O 435 (c)

These are characteristics of C2 H4 .
white
436 (a)
423 (c)
All those groups which contain at least one
Beryllium carbide gives CH4, magnesium carbide
(MgC2 ) and calcium carbide (CaC2 ) give acetylene pair of non-bonding electrons on the atom
while silicon carbide being covalent does not adjacent to the benzene ring, are
undergo hydrolysis 𝑜𝑟𝑡ℎ𝑜 and 𝑝𝑎𝑟𝑎 directing. Among the given
424 (b) options, all are 𝑜𝑟𝑡ℎ𝑜 and 𝑝𝑎𝑟𝑎 directing but
The greater the branching, smaller is surface area, their capacity of 𝑜𝑟𝑡ℎ𝑜 − 𝑝𝑎𝑟𝑎 direction
lesser is attraction among molecules and so low follows the order
b.p.
 CH3 Mg𝑋 + CH3 C ≡ CH
→ CH4 + CH3 C ≡ CMg𝑋
Hence, is the strongest 𝑜𝑟𝑡ℎ𝑜 − 452 (b)
𝑝𝑎𝑟𝑎 directing groups. CH2 = CH— CH = CH2;
437 (a) 𝑠𝑝2 𝑠𝑝2 𝑠𝑝2 𝑠𝑝 2
453 (d)
Heat
HCCl3 + 6Ag + Cl3 CH → HC ≡ CH + 6AgCl
𝜋 electrons = 4 + 2 = 6
Chloroform choloroform acetylene
As it obeys Huckel rule, it is aromatic Thus, in this reaction acetylene (HC ≡ CH) is
438 (c) produced.
An insecticide, gammexane, is formed. It is 454 (d)
also called benzene hexachloride (BHC), Methyl iodide and ethyl iodide, on treatment
though it is wrong. The correct chemical with sodium in ethereal solution, give a
name is 𝑠𝑦𝑛:hexachloro cyclohexane. mixture of propane, ethane and butane, as
follows
CH3 I + 2Na + I − CH2 CH3
Ether
→ CH3 CH2 CH3 + 2NaI
Propane
CH3 I + 2Na + I − CH3 → CH3 − CH3 + 2NaI
ethane
440 (d)
C2 H5 I + 2Na + I − C2 H5 → C2 H5 C2 H5 + 2NaI
Alkane is (C2 H5 )4 C.
441 (c) butane
455 (b)
H is replaced by Cl.
456 (c)
CH ≡ CH + HOCl
Vinylic bromide is more stable stronger base
⟶ CH(OH)2 — CHCl2
(−NH2− ) is required for elimination.
→ CHOCHCl2
443 (d) −H2 O

An infinite conformers of ethane are possible 457 (c)

HOCl
including staggered, skew and eclipsed forms. CH2 = CH2 → CH2 OH. CH2 Cl
444 (c) 458 (d)
By adding bromine water to a solution, if the Heat of hydrogenation ∝ stability
1

colour of bromine water decolourise then the

Among the given buta-1,3-diene is resonance
compound is unsaturated. This is a stabilized, 𝑖𝑒, more stable, thus it has lowest heat
confirmatory test for unsaturation. of hydrogenation
445 (a) 459 (a)
Halogenation in alkane follow free radical
mechanism. Formation of free radical occurs in
presence of light.
448 (b)
Removal of H2 O from a substrate by a A is
dehydrating agent is called dehydration. mesodiol.
449 (b) 460 (b)
The catalyst used is called Ziegler’s catalyst. Both are unsaturated and give Baeyer’s test.
451 (d) 461 (c)
Terminal alkyne has acidic hydrogen which is Conjugated alkadiene have alternate single and
enough to protonate the Grignard reagent. double bond,
 𝑒. g. , CH2 = CH— CH = CH2 . Reaction of 4-octyne and H2 can be arrested at the
463 (c) alkene stage only by using palladium partially
Natural gas is 80% CH4, coal gas contains 40% inactivated with trace of quinoline
CH4; Marsh gas is another name for CH4. 472 (c)
464 (b) It is the name of reaction.
Iodoform and Ag undergo dehalogenation 473 (d)
reaction to produce acetylene. CH3 − CH2 − CH2 − C ≡ CH + CH3 MgBr
∆
(A)HCOOK + H2 O → H2 + CO2 + KOH Methyl magnesium
∆
(B)2CHI3 + 6Ag → CH ≡ CH + 6AgI
bromide
Iodoform silver acetylene
Conc.H2 SO4
(C)CH3 CH2 OH → CH2 = CH2 + H2 O
443K
Ethylene
(D)Be2 C + H2 O → CH4
Due to the presence of acidic hydrogen
methane
(hydrogen attached to triply bonded carbon
465 (c)
atom) terminal alkyne (𝑑) will react with
In Wurtz reaction alkyl halide reacts with
methyl magnesium bromide.
sodium in presence of dry ether to give
alkanes𝑒. 𝑔. , 474 (c)
2𝑛1 +2−𝑛2
C2 H5 Cl + 2Na + Cl C2 H5 Degree of instauration= ; where, 𝑛1 is the
2
→ C4 H10 + 2NaCl number of carbon atoms and 𝑛2 the number of
(dry ether)
butane hydrogen atoms.
In Wurtz reaction wet ether is not used
because wet ether destroy the sodium metal. In compound
466 (d) Number of carbon atoms =8
When excess of benzene reacts with CH2 Cl2 in Number of hydrogen atoms=12
2×8+2−12
presence of anhy. AlCl3 ,diphenylmethane is Degree of unsaturation= =3
2
obtained 477 (a)
C2 H4 + H2 SO4 ⟶ C2 H5 HSO4; addition of H2 SO4
on ethane.
478 (b)
Peroxide effect is noticed only in case of HBr. For
HCl follow Markownikoff’s rule.
This reaction is an example of Friedel-Crafts’ 481 (c)
reaction Pent-3-yne is not correct; it is pent-2-yne;
468 (c) CH3 — C ≡ C— CH2 CH3 .
Gasoline among all has lowest b.bt. 482 (b)
[O]
469 (b) CH3 C ≡ CH → CH3 COCOOH
POCl3 is a dehydrating agent 484 (b)
It is Corey House synthesis of alkanes.
487 (b)
Like gets dissolved in like; alkane and benzene
470 (c) both are non-polar.
CH ≡ CH + HOCl ⟶ CH(OH) 488 (a)
HOCl CH4cannot be prepared by Kolbe’s electrolysis;
= CHCl → CH(OH)2 CHCl2
⟶ CHCl2 . CHO HCOONa gives H2 and CH3 COONa gives CH4.
471 (b) 490 (a)
 F2 reacts more violently. Ozonolysis
CH3 CH2 CH = CHCH3 → CH3 CH2 CHO
491 (a) + CH3 CHO
Markownikoff’s as well as 𝑎𝑛𝑡𝑖- 500 (c)
Markownikoff’s rules are valid for only Chlorination of CH4 is free radical mechanism.
asymmetric alkenes. 2-butene is a symmetric 501 (d)
alkene. Unsaturated molecules decolourise Baeyer’s
492 (c) reagent.
This is electrophilic addition of HCN 502 (c)
molecular across C ≡ C in presence of vinyl An alkene on reductive ozonolysis gives 2-
cyanide. molecules of CH2 (CHO)2 . Hence, the alkene is
CH 1, 4-cyclohexadiene.
|||
Ba(CN) 2
CH + HCN → CH2
|| 503 (b)
CHCN C2 H5 I + C3 H7 I + 2Na
Vinyl cyanide Ether
→ C2 H5 C3 H7 ; C4 H10 ; C6 H14
494 (d)
504 (d)
It is a new anti-knocking agent used in place of
Friedel-Craft’s acylation it involves the
tetraethyl lead to control lead pollution by
gasoline in developed countries. treatment of benzene with acetyl chloride or
496 (a) acetic anhydride in presence of anhydrous
Angle strain in cyclopropane is 24°44′ aluminium chloride.
360
θ = [180 − ]
𝑛
360
= [180 − ]
3
= 180 − 120 = 60°
1 505 (b)
Angle strain 𝛼 = [109°28′ − 𝜃]
2 Oxidation of 1-butene first gives a mixture of
1 propionic acid and formic acid. Formic acid,
= [109°28′ − 60°]
2 however, gets further oxidisedto
= 24°44′
CO2 and H2 O. Therefore, option (b) is correct.
497 (a)
507 (b)
When propyne reacts with water in presence
A compound is said to be aromatic if it meets
of HgSO4 and H2 SO4 acetone is formed.
of the following criteria.
Hg2+
CH3 C ≡ CH + H. OH → CH3 − C = CH2 8. The rings of the compound should be
H2 SO4
planer.
|
OH 9. The cyclic system must contain (4𝜋 +
→ CH3 − C − CH2 2)𝜋-electrons.
Ketonisation
||
Only option (b) contains6𝜋-electron, so it is
O
aromatic.
498 (b)
If two different alkyl halides (𝑅1 − 𝑋 and 𝑅2 − 𝑋) 508 (b)
are used, a mixture of three alkanes is obtained B2H6
CH3 CH = CH2 → (CH3 CH2 CH2 )3 B
which are difficult to separate H2 O2
499 (d) → CH3 CH2 CH2 OH + H3 BO3 ;
The process is called hydroboration.
509 (b) 520 (a)
O3 ̅ Cl+ → CH3 − CH − CH2
CH3 CH = CH2 + HO
(i)CH3 − CH = CH − CH3 → Zn
H2 O Propyene hypochlorous | |
CH3 CHO + CH3 CHO + ZnO acid OH Cl
2 molecules of ethanal propene chlorohydrin
O3 521 (b)
(ii)C6 H5 CH = CH2 → Zn
CH ≡ CH + N2 → 2HCN
H2 O
522 (a)
C6 H5 CHO + HCHO + ZnO
The reaction is as follows
benzaldehyde methanol
O3
(iii)CH3 CH = CH2 → Zn CH3 CHO + HCHO
H2 O

Ethanol
methanol
O3
(iv)(CH3 )2 C = C(CH3 )2 → Zn 523 (b)
H2 O
The structure of benzene is
CH3 COCH3 + CH3 COCH3 + ZnO
2 molecules of acetone
511 (c)
Alkynes are not found in free state due to their Bond order
high reactivity. number of bonds
512 (a) =
number of resonating structures
Least hindered rotation means free rotation, 𝑖. 𝑒.,
4
round a single bond. = = 1.33
513 (c) 3
HBr Since, the bond order is in between single and
H2 C = CH2 → CH3 − CH2 Br double bond, thus, it contains delocalised𝜋-
(X) bonds. Hence, it is not possible to obtain
Na2 CO3
Aq.KOH I2 excess number of single and double bonds in
→ CH3 − CH2 OH → CHI3 benzene.
(Y) (Z)
iodoform
515 (b)
In Wurtz reaction, an ether solution of an alkyl
halide is treated with sodium which removes the 524 (d)
halogen of alkyl halide and the two alkyl radicals −NO2 group withdraw electron from the ring
join together to form an alkane shows−𝑀 effect makes ring electron
517 (d) deficient, thus deactivates ring for
An immiscible and lighter substance with water electrophilic substitution.
will float over it.
525 (b)
518 (d)
Reaction of a non-terminal alkyne with a
These all are obtained from coal-tar.
solution of an alkali metal (usually
519 (b)
For 𝑡𝑟𝑎𝑛𝑠product we take Na/liquid NH3 or Li −
Na or Li or K) in liquid ammonia give
NH3 /C2 H5 OH or LiAlH4 as a reducing agnet (𝑎𝑛𝑡𝑖- a𝑡𝑟𝑎𝑛𝑠alkene.
Li⁄liq.NH3
addition) CH3 − C ≡ C − CH3 + 2[H] →
526 (d) 541 (d)
B.p. increases with increase in mol. Wt.
527 (b)
10. Benzene undergoes electrophilic Compound has 8 + 2 = 10𝜋 electrons
substitution in presence of
AlCl3 or FeCl3 or ZnCl2 .
hence is aromatic. has 4𝜋𝑒 − , has
11. Benzene does not undergo addition
reactions like alkene.
8𝜋𝑒 − , while has 8 + 1 = 9𝜋𝑒 − , hence all
H+
∴ C6 H6 + HOCl → no product and (b) is these species are not aromatic
correct answer. 542 (b)
It is a mixture of solid hydrocarbons.
528 (d) 543 (c)
C − Hbond energy is greatest in ethyne due to
the presence of triple bond.
529 (b)
CH3 — CH = CH— CH3is planer molecule due to
𝑠𝑝2 − 𝑠𝑝2-hybridised carbon atoms.
530 (a) This reaction is an example of Diel’s Alder
TEL increases the octane no. of gasoline. reaction
531 (d) 544 (d)
The refining of petroleum is distillation process. All of these can be used in cracking.
532 (b) 545 (b)
It is how Zn-Cu couple is used. General formula of a cycloalkaneis C𝑛 H2𝑛 .
533 (b) 546 (b)
CH3 — C ≡ C— CH3is linear and symmetrical and Toluene reacts with excess of Cl2 in presence
thus, dipole moment is zero. of sunlight, the last product of this reaction is
535 (a) benzotrichloride which on hydrolysis gives
𝑅COONa ⟶ 𝑅— 𝑅 + 2CO2 + 2NaOH + H2
benzoic acid, and it gives sodium benzoate on
537 (b)
reaction with NaOH.
Only terminal alkynes give precipitate with
ammoniacal silver nitrate solution.
Among the given, CH3 − C ≡ CH − CH3 is not
a terminal alkyne. Thus, it does not give
precipitate with ammoniacalAgNO3 .
539 (c)
Benzene vapours mixed with air when passed
over V2 O5 catalyst at 775 K gives maleic
anhydride

548 (d)
CH3 CH2 COOH + NaHCO3
540 (a) ⟶ CH3 CH2 COONa + H2 O + CO2
2CH3 CH2 CH2 COONa → 549 (a)
Anode Cathode 5
⏞
C2 H2 + O2 ⟶ 2CO2 + H2 O; 1 mole or 1 vol. of
CH3 CH2 CH2CH2 CH2 CH3 +2CO2 ⏞
+2NaOH+H2 2
C2 H2 requires 2.5 mole or 2.5 vol. of O2 .
550 (a) compounds.
Conjugate dienesare mores stable than the other O3
CH3 CH = CH2 → CH3 CHO + HCHO
dienes. H2 O 2
551 (c) Acetaldehyde formaldehyde
Branched chain alkanes give rise to increase on 560 (a)
octane no. Petrol or gasoline contains mainly C6 to C11 atoms
552 (d) liquid alkanes.
Follow Markownikoff’s rule. 562 (d)
553 (b) L.P.G. mainly contains butane and isobutane.
HOCl has Cl+ and OH − ions 564 (a)

[O]
CH2 = CH2 → 2HCOOH
565 (a)
554 (b) According to Markownikoff’s rule, the
negative part of the reagent gets attached to
that double bonded carbon atom which has
least number of H-atoms. Thus,
HBr
Zn − H2 Ois the reagent for reductive work up CH3 = CH − CH3 → CH3 − CH − CH3
of ozonide. H2 O2 − CH3 COOHwould give |
HOOC − (CH2 )4 − COOH. Br
555 (d) 569 (b)
The 𝜋-bond is unshared in electromeric effect to Gasoline contains alkanes from C6 to C11 carbon
give+ve and –vecentres on molecule. atom.
570 (d)
We know that,
556 (d)
Al4 C3 + 12H2 O → 4Al(OH)3 + 3CH4
Thus, in this reaction methane (CH4 ) is
produced.
Tropyliumcation is planar and have 571 (d)
6𝜋-electron according to Huckel rule, hence it Follow Saytzeff rule of elimination.
is aromatic. 573 (b)
Impurities of PH3 give garlic smell to C2 H2 .
574 (d)
In the formation of an alkane from Grignard
Cyclopentadienyl anion is planar and
reagent, alkyl group always comes from
have 6𝜋-electron, hence it is also aromatic
Grignard reagent. Hence, the number of
compound.
557 (a) carbon atoms in the Grignard reagent and
Follow peroxide effect. alkane formed Grignard reagent will be
558 (a) identical. So, the original alkyl halide is propyl
In the laboratory, nitrobenzene is prepared by bromide.
nitration of benzene with the mixture of nitric 575 (c)
acid and sulphuric acid at temperature
below60℃. In which HNO3 acts as a base
559 (d) CH2 = C(OH)CH3 ⇌ CH3 COCH3;
The reaction is ozonolysis. During the The mechanism involves tautomerism.
reaction C = C breaks to give carbonyl 576 (d)
 7 C4 H6 may contains either two double bond or
C2 H6 + O2 ⟶ 2CO2 + 3H2 O
2 triple bond
577 (c) CH2 = CH − CH = CH2 orCH3 − CH2 − C ≡ CH
HBr HBr
CH ≡ CH → CHBr = CH2 → 590 (b)
KOH(alc.) NaNH2 Due to acidic—H-atom propyne forms CH3 — C ≡
CHBr2 — CH3 → CHBr = CH2 → CH ≡ CH
CNa with Na.
578 (d)
591 (b)
According to Markownikoff’s rule the
More is b.p. lesser is volatile nature.
addition of a reagent (HX) to an 592 (d)
unsymmetrical alkene takes place in such a These all are used to increase octane number of
way that the negative part of the reagent will fuel.
be attached to that carbon atom which 594 (a)
contains lesser number of H-atom. CH2 = C = CH2;
Br 𝑠𝑝2 𝑠𝑝𝑠𝑝2
| 600 (b)
CH3 − C = CH2 + HBr → CH3 − C − CH3 Benzene undergoes electrophilic substitution
| | reaction. It is nitrated by HNO3 .
CH3 CH3
2-methylpropene
579 (b)
Follow text.
602 (b)
580 (a)
Markownikoff’s rule is for addition of
Br2 solution is decolourized by alkene or alkyne or
unsymmetrical additive on unsymmetrical alkene.
molecules having unsaturation.
603 (d)
581 (c)
Paraffin wax are solid hydrocarbons from C20 to
Eqs. (i) and (ii) drawings are Sawhorse and
C30 atoms.
Newman projections respectively for staggered
605 (d)
forms.
Methane is called marsh gas because it is
582 (a)
found in swamps or marshy places and can be
C2 H2 gives white ppt. with amm. AgNO3 .
583 (b) obtained by bacterial decomposition of fossils
Oxidation NaOH of plants and animals.
C6 H5 CH3 → C6 H5 . COOH → 606 (b)
(𝐴) Among hydrocarbons, alkynes are easily oxidised.
Soda lime
(NaOH+CaO) 607 (d)
C6 H5 COONa → C6 H6 + CO2 ↑ B.P. change with branching.
(𝐵) 608 (f)
585 (c) These are few oxidants.
Cyclobutadiene have (4π) conjugated or 609 (a)
delocalized electrons, thus it is 𝑎𝑛𝑡𝑖-aromatic The acidic character of H is,
586 (a) F— H > 𝑂— 𝐻 >≡ C — H > 𝑁— 𝐻; H-atom
sp
HOCl
CH ≡ CH → Cl2 CHCHO attached on F, O, N and triply bonded carbon is
587 (c) acidic.
Thioalcohol (mercaptons) have unpleasant odour; 610 (b)
C2 H5 SH is commonly used. H2 /Pd
CH3 CH2 CH = CH2 → CH3 CH2 CH2 CH3 .
588 (c)
611 (c)
Octane no. of triptane or 2,3,3-
Except acetylene, all terminal alkynes have only
trimethylbutane=124; octane no. of 𝑛-
one acidic H-atom.
nonane=−45.
613 (d)
589 (d)
 Alc.KOH Amm.Cu2 Cl2
C3 H6 Cl2 → CH3 C ≡ CH → CH3 C
≡ CCu ↓
red
These compounds are known as epoxy ethane or
oxirane or cyclic ethers. ppt.
614 (b) Compound (𝑋) gives an aldehyde when reacts
According to X-ray analysis all carbon-carbon with aqueous KOH. This suggests that both
bond distance (1.397Å) are equal in benzene. the halogens are present on same terminal
The bond order of carbon-carbon bond is 1.5 carbon atom. Thus, the formula of compound
in benzene. (𝑋) is
Hence, carbon-carbon bond distance
(1.397Å) is less than C − C single bond
(1.54Å) and more than C = C double and the reactions are as
bond(1.33Å). follows
615 (c)
Cracking involves decomposition of higher
alkanes to lower one on heating.
616 (a) Ammoniacal
CH3 C ≡ CH → CH3 C ≡ CCu ↓
Follow mechanism of Wurtz reaction. Cu2 Cl2

617 (c) red ppt.

CH4is a constituent of bio-gas.
620 (a)
The lowest temperature at which an oil gives
sufficient vapours to form an explosive mixture
with air is referred as flash point. It is 44C, 35C,
22.8C in India, France and England, respectively.
621 (a)
Lindlar’s catalyst is Pd − CaCO3 deactivated by 629 (a)
lead acetate. Cram 𝑒𝑡. 𝑎𝑙 gave a better catalyst for
this purpose as Pd − BaSO4 poisoned by
quinolene. This too is sometimes referred as Removal of H2 O is called dehydration.
Lindlar’s catalyst. 630 (d)
622 (b) Both vegetable and animal matter are origin of
Remember this value. petroleum.
623 (a) 631 (d)
The aldehydes formed are oxidized by All are used in drying alkanes.
H2 O2 formed during hydrolysis. 632 (b)
625 (c) The stability order is:
The acidic nature is H2 O > C2 H2 > 𝑁H3; thus, Staggered>skew>eclipsed
conjugate base order will be OH − > C2 H − > NH2− . 633 (d)
628 (d) Cyclic hydrocarbon, with carbon-carbon bond
‘𝑋’ is a three carbon compound with two length between1.34Å and 1.54Å, is benzene in
halogen atom, so its molecular formula is which due to resonance, C − C, bond length is
C3 H6 Cl2 . Only terminal alkynes give red ppt. 1.39Å (𝑖𝑒.,between 1.34Å − 1.54Å). Benzene
with ammoniacal Cu2 Cl2 , so the hydrocarbon is a hexagonal molecule with bond-angle
produced by the reaction of ‘𝑋’ with alc. KOH, equal to120°.
must be a terminal alkyne (𝑖. 𝑒. , CH3 C ≡ CH). 634 (c)
The reaction proceeds via carbocation
mechanism.
 Benzophenone (diphenylketone) can be prepared
by the Friedel-Crafts’ condensation between
benzoyl chloride and benzene
AlCl3
C6 H6 + C6 H5 COCl → C6 H5 COC6 H5 + HCl(80%)
641 (a)
Aromatic compounds have delocalised𝜋-
electrons.
Out of given choices cyclohexane, CH4 , C2 H6
635 (c)
Copper and silver alkylides are obtained by and benzene, only benzene is aromatic
passing to alkynes in the ammoniacal solution compound. Benzene has six delocalised𝜋-
of cuprous chloride and silver nitrate electrons.
642 (c)
respectively. These reactions are used for
Trivial name is allyl.
detecting the presence of acetylenic hydrogen
643 (d)
atom. These are all facts.
644 (a)
The reactivity order for sulphonation of H-atom in
alkane :
3>2>1.
645 (a)
So, alkanes and alkenes remain unaffected. As the – CH3 group increases boiling point
636 (b) decrease
Benzene reacts with chlorine in presence of 647 (b)
sunlight to give gammexane or benzene hexa Alcoholic KOH is a dehydrohalogenating
chloride. reagent, so when 𝑛-propyl bromide is treated
with alcoholic KOH, propene is obtained.
Sunlight
C6 H6 + 3Cl2 → C6 H6 Cl6 CH3 CH2 CH2 Br + alc KOH
𝑛-propyl bromide
637 (a) → CH3 CH = CH2 + HBr
Hydrogenation in presence of Pd and BaSO4 propene
as 𝑠𝑦𝑛 addition and with Na and liquid NH3 at 648 (b)
200 K is anti addition (𝑡𝑟𝑎𝑛𝑠 compounds are Knowing the number and arrangement of carbon
formed.) atoms in aldehydes and ketones the structure of
the original alkene can be worked out.

638 (c)
In benzene all the six carbon atoms are 𝑠𝑝2
hybridised. Out of these three 𝑠𝑝2 hybrid
orbitals of each C-atom, two orbitals overlap
with 𝑠𝑝2 hybrid orbitals of adjacent C-atoms 649 (a)
A method used during II world war.
to form six C − C single bonds. The remaining
650 (d)
𝑠𝑝2 orbital of each C-atom overlaps with 𝑠-
Ozonolysis of these two produces different
orbitals of each H-atom to form six C − H products.
single sigma bonds. Each C-atom is now left 652 (c)
with one unhybridised𝑝-orbital For simplest alkyne 𝑛=2; thus, alkyne is
perpendicular to the plane of the ring. C𝑛 H2𝑛−2 or C2 H2.
640 (b)
654 (d)
Alkene is CH3 CH = CHCH3, a symmetrical alkene and therefore alcohol is,

655 (b)
Cyclodecapentaene and Cyclooctatetraene both
are nonaromatic. Cyclobutadiene is antiaromatic
while benzene having 6𝜋-electrons is aromatic
656 (d)
CH3 CH2 CH2 CH2 CH2 CH3 ;
(CH3 )2 CHCH2 CH2 CH3 ;
CH3 CH2 CH(CH3 )CH2 CH3;
(CH3 )3 CCH2 CH3 ; (CH3 )2 CHCH(CH3 )2
657 (f)
These are facts about alkanes.
658 (c)
Due to resonance, benzene is quite stable and
inspite of three double bonds does not ∴ C2 H4 (an alkene) reacts with KMnO4 and
decolouriseBr2 water.
decolourises it and does not react with
659 (c)
AgNO3 , C2 H6 and CH4 are alkane they do not
Follow peroxide effect.
react with KMnO4 and NaOH.
660 (d)
663 (c)
The reaction is Wurtz’s type reaction.
It has maximum octane no.
664 (c)
Pure C2 H2 has ethereal odour.
666 (a)
661 (a) Alkylated alkenes are more stable. More the
Alkynes give different products with alkylation of alkene, more will be its stability.
different reducing agents 𝑒. 𝑔., with Lindlar’s ∴ Order of stability of alkenes is
catalyst (Pd⁄BaSO4 )or Ni 𝑐𝑖𝑠-alkene is 𝑅2 C = C𝑅2 > 𝑅2 C = CH𝑅 > 𝑅2 C = CH2
formed but with Na in liquid NH3 (Birch > 𝑅CH = CH2 > 𝐶H2 = CH2
reduction) 𝑡𝑟𝑎𝑛𝑠 alkene is formed. ∴ Tetra alkylated alkene is most stable.
668 (d)
CH2 = CH − O − CH3
HBr
→ CH3 − CH − O − CH3
|
Br
First protonation occurs, two possible
662 (c) intermediates are
(i)Alkene and alkynes both react with KMnO4
and decolourise it.
(ii)Only alkynes react with AgNO3 to give
white precipitate.
 II, is more favourable. Hence, Br − attacks, and
product is
CH3 − CH − O − CH3
|
Br 678 (c)
An alkyne has higher b.p. than corresponding
670 (b)
alkene and an alkene has higher b.p. than
Halogenation of benzene in cold and dark is
corresponding alkane.
carried by electrophilic substitution. In this
681 (d)
reaction, Cl+ electrophile takes part in the
On ozonolysis,
reaction.
CH3
|
CH2 = C = C − CH = CH2 gives two moles of
HCHO, one mole of CO2 one mole of
CH3 COCHO.
AlCl3 + Cl − Cl ⟶ Cl+ + AlCl−
4 CH3
electrophile |
671 (a) O3 ⁄H2 O
CH2 = C = C − CH = CH2 →
Since the alkadiene on reductive ozonolysis Zn

gives acetaldehyde (CH3 CHO), acetone 2CH2 O + CO2 + CH3 COCHO

(CH3 COCH3 ) and 2-methylpropane-1, 3-dial (HCHO)
[OHCCH(CH3 )CHO], the structure of 682 (c)
KOH alc.
alkadiene will be obtained as CH3 CH2 Cl → CH2 = CH2
683 (c)
3𝑛 + 1
C𝑛 H2𝑛+2 + ( ) O2 ⟶ 𝑛CO2 + (𝑛 + 1)H2 O
2
685 (b)
Cycloalkanes are isomeric with alkenes
because they have same general formula
C𝑛 H2𝑛 (𝑖. 𝑒., same molecular formula) but
possessing different structures. They show
ring chain isomerism.
672 (b)
686 (b)
These are Fischer-Tropsch and Berzius method
for synthesis of petrol.
673 (c)
It is an unsaturated two carbon atom molecule
(gives catalytic hydrogenation) but not acetylene
is symmetrical alkane and will give only one
(does not give white ppt. with amm. AgNO3 ).
monochloro substitution.
Thus, it is ethylene.
688 (d)
674 (c)
𝑅𝑋
Rest all are used to convert>CO gp. to CH2.
CH ≡ CH + Na ⟶ CH ≡ CNa → CH ≡ C𝑅 689 (d)
𝑅𝑋
CH = CH + 𝑅Mg𝑋 ⟶ CH = CMg𝑋 → CH = C𝑅 The presence of the chlorine atom on benzene
675 (b) ring makes the second substituent enter at
Addition of HBr first takes place round double 𝑜𝑟𝑡ℎ𝑜 or 𝑝𝑎𝑟𝑎 position because the chlorine
bond. atom is 𝑜𝑟𝑡ℎ𝑜 − 𝑝𝑎𝑟𝑎 directing.
677 (a) 690 (a)
CaC2 + 2H2 O → C2 H2 + Ca(OH)2 12 1
Given, C = (13) × 100%, H = (13) × 100%
 ∴ C = 92.3% H = 7.69%
92.3 7.69
C= = 7.69 = =1
12 7.69 Ether
7.69 7.69 → CH3 − CH = CH − CH3 + 4NaBr
∆
H= = 7.69 = =1 2-butene
1 7.69
∴ Empirical formula of hydrocarbon is C1 H1 = 699 (d)
CH Octane number is a measure of quality of fuel.
∴A has empirical formula CH and 700 (d)
decolourises bromine water. All possible products are obtained; C2 H6 by
CH3 COO−; C4 H10 by CH3 CH2 COO− and
∴ It is alkyne which is C2 H2 .
CH3 CH2 CH3 by CH3 COO− and CH3 CH2 COO−.
∴B has empirical formula CH and does not
701 (b)
decolourise bromine water.
Wurtz reaction is used to prepare alkanes
∴ It is benzene C6 H6 .
from alkyl halides.
691 (c) Dry ether
Due to acidic nature of the hydrogen atoms 2𝑅 − 𝑋 + 2Na → 𝑅 − 𝑅 + 2Na𝑋
attached to a triple bond, acetylenes and terminal 702 (b)
Zn dust
alkynes from metal acetylides CH2 Br— CH2 Br → CH2 = CH2
CH3 CH2 C ≡ CH + AgNO3 + NH4 OH → CH3 CH2 C 703 (a)
≡ CAg + NH4 NO3 + H2 O A group that causes attack to occur chiefly at
silver
positions 𝑜𝑟𝑡ℎ𝑜 and 𝑝𝑎𝑟𝑎 to it, is called an
butynide
𝑜𝑟𝑡ℎ𝑜 − 𝑝𝑎𝑟𝑎 director, 𝑒. 𝑔. , NH2 , OH, Cl etc.
693 (b)
704 (c)
Cetane no. represent percentage of 𝑛-hexadecane
NH3 is base, 𝑖. 𝑒., least acidic.
in mixture.
705 (c)
694 (c)
This is Wurtz reaction.
Conjugated alkadienes show 1 : 2 and 1 : 4
706 (c)
addition. HBr
695 (d) CH3 CH2 CH = CH2 → CH3 CH2 CH2 CH2 Br
C2H5 ONa
Na/C2 H5 OH, LiAlH4 or NaBH4 are used for this → CH3 CH2 CH2 CH2 OCH2 CH3
purpose. 707 (c)
696 (c) 1,1-dibromocyclooctane possess lesser strain.
This is also a mean of preparing alkene where 710 (d)
the position of the double bond is definite. In ___do____
Wittig reaction, aldehyde(−CHO) and ketone 712 (c)
(> C = O) react with methylene tryphenyl According to Markownikoff’s rule, the
phosphine [(C6 H5 )3 P = CH2 ] to give alkene. addition of a unsymmetrical reagent (HX) to
CH3 CHO + (C6 H5 )3 P = CH2 an unsymmetricalkene takes place in such a
→ CH3 − CH = CH2 + (C6 H5 )3 P = O way that the negative part of the reagent will
Propane triphenylphosphine be attached to the carbon atom which
oxide containing lesser number of H-atom. Hence, it
is best applicable to the reaction between
C3 H6 and HBr.
CH3 CH = CH2 + HBr → CH3 − CH − CH3
|
Br
713 (b)
697 (c) The addition of propene to HBr opposes the
Markownikoff’s rulein presence of organic
 peroxide.
Organic
CH3 CH = CH2 + HBr → CH3 CH2 CH2 Br
peroxide
𝑛-propyl bromide
It is also called the Kharash effect or 𝑎𝑛𝑡𝑖-
Markownikoff’s rule.
715 (d)
In presence of sunlight toluene undergoes
aliphatic substitution with chlorine and give
benzyl chloride, benzal chloride and
benzotrichloride.
716 (c)
[O]
𝑅CH3 → 𝑅COOH
717 (d)
Uses of ethene.
1) a 2) c 3) a 4) d 193) b 194) c 195) b 196) a
5) b 6) c 7) d 8) c 197) a 198) c 199) d 200) d
9) d 10) c 11) a 12) a 201) b 202) d 203) a 204) b
13) b 14) b 15) a 16) b 205) c 206) a 207) b 208) b
17) d 18) b 19) b 20) d 209) a 210) d 211) d 212) a
21) a 22) d 23) a 24) a 213) c 214) b 215) a 216) c
25) b 26) a 27) b 28) c 217) a 218) c 219) a 220) b
29) c 30) a 31) c 32) c 221) c 222) c 223) b 224) c
33) a 34) a 35) d 36) d 225) b 226) c 227) b 228) b
37) d 38) d 39) c 40) c 229) a 230) b 231) d 232) b
41) a 42) b 43) b 44) a 233) c 234) a 235) b 236) a
45) d 46) b 47) d 48) a 237) b 238) c 239) d 240) d
49) c 50) b 51) b 52) b 241) a 242) b 243) a 244) c
53) a 54) b 55) b 56) a 245) a 246) d 247) d 248) d
57) c 58) a 59) c 60) a 249) a 250) a 251) d 252) d
61) d 62) a 63) d 64) a 253) c 254) a 255) a 256) a
65) b 66) a 67) f 68) d 257) b 258) b 259) d 260) a
69) c 70) d 71) c 72) d 261) b 262) a 263) b 264) a
73) d 74) b 75) c 76) b 265) b 266) c 267) d 268) b
77) d 78) c 79) d 80) a 269) b 270) a 271) d 272) b
81) d 82) d 83) c 84) b 273) d 274) b 275) b 276) c
85) a 86) c 87) b 88) c 277) d 278) d 279) a 280) b
89) c 90) c 91) b 92) b 281) b 282) b 283) b 284) d
93) a 94) c 95) c 96) b 285) d 286) d 287) b 288) a
97) c 98) c 99) c 100) a 289) a 290) b 291) d 292) c
101) d 102) d 103) c 104) a 293) a 294) c 295) a 296) c
105) a 106) c 107) d 108) c 297) c 298) b 299) a 300) c
109) c 110) c 111) d 112) b 301) c 302) a 303) d 304) d
113) a 114) a 115) b 116) c 305) a 306) a 307) b 308) a
117) b 118) b 119) b 120) b 309) d 310) b 311) b 312) c
121) b 122) d 123) c 124) a 313) c 314) c 315) a 316) d
125) a 126) c 127) c 128) a 317) c 318) b 319) d 320) a
129) a 130) d 131) c 132) d 321) a 322) a 323) b 324) b
133) c 134) b 135) b 136) b 325) a 326) c 327) d 328) b
137) a 138) b 139) b 140) d 329) b 330) d 331) a 332) c
141) b 142) b 143) c 144) a 333) b 334) d 335) b 336) a
145) d 146) a 147) c 148) b 337) d 338) b 339) d 340) b
149) a 150) a 151) b 152) a 341) b 342) b 343) a 344) a
153) b 154) c 155) c 156) d 345) d 346) c 347) a 348) a
157) d 158) a 159) a 160) c 349) c 350) a 351) c 352) b
161) b 162) a 163) c 164) c 353) b 354) c 355) a 356) b
165) c 166) c 167) c 168) c 357) c 358) d 359) d 360) c
169) b 170) a 171) d 172) a 361) c 362) b 363) a 364) d
173) b 174) d 175) a 176) a 365) a 366) a 367) c 368) a
177) b 178) c 179) d 180) d 369) b 370) d 371) a 372) d
181) b 182) a 183) b 184) b 373) c 374) c 375) c 376) b
185) c 186) b 187) b 188) b 377) a 378) c 379) d 380) d
189) d 190) b 191) b 192) a 381) b 382) b 383) d 384) b
385) d 386) c 387) a 388) b 589) d 590) b 591) b 592) d
389) a 390) a 391) a 392) a 593) a 594) a 595) c 596) c
393) c 394) b 395) c 396) d 597) d 598) a 599) d 600) b
397) a 398) c 399) b 400) a 601) a 602) b 603) d 604) d
401) b 402) d 403) a 404) a 605) d 606) b 607) d 608) f
405) d 406) c 407) c 408) d 609) a 610) b 611) c 612) c
409) b 410) d 411) b 412) a 613) d 614) b 615) c 616) a
413) c 414) d 415) b 416) c 617) c 618) c 619) a 620) a
417) b 418) d 419) c 420) c 621) a 622) b 623) a 624) c
421) c 422) b 423) c 424) b 625) c 626) c 627) b 628) d
425) a 426) d 427) d 428) a 629) a 630) d 631) d 632) b
429) a 430) c 431) a 432) c 633) d 634) c 635) c 636) b
433) b 434) b 435) c 436) a 637) a 638) c 639) c 640) b
437) a 438) c 439) a 440) d 641) a 642) c 643) d 644) a
441) c 442) a 443) d 444) c 645) a 646) c 647) b 648) b
445) a 446) b 447) a 448) b 649) a 650) d 651) b 652) c
449) b 450) a 451) d 452) b 653) c 654) d 655) b 656) d
453) d 454) d 455) b 456) c 657) f 658) c 659) c 660) d
457) c 458) d 459) a 460) b 661) a 662) c 663) c 664) c
461) c 462) a 463) c 464) b 665) c 666) a 667) b 668) d
465) c 466) d 467) d 468) c 669) b 670) b 671) a 672) b
469) b 470) c 471) b 472) c 673) c 674) c 675) b 676) d
473) d 474) c 475) d 476) c 677) a 678) c 679) b 680) c
477) a 478) b 479) a 480) a 681) d 682) c 683) c 684) b
481) c 482) b 483) c 484) b 685) b 686) b 687) a 688) d
485) b 486) b 487) b 488) a 689) d 690) a 691) c 692) b
489) c 490) a 491) a 492) c 693) b 694) c 695) d 696) c
493) d 494) d 495) d 496) a 697) c 698) b 699) d 700) d
497) a 498) b 499) d 500) c 701) b 702) b 703) a 704) c
501) d 502) c 503) b 504) d 705) c 706) c 707) c 708) b
505) b 506) a 507) b 508) b 709) d 710) d 711) c 712) c
509) b 510) c 511) c 512) a 713) b 714) a 715) d 716) c
513) c 514) d 515) b 516) b 717) d
517) d 518) d 519) b 520) a
521) b 522) a 523) b 524) d
525) b 526) d 527) b 528) d
529) b 530) a 531) d 532) b
533) b 534) a 535) a 536) b
537) b 538) c 539) c 540) a
541) d 542) b 543) c 544) d
545) b 546) b 547) d 548) d
549) a 550) a 551) c 552) d
553) b 554) b 555) d 556) d
557) a 558) a 559) d 560) a
561) b 562) d 563) c 564) a
565) a 566) c 567) d 568) a
569) b 570) d 571) d 572) b
573) b 574) d 575) c 576) d
577) c 578) d 579) b 580) a
581) c 582) a 583) b 584) b
585) c 586) a 587) c 588) c
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Class 12 (Com) Class 12 (Hum)

 ARTHAM
ARTHAM
R E S O U R C E M AT E R I A L
SOE
R E S O U R C E M AT E R I A L
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COMPETENCY-BASED
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Coverage
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Structured Explanations Aligned Exam Focus Questions and answers are
SOE Clear, well-structured Questions modeled after Specially designed to help based on the NCERT syllabus,
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ARTHAM
R E S O U R C E M AT E R I A L
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